• Title/Summary/Keyword: Organic Cation

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Changes of Physico-chemical Soil Properties, Major Soil Nutrient Contents, and Weed Vegetation in Paddy Fields during Fallow Period (휴경답에서의 토양의 이화확적 특성, 주요 영양분 및 잡초종의 변화)

  • Han, Sung-Uk;Chung, Gap-Chae;Chon, Sang-Uk;Lee, Hee-Jae;Guh, Ja-Ock
    • Korean Journal of Environmental Agriculture
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    • v.17 no.3
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    • pp.211-214
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    • 1998
  • Changes in physico-chemical properties and major nutrient contents were investigated in the soil of paddy fields during fallow period. Weed vegetation change in the fallow paddy fields was also examined. As the fallow period became longer, organic matter content in the paddy soil has gradually increased. Soil pH of the paddy fields has not changed until three years of fallow period and thereafter slightly increased. Cation exchange capacity of the paddy soil, and exchangeable N, K, Ca and Mg contents in the soil tended to decrease until three years of fallow period and then increase with the prolonged fallow period. As the fallow period became longer, available $P_2O_5$ content in the paddy soil has continuously decreased. Available $SiO_2$ content in the paddy soil has not changed until three years of fallow period and thereafter increased. The vegetation in the fallow paddy fields have mostly been occupied by the weeds of the Gramineae, Cyperaceae, and Compositae. As the fallow period became longer, the weeds of the Polygonaceae and Juncaceae have increased, whereas the weeds of the Leguminosae, Commelinaceae, Pontederiaceae, and Onagraceae have gradually disappeared. However, the weeds of the Gramineae and Cyperaceae have always been dominant in the paddy fields during the fallow paddy period.

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Extraction Behavior of Am(III) and Eu(III) From Nitric Acid Using Room Temperature Ionic Liquid (질산용액으로부터 이온성 액체를 이용한 Am(III)과 Eu(III)의 추출 거동)

  • Kim, Ik-Soo;Chung, Dong-Yong;Lee, Keun-Young;Lee, Eil-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.3
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    • pp.347-357
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    • 2018
  • The applicability of room temperature ionic liquids (RTILs), 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([$C_nmim$] [$Tf_2N$]), was investigated for the extraction of Am(III) and Eu(III) from nitric acid using n-octyl(phenyl)-N,N-diisobutyl carbamoylmethyl phosphine oxide (CMPO) and tri-n-butylphosphate (TBP) as extractants. The distribution ratios of Am(III) and Eu(III) in CMPO-TBP/[$C_nmim$][$Tf_2N$] were measured as a function of various parameters such as the concentrations of nitric acid, CMPO, and TBP. The results were compared with those obtained in CMPO-TBP/n-dodecane (n-DD). With comparable concentrations of the extractants, the distribution ratios obtained with RTILs were much higher than those obtained with n-DD. It was observed that the extraction efficiency was less for Eu(III) than for Am(III). The extraction of Am(III) and Eu(III) decreased with increases in the feed acidity for all three RTILs. The results suggest that the extraction of Am(III) and Eu(III) by CMPO in RTILs from nitric acid proceeds through the cation-exchange mechanism. The distribution ratios of Am(III) and Eu(III) increased with increases in the concentration of CMPO for all three RTILs. A linear regression analysis of the extraction data resulted in a straight line with a slope of about 3, suggesting the involvement of 3 molecules of CMPO during the extraction process.

A Study on PCP Adsorption in Various Paddy Soils of the Choongbook Area (충북지방(忠北地方) 답토양(沓土壤)에 대(對)한 PCP 흡착에 관한 연구(硏究))

  • Ok, Hwan-Suk;Lee, Jae-Koo
    • Applied Biological Chemistry
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    • v.15 no.3
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    • pp.229-240
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    • 1972
  • Not only in order to determine reasonable application amounts of PCP in terms of soil texture, but also to get basic data for fish-toxicity-free treatment by estimating fish toxicity, some aspects of PCP adsorption were observed taking various paddy soils with different physico-chemical characteristics in the Choongbook Area as samples. The results obtained are summarized as follows: 1. There was a positive correlation between PCP adsorption and clay contents, total nitrogen, organic matter, cation exchange capacity, exchangeable bases, and phosphorus absorption coefficients, respectively; whereas there was a negative one between PCP adsorption and pH. Although they were not significant, it was remarkable that there was a relatively large amount of correlation between PCP adsorption and clay contents, $H^+,\;Mg^{++}$, and CEC, respectively. 2. PCP adsorption in terms of soil texture was in the order of Clay>Loam>Sandy loam. 3. Although PCP adsorption in the $H_2O_2-treated$ soils decreased remarkably, it was not proportional to the humus contents. 4. The order of PCP adsorption in the exchangeable base-treated soils was H^+-exchanged soil>$K^+-soil$>$Na^+-soil$>$Ca^{++}-soil$>Mg^{++}-soil. 5. Langmuir's and Freundlich's adsorption isotherms were applicable to the PCP adsorption, and thereby were able to be calculated maximum adsortion amounts of PCP, bond energy, and the depths of adsorption layers. 6. Maximum adsorbed amounts of PCP were 212.14 mg/100gr in Clayey loam, 97.28 to 121.59mg/100gr in Loam, and 32.92 to 91.74mg/100gr in Sandy loam, respectively. 7. The depths of mixed layers of limiting application for fish-toxicity-free treatment were 0.88cm of the Jinchun soil, the shallowest and 4.29 cm of the Naesan-ri Sandy loam, the deepest.

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Relativity between Growth and Soil Environment of Viola orientalis Habitat (노랑제비꽃 자생지의 생육환경과 토양환경간 상관성)

  • You, Ju-Han;Jung, Sung-Gwan;Park, Kyung-Hun;Kim, Kyung-Tae;Lee, Woo-Sung
    • Current Research on Agriculture and Life Sciences
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    • v.25
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    • pp.1-5
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    • 2007
  • This study was carried out to offer the raw data of floricultural resource by scientific analyzing the growth and soil environment in Viola orientalis habitat, and establish the ecological characteristics in developing the relative model. In the results of soil factors analysis, there showed that acidity was pH 5.1, organic matter content of 9.1%, available $P_2O_5$ of 40.6mg/kg, exchangeable $K^+$ of $0.2cmol^+/kg$, exchangeable $Ca^{2+}$ of $3.5cmol^+/kg$, exchangeable $Mg^{2+}$ of $0.8cmol^+/kg$, cation exchange capacity(C.E.C) of $13.7cmol^+/kg$ and electrical conductivity(EC) of 0.4dS/m. The growth characteristics were surveyed that height was 12.4cm, leaf width of 2.5cm, leaf length of 3.0cm, flower width of 2.5cm, peduncle of 2.3cm and chlorophyll of $38.5{\mu}g{\cdot}mg^{-1}$.

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Effects of Irrigation Interval, Medium Composition and Drainage on the Growth Response of Korea Native Fern Rumohra aristata at Indoor (실내에서 관수주기, 상토종류, 배수층의 유$\cdot$무에 따른 자생 가는쇠고사리의 생육반응)

  • Ju, Jin-Hee;Bang, Kwang-Ja
    • Journal of the Korean Institute of Landscape Architecture
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    • v.32 no.6 s.107
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    • pp.103-108
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    • 2005
  • It was aimed to promote as a material for interior landscape by validating Rumohra aristata, in an indoor environment, especially irrigation interval, medium composition and drainage at indoor. 1. The result of physico-chemical analysis of medium composition showed that porosity, pH and Ex-Ca, Ex-Mg and Ex-K were high with peatmoss: vermiculite: perlite(1:1:1) and water contents, organic matter content, total nitrogen and cation exchange capacity were high with sand: leaf mold(1:1). 2. Growth and indoor adaptability of Rumohra aristata were better with irrigation at 2 interval per week than irrigation at 7 interval per week regardless of drainage. 3. In the case of medium composition, of growth and indoor adaptability were higher with sud: leaf mold (1:1) than peatmoss: vermiculite: perlite(1:1:1). 4. Fronds fresh weight and dry weight decreased when irrigation interval increased and were higher with sand: leaf mold(1:1) than peatmoss: vermiculite: perlite(1:1:1) treatment.

A Comparison of the Components and Biological Activities of the Ethanol Extracts of Achyranthes japonica Nakai and Achyranthes bidentata Blume (토우슬과 회우슬의 에탄올 추출물의 성분 및 생리활성 비교)

  • Lee, Ye-Seol;Kim, Mi-Sun;Kim, Duck-Jin;Sohn, Ho-Yong
    • Microbiology and Biotechnology Letters
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    • v.41 no.4
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    • pp.416-424
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    • 2013
  • In the course of a study for the development of functional foods utilizing Woosul (Achyranthis radix), the components and various biological activities of Korean Woosul (AJN: Achyranthes japonica Nakai) and Chinese Woosul (ABB: Achyranthes bidentata Blume) were compared. Woosul in Korea, including AJN and ABB, are regulated and part of the Korean Pharmacopoeia. From AJN and ABB, ethanol extracts and their subsequent organic solvent fractions were prepared and their in-vitro antimicrobial, antioxidant and anti-diabetes activities were evaluated. Although AJN and ABB have no clear distinction in terms of usage in Korea, our results suggest that AJN has higher quantities of lipid-soluble components and lower amounts of water-soluble sugars than does ABB. ABB also appears to possess greater amounts of flavonoid and polyphenol substances than AJN. Analyses of biological activities showed that the fractions of AJN were more active as antibacterial agents, and possessed more pronounced ${\alpha}$-glucosidase inhibitory activities than those of the ABB fractions. However, the antioxidant activities of the ABB fractions, as determined by DPPH anion-, ABTS cation-, nitrite-scavenging activity and reducing power, were higher than those of the AJN fractions. Our results suggest that the components and bioactivity of the extracts and subsequent fractions of AJN and ABB are different. Therefore, usage of either AJN or ABB should be carefully considered, as regards their individual properties, when the active fractions of Woosul are employed in the development of functional foods or novel plant-derived medicines.

Stable Macro-aggregate in Wet Sieving and Soil Properties (습식체별에 안정한 대입단과 토양특성과의 관계)

  • Han, Kyung-Hwa;Cho, Hyun-Jun;Lee, Hyub-Sung;Oh, Dong-Shig;Kim, Lee-Yul
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.4
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    • pp.255-261
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    • 2007
  • Soil aggregates, resulting from physico-chemical and biological interactions, are important to understand carbon dynamics and material transport in soils. The objective of this study is to investigate stable macro-aggregate (> 0.25mm diameter) in wet sieving (SM) and their relation to soil properties in 15 sites. The clay contents of soils were ranged from 1% to 33%, and their land uses included bare and cultivated lands of annual upland crops, orchard, and grass. Undisturbed 3 inch cores with five replicates were sampled at topsoil (i.e., 0- to 10-cm depth), for analyzing SM and physico-chemical properties, after in situ measurement of air permeability. SM of sandy soils, with clay content less than 2%, was observed as 0%. Except the sandy soils, SM of soils mainly depended on land uses, showing 27%~35% in soils with annual plants such as vegetable and corn, 51% in orchard, and 75% in grass. This sequence of SM is probably due to the different strength of soil disturbance like tillage with different land uses. SM had significant correlation with cation exchange capacity, organic matter content, sand, clay, silt, bulk density, and exchangeable potassium (K) and magnesium (Mg), whereas fluctuating properties with fertilization such as pH, EC, and water soluble phosphorus weren't significantly correlated to the SM. Particularly, exchangeable calcium (Ca) had significant relation with SM, only except soils with oversaturating Ca. This study, therefore, suggested that SM could perceive different land uses and the change of soil properties in soils, necessarily considering soil textures and Ca over-saturation.

Habitat Environment of Epimedium koreanum Nakai (삼지구엽초(三枝九葉草) 자생지(生地生) 환경(環境) 특성(特性))

  • Park, Kyeong-Yeol;Choi, Byoung-Ryourl;Yi, Eun-Sub;Kim, Sun-Jae;Park, Cheol-Ho
    • Korean Journal of Medicinal Crop Science
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    • v.6 no.1
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    • pp.51-56
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    • 1998
  • This study was carried out to evaluate environmental and ecological characteristics of natural habitat for cultivation of Epimedium koreanum. Habitat of E. koreanum was the slope foot of mountain descending gradually toward mostly northwest from top of mountain with slope of $2{\sim}20%$ and the altitude ranged from 60 to 400m above the sea level. Some physiochemical characteristics of habitat soil were as follows: pH, $4.1{\sim}5.8$, organic matters content, $4.9{\sim}6.6%$ and cation exchange capacity, $14.8{\sim}34.3\;me/100g$ soil, respectively. Habitats were shaded by deciduous broad-leaved tree mainly, and compared with those of naked area, relative photon flux density was $3.5{\sim}13.1%$ and relative luminance was $3.3{\sim}11.9%$ due to shading. Air temperature of habitat under shade was $4.3{\sim}6.5^{\circ}C$ lower than that of naked area. Habitat soil temperature was lower than that of naked area but temperature range was smaller than that of naked area. E. koreanum plants were growing with semishading plants under shade of tree leaf. From investigation of natural characteristics of habitat, it was concluded that E. koreanum plant would grow at place with a little change in temperature and moisture of soil which was caused by shading and mulching with litterfall of broad-leaved tree.

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Mitigations of Natural Organic Matter Fouling of Polyethersulfone Microfiltration Membrane Enhanced by Deposition of $TiO_2$ Nanoparticles ($TiO_2$ 나노입자로 표면침적된 Polyethersulfone 정밀여과 분리막의 자연유기물 파울링 감소)

  • Chang, Jung-Woo;Ahn, Kyung-Min;Kim, Ki-Hyun;Khan, Sovann;Kim, Jeong-Hwan
    • Membrane Journal
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    • v.20 no.2
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    • pp.120-126
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    • 2010
  • In this study, the effect of surface deposition of $TiO_2$ nanoparticles at polyethersulfone (PES) microfiltraiton (MF) membrane on humic acid fouling was investigated. The effect was observed as a function of crystal structures of $TiO_2$ nanoparticles and solution chemistries including pH and divalent cation such as calcium. Our results showed clearly that $TiO_2$-deposited membrane could mitigate membrane fouling significantly. However, this effect was observed to be dependent upon crystal structures of $TiO_2$ nanoparticles and solution chemistries. In the absence of calcium, fouling mitigation was less pronounced for both anatase and hybrid $TiO_2$-deposited membrane than for rutile $TiO_2$-deposited membrane while opposite trend was observed after addition of calcium. In the presence of calcium, the adsorption of humic acid to $TiO_2$-deposited membrane can be reduced by electrostatic repulsions between humic acid and $TiO_2$ surface. Addition of calcium provided further beneficial effect on fouling mitigation particularly at higher pH for the anatase $TiO_2$ deposited membrane, implying that both increased hydrophilicity due to $TiO_2$ nanoparticles and negative surface charge of the membrane should affect fouling mitigation. However, rutile $TiO_2$ having more inertness generally than the anatase $TiO_2$ showed relatively robust effect on the fouling mitigation regardless of solution properties.

Preparation and Properties of Sufonated High Impact Polystyrene(HIPS) Cation Exchange Membrane Via Sulfonation (술폰화 반응에 의한 High impact polystyrene(HIPS) 양이온교환막의 제조 및 특성)

  • Kim, Yong-Tae;Kwak, Noh-Seok;Lee, Choul-Ho;Jin, Chang-Soo;Hwang, Taek-Sung
    • Korean Chemical Engineering Research
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    • v.49 no.2
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    • pp.211-217
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    • 2011
  • In this study, ion exchange membranes were prepared using high impact polystyrene(HIPS) with various crosslinking and sulfonation time. Degree of sulfonation(DS) of sulfonated HIPS(SHIPS) membrane was increased with sulfonation time and decreased with crosslinking time. The highest value of DS was 66%. Also, water uptake and ion exchange capacity(IEC) of SHIPS membrane were decreased with degree of crosslinking and increased with sulfonation time. Then their values were 35.2% and 1.55 meq/g, respectively. Electrical resistance and ion conductivity of the membranes were showed more excellent value with sulfonation time. The maximum value of electrical resistance and ion conductivity were $0.4\Omega{\cdot}cm^{2}$ and 0.1 S/cm, respectively. It is indicated that the SHIPS membrane has the higher performance compare with Nafion 117. Durability of SHIPS membranes in a organic solvent was increased with increasing crosslinking time. The surface roughness of HIPS membranes were confirmed with SEM that was become uneven surface with progressing sulfonation.