• 제목/요약/키워드: Optical quenching

검색결과 112건 처리시간 0.028초

백색 LED용 Ca3MgSi2O8:Eu2+ 백색 형광체의 발광특성 (Luminescent Characteristics of Eu2+- Doped Ca3MgSi2O8:Eu2+ White Phosphors for LED)

  • 유일
    • 한국재료학회지
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    • 제28권8호
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    • pp.474-477
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    • 2018
  • $Ca_3MgSi_2O_8:Eu^{2+}$(x = 0.003, 0.005, 0.007, 0.01, 0.03 mol) white phosphors for Light Emitting Diodes(LED) are synthesized with different concentrations of $Eu^{2+}$ ions using a solid state reaction method. The crystal structures, surface and optical properties of the phosphors are investigated using X-Ray Diffraction(XRD), Scanning Electron Microscope(SEM) and photoluminescence(PL). The X-Ray Diffraction results reveals that the crystal structure of the $Ca_3MgSi_2O_8:Eu^{2+}$ is a monoclinic system. The particle size of $Ca_3MgSi_2O_8:Eu^{2+}$ white phosphors is about $1{\sim}5{\mu}m$, as confirmed by SEM images. The maximum emission spectra of the phosphors are observed at 0.01 mol $Eu^{2+}$ concentration. The decrease in PL intensity in the $Ca_3MgSi_2O_8:Eu^{2+}$ white phosphors with $Eu^{2+}$ concentration is interpreted by concentration quenching. The International Commission on Illumination(CIE) coordinate of 0.01 mol Eu doped $Ca_3MgSi_2O_8$ is X = 0.2136, Y = 0.3771.

고농도로 도핑된 Bismuth 기반 어븀첨가 광섬유 증폭기의 이론적 모델링 기법에 관한 연구 (Theoretical Modeling of High Concentration Bismuth-based Erbium-doped Fiber Amplifier)

  • 신재현;정민완;이주한
    • 한국광학회지
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    • 제21권4호
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    • pp.139-145
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    • 2010
  • 본 논문에서는 고농도로 도핑된 Bismuth 기반 어븀첨가 광섬유 증폭기의 이득 및 노이즈 특성을 정확히 예측하기 위하여 필요한 이론적 모델링 기법에 대한 연구를 수행 하였다. 고농도의 Erbium 이온이 첨가되었을 때 발생하는 Clustering 현상에 기인한 Inhomogeneous Broadening현상, Cooperative Upconversion 현상, Pump Excited State Absorption과 Signal Excited State Absorption 현상 등 모든 현상을 고려하여 6 레벨 증폭기 System Model을 제시하고 이를 전산모사하여 실험치와 비교함으로써 제시된 모델의 유효성을 검증하였다.

Preparation and Characterization of White Phosphorescence Polymer Light Emitting Diodes Using PFO:Ir(ppy)3:MDMO-PPV Emission Layer

  • Park, Byung-Min;Chang, Ho-Jung
    • 마이크로전자및패키징학회지
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    • 제18권4호
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    • pp.79-83
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    • 2011
  • White phosphorescence polymer light emitting diodes (WPhPLEDs) with a glass/ITO/PEDOT:PSS/PFO:$Ir(ppy)_3$:MDMO-PPV/TPBI/LiF/Al structure were fabricated to investigate the effects of $Ir(ppy)_3$ doping concentrations on the optical and electrical properties of the devices. PFO, $Ir(ppy)_3$ and MDMO-PPV conjugated polymers as host and guest materials in the emission layer were spin coated at various concentrations of $Ir(ppy)_3$ ranging from 0.0 to 20.0 vol.%. As the concentration of $Ir(ppy)_3$ increased from 5.0 to 20.0 vol.%, the luminance and current efficiency values of the devices decreased clearly, which are attributable to the quenching effect at a high doping concentration. The maximum luminance and current density were 2850 $cd/m^2$ and 741 $mA/cm^2$, respectively for a WPhPLED with an $Ir(ppy)_3$ concentration of 5.0 vol.%. The CIE color coordinates were about x=0.33 and y=0.34 at 11V, showing a good white color.

연속파형 Nd:YAG 레이저를 이용한 SCM4강의 표면경화에 관한 연구 (A Study on the Surface Hardening of SCM4 Steel Using a Continuous Wave Nd:YAG Laser)

  • 나기대;신병헌;신호준;유영태
    • 한국공작기계학회논문집
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    • 제16권5호
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    • pp.24-32
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    • 2007
  • Laser surface hardening is beneficially used for surface treatment of structural steel. Due to very rapid heating and cooling rates, structural low-alloy steel(SCM4) can be hardened as self quenching. The aim of this research project is to improve the influence of the process laser parameters: laser power, spot size, surface roughness, and traverse speed. The laser beam is allowed to scan on the surface of the workpiece at the constant power(1095W), varying the traverse speed at 0.3m/min, 0.5m/min and 0.8m/min. The optical lens with the elliptical profile is designed to obtain a wide surface hardening area with uniform hardness. From the results of the experiment, it has been shown that the stable hardness is about 600$\sim$700Hv, when the laser power, focal position and the traverse speed are P=1095W, z=0mm and v=0.3m/min.

Tm3+ 도핑에 따른 YTa7O19의 형광특성 (Luminescence Properties of YTa7O19 doped with Tm3+)

  • 류호진;박희동
    • 공업화학
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    • 제8권4호
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    • pp.637-639
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    • 1997
  • 본 연구에서는 고상반응에 의하여 $Tm^{3+}$를 도핑한 $YTa_7O_{19}$를 제조하고, 이들에 대한 빛발광 특성을 조사하였다. 시료의 특성평가에는 XRD, SEM 및 PL을 사용하였다. 359 nm의 여기하에서, $Tm^{3+}$를 도핑한 $YTa_7O_{19}$의 발광 스팩트럼은 455 nm에서 피크를 나타내며, 매우 좁은 발광밴드를 갖는 청색 형광체가 얻어졌다. $YTa_7O_{19}$의 최대발광강도는 $Tm^{3+}$의 농도를 0.12몰 도핑하였을 때 얻어졌으며, 이는 발광강도의 농도퀀칭과 관련이 있다.

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유무기 페로브스카이트 나노입자의 휘발성 유기화합물 감응특성 (Detection of Volatile Organic Compounds (VOCs) using Organic-Inorganic Hybrid Perovskite Nanoparticles)

  • 최한솔;최지훈
    • 한국재료학회지
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    • 제30권10호
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    • pp.515-521
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    • 2020
  • Organic-inorganic hybrid perovskite nanocrystals have attracted a lot of attention owing to their excellent optical properties such as high absorption coefficient, high diffusion length, and photoluminescence quantum yield in optoelectronic applications. Despite the many advantages of optoelectronic materials, understanding on how these materials interact with their environments is still lacking. In this study, the fluorescence properties of methylammonium lead bromide (CH3NH3PbBr3, MAPbBr3) nanoparticles are investigated for the detection of volatile organic compounds (VOCs) and aliphatic amines (monoethylamine, diethylamine, and trimethylamine). In particular, colloidal MAPbBr3 nanoparticles demonstrate a high selectivity in response to diethylamine, in which a significant photoluminescence (PL) quenching (~ 100 %) is observed at a concentration of 100 ppm. This selectivity to the aliphatic amines may originate from the relative size of the amine molecules that must be accommodated in the perovskite crystals structure with a narrow range of tolerance factor. Sensitive PL response of MAPbBr3 nanocrystals suggests a simple and effective strategy for colorimetric and fluorescence sensing of aliphatic amines in organic solution phase.

Characteristics of 14K white gold by age-hardening treatment

  • 윤돈규;서진교;신소라;박종완
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2012년도 춘계학술발표대회
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    • pp.107.1-107.1
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    • 2012
  • Because of beautiful glossy and color, the value of gold leverage is very high in Europe. For improve the quality of white gold, we performed heat treatment on 14K white gold alloys at various age-hardening conditions. Age-hardening behavior and the related phase transformation changes were studied to elucidate the hardening mechanism of 14K white gold alloys. For solid solution treatment [ST], casted 14K white gold alloy specimens were treated at high temperature ($750^{\circ}C$) during 30 minute, and the specimens dropped to water for quenching immediately. For Age-hardening treatment [AT], the specimens were treated at various temperatures ($250^{\circ}C{\sim}300^{\circ}C$). After the heat treatment, we observed increased hardness from 144 Hv to 214 Hv by Vicker's hardness tester. Variation of the grain size measured by optical microscopy (OM) and scanning electron microscopy (SEM) images. By electron probe micro-analysis (EPMA) mapping analysis, we investigated that irregular particles were changed uniformly. After heat treatment, 14K white gold alloys showed improved hardness and became uniformity of grain size by age-hardening treatment.

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Structural and Optical Properties of Yellow-Emitting CaGd2ZrSc(AlO4)3:Ce3+ Phosphor for Solid-State Lighting

  • Kim, Yoon Hwa;Kim, Bo Young;Viswanath, Noolu S.M.;Arunkumar, Paulraj;Im, Won Bin
    • 한국세라믹학회지
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    • 제54권5호
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    • pp.422-428
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    • 2017
  • Single-phase yellow phosphor, $CaGd_{2-x}ZrSc(AlO_4)_3:xCe^{3+}$ ($CGZSA:Ce^{3+}$), possessing cubic symmetry with varied $Ce^{3+}$ concentrations, was synthesized using the solid-state reaction method. The samples were characterized using X-ray diffraction (XRD), excitation spectra, emission spectra, thermal quenching, and decay curves. The cubic phase of $CGZSA:Ce^{3+}$ phosphor was confirmed via XRD analysis. The photoluminescence spectra of $CGZSA:Ce^{3+}$ phosphor demonstrated that the phosphor could be excited at the wavelength of 440 nm; a broad yellow emission band was centered at 541 nm. These results indicate that the phosphors are adequately excited by blue light and have the potential to function as yellow-emitting phosphors for applications in white light-emitting diodes.

SM45C의 레이저 표면경화특성 (Laser surface hardening characterization of SM45C)

  • 신호준;유영태;안동규;임기건
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 2005년도 춘계학술대회 논문집
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    • pp.246-251
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    • 2005
  • Laser surface hardening is an effective technique used to improve the tribological properties and also to increase the service life of automobile components such as camshafts, crankshatfs, lorry brake drums and gears. High power $CO_2$ lasers and Nd:YAG lasers are employed for localized hardening of materials and hence are of potential application in the automobile industries. The heat is conducted rapidly into the bulk of the specimen causing self-quenching to occur and the formation of martensitic structure. In this investigation, the microstructure features occurring in Nd:YAG laser hardening SM45C steel are discussed with the use of optical microscopic and scanning electron microscopic analysis. Moreover, This paper describes the optimism of the processing parameters for maximum hardened depth of SM45C steel specimens of 3mm thickness by using CW Nd:YAG laser. Travel speed was varied from 0.6m/min to 1.0m/min. The maximum hardness and case depth fo SM45C steel are 780Hv and 0.4mm by laser hardening.

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