• Title/Summary/Keyword: Organic Compound

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Changes of Free Sugars, Non-Volatile Organic Acids and Fatty Acids in Flue-cured Leaf Tobacco during Aging (황색종 잎담배의 후숙과정 중 유리당, 비휘발성 유기산 및 지방산의 변화)

  • Bock, Jin-Young;Park, Yoon-Shin;Park, Won-Jong;Lee, Joung-Ryoul
    • Journal of the Korean Society of Tobacco Science
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    • v.28 no.2
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    • pp.75-82
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    • 2006
  • This study was carried out to investigate the changes of free sugars, non-volatile organic and fatty acids in flue-cured leaf tobacco during aging. The threshed leaf tobacco(B1O and C1L) produced in 2002 crop year was aged for 21 month in warehouse of Oc-Cheon Leaf Tobacco Processing Factory. The leaf tobacco were sampled at three month intervals for analysis of free sugars, non-volatile organic and fatty acids. The major free sugars of flue-cured were glucose and fructose regardless of tobacco grades. After aging period of 21 months, the contents of glucose and fructose showed a tendency to slightly decrease, and there was no appreciable change in the contents of sucrose in B1O and C1L grades. The major compound of non-volatile organic acid and fatty acid were malic, oxalic and citric, linolenic, linoleic and palmitic acid regardless of tobacco grade. After aging period of 21 months, the contents of malic, malonic, oxalic and fumaric acid showed a tendency to slightly decrease, whereas succinic acid was slightly increased, and maleic acid was not changed in B1O and C1L grades. The decreases in fatty acid contents in B1O and C1L grade tobacco loaves after 21 month aging were 16.5% and 9.8%, respectively. The decreases in linolenic acid contents in two grades were the highest, showing 22.1% and 12.0% reduction after 21 month aging.

Formation and Characterization of Polyvinyl Series Organic Insulating Layers (폴리비닐 계열 유기절연막 형성과 특성평가)

  • Jang Ji-Geun;Jeong Jin-Cheol;Shin Se-Jin;Kim Hee-Won;Kang Eui-Jung;Ahn Jong-Myong;Seo Dong-Gyun;Lim Yong-Gyu;Kim Min-Young
    • Journal of the Semiconductor & Display Technology
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    • v.5 no.1 s.14
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    • pp.39-43
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    • 2006
  • The polyvinyl series organic films as gate insulators of thin film transistor(TFT) have been processed and characterized on the polyether sulphone (PES) substrates . The poly-4-vinyl phenol(PVP) and polyvinyl toluene (PVT) were used as solutes and propylene glycol monomethyl ether acetate(PGMEA) as a solvent in the formation of organic insulators. The cross-linking of organic insulators was also attempted by adding the thermosetting material, poly (melamine-co-formaldehyde) as a hardener in the compound. The electrical characteristics measured in the metal-insulator-metal (MIM) structures showed that insulating properties of PVP layers were generally superior to those of PVT layers. Among the layers of PVP series; copolymer PVP(10 wt%), 5wt% cross-linked PVP(10 wt%), copolymer PVP(20 wt%), 5 wt% cross-linked PVP(20 wt%) and 10 wt% cross-linked PVP(20 wt%), the 10 wt% cross-linked PVP(20 wt%) layer showed the lowest leakage current of 1.2 pA at ${\pm}10V$. The ms value of surface roughness and the capcitance per unit area are 2.41 and $1.76nF/cm^2$ in the case of 10 wt% cross-linked PVP(20 wt%) layer, respectively.

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Technical Tasks and Development Current Status of Organic Solar Cells (유기 태양전지의 개발 현황과 기술 과제)

  • Jang, Ji Geun;Park, Byung Min;Lim, Sungkyoo;Chang, Ho Jung
    • Korean Journal of Materials Research
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    • v.24 no.8
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    • pp.434-442
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    • 2014
  • Serious environmental problems have been caused by the greenhouse effect due to carbon dioxide($CO_2$) or nitrogen oxides($NO_x$) generated by the use of fossil fuels, including oil and liquefied natural gas. Many countries, including our own, the United States, those of the European Union and other developed countries around the world; have shown growing interest in clean energy, and have been concentrating on the development of new energy-saving materials and devices. Typical non-fossil-fuel sources include solar cells, wind power, tidal power, nuclear power, and fuel cells. In particular, organic solar cells(OSCs) have relatively low power-conversion efficiency(PCE) in comparison with inorganic(silicon) based solar cells, compound semiconductor solar cells and the CIGS [$Cu(In_{1-x}Ga_x)Se_2$] thin film solar cells. Recently, organic cell efficiencies greater than 10 % have been obtained by means of the development of new organic semiconducting materials, which feature improvements in crystalline properties, as well as in the quantum-dot nano-structure of the active layers. In this paper, a brief overview of solar cells in general is presented. In particular, the current development status of the next-generation OSCs including their operation principle, device-manufacturing processes, and improvements in the PCE are described.

Changes in the Contents of Sugar, Organic Acid, Free Amino Acid and Nucleic Acid-Related Compounds during Fermentation of Leaf Mustard-Kimchi (갓김치 숙성중 당, 유기산, 유리아미노산 및 핵산관련 물질 함량의 변화)

  • 박석규;조영숙;박정로;문주석;이용수
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.24 no.1
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    • pp.48-53
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    • 1995
  • Changes in the contents of sugar, organic acid, free amino acid and uncleic acid-related compounds of leaf mustard-Kimchi during fermentation at 5~7$^{\circ}C$ were investigated. The leaf mustard-Kimchi was formulated with 4kg leaf mustard, 120g garlic, 80g ginger, 540ml salted anchovies, 1kg green onion, 200g red pepper powder, 200g ground red pepper, 60g whole sesame and 600ml glutinous rice paste. Changes in pH and acidity were relatively slow. Major free sugars were glucose(0.13%) and maltose(0.42%), and residual sugars(0.03-0.04%) were also detected after 32 days of fermentation. Major free amino acids containing more than 26.5mg% were proline, glutamic acid, alanine and histidine. Contents of total free amino acids increased from 244.8 to 397.2mg% by 24 days of fermentation. Of non-volatile organic acid, lactic acid was the most abundant(119.3mg%), and its content increased markedly after 10 days of fermentation. Other organic acids(below 53.1mg%) observed were malic, oxalic and citric acid. Contents of nucleic acid-related compounds were high in the order of hypoxanthine(22.8mg%), IMP(8.3mg%) and GMP(6.9mg%). Hypoxanthine content increased by 10 days(27.3mg%) and decreased thereafter, while the others decreased gradually during the overall period of fermentation.

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Effect of Chemical Fertilizers and Organic Materials on Soil Actinomycetes Flora (화학비료(化學肥料) 및 유기물(有機物) 시용시(施用時) 방선균(放線菌) Flora의 구성변화(構成變化))

  • Hong, Sa-Hyun;Yang, Chang-Sool
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.4
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    • pp.420-426
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    • 1998
  • This investigation was undertaken to clarify the effects of application of chemical fertilizers (Compound fertilizer and commercial compost) and organic matters (straw and clover) on changes of the composition of soil actinomycetes flora. Actinomycetes were isolated from chemical fertilizer and organic materials treated soils, and then grown on HV agar plate. The isolated strains were classified by Bergey's manual based on the morphological characteristics and color of substrate mycelium of actinomycetes. The number of actinomycetes increased 4 times in control, 36 times in clover, 20 times in straw, 5 times in chemical fertilizer and 4 times in commercial compost treated soil after 14th day of incubation. This result suggests that the application of straw or clover is more effective to increase the number of actinomycetes than compound fertilizer or commercial compost. It also showed that the application of chemical fertilizer or organic materials considerably changed the composition of soil actinomycetes flora. The proportion of streptomyces strains to the isolated total actinomycetes was 62% in control, 60% in clover, 68% in straw, 67% in chemical fertilizer and 64% in commercial compost treated soils at the 14th day.

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Growth Characteristic of Pinus densiflora by Soil Generated at Civil Works Site (현장발생토 활용 식재기반 조성유형별 소나무 생육 특성 평가)

  • Oh, Deuk-Kyun;Kim, Phil-Lip;Yoon, Yong-Han;Kim, Won-Tae
    • Journal of Environmental Science International
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    • v.28 no.8
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    • pp.655-667
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    • 2019
  • This research aims to identify the possibility of developing A horizon resources that can be used for construction and civil engineering work. As such, the utility of A horizon resources was examined by establishing planting ground through a mixture of soil layers and by analyzing the growth and development of Pinus densiflora. The physicochemical and physical properties of the soil were as follows: the A horizon was sandy clay loam, B horizon was sandy loam, and the mixture of two layers appeared as sandy loam, which was identical to the B horizon. The experimental groups did not show any significant difference in their physical properties of porosity and degree of water-stable aggregates. With regards to chemical properties, the A horizon as well as the mixture of A and B horizon showed acidity while the B horizon showed alkalinity. The figures of organic matter, total nitrogen, available phosphate, and replaceable potassium were greater as the A horizon content increased, whereas the figures of replaceable calcium, replaceable magnesium, and conductivity increased as the A horizon content decreased. As a result of the growth and development of Pinus densiflora in each planting ground, the final survival rates were all above 100%. However, the tree height and the rate of growth for the diameter of root were higher in the order of A horizon > A horizon + B horizon > B horizon,indicating that the increased A horizon content is related to the growth and development of Pinus densiflora. The treatment of soil with improvement agents, used to recover the functions of in-situ soil showing poor growth and development, did not have a clear impact on the soil texture and porosity. However, the degree of water-stable aggregates increased significantly when using O horizon as the soil improvement agent among the types of in-situ soil. In contrast, all items related to the chemical properties showed significant differences following the treatment by soil improvement agents. The survival rate according to the treatment of soil improvement agents for the growth and development of Pinus densiflora was higher in the order of organic horizon = no treatment > compound fertilizer > organic fertilizer + compound fertilizer > organic fertilizer; this result was statistically significant with a marginal significance value of the log-rank test(p < 0.05).

Studies on the development of seed disinfectant in non-mercurious compounds (비유기수은 종자소독제개발에 관한 연구)

  • Lee Du-Hyung
    • Korean journal of applied entomology
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    • v.18 no.2 s.39
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    • pp.63-71
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    • 1979
  • Tests were made to find new non-mercurious seed disinfectants that were best for rice seeds. For these experiments four seed samples carr)?ing natural infection of Pyricularia oryzae, Helminthosporium oryzae, and Fusarium moniliforme were used and the following fungicides were used; Zinc Omadine, Sodium Omadine, Panoctine, Tecto-F, Benlate-T, Homai, Sisthane, $P_{242}$, Busan 30, Tecto-Wp and Terracoat Zn. Blotter method and water agar plate method used in the laboratory and growing-on test used in greenhouse. Results have shown that Sisthane, $P_{242}$ and Sodium Omadine have equal or superior effect to organic mercury compound against P. oryzae, H. oryzae, and F. moniliforme. Benlate T and Homai are effective against blast and Bakanae disease, but are inferior to organic mercury compound against brown spot disease. Busan 30 and Panoctine are effective against blast and brown spot disease, but have moderately inferior effects against F. monilifome. It is considered that the recommendable testing methods of seed treatment were blotter method for P. oryzae and water agar plate method for H, oryzae and F. moniliforme according to the experimental results obtained. No phytotoxicity against seed germination and seedling growth were observed when treated with disinfectants before germination of seeds.

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Utilization of Industrial Wastes as Fertilizer (산업폐기물(産業廢棄物)의 비료화(肥料化))

  • Shin, Jae-Sung;Han, Ki-Hak
    • Applied Biological Chemistry
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    • v.27
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    • pp.68-79
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    • 1984
  • An increased population and rapidly expanding industrial development have led to enormous amounts of various domestic and industrial wastes. The proper disposal of ever-increasing wastes is a growing global problem. Land treatment is one of the rational approaches that are environmentally safe and economically practical. It has long been practised in many sites. Recycling of industrial wastes on agricultural land can provide better possible means for maintaining environmental quality and utilizing waste-resources. Even though industrial wastes are beneficial as soil amendment and fertilizer, they have some limitation on land application because of wide variability as well as physicochemical problem in their composition. A direct application of solid and liquid wastes on land is being practised in Korea and some experimental results are presented. The direct application of fermentation waste on rice resulted in a 6 percent yield increase. Another organic residue from glutamic acid fermentation is widely used not only as a direct application as a liquid fertilizer but also for a raw material of organic compound fertilizer. These wastes are much promising as sources of plant nutrients, since they have large amounts of nutrients, especially nitrogen with few toxic metals. On the other hand, fertilizers developed from inorganic industrial wastes include calcium silicate, calcium sulfate and ammonium sulfate. The calcium silicate fertilizer simply produced from slag, by-product of iron and steel manufacturing plant is one of the most successful example of the conversion of wastes to fertilizer and slag production capacity totals to over three million MT/year. About 200,000 MT of calcium silicate fertilizer is currently applied in the paddy rice every year. Calcium sulfate, a waste from the wet phosphoric acid process is to some extent used as a filler of compound fertilizers but quite large quantites are directly applied for the reclamation of tidal flat.

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A Study on Developing of Soldering Flux (납땜 플럭스 개발에 관한 연구)

  • 이통영
    • Fire Science and Engineering
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    • v.14 no.2
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    • pp.33-38
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    • 2000
  • Flux, essentially used in soldering process of PCB (Printed Circuit Board) in electronics industry, contains IPA (Isopropyl alcohol) and methanol, which are highly inflammable and explosive. Hazard Chemical Controlling Law classified methanol as toxic material and Environmental Law classified methanol as VOC (Volatile Organic Compound). So there have been pressing needs of developing substitutes for the existing Flux. New solvent which is non-flammable and main component is DCP having same specific character of the existing Flux. It's been combirated with proper composition ratio adding stabilizer. As a result, it relieved working Environment Allowance thickness 200 ppm to 470 ppm, chance of not been soldered 0.083% to 0%, spread 85% to 87%, power saving resistance 1.0$\times$$10^{12}$$\Omega$ to 6.9$\times$$10^{12}$$\Omega$, which means a lot better than the existing Flux. Therefore, Flux confirmed the chance of improving productivity, safety, environment safety and quality. Also, Flux got a satisfied result after product quality test and product reliability test.

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Catalytic Deep Oxidation of Volatile Organic Compound Toluene over CuO/γ-Al2O3 Catalysts at Lower Temperatures (CuO/γ-Al2O3 촉매상에서 휘발성 유기화합물 톨루엔의 저온산화)

  • Kim Sang-Hwan;Kim Jae-Sik;Yang Hee-Sung;Y Vu Trinh Nhu;Park Hyung-Sang
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.1
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    • pp.64-73
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    • 2007
  • The catalytic activity of transition metals (Cu, Co, Mn, Fe and Ni) supported on ${\gamma}-Al_2O_3$ for the oxidation of toluene was investigated in the microreactor of fixed-bed type. The catalytic activity of transition metals for the oxidation of toluene turned out to be increasing in the order of Ni$Cu/{\gamma}-Al_2O_3$ catalysts for the oxidation of toluene increased with the increasing loadings of copper, reached the maximum activity at 5% loadings of copper, and decreased with higher loadings of copper in the catalysts. The activity of $Cu/{\gamma}-Al_2O_3$ catalysts for the oxidation of toluene decreased with the increasing calcination temperatures. This might result from the decreasing surface area of catalysts due to the sintering of copper oxide as well as ${\gamma}-Al_2O_3$ supports. The 5wt% $Cu/{\gamma}-Al_2O_3$ catalysts calcined at $400^{\circ}C$ for 4 hrs in the air showed the highest activity for the oxidation of toluene. Mutual inhibition was observed for the binary mixture of toluene and xylene. The activity of the easy-to-oxidize toluene was greatly decreased while the difficult-to-oxidize xylene was slightly decreased in the binary mixture of toluene and xylene. It might suggest that the inhibition of toluene and xylene in the binary mixture resulted from the competitive adsorption for the adsorbed oxygen on the catalytic surface.