• Title/Summary/Keyword: Organic Compound

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A Mono-Chelated Boron Complex as a New Blue Emission Layer in Organic Light Emitting Diodes

  • Jeong, Ji-Hoon;Rho, Hyeon-Hee;Kim, Jun-Ho;Ha, Yun-Kyung;Kim, Young-Sik;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.620-622
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    • 2004
  • In this study, a mono-chelated compound as novel blue light emitting material, $BPh_2$(pbi) (pbi = 2-(2-Pyridyl)benzimidazole) was synthesized Organic light emitting Diodes (OLEDs), which has a ITO/NPB(40 nm)/Boron(30 nm)/$Alq_3$(1 nm)/Liq(3 nm)/Al(150 nm) structure, has been fabricated. The maximum brightness of the device is up to about 900 cd/$m^2$ and 0.54 cd/A at 11.5 V. The EL peaks and CIE coordinates of our OLEDs is 457 nm and (0.26, 0.29), respectively.

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Synthesis and Anti-Inflammatory Testing of Some New Compounds Incorporating 5-Aminosalicylic Acid (5-ASA) as Potential Prodrugs

  • Abdel-Alim Abdel-Alim Mohamed;EI-Shorbagi Abdel-Nasser Ahmed;Abdel-Moty Samia Galal;Abdel-Allah Hajjaj Hassan Mohamed
    • Archives of Pharmacal Research
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    • v.28 no.6
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    • pp.637-647
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    • 2005
  • This work includes the synthesis of 15 final compounds (6a-h and 7b-h) as prod rugs of 5-ASA in the form of the acid itself, esters and amides linked by an amide linkage through a spacer to the endocyclic ring N of nicotinamide. Also, 15 new intermediate compounds were prepared. The target compounds (6b, 6f, 7b, and 7e-h) revealed potent analgesic and anti-inflammatory activities in comparison to sulfasalazine and 5-ASA. In addition, ulcerogenicity, $LD_{50}$, in vivo and in vitro metabolism of compound 7f were determined.

Separation of Dichlorinated Bydrocarbons by Pervaporntion Using ZSM-5 Zeolite Membrane

  • Lee, Young-Jin;Lee, Hye-Ryeon;Shim, Eun-Young;Ahn, Hyo-Sung;Lee, Yong-Taek
    • Korean Membrane Journal
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    • v.7 no.1
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    • pp.51-57
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    • 2005
  • Pervaporation with a membrane is one of the economic technologies for separation of liquid mixtures including organic/water mixtures. The ZSM-5 membrane was used fur pervaporation of dichloromethane, 1,2-dichloroethane and trans-1,2-dichloroethylene from their aqueous solutions since its physical property shows very hydrophobic. ZSM-5 crystals were hydrothermally grown and deposited on the inside of a porous sintered stainless steel tube by the secondary growth method. Fluxes of dichlorinated organic compounds were observed to be $50{\~}429\;g/m^2/h$ while separation factors were $15{\~}320$ depending on a mole fraction of a dichlorinated organic compound in a feed solution ranged from 0.0001 to 0.001 mole fraction and the operation temperature between $25^{\circ}C\;and\;35^{\circ}C$.

Effect of Organic Sulfur-Containing Compounds on Hepatotoxicity in Rats Induced by N, N-Dimethylnitrosamine (디메틸니트로자민에 의한 흰쥐의 간독성에 미치는 유기황화합물의 효과)

  • Shin Hea Soon;Kang Joo Yeon
    • Environmental Analysis Health and Toxicology
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    • v.20 no.3 s.50
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    • pp.237-242
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    • 2005
  • This study il focused on the hepatopreventive effect in cirrhotic rats induced by N, N -dimethylnitrosamine treatment when organir Lulfur -containing compoundE were orally injected. Biochemical parameters (aspatate transaminase (AST), alanine transaminase (ALT) alkaline phosphatase (ALP), 1-protein and t-bilirubin) were measured in serum injured liver tissue. The increased AST and ALT values were significantly reduced by organic sulfur-containing compounds at the oral dotes of 50 mg/kg. The result of morphological changes have illustrated the accumulation of liver damages, Each as inflammatory cell accumulation and cirrhosis, caused by N, N-dimethylnitrosamine. Also, it was found that liver damages were prevented by the treatment of organic sulfur- containing compounds.

Concentration of Volatile Organic Compounds at Main Stream and Branch Stream of Kumho River (금호강 본류와 지류에서의 휘발성 유기화합물질 농도)

  • 김용혜;장봉기;홍성철;이종영
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.135-146
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    • 1998
  • In this study, we investigated to measured concentration, seasonal characteristics and load quantity of volatile organic compounds(VOCs) for 11 sites in the main stream and 8 sites in the branch stream of Kumho river, during from October 1995 to April 1997. As a results, the small amount of volatile compounds, such as dichloromethane, chloroform, toluene, benzene, trichloroethene, tetrachloroethene, p-xylene and 1,3,5-trimethyl-benzene were detected from the main stream of Kumho river. Also detected to dichloromethene, chloroform, toluene, benzene, trichloroethene, tetrachloroethene, ethylbenzene, p-xylene, 1,3,5-trimethylbebzene and 1,2,4-trimethylbenzene in the branch stream, and dichloromerhane, chloroform and toluene were detected to all site of sampling. And seasonal variation of volatile organic compounds showed higher concentration in the July 1996 as a winter season than January 1997 as a summer season in most places. Also the load quantity of volatile organic compound at Gangchang site in the last downstream of Kumho river, was in order of chloroform > dichloromethane > toluene > trichloroethene.

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Properties of electrodeposited copper foil by organic compounds (유기물 첨가에 의한 전해동박의 특성)

  • Lee, K.W.;No, S.S.;Choi, C.H.;Kim, S.K.;Son, S.H.;Moon, H.K.;Park, D.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.88-91
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    • 2001
  • The mechanical properties and surface luminous intensities of copper foil have been studied with variation of the amount of additives into the electrolyte. Especially, organic compound of HEC was added from 0.1 to 10ppm for the propose of increasing the mechanical property and the surface state. The total thickness of electrodeposited copper foil was decreased with increasing the amount of organic compounds. There was not so much significant effect of the current density. It has been observed that mechanical property and surface luminous intensity increase with increasing concentration of organic compounds.

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Hot Atom Chemistry of Aromatic Halides : Scavenger, Temperature and Oxygen Effect (芳香族할라이드의 Hot Atom Chemistry 스캐벤져, 溫度 및 酸素의 效果)

  • Choi, Jae-Ho;Park, Yong-Chan;Son, Mi-Ja
    • Journal of the Korean Chemical Society
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    • v.9 no.2
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    • pp.78-80
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    • 1965
  • The organic yields(i.e., fraction of nuclear events resulting in organic compound formation) of the radioactive neutron capture reactions of the halogens in purified aromatic halides have been determined in the liquid and solid state, in the presence of scavenger, elemental halogen for thermal atoms, and in the presence of oxygen. Among the important results are; (1) organic yields of the halides are due in part to hot processes and in part to thermal processes; (2) temperature (from liquid state to solid state); (3) the organic yield of chlorobenzene is the same in the solid phase as in the liquid phase whereas the yields of the bromo-and iodobenzene are higher in the solid.

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Cross-Coupling Reaction of 2-halo1-methyl-1H-imidazo[4,5-b]pyridine Offers a New Synthetic Route to Mutagenic Heterocyclic Amine-PHIP and DMIP

  • Sajith, Ayyiliath M.;Muralidharan, Arayambath;Karuvalam, Ranjith P.;Haridas, Karickal R.
    • Journal of the Korean Chemical Society
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    • v.57 no.3
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    • pp.361-364
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    • 2013
  • A modified synthetic approach to the synthesis of heterocyclic food mutagens, 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine (PHIP) and 2-amino-1,6-dimethylimidazo[4,5-b]pyridine (DMIP) is reported. This route highlights an optimized palladium catalysed Buchwald cross-coupling of 2-halo-1-methyl-imidazo[4,5-b]pyridine with benzophenoneimine followed by acidic hydrolysis to yield compound 7. Using finely tailored conditions, Suzuki cross-coupling reactions with highly efficient catalytic systems were performed as the final step on 8 to introduce the aryl group and methyl group on the heterocyclic core.

Comparison of the tribological behaviors of various organic molecular films (다양한 유기분자막의 마찰특성 비교)

  • ;;;V. Tsukruk
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.06a
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    • pp.49-54
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    • 2001
  • Monolayers such as self-assembled monolayer (SAM) have received considerable attention to reduce stiction and friction in micro-devices and microelectromechanical systems (MEMS). Various organic molecular films were investigated to obtain better understanding of their tribological behaviors and adhesion property. The organic molecular films studied in this work are: epoxysilane SAMs, octadecyltricholosilane (OST), multi-layers composed of epoxysilane SAMs, poly〔styrene-b-(ethylene-co-butylene)-b-styrene〕(SEBS) and compound of epoxy resin and poly (paraphenylene) (EP/PPP). The pull-off forces of these films were also obtained from force-distance curves measured in static mode of operation of atomic force microscope (AFM). Tribological tests were conducted with a ball-on-flat reciprocating friction tester. The OST showed the lowest pull-off force, indicating its low adhesion property. It was revealed that, the OST, EP/PPP and the multi-layer of epoxysilane SAMs, SEBS and EP/PPP exhibited good tribological properties at the lower load (0.3 N) whereas the OST showed best performance at the higher load (1.8 N).

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Macasiamenene V, a New Stilbenoid from the Leaves of Macaranga inermis

  • Aldin, Muhammad Fajar;Tjahjandarie, Tjitjik Srie;Saputri, Ratih Dewi;Tanjung, Mulyadi
    • Natural Product Sciences
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    • v.27 no.1
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    • pp.45-48
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    • 2021
  • One new compound, macasiamenene V (1), and two known stilbenes (2-3) were isolated from Macaranga inermis Pax & K.Hoffm leaves. The structure of 1 was fully assigned based on the information on high-resolution MS and (1D, 2D) NMR spectra. The cytotoxic of compounds 1-3 was evaluated against 4T1 and HeLa cells. Compounds 2-3 showed high activity against HeLa cells with an IC50 value of 1.09 and 0.88 ㎍/mL, respectively.