• Title/Summary/Keyword: Organic Matter Reduction

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Effects of Organic Matter and pH on Chromium Oxidation Potential of Soil

  • Chung, Jong-Bae;Eum, Jin-Sup
    • Korean Journal of Environmental Agriculture
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    • v.20 no.5
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    • pp.346-351
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    • 2001
  • Oxidation of Cr(III) to Cr(VI) can increase availability and toxicity of chromium. In this study, possible mechanisms by which pH and organic matter can control the chromium oxidation and reduction in soil system were examined using four soils of different pHs and organic matter contents. Reduction of Mn-oxides occurred in the soils of higher organic matter content (4.0%), but Mn-oxide was quite stable during the incubation in the soil of pH 7.0 and 0.5% organic matter content. Manganese oxides can be reductively dissolved at lower pH and higher organic matter conditions. The soil of pH 7.0 and 4.0% organic matter content showed the highest Cr-oxidation potential. Reduction of soluble Cr(VI) was observed in all the soils examined. The most rapid reduction was found in soil of pH 5.5 and 4.0% organic matter content, but the reduction was slow in soil of pH 7.0 and 0.5% organic matter content. Thus, the reductive capacity of organic matter added soils was much higher as compared to other two soils of lower organic matter content. In all the soils examined, the reductive capacity of soluble chromium was much higher than the oxidative capacity. Organic matter was found to be the most important controlling factor in the chromium oxidation and reduction. Reduction of Cr(VI) to Cr(III) could be a potentially useful remediation or detoxification process, and availability and toxicity of chromium in soil would be controlled by controlling organic matter content and pH of the soils.

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Anaerobic Mineralization of Organic Matter and Sulfate Reduction in Summer at Ganghwa Intertidal Flat, Korea (하계 강화도 갯벌의 혐기성 유기물 분해능 및 황산염 환원력)

  • Hyun, Jung-Ho;Mok, Jin Sook;Cho, Hye Youn;Cho, Byung Cheol;Choi, Joong Ki
    • Journal of Wetlands Research
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    • v.6 no.1
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    • pp.117-132
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    • 2004
  • Despite its significance in understanding ecological structure and biogeochemical element cycles, there have been few studies on the microbial mineralization of organic matter and mineralization pathway in the intertidal flat of Korea. We measured anaerobic mineralization of organic matter and sulfate reduction rate, and evaluated the significance of sulfate reduction in total anaerobic carbon respiration at the southern part of Ganghwa Island. Depth-integrated carbon mineralization rate down to 6 cm depth ranged from 41.9 to $89.4mmol\;m^{-2}d^{-1}$, which accounted for approximately 216 tons of organic matter mineralization in entire intertidal flat area of Ganghwa($300km^2$). The results indicated that capacity for the organic matter mineralization in the Ganghwa tidal flat is comparable to highly productive salt marsh environments. Mineralization rates in the sediment amended with acetate were 2~5 times higher than in unamended sediment. The results implied that microbial mineralization was limited by the availability of organic substrates, and the organic matter mineralization capacity seems to be higher than estimated at ambient organic substrate level. Depth-integrated sulfate reduction rates within 6 cm depth of the sediment ranged from 20.7 to $45.1mmol\;SO{_4}^{2-}m^{-2}d^{-1}$, and sulfate reduction was mostly responsible for organic matter remineralization. It should be noticed that the increase of $H_2S$ in the sulfate reduction dominated tidal flat may result in the decrease of biological diversity.

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Optimization of Ultrafiltration Process using $MIEX^{(R)}$+Coagulation Process ($MIEX^{(R)}$+응집공정을 이용한 한외여과 공정의 최적화 : 다양한 전처리 공정의 적용에 따른 막 오염 현상 규명)

  • Son, Hee-Jong;Hwang, Young-Do;Roh, Jae-Soon;Jung, Chul-Woo;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.7
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    • pp.753-761
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    • 2005
  • In this study, pretreatment of organic matters with $MIEX^{(R)}$ was evaluated using bench-scale experimental procedures on four organic matters to determine its effect on subsequent UF membrane filtration. For comparison, coagulation process was also used as a pretreatment of UF membrane filtration. Moreover, the membrane fouling potential was identified using different fractions and molecular weights of organic matters. From the removal property of MW organic matters by coagulation process for the sample water NOM and AOM, the removal efficiency of high MW organic matters were much higher than those of low MW organic matters. It was shown that the removal efficiency of high MW organic matter more than 10 kDa was lower than that of low MW organic matter for $MIEX^{(R)}$ process. For the change of permeate flux by the pretreatment process, $MIEX^{(R)}$+UF process showed high removal efficiency of organic matter as compared with coagulation-UF processes, but high reduction rate of permeate flux was presented through the reduction of removal efficiency of high MW organic matter. From sequential filtration test results in order to examine the effect of MW of organic matter on membrane fouling, it was found that the membrane foulant was occurred by high MW organic matter, and the DOC of organic matter less than 0.5 mg/L was working as the membrane foulant. In the case of sample water composed of low MW organic matter less than 10 kDa, since the low MW organic matter less than 10 kDa has high removal efficiency by $MIEX^{(R)}$, low reduction rate of permeate flux is obtained as compared with coagulation-UF processes. In summary, it is required to conduct the research on physical/chemical characteristic of original water before pretreatment process of membrane process is selected, and a pertinent pre-treatment process should be employed based on the physical/chemical characteristic of original water.

Effects of Organic Materials on Soil Chemical Properties (유기물(有機物)의 시용(施用)이 토양(土壤)의 화학적(化學的) 성질(性質)에 미치는 영향(影響))

  • Oh, Wang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.11 no.3
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    • pp.161-174
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    • 1979
  • A review was made on the effect of organic matter application on the chemical characteristics of soils such as pH, solubilities of minerals, and cation exchange capacity mainly at flooded rice soils. The review can be summarized as follows: 1. Application of organic material such as rice straw and compost in flooded rice soil leads to a temporary lowering of soil pH at the earlier stage of soil reduction, due to the production of various organic acids and carbonic acid. This temporary lowered pH is replaced with the production of alkaline substances such as ammonia as the reduction of soil proceeds. 2. Incorporation of organic materials intensifies the ferrous iron, dissolving various minerals, virtually to the increase in electrical conductivity of soils. 3. Organic materials also play an important role in dissolving soil minerals through the production of various chelating agents. 4. Application of soil organic matter significantly increases cation exchange capacity of soils. 5. Continuous application of rice straw or compost leads to the increase in soil organic matter content to some extent, up to the level of equilibrium. In soils low in organic matter the equilibrium level is attained with five years continuous application of compost. 6. The manner of chemical fertilizer application influences the accumulation of organic matter applied in soils. Low levels of fertilization lowers the accumulation while high levels of fertilization accerelates the accumulation.

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Elution Patterns and Hydraulic Conductivity Depending on the Incorporated Organic Matter Contents in a Multi-Layered Soil Column (토양내 유기물 함량 변화에 따른 다층 토주의 수리전도도 및 용출 경향)

  • Chung, Doug Young
    • Korean Journal of Agricultural Science
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    • v.27 no.2
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    • pp.125-134
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    • 2000
  • This observation was to investigate the influence of raw organic matter incorporated into soil at various rates on hydraulic conductivity and elution of solute throughout soil column. Generally the organic matter content in a practical agricultural field was approximately 3%. However, the application rate of organic matter in the field tends to rapidly increase in these days. Therefore, we raised the application rate of organic matter up to 10% in this investigation. From the experiment, we found that the hydraulic conductivities rapidly decreased with increasing rate of organic matter as well as rapid decrease in total volume of eluent during the same period. And electrical conductivities in the effluent significantly decreased after 2 pore volume, resulting in approaching to the criteria of saline soli. From this we could assume that the organic matter may influence the crop growth in the beginning. However excessive irrigation in the field may cause saturation of soil leading to reduction of soil. Therefore, there must be a management methods in application of organic matter with respect to soil water control.

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A Study on Optimal Conditions for Organic Matter Reduction and Hydrogen Production Using Electrolysis Process (전기분해공정을 이용한 유기물저감 및 수소 생산을 위한 최적 조건에 관한 연구)

  • AHN, JEONGYOON;RO, YEONHEE;CHANG, SOONWOONG
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.6
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    • pp.546-552
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    • 2020
  • In this study, optimization research was conducted through statistical analysis with the aim of maximizing the efficiency of organic matter reduction and hydrogen production by applying electrolysis process at sewage treatment plant. Statistical analysis and optimal operating conditions of organic matter removal efficiency and H2 generation, which varied with various conditions in the electrolysis process, were derived using response surface methodology. As a result, 1,268 μS/cm of conductivity, 350 A current, and pH 3.2 was found to be the optimum condition to reach the desired value as 38% of organic matter reduction and 2.58 L/min of H2 production. The experiment also determined that the optimization study was reliable. Base on this study, it was confirmed that the removal of organic matter and hydrogen production could be stably by applying the electrolysis process in the sewage treatment plant.

The Study on Decline Plan of Primary Production Organic Matter of Uiam Lake Basin (의암호 유역에서 발생하는 자체생산 유기물 저감방안에 관한 연구)

  • 허인량;이건호;함광준;최지용;정의호
    • Journal of Environmental Health Sciences
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    • v.30 no.1
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    • pp.50-58
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    • 2004
  • The present study was designed to evaluate primary production organic matter in basin of lake around by execution of total maximum daily loading. BOD influent loading of Uiam lake was 2,819 kg/day, which was less then 28.3 percent, total effuluent loading as 3,619 kg/day, in comparision with BOD, total nitrogen influent loading was 4,681 kg/day, which was less then 10.0 percent, total effuluent loading as 5,150 kg/day. But in case of total phosphors influent loading was 73.3 kg/day, which was more then 34.2 percent, total run off loading as 48.3 kg/day. The result of survey reduction plan of primary production organic matter in basin of lake around which objectives of abstract is as follows. First plan was reduction of primary production organic matter by moving the outlet of municipal wastewater treatment center from present place to lake downstream. Secondary plan was improvement by diffusion type of outlet municipal wastewater treatment center. The third plan was reduction of environmental impact by passing and storing of municipal wastewater. Finally plan was decline water surface level which was present hydrouric retention time was reduction from 7.6 day to 6.0 day per meter.

Variation of organic matter and rice yield in in continuous forage use of barley and rice straw

  • Ku, Bon-Il;Hwang, Jae-Bok;Choi, In-Bea;Bae, Hui-Su;Kim, Hag-Sin;Park, Tae-Seon;Park, Hong-Kyu;Lee, Geon-Hwi
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.184-184
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    • 2017
  • Organic matter is very important and essential factor to maintain productivity of paddy field. But as meat consumption and the demand of grain increase, the demand of forage also increased gradually in Korea. So the amount of organic matter in paddy field have been declined gradually by the reduction of return of rice straw for the forage use for cattle. There is not enough alternative resources for forage, we guess this trend of organic matter decline in paddy field would continue for the time being in Korea. So this study was performed to confirm the variation of organic matter and change of rice yield to select suitable rice cultivars which yield reduction is small in condition of organic matter decrease in paddy field. To confirm the change of rice growth and yield in condition of organic matter decrease in paddy field, we transplanted 10 rice cultivars which yield reduction are small in low fertilizer condition. We transplanted it Buan where double cropping of winter barley continues several years on June 10. Planting density were $70plants/3.3m^2$ Fertilizer amount was $N-P_2O_5-K_2O=9-4.5-5.7kg/10a$ and fertilizer split application of nitrogen was basal-tillering stage-panicle initiation = 50-20-30%. And in the other cultivation management, we observed rice standard culture of NICS. In paddy field where withdraw straws of barley and rice, the organic matter content showed tendency to decrease as the years go on. During rice cultivation season, organic matter decreased little by little, but it increased again after rice harvest season. Rice yield was more in order of Sodami, Chunghaejinmi and Saenuri. We judge that there is an advantage in rice yield of rice cultivars which have later heading date because of suitable ripening temperature. Although Sobibyeo and Shindongjinbyeo showed high yield, head rice yield decreased severely owing to chalky and cracked rice.

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Effects of Organic Material Application on the Growth and Yield of Crops in Korea (우리나라에서의 유기물(有機物) 시용효과(施用效果))

  • Park, Chon-Suh
    • Korean Journal of Soil Science and Fertilizer
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    • v.11 no.3
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    • pp.175-194
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    • 1979
  • The soil organic matter contents in arable land are generally low in Korea. Thus it is generally agreed that the application of organic materials to soils would be much beneficial. Present paper is a review on the effectiveness of organic mat ter application in uplands and lowlands. 1. The effect of organic matter application in uplands are of more clear and simple to explain as compared to that in lowlands. In uplands, appropriate application of organic matters such as compost and various crops residues improves the physical properties of soils leasing to increased water holding capacity, better aeration, and decrease in soil erosion. 2. In lowland, rice soils under water logged conditions the effect of organic matter application on rice yield is not straight borward and demands more refined knowledges for the interpretation of it. 3. It is found that the application of compost in rice soils is more effective when nitrogen fertilizer application is limited it dicating that nitrogen contained in the organic maerials can become available to rice plant and plays an important role for increased yield of rice under the condition where nitrogen fertilizer supply is limited. 4. Application of organic matter does not always bring about the desirable effects. Very often the organic matter application results in more intensive soil reduction leading to the accumulation of harmful substances which would can cancel out the positive effects of organic matter. This is partiunlarly true in poorly drained soils. 5. Rice straw or compost, when applied rice soils, supply sizeable amounts of available silicate to rice plant resulting in yield increase. 6. Although the effectiveness of organic matter application on rice yield in short term experiments is not consistent due to many reasons, the long term effect of organic matter is significant. 7. The term of the $O.M/SiO_2$ ratio in rice soils can serve as a criterion for the judgement of whether organic matter or silicate fertilizer is needed to be applied in a certain soil.

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Study on Controlling Factors for Soil Structure in Creation of Man-made Tidal Flat (인공 간석지 창출에 있어서 토양구조를 결정하는 인자에 관한 연구)

  • 이정규;최영찬
    • Journal of Environmental Science International
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    • v.8 no.5
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    • pp.587-592
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    • 1999
  • The purpose of this study was to identify the controlling factors to construct tidal flat ecosystems having similar characteristics as natural ones. We transplanted the soil in a constructed tidal flat to a natural one and vice versa. Parameters monitored after these transplantations were silt content, organic matter, bacterial population and oxidation-reduction potential. Moreover, the relationship among silt content, organic matter and bacterial population was investigated by laboratory column experiment. The silt content, organic matter, bacterial population and vertical profile of oxidation-reduction potential in the soil transplanted from the constructed tidal flat to the natural one changed to similar values to those in the natural one. On the contrary, all the parameters for the soil transplanted from the natural tidal flat to the constructed one changed to similar values as those in the constructed one. The silt contents in thses two transplanted solis were in proportion to the organic carbon contents and bacterial population. Similarly, the bacterial population in laboratory column experiment increased with the increase in silt and organic matter contents. It seemed to be important to select a place to enhance accumulative of silt and/or to maintain the silt content by hydrodynamic control of seawater in order to construct a tidal flat having similar characteristics as natural one.

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