• 제목/요약/키워드: Organic Contaminants

검색결과 383건 처리시간 0.032초

위생매립지 차수재로써의 부산석회 이용에 관한 연구 (A study on using the lime sludge as a sanitary landfill liner)

  • 구자공;도남영;임재신;이상민;김남돈
    • 한국토양환경학회지
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    • 제4권2호
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    • pp.149-161
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    • 1999
  • 본 연구에서는 위생매립지 차수재로써 부산석회의 이용방안을 검토하기 위하여 1) 부산석회의 지반 공학적 특성, 2) 오염물질 거동특성, 그리고 3) 용출특성을 살펴보았다. 연구결과 부산석회의 투수계수는 차수재의 허용 최대 투수계수($10^{-7}$ cm/s)보다 약 10배정도 낮은 투수계수를 보였다. 유기물(페놀)과 중금속(Cu, Pb)에 대한 지연효과는 부산석회의 높은 pH(> 11)로 인해 중금속에 대한 지연효과가 더 큰 것으로 나타났다. 용출실험 결과 비록 규제치를 상회하지는 않았지만, Pb과 Cd이 제한 기준치에 근접한 농도를 나타내어 지속적인 관찰이 요구되는 물질로 나타났다.

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활성탄을 이용한 역삼투 농축수의 유기물 및 영양염류 제거 평가 (Evaluation on Removal of Organics and Nutrients from Reverse Osmosis Concentrate using Activated Carbon)

  • 주성희;박종민;이양우
    • 한국물환경학회지
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    • 제28권3호
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    • pp.479-482
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    • 2012
  • Membrane process has been one of the widely applied wastewater treatment options, especially in field. However, one of the tricky issues in the process is to treat concentrates generated from reverse osmosis (RO) system in a manner of saving cost with maximum efficiency for treating a wide range of contaminants. Stimulated with the challenging issues, we have conducted a series of experimental studies in the evaluation for removing organics and nutrients using activated carbon. Results indicated that while powdered activated carbon (PAC) efficiently removed organics and the extent of removal was proportional to the PAC dosage, little removal of nitrogen and phosphorus was observed despite increasing the PAC dose. Interestingly, applying PAC was superior in removing organics than using granular activated carbon (GAC). These results suggest smaller particle size with higher surface area could provide greater chemical reactivity in removing organics.

국내 최초로 도입된 GC-IRMS와 응용분야 소개 (First GC-IRMS in Korea and Its Application Fields)

  • 신우진;이광식;고경석
    • 자원환경지질
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    • 제40권5호
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    • pp.699-703
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    • 2007
  • 가스크로마토그래피와 동위원소질량분석기를 온라인으로 연결하여 이루어지는 성분별동위원소분석기술은 지구과학, 환경과학 및 법의학 분야에서 안정동위원소 분석의 최신 기술이다. 1990년대부터 GC-IRMS는 법의학 분야에서 식품의 진위감별과 환경과학 분야의 유기오염물질의 오염원 추적에 널리 이용되어 왔다. 국내에서는 한국기초과학지원연구원에 2005년 초에 처음으로 GC-IRMS가 설치되었다. 이 연구에서는 한국기초과학지원연구원에서 운영중인 GC-IRMS를 간단히 소개하고 제조사가 다른 BTEX의 성분별탄소동위원소의 예비분석결과를 소개한다.

반도체 클린룸용 배기 열회수식 에어와셔의 에너지 소비량 성능평가 실험 (An Experiment on Performance Evaluation of Energy Consumption of an Exhaust Air Heat Recovery Type Air Washer for Semiconductor Manufacturing Clean Rooms)

  • 송근수;유경훈;신대건;손승우
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 하계학술발표대회 논문집
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    • pp.844-849
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    • 2008
  • In recent semiconductor manufacturing clean rooms, in order to improve clean room air quality, air washers are used to remove airborne gaseous contaminants such as $NH_3$, SOx and organic gases from outdoor air introduced into clean room. Meanwhile, there is a large quantity of exhaust air from clean room. From the energy saving point of view, heat recovery is useful for the reduction of air conditioning energy consumption for clean room. Therefore it is desirable to recover heat from the exhaust air and use it to reheat the outdoor air. However, so far there have not been sufficient studies of analyzing the comparison of the amounts of energy consumption and saving. In the present study, an experiment was conducted to investigate the energy consumption and heat recovery of a fin-coil type air washer system for semiconductor manufacturing clean rooms.

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SC1 세척공정을 이용한 고품질 Poly(3,4-ethylenedioxythiophene) 전극 패턴 어레이의 개발 (Development of High-Quality Poly(3,4-ethylenedioxythiophene) Electrode Pattern Array Using SC1 Cleaning Process)

  • 최상일;김원대;김성수
    • 통합자연과학논문집
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    • 제4권4호
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    • pp.311-314
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    • 2011
  • Application of self-assembled monolayers (SAMs) to the fabrication of organic thin film transistor has been recently reported very often since it can help to provide ohmic contact between films as well as to form simple and effective electrode pattern. Accordingly, quality of these ultra-thin films is becoming more imperative. In this study, in order to manufacture a high quality SAM pattern, a hydrophobic alkylsilane monolayer and a hydrophilic aminosilane monolayer were selectively coated on $SiO_2$ surface through the consecutive procedures of a micro-contact printing (${\mu}CP$) and dip-coating methods under extremely dry condition. On a SAM pattern cleaned with SC1 solution immediately after ${\mu}CP$, poly(3,4-ethylenedioxythiophene) (PEDOT) source and drain electrode array were very selectively and nicely vapour phase polymerized. On the other side, on a SC1-untreated SAM pattern, PEDOT array was very poorly polymerized. It strongly suggests that the SC1 cleaning process effectively removes unwanted contaminants on SAM pattern, thereby resulting in very selective growth of PEDOT electrode pattern.

산소-플라즈마 방전을 이용한 수중의 페놀 제거 (Phenol Removal Using Oxygen-Plasma Discharge in the Water)

  • 박영식
    • 한국환경과학회지
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    • 제22권7호
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    • pp.915-923
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    • 2013
  • Decomposition of non-biodegradable contaminants such as phenol contained in water was investigated using a dielectric barrier discharge (DBD) plasma reactor in the aqueous solutions with continuous oxygen bubbling. Effects of various parameters on the removal of phenol in aqueous solution with high-voltage streamer discharge plasma are studied. In order to choose plasma gas, gas of three types (argon, air, oxygen) were investigated. After the selection of gas, effects of 1st voltage (80 ~ 220 V), oxygen flow rate (2 ~ 7 L/min), pH (3 ~ 11), and initial phenol concentration (12.5 ~ 100.0 mg/L) on phenol degradation and change of $UV_{254}$ absorbance were investigated. Absorbance of $UV_{254}$ can be used as an indirect indicator of phenol degradation and the generation and disappearance of the non-biodegradable organic compounds. Removal of phenol and COD were found to follow pseudo first-order kinetics. The removal rate constants for phenol and COD of phenol were $5.204{\times}10^{-1}min^{-1}$ and $3.26{\times}10^{-2}min^{-1}$, respectively.

Nd:YAG 레이저로 표면처리된 ITO를 전극으로 한 유기EL 소자의 특성 (Surface treatment of ITO with Nd:YAG laser and OLED device characteristic)

  • 노임준;신백균;김형권;김용운;임응춘;박강식;정무영
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 C
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    • pp.1359-1360
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    • 2006
  • lTO(Indium-Tin-Oxide) was used as anode material for OLED. Characteristics of ITO have great effect on efficiency of OLEDS(Organic light emitting diodes). ITO surface was treated by Nd:YAG laser in order to improve its chemical properties, wettability, adhesive property and to remove the surface contaminants while maintaining its original function. In this study, main purpose was to improve the efficiency of OLEDs by the ITO surface treatment: ITO surface was treated using a Nd:YAG(${\lambda}=266nm$, pulse) with a fixed power of 0.06[w] and various stage scanning velocities. Surface morphology of the ITO was investigated by AFM. Test OLEDs with surface treated ITO were fabricated by deposition of TPD (HTL), Ald3 (ETL/TML) and Al (cathode) thin films. Device performance of the OLEDs such as V-I-L was investigated using Source Measurement Unit (SMU: Keithly. Model 2400) and Luminance Measurement (TOPCON. BM-8).

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상압 플라즈마 표면처리를 통한 태양광모듈 커버글라스와 불소계 코팅의 응착력 향상 (Improved Adhesion of Solar Cell Cover Glass with Surface-Flourinated Coating Using Atmospheric Pressure Plasma Treatment)

  • 김태현;박우상
    • 한국전기전자재료학회논문지
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    • 제31권4호
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    • pp.244-248
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    • 2018
  • We propose a method for improving the reliability of a solar cell by applying a fluorinated surface coating to protect the cell from the outdoor environment using an atmospheric pressure plasma (APP) treatment. An APP source is operated by radio frequency (RF) power, Ar gas, and $O_2gas$. APP treatment can remove organic contaminants from the surface and improve other surface properties such as the surface free energy. We determined the optimal APP parameters to maximize the surface free energy by using the dyne pen test. Then we used the scratch test in order to confirm the correlation between the APP parameters and the surface properties by measuring the surface free energy and adhesive characteristics of the coating. Consequently, an increase in the surface free energy of the cover glass caused an improvement in the adhesion between the coating layer and the cover glass. After treatment, adhesion between the coating and cover glass was improved by 35%.

커피 찌꺼기의 카페인 용출 및 산화분해 특성 (Extraction of Caffeine from Spent Coffee Grounds and Oxidative Degradation of Caffeine)

  • 신민정;김영훈
    • 한국환경과학회지
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    • 제27권12호
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    • pp.1205-1214
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    • 2018
  • During the past few decades, significant increase in the consumption of coffee has led to rapid increase in the production of coffee waste in South Korea. Spent coffee waste is often treated as a general waste and is directly disposed without the necessary treatment. Spent Coffee Grounds (SCGs) can release several organic contaminants, including caffeine. In this study, leaching tests were conducted for SCGs and oxidative degradation of caffeine were also conducted. The tested SCGs contained approximately 4.4 mg caffeine per gram of coffee waste. Results from the leaching tests show that approximately 90% of the caffeine can be extracted at each step during sequential extraction. Advanced oxidation methods for the degradation of caffeine, such as $UV/H_2O_2$, photo-Fenton reaction, and $UV/O_3$, were tested. UV radiation has a limited effect on the degradation of caffeine. In particular, UV-A and UV-B radiations present in sunlight cause marginal degradation, thereby indicating that natural degradation of caffeine is minimal. However, $O_3$ can cause rapid degradation of caffeine, and the values of pseudo-first order rate constants were found to be ranging from $0.817min^{-1}$ to $1.506min^{-1}$ when the ozone generation rate was $37.1g/m^3$. Additionally, the degradation rate of caffeine is dependent on the wavelength of irradiation.

Advanced Bioremediation Strategies for Organophosphorus Compounds

  • Anish Kumar Sharma;Jyotsana Pandit
    • 한국미생물·생명공학회지
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    • 제51권4호
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    • pp.374-389
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    • 2023
  • Organophosphorus (OP) pesticides, particularly malathion, parathion, diazinon, and chlorpyrifos, are widely used in both agricultural and residential contexts. This refractory quality is shared by certain organ phosphorus insecticides, and it may have unintended consequences for certain non-target soil species. Bioremediation cleans organic and inorganic contaminants using microbes and plants. Organophosphate-hydrolyzing enzymes can transform pesticide residues into non-hazardous byproducts and are increasingly being considered viable solutions to the problem of decontamination. When coupled with system analysis, the multi-omics technique produces important data for functional validation and genetic manipulation, both of which may be used to boost the efficiency of bioremediation systems. RNA-guided nucleases and RNA-guided base editors include zinc-finger nucleases (ZFNs), transcription activator-like effector nucleases (TALENs), and clustered regularly interspaced short palindromic repeats (CRISPR), which are used to alter genes and edit genomes. The review sheds light on key knowledge gaps and suggests approaches to pesticide cleanup using a variety of microbe-assisted methods. Researches, ecologists, and decision-makers can all benefit from having a better understanding of the usefulness and application of systems biology and gene editing in bioremediation evaluations.