• 제목/요약/키워드: Organic Se

검색결과 601건 처리시간 0.024초

Effect of Organic Solvent Extractives on Korean Softwoods Classification Using Near-infrared Spectroscopy

  • Yeon, Seungheon;Park, Se-Yeong;Kim, Jong-Hwa;Kim, Jong-Chan;Yang, Sang-Yun;Yeo, Hwanmyeong;Kwon, Ohkyung;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • 제47권4호
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    • pp.509-518
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    • 2019
  • This study analyzed the effect of organic solvent extractives on the classification of wood species via near-infrared spectroscopy (NIR). In our previous research, five species of Korean softwood were classified into three groups (i.e., Cryptomeria japonica (cedar)/Chamaecyparis obtuse (cypress), Pinus densiflora (red pine)/Pinus koraiensis (Korean pine), and Larix kaempferi (Larch)) using an NIR-based principal component analysis method. Similar tendencies of extractive distribution were observed among the three groups in that study. Therefore, in this study, we qualitatively analyzed extractives extracted by an organic solvent and analyzed the NIR spectra in terms of the extractives' chemical structure and band assignment to determine their effect in more detail. Cedar/cypress showed a similar NIR spectra patterns by removing the extractives at 1695, 1724, and 2291 nm. D-pinitol, which was detected in cedar, contributed to that wavelength. Red pine/Korean pine showed spectra changes at 1616, 1695, 1681, 1705, 1724, 1731, 1765, 1780, and 2300 nm. Diterpenoids and fatty acid, which have a carboxylic group and an aliphatic double bond, contributed to that wavelength. Larch showed a catechin peak in gas chromatography and mass spectroscopy analysis, but it exhibited very small NIR spectra changes. The aromatic bond in larch seemed to have low sensitivity because of the 1st overtone of the O-H bond of the sawdust cellulose. The three groups sorted via NIR spectroscopy in the previous research showed quite different compositions of extractives, in accordance with the NIR band assignment. Thus, organic solvent extractives are expected to affect the classification of wood species using NIR spectroscopy.

국내 유기낙농(시유) 농가의 사양관리에 관한 실태조사 (A Survey on Feeding Management in Domestic Organic Dairy Farms)

  • 기광석;임현주;임동현;박성민;김태일;이현준;최순호;박수범;권응기;이세영
    • 한국유기농업학회지
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    • 제21권3호
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    • pp.391-401
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    • 2013
  • 본 연구는 국내 유기축산물(시유) 생산농가에 대한 사양관리 실태 및 생산수준에 관한 조사 연구를 통해 애로사항을 파악하고 개선방안을 모색하고자 수행하였다. 2010년 말 현재 전체 낙농가 6,347호 중 유기축산물(시유) 인증 농가수는 35호로 0.57%였다. 유기축산물 인증농가 35호 중 11농가에 대한 조사결과, 호당 평균 총사육두수는 142두로 그 중 평균 착유우 69두, 건유우 13두, 육성우 및 송아지 60두였다. 성우 대비 후보축의 비율은 42.4%를 차지하고 있었다. 조사농가의 평균 산유량은 분포는 20kg 미만이 14.3%, 25~30kg 미만이 57.1%, 30kg 이상 28.6%로 분포되어 있었다. 조사농가의 유성분 및 유질분포를 보면, 유지율은 3.3%로 전국 평균 유지율 3.95%보다 많이 낮았다. 평균 세균수는 5,775개/ml로 1A 등급, 체세포수는 192,500개/ml로 1등급에 해당되어 유질등급은 우수한 것으로 나타났다. 유기축산물(시유) 생산이 농가소득에 도움이 되는지에 대한 조사결과, 도움이 된다는 응답이 90%로 나타났으나 실제적인 경영자료를 분석한 연구가 추가적으로 수행되어야 할 필요가 있다고 생각된다. 일반 우유 생산에서 유기축산물(시유)로 전환한 이유는 친환경적 목장경영을 위해서라고 응답한 비율이 54.5%로 가장 높았다. 일반 낙농에 비해 유기낙농의 어려운 점으로는 유기사료 공급의 어려움이라고 대답한 비율이 45.5%로 가장 높았다. 실제적으로 유기 조사료 자가 생산 이용률은 43.0%였고, 구입하여 이용하는 비율은 57.0%로 나타나 유기 조사료 자급에 대한 비율을 더 높이는 것이 유기낙농 발전을 위해 해결해야 할 과제임을 알 수 있다. 평균 조농비율은 38.6:61.4로 조사료 급여비율이 매우 낮음을 알 수 있었다. 향후 유기축산물(시유) 확대를 위해서는 유기사료의 안정적인 공급이 우선되어야 할 과제라 생각된다.

도시지역 PM2.5의 HULIS 화학 특성 및 발생 과정 조사 (Chemical Characteristics and Formation Pathways of Humic Like Substances (HULIS) in PM2.5 in an Urban Area)

  • 손세창;배민석;박승식
    • 한국대기환경학회지
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    • 제31권3호
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    • pp.239-254
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    • 2015
  • Little information on HUmic-Like Substances (HULIS) in ambient particulate matter has been reported yet in Korea. HULIS makes up a significant fraction of the water-soluble organic mass in the atmospheric aerosols and influence their water uptake properties. In this study 24-hr $PM_{2.5}$ samples were collected between December 2013 and October 2014 at an urban site in Gwangju and analyzed for organic carbon (OC), elemental carbon (EC), water-soluble OC (WSOC), HULIS, and ionic species, to investigate possible sources and formation processes of HULIS. HULIS was separated using solid phase extraction method and quantified by total organic carbon analyzer. During the study period, HULIS concentration ranged from 0.19 to $5.65{\mu}gC/m^3$ with an average of $1.83{\pm}1.22{\mu}gC/m^3$, accounting for on average 45% of the WSOC (12~ 73%), with higher in cold season than in warm season. Strong correlation of WSOC with HULIS ($R^2=0.91$) indicates their similar chemical characteristics. On the basis of the relationships between HULIS and a variety of chemical species (EC, $K^+$, $NO_3{^-}$, $SO_4{^{2-}}$, and oxalate), it was postulated that HULIS observed during summer and winter were likely attributed to secondary formation and primary emissions from biomass burning (BB) and traffics. Stronger correlation of HULIS with $K^+$, which is a BB tracer, in winter ($R^2=0.81$) than in summer ($R^2=0.66$), suggests more significant contribution of BB emissions in winter to the observed HULIS. It is interesting to note that BB emissions may also have an influence on the HULIS in summer, but further study using levoglucosan that is a unique organic marker of BB emissions is required during summer. Higher correlation between HULIS and oxalate, which is mainly formed through cloud processing and/or photochemical oxidation processes, was found in the summer ($R^2=0.76$) than in the winter ($R^2=0.63$), reflecting a high fraction of secondary organic aerosol in the summer.

Human Serum Amyloid A-1 단백질 농도 분석을 위한 CdSe/ZnS 양자점 기반의 Lateral Flow Immunoassay 방법 개발 (Analysis of Human Serum Amyloid A-1 Concentrations Using a Lateral Flow Immunoassay with CdSe/ZnS Quantum Dots)

  • 아이딜파지리;고은서;이상혁;이혜진
    • 공업화학
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    • 제30권4호
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    • pp.429-434
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    • 2019
  • 본 논문에서는 수용성의 CdSe/ZnS 양자점을 합성하고 이에 항체기능성을 도입하여 lateral flow immunoassay (LFIA) 플랫폼에 융합하여 폐암 질병진단에 활용 가능한 단백질 바이오마커[예: 인간 혈청 아밀로이드 A-1 (hSAA1)]의 농도 분석에 적용하고자 한다. 면역분석법 센서 스트립은 니트로셀룰로오즈 막에 테스트라인과 대조라인으로 각각 항hSAA1 단일클론항체(10G1)(anti-hSAA1)와 항chicken IgY (anti-chicken IgY)를 스프레이하여 제작하였다. 이와 함께, 유기상에서 합성된 CdSe/ZnS 양자점은 카르복실기로 변형된 알케인티올기를 이용한 리간드 교환방법으로 수용성으로 전환하였으며, 이에 타겟 단백질인 hSAA1에 특이적으로 결합 가능한 항체인 항hSAA1 단일클론항체(14F8)로 컨쥬게이션하여 형광검출용 입자[QDs-anti hSAA1 (14F8)]로 사용하였다. 제작된 LFIA 스트립 위에 순차적으로 다른 농도의 hSAA1과 QDs-anti hSAA1 (14F8)의 복합체를 흘려주면, 테스트라인에 anti hSAA1 (10G1)/hSAA1/QDs-anti hSAA1 (14F8) 샌드위치 복합체가 형성되어 양자점에 의한 발광신호가 검출됨을 측정하였다. 최적화된 측방흐름이 가능한 완충용액 조건에서 100 nM 농도의 hSAA1 단백질의 유무를 5 min 안에 눈으로 확인 가능하였다.

보성산 유기농 녹차의 품질에 따른 카테킨 함량과 항산화능 비교 분석 (Comparative Analysis of Catechins and Antioxidant Capacity in Various Grades of Organic Green Teas Grown in Boseong, Korea)

  • 박경련;이상길;남태규;김영준;김영록;김대옥
    • 한국식품과학회지
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    • 제41권1호
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    • pp.82-86
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    • 2009
  • 유기농 녹차의 등급별 총페놀 함량과 항산화능은 각 추출 용매에 따른 수율을 확인하였을 때 물 추출에 비하여 수용성 유기 용매의 추출 수율이 유의적으로 높았다. 유기용매를 이용한 추출 수율은 물을 이용할 때 보다 총페놀 함량은 1.5에서 3.2배, 항산화능은 1.8에서 3.8배 정도 높게 나타났다. HPLC 분석을 통하여 총페놀 함량과 항산화능의 상관관계를 비교 시 총페놀 함량이 증가함에 따라 항산화능이 1차 선형관계로 증가하는 경향을 보였다. HPLC분석을 통하여 유기농 녹차에 함유되어 있는 다양한 카테킨의 함량이 채엽시기에 따라 변화가 나타났다. 유기농 녹차의 카테킨 성분 중 가장 많이 존재하는 EGCG가 건조중량당 5.8-7.7%의 함량을 보였고, caffeine은 1.7-2.9%의 함량을 보였다. 유기농 녹차의 카테킨 함량은 일반적으로 채엽 시기가 늦어짐에 따라서 점차 감소하였다. 유기농 녹차의 등급에 따른 항산화능은 최상급인 우전에서 가장 높았으며 최하등급인 엽차에서 가장 낮게 나타났다. HPLC 분석에 의한 유기농 녹차의 등급에 따른 총 카테킨 함량(mg/g)은 우전(155.4), 세작(147.7), 중작(143.2), 엽차(135.1), 대작(130.5)의 순서로 감소하였다. 이를 통해 녹차의 채엽 시기가 유기농 녹차의 카테킨 성분 및 항산화능에도 영향을 미치는 것을 확인하였다. 전반적으로 상급의 유기농 녹차 일수록 총페놀 및 카테킨 함량이 많으며 또한 더 높은 항산화능을 가지는 것으로 나타났다.

MINERAL CONCENTRATION IN RICE STRAW AND SOIL IN KYONGBUK PROVINCE, KOREA

  • Ramirez, C.E.;Kumagai, H.;Hosoi, E.;Yano, F.;Yano, H.;Jung, K.K.;Kim, S.W.
    • Asian-Australasian Journal of Animal Sciences
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    • 제7권1호
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    • pp.125-129
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    • 1994
  • A field survey was carried out in Korea to assess the mineral composition of rice straw since it is a cheap and available cattle feedstuff. Forage and soil samples were collected in 4 localities in the Kyongbuk province. Soil analysis were also carried out in order to establish the relationships between soil composition and mineral content in the rice straw. Based on NRC tables, the rice straw samples provided adequate amounts of Mg, Ca, K, S, Mo, Mn and Zn. Percentages of samples deficient in P, Na, Cu and Se were 83, 50, 67 and 83 respectively. Soil samples, whose mean pH was 5.8 and mean organic matter content was 3.99%, were comparatively acidic and had high organic matter content. They also had high amounts of extractable Fe and Mn. Correlation coefficients between mineral content in soil and rice straw were low, i.e., 0.42 for Me (p < 0.05), and 0.37 for Mo (p < 0.05). The low or nonexistent correlation between soil and forage composition indicates the difficulty of establishing appropriate methods of mineral availability to the plants.

한.미 FTA 체결에 따른 한우농가 피해보전효과 분석 (An Analysis on the Damage Compensation of Hanwoo Farmers as a Result of the Korea-U. S. Free Trade Agreement)

  • 최세현;조재환;김은순
    • 한국유기농업학회지
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    • 제21권4호
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    • pp.523-538
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    • 2013
  • To help improve the current government practice of direct damage-compensation policies, resulting from the loss of profit, sustained by Hanwoo farmers, as a result of the recent Korea-U. S. Free Trade Agreement (FTA), this research aims to examine any problems or issues caused by said policies. To accomplish this task, we have established Hanwoo-SIMO model and estimated the damage of Hanwoo farmers, one without the implementation of the FTA and another with the FTA, to compare and contrast the two. We then analyzed the efficacy of the current government policies. According to our analysis, the current direct compensation policies for the loss of profit on the part of Hanwoo farmers are insufficient. To address this problem, we recommend the government enact a new direct damagecompensation law to address the following issues. First, as the base formula of damage-compensation, the government should use current price of the beef rather than the annually changing flexible price. Second, the flexible control index should remain fixed at 1.0 rate while the government prepares the adequate amount of the damage compensating direct payment resulting from the FTA. Third, the direct government compensation policy should extend beyond the current 15 years (2013-2026) as the profit loss is expected to increase after the midpoint of the FTA.

중국산 수입식품 안전성에 대한 소비자 인식 - 원료 콩의 원산지인가 친환경성인가? - (A consumer perception for the safety of imported chinese food : the place of origin or environmental-friendliness of the raw bean?)

  • 최세현;김은순;이현주;조재환
    • 농업과학연구
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    • 제38권2호
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    • pp.361-368
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    • 2011
  • This study aims to examine the consumer preference for packaged bean curd that takes a growing public interest. Specifically, this study tried to examine which is more important - the place of origin of the raw bean or the environmental-friendliness of the raw bean. Surveys were conducted to obtain information, such as the consumer evaluation for food safety on imported food products from China and the consumer perception of Chinese organic food products, Using the binary probit model, the relationship between consumer's choice of packaged bean curd and potentially important factors that can affect the consumer's choice was analyzed. A summary of this research and some policy implications follow. The results of this study can be used as the basic guideline as to how to extend the safety of imported food products, in general, and how to further develop the packaged bean curd industry in Korea, in particular.

2층 구조 유기 박막 EL 소자의 전기-광학적특성 (Electro-optical characterization of heterostructure organic electroluminescent devices)

  • 김민수;박세광
    • 센서학회지
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    • 제4권4호
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    • pp.10-15
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    • 1995
  • 유기 박막 electoluminescent(EL) 소자를 제작하여 전극의 일함수에 따른 출력휘도의 의존성과 휘도-전압 특성을 측정하였다. 제작된 소자의 구조는 Indium-Tin-Oxide(ITO)/정공수송층/발광층(전자수송층)/금속전극이며, 정공수송층으로는 PMMA+TPD(0.5wt%)와 측쇄 액정 고분자 메트릭스인 MC homopolymer+TPD(0.005wt%)와 (MC/MMA)copolymer+TPD(0.005wt%)을 사용하였으며, 발광층은 $Alq_{3}$을, 금속전극으로는 Ca, Mg, Mg:Ag(10:1) 와 Al을 사용하였다. 출력특성이 전압에 따른 정류특성을 가짐을 보였으며, 소자의 문턱전압은 5볼트이고, 출력 휘도는 10 볼트에서 700 $Cd/m^{2}$이상의 휘도를 보였다.

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낙동강수계 고도정수시설 도입을 위한 PILOT 실험 연구 (A Pilot Study for Introducing Advanced Water Treatment Facilities at Nakdong River)

  • 오세원;최광호;최수일;손성섭
    • 상하수도학회지
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    • 제11권1호
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    • pp.88-98
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    • 1997
  • To obtain design and operating parameters for advanced water facilities, pilot test consisted of ozonation and GAC filtration was conducted at midstream of Nakdong River. Even though the concentrations were very low, 62 chemicals were detected above $0.005{\mu}g/L$ in raw water. In the preozonation, natural organic matters which could produce THMs and organics such as phenols and amines were effectively removed. The performance of TOC removal of GAC filtration with ozonation was better than GAC filtration alone and adsorption capacity of GAC adsorbers were ranged 3~6mg-TOC/g-carbon. And also the life of GAC adsorber for removing TOC was predicted more than 1 years if ozonation is introduced. This indicates that biological degradation of organics happened in GAC filters. Most organics detected at ppt level were removed below detection limit by GAC filtration with ozonation. These results show that ozonation and GAC filtration are the reliable and safe process for organic contaminants and chlorinated byproducts control at Nakdong River.

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