• Title/Summary/Keyword: Optimized mechanism

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Spectrofluorimetric Determination of Sparfloxacin Using Europium(III) as a Fluorescence Probe in Micellar Medium

  • Kamruzzaman, Mohammad;Alam, Al-Mahmnur;Lee, Sang-Hak;Kim, Young-Ho;Kim, Sung-Hong;Kim, Gyu-Man
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.105-110
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    • 2012
  • A europium (III)-sensitized, spectrofluorimetric (FL) method is presented for the determination of sparfloxacin (SPAR) using an anionic surfactant, sodium dodecyl benzene sulphonate (SDBS). The method is based on the strong fluorescence (FL) enhancement of SPAR after the addition of $Eu^{3+}$ ions as fluorescence probes. The experimental results indicated that the FL intensity of the SPAR-$Eu^{3+}$ system was enhanced markedly by SDBS. The maximum FL emission signal was obtained at about 615 nm when excited at 372 nm. The experimental conditions that affected the FL intensity of the SPAR-$Eu^{3+}$-SDBS system were optimized systematically. The enhanced FL intensity of the system exhibited a good linear relationship with the SPAR concentration over the range of $1.5{\times}10^{-9}-1.2{\times}10^{-7}mol\;L^{-1}$ with a correlation coefficient (r) of 0.9987. The limit of detection ($3{\delta}$) was $4.15{\times}10^{-10}mol\;L^{-1}$ with a relative standard deviation (RSD) of 1.65%. This method was successfully applied for the determination of SPAR in pharmaceuticals, and human serum and urine samples with higher sensitivity, wide dynamic range and better stability. The possible interaction mechanism of the system is also discussed in detail by ultraviolet absorption spectra and FL spectra.

Design and Implementation of μ-Webpage based on QR Code (QR 코드 기반 마이크로 웹페이지 설계 및 구현)

  • Ha, Sunju;Eun, Seongbae;So, SeonSub;Yun, Young-Sun;Jung, Jinman
    • KIISE Transactions on Computing Practices
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    • v.21 no.3
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    • pp.239-246
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    • 2015
  • QR(Quick Response) Code has been developed to provide greater storage capacity and more functionality compared to 1D bar codes. With the emergence of increasingly mobile devices equipped with cameras such as smart-phones and tablets, QR codes have become very popular and more important in mobile businesses. Typically, most QR codes are used as a URL link for redirecting users to webpages. However, the URL based QR codes are required to be connected over the internet and to be run a server. This can incur unnecessary traffics in the Internet. Furthermore, it is not suitable for the country lagging behind others in its network infrastructure. In this paper, we propose a server-less ${\mu}$-webpage to provide mobile web services and be optimized for the capabilities and limitations of QR Code. We have implemented the ${\mu}$-webpage in Android, and the results showed that the proposed mechanism can provide web-services without requiring extra servers or incurring mobile traffic data compared to the URL-based QR Codes.

Effects of Firing Ambient on Rear Metallization for Silicon Solar Cells (분위기에 따른 실리콘 태양전지 후면 전극 및 후면 전계의 형상과 특성 분석)

  • Park, Sungeun;Kim, Young Do;Park, Hyomin;Kang, Yoonmook;Lee, Hae-Seok;Kim, Donghwan
    • Korean Journal of Materials Research
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    • v.25 no.7
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    • pp.336-340
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    • 2015
  • For rear metallization with Al paste, Al back contacts require good passivation, high reflectance, and a processing temperature window compatible with the front metal. In this paper, the effect of the firing ambient during the metallization process on the formation of Al rear metal was investigated. We chose three different gases as ambient gases during the firing process. Using SEM, we observed the formation of a back surface field in $N_2$, $O_2$, and Air ambients. To determine the effect of the ambient on Voc, the suns-Voc tool was used. In this study, we described the mechanism of burn-out of organic materials in Al paste during the firing process. The oxygen ambient plays an important role in the burn-out process. We calculated the efficiency with obtained the back surface recombination velocities using PC1D simulation. It was found that the presence of oxygen during the firing process influenced the uniform back surface field because the organic materials in the Al paste were efficiently burned out during heating. The optimized temperature with oxygen flow shows an absolute efficiency of 19.1% at PC1D simulation.

Effects of Extrusion Process Parameters on Puffing of Extruded Pellets (압출성형 공정변수가 압출성형 펠릿의 팽화에 미치는 영향)

  • Kim, Jae-Hyun;Ryu, Gi-Hyung
    • Korean Journal of Food Science and Technology
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    • v.33 no.1
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    • pp.55-59
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    • 2001
  • Pressure-puffing system or extruder has been used to puff rice kernel or rice flour. Most of the study on rice puffing were the effect of process conditions such as moisture content and heating temperature on physical and chemical characteristics of popped rice. The study on mechanism and development of instant puffed rice like popcorn has been limited. Extruded waxy rice pellets were puffed in a microwave oven after drying and conditioning. Extruded pellets were formed with extrusion conditions of $20{\sim}27%$ moisture content, 2.76 MPa $CO_2$ gas injection pressure and 200 rpm screw speed. Under these conditions, puffed waxy rice pellets in microwave oven had low density and soft texture. Density and texture of puffed waxy rice pellet could be optimized by control of moisture content, $CO_2$ gas injection pressure and screw speed that affect significantly when puffing extruded waxy rice pellet.

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Binary transition metal sulfides hierarchical multi-shelled hollow nanospheres with enhanced energy storage performance (향상된 에너지 저장 능력을 가진 이중 전이금속 황화물 계층적 중공 구조의 나노구)

  • Lee, Young Hun;Choi, Hyung Wook;Kim, Min Seob;Jeong, Dong In;Tiruneh, Sintayehu Nibret;Kang, Bong Kyun;Yoon, Dae Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.3
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    • pp.112-117
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    • 2018
  • The metal alkoxide, CuCo-glycerate nanospheres (NSs), were successfully synthesized as Cu-Co bimetallic sulfides hierarchical multi-shelled hollow nanospheres ($CuCo_2S_4$ HMHNSs) through solvothermal synthesis. In this reaction mechanism, the solvothermal temperature and the amount of glycerol as a cosurfactant play significant role to optimize the morphology of CuCo-glycerate NSs. Furthermore, $CuCo_2S_4$ HMHNSs were obtained under optimized sulfurization reaction time of 10 h via anion exchange reaction between glycerate and sulfur ions. Finally, the structural and chemical compositions of CuCo-glycerate NSs and $CuCo_2S_4$ HMHNSs were confirmed through field emission scanning electron microscopy (FESEM), transmission electron microscope (TEM), X-ray diffraction (XRD) and electrochemical performances.

A Study on Etching Characteristics of SnO2 Thin Films Using High Density Plasma (고밀도 플라즈마를 이용한 SnO2 박막의 건식 식각 특성)

  • Kim, Hwan-Jun;Joo, Young-Hee;Kim, Seung-Han;Woo, Jong-Chang;Kim, Chang-Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.11
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    • pp.826-830
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    • 2013
  • In this paper, we carried out the investigations of both etch characteristics and mechanisms for the $SnO_2$ thin films in $O_2/BCl_3/Ar$ plasma. The dry etching characteristics of the $SnO_2$ thin films was studied by varying the $O_2/BCl_3/Ar$ gas mixing ratio. We determined the optimized process conditions that were as follows: a RF power of 700 W, a DC-bias voltage of - 150 V, and a process pressure of 2 Pa. The maximum etch rate was 509.9 nm/min in $O_2/BCl_3/Ar$=(3:4:16 sccm) plasma. From XPS analysis, the etch mechanism of the $SnO_2$ thin films in the $O_2/BCl_3/Ar$ plasma can be identified as the ion-assisted chemical reaction while the role of ion bombardment includes the destruction of the metal-oxide bonds as well as the cleaning of the etched surface form the reaction products.

Efficient Multicasting Mechanism for Mobile Computing Environment (물류트랙킹 장비에 활용되는 WCDMA/GSM 이중 대역 안테나 설계 및 성능 검증)

  • Lee, Eun-Kyu;Choi, Sung-Pill;Moon, Young-Sik;Jeon, Mi-Jin;Jo, Jae-Hui;Kim, Jae-Joong;Choi, Hyung-Rim
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2013.10a
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    • pp.896-897
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    • 2013
  • In recent years, logistics tracking Device using GSM & WCDMA to improve logistics efficiency are being extensively researched. The purpose of this paper is to examine the performance development antenna usable cargo container security transport. Antenna developed by study were optimized to match logistics environment apply to GSM & WCDMA dual frequency for monitering system. The measure of antenna have confirmation VSWR is 3:1 measured in return loss -10dB. Reliability of this antenna has been verified about GSM & WCDMA through test-operation between the south korea and Russia.

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Development of photo-sensitive aluminum electrode materials in PDPs

  • Kim, Chul-Hong;Chae, So-Ra;Hwang, Yun-Tae;Kim, Min-Jae;Heo, Eun-Gi;Lee, Byung-Hak;Park, Yung-Jun;Chung, Chong-In;Kim, Dong-Jun;Cho, Jae-Hwi;Kim, Hyun-Don;Okamoto, Kuninori;Kweon, Tae-Jong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.269-271
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    • 2009
  • We investigated on the sintering behaviors and electrical properties of photo-sensitive aluminum (Al) electrode materials in plasma display panels. General characteristics of Al electrodes was totally different to that of conventional Ag materials; resistivity was decreased with the increasing of metal particle sizes and the amount of frit content and there is almost no width difference between developed and fired electrodes layers. Microstructures of fired electrodes revealed that Al electrodes had different mechanism on necking between metal particles and making electrical conducting path. Chemical durability (especially, antialkalinity) and adhesion of Al electrodes must be carefully controlled. Nevertheless there are difficulties of processing Al electrodes, we developed and optimized photo-sensitive Al materials as address electrodes without any changes of existing patterning equipment and sintering conditions.

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An Optimal Resource Distribution Scheme for P2P Streaming Service over Centralized DU Environment in LTE (LTE에서 집중화된 DU 환경에서 P2P 스트리밍 서비스를 위한 최적의 자원 배분 방안)

  • Kim, Yangjung;Chong, Ilyoung
    • KIPS Transactions on Computer and Communication Systems
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    • v.3 no.3
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    • pp.81-86
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    • 2014
  • According to the development of streaming services with P2P and mobile network technologies, researches to enhance the service quality in mobile environment have been proposed. However, streaming services considering high-speed mobile environment and characteristics of heterogenous terminals have been hindered from being provided with the required quality from user because of bandwidth congestion between selfish peers of existing P2P system. It is also prone to long delay and loss in accordance with the repeated traffic amounts because there are no optimized solution for traffic localization. The structure to enhance peer contribution for service differentiation and peer selection with clustering scheme with location information of terminal can satisfy both users and service providers with service quality and efficiency. In this paper, we propose an incentive mechanism and resource distribution scheme with user contribution and traffic cost information based on user location, which make mobile users increase the satisfaction of service quality in LTE environments.

A Study of Wear Behavior for Sealing Graphite at Elevated Temperature (씰링 그라파이트의 고온 마모 거동에 관한 연구)

  • Kim, Yeonwook;Kim, Jaehoon;Yang, Hoyoung;Park, Sunghan;Lee, Hwankyu;Kim, Bumkeun;Lee, Seungbum;Kwak, Jaesu
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.5
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    • pp.113-120
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    • 2013
  • Graphite is commonly used as a solid lubricant leading to low friction coefficient and abrasion. In this study, wear behavior of sealing graphite(HK-6) at elevated temperature was evaluated. Reciprocating wear test was carried out as wear occurred graphite as a seal(HK-6) is positioned between the liner and driving shaft. Variables which are temperature, sliding speed and contact load are set. This study suggest optimized environment conditions through the wear properties of graphite.