• Title/Summary/Keyword: Organic battery

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A Study on the Removal of Minor Elements from Aluminum Hydroxide with Organic Acids (유기산(有機酸)을 이용(利用)한 Aluminum Hydroxide의 미량원소(微量元素) 제거연구(除去硏究))

  • Lee, Hwa-Young;Cho, Sung-Baek
    • Resources Recycling
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    • v.17 no.5
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    • pp.44-51
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    • 2008
  • The removal of minor elements such as Na, Ca and Fe has been performed from domestic aluminum hydroxide of 99.7% purity with organic acids. Oxalic and citric acid were used as the leaching agent, respectively and aluminum hydroxides of different particle size were also employed for the purification with organic acid leaching. Fine grinding of aluminum hydroxide has been tested using ball mills and leaching characteristics of each element have also been examined in terms of leaching parameters such as temperature, acid concentration, and solid density. As a result, it was found that oxalic acid showed higher leaching efficiency than citric acid in the concentration range of 0.1 to 1.0 mole/l and leaching amount of each element was also increased with the acid concentration and reaction temperature. It was observed that about 45% of Na was leached out during ball milling process which implied that the majority of Na contained in aluminum hydroxide was water soluble compound.

Occupational Styrene Exposure on Auditory Function Among Adults: A Systematic Review of Selected Workers

  • Pleban, Francis T.;Oketope, Olutosin;Shrestha, Laxmi
    • Safety and Health at Work
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    • v.8 no.4
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    • pp.329-336
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    • 2017
  • A review study was conducted to examine the adverse effects of styrene, styrene mixtures, or styrene and/or styrene mixtures and noise on the auditory system in humans employed in occupational settings. The search included peer-reviewed articles published in English language involving human volunteers spanning a 25-year period (1990-2015). Studies included peer review journals, caseecontrol studies, and case reports. Animal studies were excluded. An initial search identified 40 studies. After screening for inclusion, 13 studies were retrieved for full journal detail examination and review. As a whole, the results range from no to mild associations between styrene exposure and auditory dysfunction, noting relatively small sample sizes. However, four studies investigating styrene with other organic solvent mixtures and noise suggested combined exposures to both styrene organic solvent mixtures may be more ototoxic than exposure to noise alone. There is little literature examining the effect of styrene on auditory functioning in humans. Nonetheless, findings suggest public health professionals and policy makers should be made aware of the future research needs pertaining to hearing impairment and ototoxicity from styrene. It is recommended that chronic styrene-exposed individuals be routinely evaluated with a comprehensive audiological test battery to detect early signs of auditory dysfunction.

Neurobehavioral Performance Test of Workers Exposed to Mixed Organic Solvents (복합유기용제에 폭로된 근로자들에 대한 신경행동학적 기능의 평가)

  • Kim, Chang-Youn;SaKong, Joon;Chung, Jong-Hak;Joo, Ree;Jeon, Man-Joong;Sung, Nag-Jung;Kim, Sang-Kyu
    • Journal of Yeungnam Medical Science
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    • v.14 no.2
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    • pp.314-328
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    • 1997
  • A cross-sectional study was performed to evaluate the effects of chronic exposure to low-dose solvent on neurobehavioral performance of 48 male workers exposed to organic solvents. A control group of 50 workers was selected from same factories. Each worker completed a medical and occupational questionnaire and four tests of Neurobehavioral Core Test Battery. These included Benton visual retention test, digit symbol, digit span, and pursuit aiming. Comparison of mean performance showed a significantly poorer performance on digit symbol, digit span, and pursuit aiming. In univariate analysis, age contributed to poor performance on Benton visual retention test and educational level was found to reduce the performance on symbol digit in both groups. Amount of alcohol intake was found to reduce the performance on digit symbol and smoking appeared to slow pursuit aiming in the exposure group. In multiple regression analysis, controlling for age, educational level, alcohol, and smoking, Solvent exposure was found to be associated with performance of digit span, and number of correct dot of pursuit aiming. Age on Benton visual retention, educational level on digit symbol, arid smoking on pursuit aiming were found to be a significant factors on each test items. This study suggest that short-term memory, and perception can be affected easily by chronic exposure of organic solvents which air concentration levels were under the Threshold Limit Value.

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A Study on the Dissolution of Aluminum Hydroxide with Mineral and Organic Acid (Aluminum Hydroxide의 유무기산(有無機酸)에 의한 용해특성(溶解特性) 연구(硏究))

  • Lee, Hwa-Young
    • Resources Recycling
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    • v.18 no.2
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    • pp.56-61
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    • 2009
  • The dissolution of domestic aluminum hydroxide of 99.7% purity has been performed with mineral and organic acid prior to the synthesis of aluminum compounds from aluminum solution. Mean particle size of aluminum hydroxide used in the work was $14.4{\mu}m$, $22.9{\mu}m$ and $62.3{\mu}m$, respectively and the effect of reaction temperature, concentration of acid and reaction time on the dissolution of aluminum hydroxide has been examined. As a result, the dissolution of aluminum hydroxide was increased with the concentration of HCl and more than 70% dissolution was obtained with 5 mole/l HCl at $70^{\circ}C$ for reaction time of 4 hr. As far as the dissolution of aluminum hydroxide with sulfuric acid was concerned, it was found that the optimum concentration of sulfuric acid was about 6 mole/l for the effective dissolution of aluminum hydroxide. When oxalic acid was used for the dissolution of aluminum hydroxide, nearly complete dissolution could be obtained by the dissolution for 16 hr with 1.0 mole/l oxalic acid at $90^{\circ}C$.

Corrosion Resistance of Al6061-T6 by Organic/Inorganic Hybrid Coating Solution (유/무기하이브리드 코팅액에 의한 Al6061-T6의 내식 특성)

  • Mi-Hyang Park;Ki-Hang Shin;Byoung-Chul Choi;Byung-Hyun Ahn;Gum-Hwa Lee;Ki-Woo Nam
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.4_2
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    • pp.591-598
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    • 2023
  • In this study, the corrosion resistance by salt spray was evaluated using A6061-T6 for an electric vehicle battery pack case coated with an organic/inorganic hybrid solution. The lowest curing temperature of 190 ℃ resulted in significant corrosion and pitting. Meanwhile, no corrosion was observed in the coated specimens at 210 ℃ and 230 ℃ except at 210 ℃ - 6 min and 8 min. The surface of the as-received coating specimen observed by FE-SEM exhibited streaks and dents in the rolling direction, but the coating surface was clean. On the 190 ℃ - 6 min coating specimen, which had a lot of corrosion, rolling streaks spread, and dents were caused by corrosion. The 200 ℃ - 12 min coating specimen did not show corrosion, but it showed an etched surface. In the line profile, Si, the main component of the coating solution, was detected the most, and Ti was also detected. In the coating specimens with salt spray, O increased and Si decreased, regardless of corrosion. The peeling rate by adhesion evaluation was 26 - 87% for the 190 ℃ coating specimen, 4 - 83% for the 210 ℃ coating specimen, and 94 - 100% for the 230 ℃ coating specimen. The optimal curing conditions for the coating solution used in this study were 210 ℃ for 10 min.

Measurement of Combustible Characteristics of EC(Ethylene Carbonate) for Battery Electrolyte Organic Solvent (배터리 전해질 유기용매인 EC(Ethylene Carbonate)의 연소특성치 측정)

  • Yu-Ri Jang;Yu-Seon Jang;Jae-Jun Choi;Dong-Myeong Ha
    • Journal of the Korean Institute of Gas
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    • v.27 no.4
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    • pp.50-55
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    • 2023
  • Lithium-ion secondary batteries are currently in high demand and supply. The purpose of this study is to secure the safety of the process by studying the combustion characteristics of EC(Ethylene Carbonate), Which is mainly used as an electrolyte organic solvent for lithium ion batteries. The flash points of the EC by using Setaflash and Pensky-Martens closed-cup testers were experimented at 141 ℃ and 143 ℃, respectively. The flash points of the EC by Tag and Cleveland open cup testers were experimented at 152 ℃ and 156 ℃, respectively. The AIT(Auto Ignition Temperature) of the EC was experimented at 420 ℃. The LEL(Lower Explosive Limit) calculated by using lower flash point of Setaflash was calculated at 3.6 Vol.%.

Energy Harvesting from Bio-Organic Substance Using Microbial Fuel Cell and Power Conditioning System (미생물 연료 전지와 전력 조절 시스템을 이용한 생체 유기 물질로부터의 전력 생산)

  • Yeo, Jeongjin;Yang, Yoonseok
    • Journal of Biomedical Engineering Research
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    • v.38 no.5
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    • pp.242-247
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    • 2017
  • This study presents a bio-chemical energy harvesting system which can generate electric power from bioorganic substance contained in vermicompost. It produced electricity by inoculating microbial fuel cell(MFC) with earthworm-composted food waste. The generated electricity was converted into usable voltage level for mobile electronics through power conditioning circuits. The implemented prototype showed $200{\mu}W$ of maximum output electric power, which successfully supplied a beacon device which continuously transmitted data to nearby smartphone without a battery. The proposed system can help develop portable or bio-mimetic energy supply for sustainable use with further improvement.

Study on electrochemical performances of sulfur-containing graphene nanosheets electrodes for lithium-sulfur cells

  • Son, Ki-Soo;Kim, Seok
    • Carbon letters
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    • v.15 no.2
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    • pp.113-116
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    • 2014
  • Due to their morphology, electrochemical stability, and function as a conducting carbon matrix, graphene nanosheets (GNS) have been studied for their potential roles in improving the performance of sulfur cathodes. In this study, a GNS/sulfur (GNS/S) composite was prepared using the infiltration method with organic solvent. The structure, morphology and crystallinity of the composites were examined using scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. The electrochemical properties were also characterized using cyclic voltammetry (CV). The CV data revealed that the GNS/S composites exhibited enhanced specific-current density and ~10% higher capacity, in comparison with the S-containing, activated-carbon samples. The composite electrode also showed better cycling performance for multiple charge/discharge cycles. The improvement in the capacity and cycling stability of the GNS/S composite electrode is probably related to the fact that the graphene in the composite improves conductivity and that the graphene is well dispersed in the composites.

Electrochemical Performance of Carbon Coated LiMn2O4 Nanoparticles using a New Carbon Source

  • Park, Jin Seo;Park, Yong Joon
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.139-145
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    • 2016
  • The electrochemical performance of carbon-coated LiMn2O4 nanoparticles was reported. The polydopamine layer was introduced as a new organic carbon source. The carbon layer was homogeneously coated onto the surface of the LiMn2O4 nanoparticles because the polymerization process from the dopamine solution (in a buffer solution, pH 8.5) easily and uniformly formed a polydopamine layer. The phase integrity of LiMn2O4 deteriorated during the carbon-coating process due to oxygen loss, although the main structure was maintained. The carbon-coated sample led to improved rate capability because of the effect of the conductive carbon layer. Moreover, the carbon coating also enhanced the cyclic performance. This indicates that the carbon layer may suppress unwanted side reactions with the electrolytes and compensate for the low electronic conductivity of the pristine LiMn2O4.

Surface-modified Li[Ni0.8Co0.15Al0.05]O2 Cathode Fabricated using Polyvinylidene Fluoride as a Novel Coating

  • Lee, Jun Won;Park, Yong Joon
    • Journal of Electrochemical Science and Technology
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    • v.7 no.4
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    • pp.263-268
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    • 2016
  • This study describes the effect of coating the $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ cathode surface with a homogeneous carbon layer produced by carbonization of polyvinylidene fluoride (PVDF) as a novel organic source. The phase integrity of the above cathode was not affected by the carbon coating, whereas its rate capability and cycling performance were enhanced. Similarly, the cathode thermal stability was also improved after coating, which additionally protected the cathode surface against the reactive electrolyte containing hydrofluoric acid (HF). The results show that coating the $Li[Ni_{0.8}Co_{0.15}Al_{0.05}]O_2$ cathode with carbon using the PVDF precursor is an effective approach to enhance its electrochemical properties.