• Title/Summary/Keyword: Ordinary Portland Cement

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Physicochemical Properties of Cement Paste Containing Mg(OH)2 Cured by CO2 curing Method (CO2 양생을 이용한 Mg(OH)2 혼입 시멘트 페이스트의 물리화학적 특성)

  • Chen, Zheng-Xin;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.3
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    • pp.203-210
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    • 2018
  • Corrosion of the rebar is one of the main factors affecting the durability of reinforced concrete in the world which lead to the failure of the reinforced concrete structures. In this research, a new method of fixing $CO_2$ is practiced to improve the carbonation resistance of the concrete. Brucite($Mg(OH)_2$), a kind of common $CO_2$ fixation materials, was added into ordinary Portland cement paste. Samples containing 0%, 5%, 10%, and 15% $Mg(OH)_2$ were exposed to an accelerated carbonation curing regime with 20% concentration of $CO_2$, 60% relative humidity, and a temperature of $20^{\circ}C$ until tested at 3d, 7d, 14d and 28d. After 28d of $CO_2$ accelerated curing, in the paste containing $Mg(OH)_2$, magnesian calcite was detected by SEM-EDX. Meanwhile, the paste containing $Mg(OH)_2$ exhibit the better pore distribution than ordinary Portland cement paste and the compressive strength of the cement paste containing $Mg(OH)_2$ were more than 50Mpa.

A Study on the Performance Improvement and Long-Term Strength Properties of Eco-cement Concrete (에코시멘트 콘크리트의 장기강도 특성 및 성능 향상 방안에 관한 연구)

  • Park, Kwang-Min;Lee, Gun-Cheol
    • Journal of the Korea Concrete Institute
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    • v.23 no.6
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    • pp.817-826
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    • 2011
  • Concrete using eco-cement has a problem with long-term strength development. However, currently, a long-term strength development mechanism is not confirmed, resulting in a lack of application of eco-cement in construction fields. In this study, the curing humidity influence on development in long-term strength of concrete using eco-cement and the relationship between strength and pore structure were examined. The results showed that wet cured eco-cement with a high water/cement ratio showed serious long-term strength reduction due to non-reduction of pore volume (pore size over 10 nm) in mortar caste with eco-cement. Also, the study results on improvement of long-term strength of eco-cement by partial replacement with ordinary portland cement and finely-ground fly ash showed that both of these alternatives improved long-term strength of concrete caste with eco-cement due to gradual refinement of their micro-structure.

Influence of fly ash and GGBFS on the pH value of cement mortar in different curing conditions

  • Shafigh, Payam;Yousuf, Sumra;Ibrahim, Zainah;Alsubari, Belal;Asadi, Iman
    • Advances in concrete construction
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    • v.11 no.5
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    • pp.419-428
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    • 2021
  • The pH of cement-based materials (CBMs) is an important factor for their durability, sustainability, and long service life. Currently, the use of supplementary cementitious materials (SCMs) is becoming mandatory due to economic, environmental, and sustainable issues. There is a decreasing trend in pH of CBMs due to incorporation of SCMs. The determination of numerical values of pH is very important for various low and high volume SCMs blended cement mortars for the better understanding of different defects and durability issues during their service life. In addition, the effect of cement hydration and pozzolanic reaction of SCMs on the pH should be determined at initial and later ages. In this study, the effect of low and high-volume fly ash (FA) and ground granulated ballast furnace slag (GGBFS) cement mortars in different curing conditions on their pH values has been determined. Thermal gravimetric analysis (TGA) was carried out to support the findings from pH measurements. In addition, thermal conductivity (k-value) and strength activity indices of these cement mortars were discussed. The results showed that pH values of all blended cement mortars were less than ordinary Portland cement (OPC) mortar in all curing conditions used. There was a decreasing tendency in pH of all mortars with passage of time. In addition, the pH of cement mortars was not only dependent on the quantity of Ca(OH)2. The effect of adding SCMs on the pH value of cement mortar should be monitored and measured for both short and long terms.

Estimation of Compressive Strength of Fly Ash Concrete subjected to High Temperature (고온조건하에서 플라이애시를 사용한 콘크리트의 압축강도증진 해석)

  • Han Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.6 no.3 s.21
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    • pp.99-105
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    • 2006
  • In this paper, the estimation of compressive strength of concrete incorporating fly ash subjected to high temperature is discussed. Ordinary Portland cement and fly ash cement(30% of fly ash) were used, respectively. Water to binder ration ranging from 30% to 60% and curing temperature ranging from $20^{\circ}C{\sim}65^{\circ}C$ were also adopted for the experimental parameters. According to results, at the high temperature, FAC had higher strength development at early age than OPC concrete and it kept its high strength development at later age due to accelerated pozzolanic reaction subjected to high temperature. For strength estimation, Logistic model based on maturity equation and Carino model based on equivalent age were applied to verify the availability of estimation model. It shows that fair agreements between calculated values and measured values were obtained evaluating compressive strength with logistic curve. The application of logistic model at high temperature had remarkable deviations in the same maturity. Whereas, the application of Carino model showed good agreements between calculated values and measured ones regardless of type of cement and W/B. However, some correction factors should be considered to enhance the accuracy of strength estimation of concrete.

Durability Enhancement in Nano-Silica Admixed Reinforced Mortar

  • Saraswathy, Velu;Karthick, Subbiah;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.4
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    • pp.297-306
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    • 2014
  • Recently nano-materials are gaining more importance in the construction industry due to its enhanced energy efficiency, durability, economy, and sustainability. Nano-silica addition to cement based materials can control the degradation of the fundamental calcium-silicate-hydrate reaction of concrete caused by calcium leaching in water as well as block water penetration and therefore lead to improvements in durability. In this paper, the influence of synthesized nano silica from locally available rice husk on the mechanical properties and corrosion resistant properties of OPC (Ordinary Portland Cement) has been studied by conducting various experimental investigations. Micro structural properties have been assessed by conducting Scanning Electron Microscopy, Thermo gravimetry and Differential Thermal Analysis, X-Ray Diffraction analysis, and FTIR studies. The experimental results revealed that NS reacted with calcium hydroxide crystals in the cement paste and produces Calcium Silicate Hydrate gel which enhanced the strength and acts as a filler which filled the nano pores present in concrete. Hence the strength and corrosion resistant properties were enhanced than the control.

Influence of Polycarboxylate type Superplasticizer on the Fluidity and Rate of Heat Liberation of Cement Paste (시멘트페이스트의 유동성 및 수화발열속도에 미치는 폴리카르본산계 고성능AE감수제의 영향)

  • Daiki, Atarashi;Song, Young-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.813-816
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    • 2008
  • Polycarboxylate-type superplasticizer is widely used for producing self-compacting and high-strength concrete and improving concrete durability. This paper discusses the influence of molecular structure of polycarboxylate-type superplasticizer on the fluidity and the rate of heat liberation of ordinary Portland cement paste. The fluidity of cement paste was increased by addition of polycarboxylate-type superplasticizer. The arrival time up to the maximum rate of heat liberation was increased by addition of polycarboxylate-type superplasticizer. The fluidity and the arrival time up to the maximum rate of heat liberation were more influenced by addition of polycarboxylate-type superplasticizer having shorter grafted chain than that having longer grafted chain.

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A Study on the Determination of mix Proportion of Water-Permeable Concretes for Site Application (현장적용 투수성 콘크리트의 배합조건 결정에 관한 실험적 연구)

  • 김봉찬;은재기;김완기;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.130-135
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    • 2000
  • The purpose of this study is to examine the physical properties of water-permeable concretes. The water-permeable concrete with cement-aggregate ratios of 1:3.5 to 1:6.0 and two type of coarse aggregate size of 8~13 and 13~18mm used OPC(ordinary portland cement) as a binder and superplasticizer are prepared, and then tested for flexural strength, compressive strength, compressive strength, continuous void percentage and coefficient of water permeability. It is concluded from the test result that the superior flexural and compressive strengths, coefficient of water permeability and continuous void percentage of water-permeable concretes that use OPC were obtained at cement-aggregate ratios of 1:3.2, 1:6.0 respectively, The water-permeable concretes with coarse aggregate of 8~13 and 13~18mm size used OPC as a binder havinga flexural strength of 24.81~45.56kgf/$\textrm{cm}^2$, 21.99~40.62kgf/$\textrm{cm}^2$, a compressive stength of 93.63~ 242kgf/$\textrm{cm}^2$, 114.8~191.7.kgf/$\textrm{cm}^2$, a coefficient of permeability of 0.59~1.85kgf/$\textrm{cm}^2$, 0.73~ 2.25kgf/$\textrm{cm}^2$, and a continuos void percentage of 16.6~26.32%, 13.52~24.35% respectively during 28 curing days.

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Peat stabilization using cement, polypropylene and steel fibres

  • Kalantari, Behzad;Prasad, Arun;Huat, Bujang B.K.
    • Geomechanics and Engineering
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    • v.2 no.4
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    • pp.321-335
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    • 2010
  • This article describes a laboratory research on stabilizing tropical peat using ordinary Portland cement (OPC) as a binding agent, and polypropylene and steel fibres as chemically inert additives. California bearing ratio (CBR) and unconfined compressive strength (UCS) tests were carried out to evaluate the increase in the strength of the stabilized samples compacted at their optimum moisture contents and air cured for up to 90 days. The results show that the UCS values of stabilized peat samples increased by as high as 748.8% by using OPC (5%), polypropylene fibres (0.15%), and steel fibres (2%). The CBR values of the samples stabilized with OPC (5%), polypropylene fibres (0.15%), and steel fibres (4%) showed an increase of as high as 122.7%. The stabilized samples showed a shrinkage in volume upon air curing and this shrinkage was measured by an index called, volume shrinkage index (VSI). The highest VSI recorded was 36.19% for peat without any additives; and the minimum was 0% for the sample containing 30% OPC, 0.15% polypropylene fibres and 2% steel fibres. The technique of stabilizing peat with OPC, polypropylene and fibres, coupled with air curing, appears to be cost-effective compared with other frequently used techniques.

Estimation of Compressive Strength of Concrete Using Blast Furnace Slag Subjected to High Temperature Environment (고온환경 조건하에서 고로슬래그를 사용한 콘크리트의 압축강도 증진 해석)

  • Han, Min-Cheol;Shin, Byung-Cheol
    • Journal of Environmental Science International
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    • v.16 no.3
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    • pp.347-355
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    • 2007
  • In this paper, estimation of the compressive strength of the concrete incorporating blast furnace slag subjected to high temperature was discussed. Ordinary Portland cement and blast furnace slag cement (BSC;30% of blast furnace slag) were used, respectively. Water to binder ratio ranging from 30% to 60% and curing temperature ranging from $20^{\circ}C{\sim}65^{\circ}C$ were also chosen for the experimental parameters, respectively. At the high temperature, BSC had higher strength development at early age than OPC concrete and it kept its high strength development at later age due to accelerated latent hydration reaction subjected to high temperature. For the strength estimation, the Logistic model based on maturity equation and the Carino model based on equivalent age were applied to verify the availability of estimation model. It was found that fair agreements between calculated values and measured values were obtained evaluating compressive strength with logistic curve. The application of logistic model at high temperature had remarkable deviations in the same maturity. Whereas, the application of Carino model showed good agreements between calculated values and measured ones regardless of type of cement and W/B. However, some correction factors should be considered to enhance the accuracy of strength estimation of concrete.

Nitrogen Oxides Adsorbing Capacity of High Carbon Fly Ash Containing Cementitious Materials (탄소함량이 높은 플라이애쉬를 함유한 시멘트 페이스트의 질소산화물 흡착 성능)

  • Lee, Bo Yeon
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.34 no.3
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    • pp.37-42
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    • 2018
  • The use of fly ash in construction materials is increasing worldwide due the various advantages of using it, such as to produce durable concrete, or to use less cement and thus lower carbon dioxide emissions. The quality of fly ash is often determined by loss on ignition value (LOI), where an upper limit of LOI is set in each country for quality control purpose. However, due to many reasons, production of high LOI fly ash is increasing that cannot be utilized in concrete, ending up in landfill. In this study, the effect of fly ash use in cementitious materials on nitrogen oxides adsorption is examined. In particular, the effect of using high LOI, and thus high carbon content fly ash on nitrogen oxides adsorption is investigated. The results suggest that the higher carbon content fly ash is related to higher nitrogen dioxide adsorption, although normal fly ash was also more effective in nitrogen dioxide adsorption than ordinary portland cement. Also, higher replacement rate of up to 40% of fly ash is beneficial for nitrogen dioxide adsorption. These results demonstrate that high carbon fly ash can be used as construction materials in an environmentally friendly way where strength requirement is low and where nitrogen oxides emissions are high.