• 자원리싸이클링
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• 제20권3호
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• pp.40-47
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• 2011

본 논문에서는 시멘트를 전혀 사용하지 않고 결합재로서 고로슬래그를 단독으로 사용한 배합과 고로슬래그와 플라이애쉬를 혼합한 배합의 강도, 수축 및 내구성에 대해 검토하였다. 그리고 비교를 위해 보통포틀랜드시멘트를 사용한 일반 모르타르에 대해서도 동일한 실험을 수행하였다. 그 결과, 알칼리 활성 모르타르는 일반 시멘트 모르타르에 비해 강도발현, 수축 및 동결융해 저항성 측면에서 우수한 것으로 나타났다. 특히 고로슬래그와 플라이애쉬를 혼합사용한 경우에는 압축강도 60 MPa 이상 달성이 가능하고, 일반 시멘트 모르타르에 비하여 수축량은 40% 정도 감소하고 동결융해 저항성은 20% 정도 향상되나, 탄산화 속도는 2~3배 촉진되는 것으로 나타났다.

• 한국건설순환자원학회논문집
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• 제1권1호
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• pp.35-41
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• 2013

본 논문에서는 시멘트를 전혀 사용하지 않은 지오폴리머 콘크리트를 개발할 목적으로 시멘트 대신에 결합재로 고로슬래그 미분말 또는 고로슬래그 미분말과 플라이애시를 혼합 사용한 지오폴리머 모르타르의 강도발현과 탄산화 및 동결융해 저항성에 대해 검토하였다. 그리고 비교를 위해 보통포틀랜드 시멘트를 사용한 일반 모르타르에 대해서도 동일한 실험을 수행하였다. 그 결과, 지오폴리머 모르타르는 일반 시멘트 모르타르에 비해 강도발현, 동결융해 저항성 측면에서 우수한 것으로 나타났다. 특히 고로슬래그와 플라이애시를 혼합사용한 지오폴리머 모르타르는 압축강도 60MPa 이상 달성이 가능하고, 일반 시멘트 모르타르에 비하여 동결융해 저항성은 20% 정도 향상되나, 탄산화 속도는 2.2~3.5배 촉진되는 것으로 나타났다.

• 한국구조물진단유지관리공학회 논문집
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• 제20권5호
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• pp.44-49
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• 2016

철근 콘크리트 구조물의 철근에 대한 부식을 발생시키는 다양한 유해 열화인자 중 염화물 이온(Cl-)은 침투로 인한 확산속도가 빠르고, 철근에 직접적으로 관여하여 부식을 야기시켜 매우 중요한 열화원인이다. 대형 콘크리트 구조물의 타설에서 불가피하게 발생하는 콜드 조인트는 전단력에 취약하여, 이는 내구적 열화에 대한 피해를 증가시키는 경향을 보인다. 본 연구에서는 콜드조인트를 가진 OPC(Ordinary Portland Cement) 콘크리트와 GGBFS(Ground Granulated Blast Furnace Slag) 염화물 촉진 실험으로 염화물 확산계수를 정량적으로 평가하였다. GGBFS 콘크리트에서는 $6.6{\times}10^{-12}m^2/sec$의 확산계수가 측정되었는데. 이는 OPC 콘크리트에 비하여 약 30% 수준의 낮은 확산계수값을 나타내었으며, 콜드조인트를 가진 콘크리트에서도 비슷한 경향이 관측되었다. OPC 건전부 콘크리트에 비하여 GGBFS 콘크리트의 염화물 확산계수는 건전부에서 0.30배, 콜드조인트부에서 0.39배 정도의 우수한 염해 저항성을 나타내었다.

• 한국구조물진단유지관리공학회 논문집
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• 제20권4호
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• pp.51-58
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• 2016

콘크리트 구조물은 내구성과 경제성이 확보된 건설재료이지만, 매립된 철근의 부식은 내구적인 문제뿐 아니라 구조물의 안전성에 큰 영향을 준다. 본 연구는 유리섬유와 강재를 에폭시로 일체화 시킨 FRP Hybrid Bar를 적용한 콘크리트에 대해 염해 침투 저항성과 부식수준에 따른 부착성능을 평가하였다. 이를 위해 일반 강재를 적용한 OPC(Ordinary Portland Cement)시편과 GGBFS를 30% 혼입한 시편에 대하여 부식을 0~10% 촉진하여 부착력을 평가하였다. 또한 FRP Hybrid Bar는 에폭시 코팅으로 인해 보통 상태에서는 부식 진전이 매우 작으므로 notch를 인위적으로 가하여 OPC 콘크리트에 매립시켰으며, 이후 부식실험을 수행하였다. 실험 결과, 부식된 철근의 부착력이 21% 수준으로 감소해도 FRP Hybrid Bar에 발생된 notch는 부착력에 큰 영향이 없는 것으로 평가되었다. 또한 GGBFS 콘크리트를 사용한 부재의 경우, 통과 전류가 감소하여 일반철근을 사용해도 70%이상의 부착력을 유지하고 있었다.

• Advances in concrete construction
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• 제9권3호
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• pp.279-287
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• 2020

This paper focuses on the engineering properties of Bentonite-Cement-Sodium silicate (BCS) grout, which was prepared by partially replacing the ordinary Portland cement in Cement-Sodium silicate grout with lithium bentonite (Li-bent) and sodium bentonite (Na-bent), respectively. The effect of different Water-to-Solid ratio (W/S) and various replacement percentages of bentonite on the apparent viscosity, bleeding, setting time, and early compressive strength of BCS grout were investigated. The XRD method was used to detect its hydration products. The results showed that both bentonites played a positive role in the stability of BCS grout, increased its apparent viscosity. Na-bent prolonged the setting time of BCS, while 5% of Li-bent shortened the setting time of BCS. The XRD analysis indicated that the hydration products between the mixture containing Na-bent and Li-bent did not differ much. Using bentonite as supplementary cementitious material (SCM) to replace partial cement is a promising way to cut down on carbon dioxide emissions and to produce low-cost, eco-friendly, non-toxic, and water-resistant grout. In addition, Li-bent was superior to Na-bent in improving the strength and the thickening of BCS grouts.

• Geomechanics and Engineering
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• 제14권6호
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• pp.553-562
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• 2018

Road construction is becoming increasingly important in marine and desert areas due to population growth and economic development. However, the load carrying capacity of pavement is of gear concern to design and geotechnical engineers because of the poor engineering properties of the soils in these areas. Therefore, stabilization of the soils is regarded as an important issue. Besides, due to the fuels combustion and carbonate decomposition, cement industry generates around 5% of global $CO_2$ emission. Thus, using bentonite as a natural pozzolan in soil stabilization is more eco-friendly than using cement. The aim of this research is to experimentally study of the stabilized marine and desert sands using deep mixing method by ordinary Portland cement and sodium bentonite. Different partial percentages of cement along with different weight percentages of sodium bentonite were added to the sands. Unconfined compression test (UCS), Energy Dispersive X-ray (EDX), and Scanning Electron Microscope (SEM) were conducted on the specimens. Moreover, a mathematical model was developed for predicting the strength of the treated soils.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.583-586
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• 2005

Strength of concrete is very important factor in design and quality management and may represent overall quality of concrete. Such strength of concrete may differ depending on amount of cement mixed, water and fine aggregate ratio. Classic concrete products have been produced mainly with ordinary portland cement(hereinafter 'cement'), water and fine aggregate as shown above, but various additives and mixture materials have been used for concrete manufacturing, along with development of high functional concrete and diversification of structures. Various kinds of chemical mixtures agents and mixture materials have been used as it requires concretes with other features which cannot be solved with existing materials only, such as high strength, high flexibility and no-separation in the water. Such addition of various mixture agents may cause change in cement hydrate, affecting strength. Hydration of cement is the process of producing potassium hydroxide, C-S-H, C-A-H and Ettringite, while causing heat generation reaction after it is mixed with water, and generation amounts of such hydrates play lots of roles in condensation and hardening. This study aims to analyze its strength and features with hydrates by making specimen according to curing temperature, types of mixture agent, mixing ratio and ages and by analyzing such hydrates in order to analyze role of cement hydrate on early strength of concrete.

• 한국세라믹학회지
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• 제42권11호
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• pp.737-742
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• 2005

Rheological properties of ordinary portland cement (OPC) containing metakaoline (MK), granulated blast furnace slag (GBS) and polycarboxylate type superplasticizer (PCA) were investigated using a mini-slump test, sedimentation test and viscometer. Fluidity of cement pastes containing MK (OPC-MK, OPC-MK-GBS systems) with PCA were higher than those of the cement pastes without MK(OPC, OPC-GBS systems). Colloid suspensions with $0.1\%$ PCA were changed from stable sedimentation behaviors to flocculation behaviors in the OPC-MK, OPC-GBS and OPC-MK-GBS systems. The colloid suspensions showed stable sedimentation behaviors with PCA greater than $0.2\%$. The OPC system showed shear thinning behavior. However, the other systems showed weak shear thinning behaviors with PCA. Rheological properties of cement pastes were improved when MK and GBS were contained together. The rheological properties of OPC-MK, OPC-GBS and OPC-MK-GBS systems were improved by PCA added greater than $0.2\%$.

• 콘크리트학회논문집
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• 제11권4호
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• pp.31-41
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• 1999

Blended Low Heat type cement is ground granulated blast furnace slag and fly ash mixed ternary with ordinary portland cement. From the viewpoint of X-ray patterns of domestic LHC, the main components of cement such as $C_2$S, $C_3$A, $C_3$S are considerably reduced. Therefore the heat evolution of LHC paste is 42cal/g lower than of OPC paste. At early age, the compressive strength development of LHC concrete is delayed, but the slump loss ratio of fresh concrete is reduced more than 20% with elapsed time. The penetrability of LHC is lower than that of OPC by 1/7.8 with the penetrability of chloride ion into the concrete until the age of 120 days. And the PD Index value of LHC is 0.44$\times$10-6 $\textrm{cm}^2$/s, which indicates only 39.3% of OPC. From the Mercury Intrusion Porosimetry test of cement past, we know that the pore size of LHC is more dense than that of OPC by production of C-S-H.

• 한국세라믹학회지
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• 제53권6호
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• pp.676-681
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• 2016

For the purpose of reducing the amount of limestone, which is used as a desulfurization agent to absorbing $SO_X$ gas in thermal power plants, and to recycle limestone sludge generated from a steel mill, limestone sludge was utilized as a desulfurization agent. In this study, cement, made of flue gas desulfurization (FGD) gypsum obtained in a desulfurization process using limestone sludge, was manufactured then, experiments were conducted to identify the physical properties of the paste and mortar using the cement. The results of the crystal phase and microstructure analyses showed that the hydration product of the manufactured cement was similar to that of ordinary Portland cement. No significant decline of workability or compressive strength was observed for any of the specimens. From the results of the experiment, it was determined that FGD gypsum manufactured from limestone sludge did not influence the physical properties of the cement also, quality change did not occur with the use of limestone sludge in the flue gas desulfurization process.