• Title/Summary/Keyword: Optical spectroscopy

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Study of Synthesis and Optical Characterization of Amino-functionalized Tetraphenylsilole (아미노기로 기능화 된 실올의 합성 및 광학적 특성에 관한 연구)

  • Cho, Sungdong
    • Journal of Integrative Natural Science
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    • v.2 no.3
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    • pp.194-197
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    • 2009
  • Organometallic containing silole unit has been interested, since silole has a unique optical and electronic properties. The main goal of this work is to develop new selective sensors for organosilicon of 1-methyl-2,3,4,5-tetraphenyl-1H-silole and 1-methyl-1-(3-aminopropyl)-2,3,4,5-tetraphenylsilole based on new silole have been characterized by UV-vis absorption spectroscopy. their optical characteristics have been also investigate using photoluminescence spectroscopy.

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QUANTITATIVE MONITORING OF TISSUE OXYGENATION BY TIME-RESOLVED SPECTROSCOPY

  • Yamashita, Yutaka;Oda, Motoki;Ohmae, Etsuko;Tsuchiya, Yutaka
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.2101-2101
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    • 2001
  • Near-infrared spectroscopy is now being used in clinical diagnosis as a non-invasive monitor of tissue oxygenation state. However, due to lack of the optical pathlength information within tissues, it is still difficult to quantitate the hemoglobin concentration with present CW techniques. Time-resolved spectroscopy (TRS), which measures temporal profiles of emerging light from tissues, enables to estimate the pathlength distribution within tissues by converting time to distance. Consequently, quantitative measurement of tissue oxygenation is possible by analyzing the data with optical diffusion equation 1) or our Microscopic Beer-Lambert law2). Time-Resolved Spectroscopy System : TRS-1O3) Our TRS-10 system consists of a three-wavelength (759, 797, 833 nm) PLP as pulsed light source, a high speed PMT with high sensitivity and three signal-processing circuits for time-resolved measurement (CFD/TAC, A/D converter and histogram memory). Optical pulse train consisting of 759, 797 and 833nm is generated by PLP at 5㎒ repetition rate and irradiated a sample through a single optical fiber. The diffuse-reflected light from the sample is collected by a bundle fiber and then detected by the PMT for single photon measurement. After being amplified by a following fast amplifier, the electrical signals for each wavelength are picked out by CFD/TAC module. Then, a signal processing circuit integrated the TRS data for each wavelength individually. The simultaneous TRS measurement for three wavelengths achieved without any optical or mechanical switch. Experiment and Results Input and detection fibers of TRS-10 were attached at the human forehead with a fiber separation of 3cm. TRS measurements were continuously performed for about 20 minutes including 2 minutes hyper ventilation. It was observed that the total hemoglobin concentration was decreasing during the hyper ventilation and recovered until 2 minutes after hyper ventilation. On the other hand, the deoxy-hemoglobin concentration began to increase after hyper ventilation and had its peak at around 2 minute later, showing 502 drop from 75% to 60% due to inhibition of breathing by performing hyper ventilation. The results showed that this system might be able to quantitate the concentrations of oxy- and deoxy-hemoglobin in the human brain.

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Scanning Probe Microscopy Study on the Degradation of Optical Recoding Disks by Environmental Factors (광디스크의 노화에 관한 주사 탐침 현미경 연구)

  • Yoon, Man-Young;Shin, Hyun-Chang
    • Journal of the Korean Graphic Arts Communication Society
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    • v.29 no.3
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    • pp.97-104
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    • 2011
  • The storing ability of information of optical disks directly depends on the physical property of recording unit cells. It means that the degradation of optical disks ultimately causes the loss of the physical and chemical properties of recording unit cells and leads also information, too. We investigated the degradation and life time of optical disks which tell us the longevity of the preservation of information. Optical disks were aged using the accelerated aging system and studied by optical reflectivity spectroscopy and atomic force microscopy(AFM), and the preservation environment of electronic media in National central library of Korea also were analysed. Results show that the double reflective coated optical disks have good preservation of recording information but revealed some deformation of dye area in the AFM images. It means that we should include the mechanical and chemical degradation of the optical disks in the life time expectation evaluation.

Medical Applications of Near Infrared Spectroscopy and Diffuse Optical Imaging (Review) (근적외선 분광법 및 확산 광 영상법의 최근 연구 동향)

  • Lee, Seung-Duk;Kwon, Ki-Won;Koh, Dal-Kwon;Kim, Beop-Min
    • Journal of Biomedical Engineering Research
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    • v.29 no.2
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    • pp.89-98
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    • 2008
  • NIRS (Near-infrared Spectroscopy) and DOI (Diffuse Optical Imaging) are relatively new, non-invasive, and non-ionizing methods that measure or image optical properties (Scattering and Absorption Coefficient) and physiological properties (Water Fraction, concentration of Oxy-, Deoxy-Hemoglobin, Cytochrome Oxidase, etc) of biological tissues. In this paper, three different types of NIRS systems, mathematical modeling, and reconstruction algorithms are described. Also, recent applications such as functional brain imaging, optical mammography, NIRS based BMI (Brain-Machine Interface), and small animal study are reviewed.

Analytical Solutions of Birefringence and Dichroism Spectroscopy for the Jg = 0 → Je = 1 Transition

  • Noh, Heung-Ryoul
    • Journal of the Optical Society of Korea
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    • v.18 no.4
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    • pp.365-369
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    • 2014
  • We present accurate analytical solutions of the lineshapes of birefringence (rotation) and dichroism (absorption) spectroscopy for a circular anisotropic medium composed of atoms of the transition $J_g=0{\rightarrow}J_e=1$. The susceptibility of a weak probe beam was analytically calculated and was averaged over a Maxwell-Boltzmann velocity distribution. The lineshapes of the two spectroscopies were then presented in analytical forms at arbitrary values of the linewidths of the inhomogeneous (Doppler) broadening and the homogeneous (natural) broadening of the atoms.

Polarization dependence on Cavity Ringdown Spectroscopy (공동 광자감쇠 분광학에서의 편광의존성)

  • 김재완;한재원
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.08a
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    • pp.216-217
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    • 2000
  • 상자성을 갖는 분자에 대한 분광학 연구에서는 제만(Zeeman) 효과로 생기는 이색성을 이용한 magnetic rotation spectroscopy (MRS)가 널리 사용되고 있다.$^{(1)}$ MRS가 일반적인 흡수 분광법에 비해 더 민감한 측정을 할 수 있기는 하지만 사용하는 편광기의 extinction ratio에 의해 감도가 한정된다. MRS의 감도를 높이는 방법으로는 광경로를 길게 만드는 것을 고려할 수 있다. 일반적으로 공진기 광자감쇠 분광학(Cavity Ring-Down Spectroscopy, CRDS)은$^{(2)}$ 높은 반사율을 갖는 거울을 사용해서 수 km 이상의 광 경로를 만들기 때문에 감도가 높다. (중략)

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Study on Frequency Modulation Spectroscopy (주파수 변조 분광학 연구)

  • 서호성;류갑열
    • Proceedings of the Optical Society of Korea Conference
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    • 1991.07a
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    • pp.23-31
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    • 1991
  • 최근 레이저 분광학에 있어서 고감도 분광법으로 알려져 있는 주파수 변조 분광법(frequency modulation spectroscopy)과 레이저 광 주파수 안정화 응용에 대한 원리와 특징을 살펴본다. 또 super-cavity을 이용한 단일모드 He-Ne 레이저를 사용하여 FM 분광신호를 검출하고 그 신호특성에 대하여 기술하였다.

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Planar Waveguide Devices for Communication and Sensing Applications

  • Okamoto, Katsunari
    • Journal of the Optical Society of Korea
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    • v.14 no.4
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    • pp.290-297
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    • 2010
  • The paper reviews progress and future prospects of two kinds of planar waveguide devices; they are (a) silica and silicon photonics multi/demultiplexers for communications and signal processing applications, and (b) a novel waveguide spectrometer based on Fourier transform spectroscopy for sensing applications.

Plasma monitoring using optical emission spectroscopy and expert system (광반사분광기와 전문가 시스템을 이용한 플라즈마 감시)

  • Kim, Dae-Hyeon;Kim, Byeong-Hwan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.10a
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    • pp.235-236
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    • 2009
  • 본 연구에서는 Optical emission spectroscopy (OES)에 CUSUM과 전문가 시스템을 이용하여 플라즈마를 감시하는 기법을 개발하였다. CUSUM과 Dempster-Shafer를 이용하여 고장에 민감한 OES파장을 추출하였으며, 추출된 파장은 플라즈마 감시에 이용될 것으로 기대된다.

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