• 제목/요약/키워드: Organic fibers

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Removal of volatile organic compounds from air using activated carbon impregnated cellulose acetate electrospun mats

  • Patil, Kashyap;Jeong, Seonju;Lim, Hankwon;Byun, Hun-Soo;Han, Sangil
    • Environmental Engineering Research
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    • v.24 no.4
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    • pp.600-607
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    • 2019
  • Volatile organic compounds (VOCs) are released from various sources and are unsafe for human health. Porous materials are promising candidates for the adsorption of VOCs owing to their increased ratio of surface area to volume. In this study, activated carbon (AC) impregnated cellulose acetate (CA) electrospun mats were synthesized using electrospinning for the removal of VOCs from the air mixture of ACs, and CA solution was electrospun at different proportions (5%, 10%, and 15%) in a single nozzle system. The different AC amounts in the electrospun mats were distributed within the AC fibers. The adsorption capacities were measured for acetone, benzene, and dichloromethane, using quartz crystal microbalance. The results elicited an increasing adsorption capacity trend as a function of the impregnation of ACs in the electrospun mats, while their capacities increased as a function of the AC concentration. Dichloromethane resulted in a faster adsorption process than acetone and benzene owing to its smaller molecular size. VOCs were desorbed with the N2 gas purging, while VOCs were adsorbed at higher temperatures owing to the increased vapor pressures. The adsorption analysis using Dubinin-Astakhov equation showed that dichloromethane is more strongly adsorbed on mats.

Mechanical Behaviors and Characterization of Electrospun Polysulfone/Polyurethane Blend Nonwovens

  • Cha Dong-Il;Kim Kwan-Woo;Chu Gong-Hee;Kim Hak-Yong;Lee Keun-Hyung;Bhattarai Narayan
    • Macromolecular Research
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    • v.14 no.3
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    • pp.331-337
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    • 2006
  • In the present study we investigated the relationship between the morphology and mechanical properties of electrospun polysulfone (PSF)/polyurethane (PU) blend nonwovens, by using the electrospinning process to prepare three types of electrospun nonwovens: PSF, PU and PSF/PU blends. The viscosity, conductivity and surface tension of the polymer solutions, were measured by rheometer, electrical conductivity meter and tensiometer, respectively. The electrospun PSF/PU blend nonwovens were characterized by scanning electron microscopy (SEM) and with a universal testing machine. The SEM results revealed that the electrospun PSF nonwoven had a structure consisting of cross-bonding between fibers, whereas the electrospun PU nonwoven showed a typical, point-bonding structure. In the electrospun PSF/PU blend nonwovens, the exact nature of the point-bonding structure depended on the PU contents. The mechanical properties of the electrospun PSF/PU blend nonwoven were affected by the structure or the morphology. With increasing PU content, the mechanical behaviors, such as Young's modulus, yield stress, tensile strength and strain, of the electrospun PSF/PU blend nonwovens were by up to 80%.

Mechanical and Thermal Properties of Industrial Protective Fabric with Recycled m-Aramid and Natural Fiber

  • Sung, Eun Ji;Baek, Young Mee;An, Seung Kook
    • Textile Coloration and Finishing
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    • v.30 no.4
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    • pp.227-236
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    • 2018
  • As consciousness of safety becomes an important social issue, the demand for protective clothing is increasing. Conventional flame-retardant cotton working wear has low durability, and working wear with m-aramid fibers are stiff, heavy, less permeable, and expensive. In this study, recycled m-aramid and cotton have been blended to produce woven fabric of different compositions to enhance high performance and comfort to solve aforementioned problems. The fabrics were analyzed according to constituents and various structural factors. Mechanical properties were measured using KES-FB system. The measured thermal properties are TGA, $Q_{max}$, TPP and RPP. Fabric with polyurethane yarn covered by m-aramid/cotton spun yarn is observed to have good wearability. The fabric of open end spun yarn showed more stiffness than that of ring spun yarn. The sample with the high count of yarn has more smooth surface. In addition, high m-aramid content fabric is considered to have relatively high stiffness when using as clothing. In TGA the fabric with higher m-aramid content showed more stable decomposition behavior. The fabric having rough surface showed lower heat transfer properties in $Q_{max}$. The influence of the fabric thickness was important in convection and radiant heat test.

Development of Filtration Filter Using of Wood and Non-Wood Fiber (목재 및 비목재 화이버를 이용한 여과필터 개발)

  • Cho, Jun Hyung;Choi, Yun Sung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.3
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    • pp.87-91
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    • 2010
  • Wood and non-wood material is widely used as a medium for filtration. It is a relatively low cost material and because of its construction, can be used to filter small particles(${\sim}5{\mu}m$). This fiber filter is concerned with characterizing some of the physical properties of wood & non-wood materials particularly relating to filtration of particles from dilute suspensions. In addition, they are nonuniform and tortuous as a result of the formation and variations in individual fibers.

A Study on the Liquid-Liquid Extraction by Use of Hydrophobic Hollow Fiber Module (소수성 중공사 모듈에 의한 액-액 추출에 관한 연구)

  • Kim, Young-II;Park, Dong-Won
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.237-244
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    • 1996
  • Liquid-liquid extractions by use of microporous hollow fiber modules are fast compared with conventional extraction equipment because of the large surface area per volume. In these modules, the extractant and feed can be contacted at high speed and two flows are completely independent, so there are no problems with loading and channeling. In this paper, it was investigated the extraction selectivities for liquid-liquid extraction of Fe(II) and Ni(II) from dilute aqueous solution into TOA (tri-n-octylamine) and EHPNA (bis(2-ethylhexyle)hydrogenphosphite) as organic extractants by using the hydrophobic hollow fiber module. To determine the rate controlling step for mass transfer in hollow fibers, we also examined the effect of inside and outside flow rates of the hollow fiber module. From these experiments, we identified for the extraction of system with high partition coefficient in hydrophobic hollow fibers, mass transfer in the inside aqueous feed dominated the overall mass transfer, and in this paper, correlation between $K_w$ and $v_t$ was obtained as $K_w{\frac{d}{D}}=6.22\(\frac{d^2v_t}{LD}\)^{1/3}$ On the other hand, for the system with low partition coefficient, the resistance in the inside of hollow fibers was much less than membrane resistance because the extraction was not simple in the micropore. Thus, for systems with high partition coefficients, hydrophobic hollow fibers would be a better choice.

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Engineering Properties of HPFRCC Including Both Organic and Inoranic Fibers (유·무기 섬유를 복합사용한 HPFRCC의 공학적 특성)

  • Lee, Jong Tae;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.6
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    • pp.615-620
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    • 2015
  • The high performance fiber reinforced cementitious composite (HPFRCC) controls the cracking development of the structure by inducing micro-cracking and strain hardening behavior after the initial cracking under the tensile conditions. Although, in Korea, the research about manufacturing the single-fiber reinforced cementitious composite or the mechanical properties of hardened status has been conducted, the research to apply the HPFRCC with multi-fiber is not sufficient. Hence, in this research, considering the workability and economic aspect for practical applications, the engineering properties of HPFRCC with combined long steel fiber (SL) and long organic fiber (OL) are evaluated such as workability and strength. As a result of evaluating the engineering properties of HPFRCC, the most favorable performance was obtained when the mixture contained 1.5% of combined SL and OL.

A Molecular Dynamics Simulation on the Self-assembly of ABC Triblok Copolymers. 2. Effects of Block Sequence

  • Jo, Won-Ho;Ko, Min-Jae;Kim, Seung-Hyun
    • Fibers and Polymers
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    • v.3 no.1
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    • pp.8-13
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    • 2002
  • The effect of block sequence on the self-assembly of ABC-type triblock copolymers in the ordered state is investigated using an isothermal-isobaric molecular dynamics simulation. The block sequence has an important effect ,on the ]norphology of ABC triblock copolymers. Different morphologies are observed depending on the block sequence as well as the block composition. The triblock copolymers with the volume fraction of 1 : 1 : 1 ($f_A$=$f_B$=$f_C$= 0.33) show the three phase and four layered lamellar structures irrespective of the block sequence. The $A_{32}$$B_{16}$$C_{32}$triblock copolymer with $f_B$=0.2 shows a morphology In which cylinders of midblock B are formed at the interface between A and C lamellae, whereas the morphology of triblock copolymer $B_{16}$$C_{32}$ $A_{32}$ and $C_{32}$ $A_{32}$ $B_{16}$ show a cylindrical core-shell structure and a lamellar type morphology, respectively. The $A_{20}$$B_{40}$$C_{20}$the triblock copolymer with the block B as a major component shows a tricontinuous structure, whereas both $B_{40}$$C_{20}$$A_{20}$ and $C_{20}$$A_{20}$$B_{40}$ triblock coolymers exhibit the lamellar structures. When the block B has larger volrome fraction with $f_B$=0.75, the matrix is composed of block B, and other two blocks A and C form spherical domains.

Evaluation of Impact Resistance of Steel Fiber and Organic Fiber Reinforced Concrete and Mortar

  • Kim, Gyu-Yong;Hwang, Heon-Kyu;Nam, Jeong-Soo;Kim, Hong-Seop;Park, Jong-Ho;Kim, Jeong-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.4
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    • pp.377-385
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    • 2012
  • In this study, the Impact resistance of steel fiber and organic fiber reinforced concrete and mortar was evaluated and the improvement in toughness resulting from an increase in compressive strength and mixing fiber for impact resistance on performance was examined. The types of fiber were steel fiber, PP and PVA, and these were mixed in at 0.1, 0.5 and 1.0 vol.%, respectively. Impact resistance is evaluated with an apparatus for testing impact resistance performance by high-speed projectile crash by gas-pressure. For the experimental conditions, Specimen size was $100{\times}100{\times}20$, 30mm ($width{\times}height{\times}thickness$). Projectile diameter was 7 and 10 mm and impact speed is 350m/s. After impact test, destruction grade, penetration depth, spalling thickness and crater area were evaluated. Through this evaluation, it was found that as compressive strength is increased, penetration is suppressed. In addition, as the mixing ratio of fiber is increased, the spalling thickness and crater area are suppressed. Organic fibers have lower density than the steel fiber, and population number per unit area is bigger. As a result, the improvement of impact resistance is more significant thanks to dispersion and degraded attachment performance.

Evaluation of Mechanical Property of Carbon Fiber/Polypropylene Composite According to Carbon Fiber Surface Treatment (탄소섬유 표면처리에 따른 탄소섬유/폴리프로필렌 복합재료의 기계적 물성 평가)

  • Han, Song Hee;Oh, Hyun Ju;Kim, Seong Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.6
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    • pp.791-796
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    • 2013
  • In this study, the mechanical properties of a carbon fiber/polypropylene composite were evaluated according to the carbon fiber surface treatment. Carbon fiber surface treatments such as silane coupling agents and plasma treatment were performed to enhance the interfacial strength between carbon fibers and polypropylene. The treated carbon fiber surface was characterized by XPS, SEM, and single-filament tensile test. The interlaminar shear strength (ILSS) of the composite with respect to the surface treatment was determined by a short beam shear test. The test results showed that the ILSS of the plasma-treated specimen increased with the treatment time. The ILSS of the specimen treated with a silane coupling agent after plasma treatment increased by 48.7% compared to that of the untreated specimen.

Dyeing Characteristics and Mechanical Properties of High Tenacity Polyethylene(HTPE) Filament using Solvent Dyes (솔벤트 염료를 이용한 고강도 폴리에틸렌(HTPE) 필라멘트사의 염색성 및 기계적 물성 평가)

  • Lee, Jeong Hoon;Lee, Beom Young;Lee, Seung O;Choi, Kyeong Yong;Ko, Jae Wang;Kim, Jung Su;Kim, Taekyeong;Lee, Seung Geol
    • Textile Coloration and Finishing
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    • v.29 no.3
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    • pp.105-114
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    • 2017
  • High tenacity polyethylene(HTPE) fiber is one of the most important synthetic fibers which possesses outstanding properties such as low density, excellent surface hardness and scratch resistance, superior electrical insulation and low cost. In this study, we dyed high tenacity polyethylene filaments using three different solvent dyes based on log P calculations. We evaluated the dyeing characteristics of dyed high tenacity polyethylene filaments based on dyeing temperature, dyeing time and concentration of solvent dyes. We also analyzed the tensile strength and elongation properties of dyed high tenacity polyethylene filaments with various dyeing temperature and dyeing times. The optimized dyeing condition can be found at $120^{\circ}C$ for dyeing time of 1 hour with 4%(o.w.f.) of solvent dyes.