• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 1999년도 추계학술대회 논문집
• /
• pp.464-467
• /
• 1999

The undoped-InSe and Sn-doped InSe single crystals were grown by vertical Bridgman method and their properties were invesigated. The orientations and the crystallinites of these crystals were identified by X-ray diffraction(XRD), double crystal rocking curve(DCRC) and etch-pit density(EPD) measurements. From the Raman spectrum at room temperature, TO, LO modes and together with their overtones and combinations were observed. Optical properties were inves ated by PL at 12K and direct band gap of these crystals obtained from optical absorption spectrum. Compared with undo&-InSe, electrical properties of Sn-doped InSe were increased and the electrical conductivity type were n-type. But electrical properties along growth direction of crystals and radial direction of wafer showed nearly uniform distribution. The Zn diffusion mechanism in InSe could be explained by interstitial-substitutional and vacancy complex models and the activation energy of 1.15-3.01eV were needed for diffusion.fusion.

• Journal of the Optical Society of Korea
• /
• 제18권3호
• /
• pp.274-282
• /
• 2014

In this study, closely spaced Au nanoparticles which are arranged in nanocluster (heptamer) configurations have been employed to design efficient plasmonic subwavelength devices to function at the telecommunication spectrum (${\lambda}$~1550 nm). Utilizing two kinds of nanoparticles, the optical properties of heptamer clusters composed of Au rod and shell particles that are oriented in triphenylene molecular fashion have been investigated numerically, and the cross-sectional profiles of the scattering and absorption of the optical power have been calculated based on a finite-difference time-domain (FDTD) method. Plasmon hybridization theory has been utilized as a theoretical approach to characterize the features and properties of the adjacent and mutual heptamer clusters. Using these given nanostructures, we designed a complex four-branch ($1{\times}4$) Y-shape splitter that is able to work at the near infrared region (NIR). This splitter divides and transmits the magnetic plasmon mode along the mutual heptamers arrays. Besides, as an important and crucial parameter, we studied the impact of arm spacing (offset distance) on the guiding and dividing of the magnetic plasmon resonance propagation and by calculating the ratio of transported power in both nanorod and nanoshell-based structures. Finally, we have presented the optimal structure, that is the four-branch Y-splitter based on shell heptamers which yields the power ratio of 23.9% at each branch, 4.4 ${\mu}m$ decaying length, and 1450 nm offset distance. These results pave the way toward the use of nanoparticles clusters in molecular fashions in designing various efficient devices that are able to be efficient at NIR.

• 한국전기전자재료학회논문지
• /
• 제14권2호
• /
• pp.133-138
• /
• 2001

We studied the optical properties of poly(3-hexylthiophene) for applying to the emitting material of organic electro luminescent device. The infrared spectrum and NMR of synthesized polymer gave good evidence for the conjugation of 3-hexylthiophene monomer unit. We confirmed that poly(3-hexylthiophene) contains the HT(head-to-tail)-HT(head-to-Tail) linkage larger than 65% based on NMR analysis. FTIR and raman spectroscopy show that poly(3-hexylthiophene) has two main vibration levels which have an energy about 0.18eV and 0.36eV. Electronic absorption spectra shifted to the shorter wavelength with increasing temperature, which is related to a conformational transition of the polymer. Photoluminescence spectrum generated at low temperature(10K) is separated at 669nm, 733nm and 812nm that it's because of phonon energy generated from the lattice vibration.

• Bulletin of the Korean Chemical Society
• /
• 제10권1호
• /
• pp.5-8
• /
• 1989

Conventional ceramic method has been used to prepare the green phase, $Y_2BaCuO_5$, commonly observed in 90-K superconductor $YBa_2Cu_3O_P{7-{\delta}}$as an impurity phase. The powder X-ray diffraction analysis indicates that $Y_2BaCuO_5$ has an orthorhombic symmetry with lattice parameter of a = 12.2 $\AA$, b = 5.61 $\AA$, and c = 7.14 $\AA.$ The average g-value 2.13 observed in ESR spectrum is attributable to Cu2+ stabilized in $C_{4v}$ field. From the magnetic susceptibility ($\mu$eff = 2.29 BM) and the ESR measurements, it is confirmed that Cu(II) $3d^9$ electrons in $Y_2BaCuO_5$ are localized and can be characterized by Curie-Weiss behavior. Optical reflectance spectrum shows a broad absorption peak around 680 nm due to dxy ${\rightarrow}$ $dx^2-y^2$ eletronic transition.

• 대한원격탐사학회:학술대회논문집
• /
• 대한원격탐사학회 2006년도 Proceedings of ISRS 2006 PORSEC Volume I
• /
• pp.479-482
• /
• 2006

The absorption coefficient and backscattering properties of phytoplankton were calculated from the Mie theory. Given a simple case that phytoplankton and mineral particles are the only constitutions in seawater, the reflectance $b_b({\lambda})/[a({\lambda})+b_b({\lambda})]$was analyzed. Then the chlorophyll concentrations were estimated from remote sensing OC2 algorithm. The results show that reflectance in short wavelength region is more sensitive to the Chl variation; High mineral concentrations in seawater have significant influence on the reflectance spectrum; the existence of high mineral concentration may result in the mistake in chlorophyll estimation from OC2 algorithm.

• Rapid Communication in Photoscience
• /
• 제4권2호
• /
• pp.34-36
• /
• 2015

New spectroscopic characteristics of amorphous ferric hydroxide ($Fe(OH)_3$), interestingly in the near infrared (NIR) region, are presented in this study. The absorption spectrum of ferric hydroxide covers wide spectral regions from ultraviolet to NIR (200~900 nm). Unique emission bands were newly observed in the NIR regions (800~1400 nm). Several bands of this NIR emission are quiet well overlapped with the combinational vibrational absorption bands of water. From photothermal conversion study, very interestingly, temperature of aqueous mixture solution including the amorphous ferric hydroxide was significantly increased from ambient temperature to $38^{\circ}C$ for 30 minutes under irradiation of a standard helium lamp.

• 천문학회보
• /
• 제41권1호
• /
• pp.38.1-38.1
• /
• 2016

Gamma ray burst, the most brightest explosion phenomena in the current universe is well suited for study of high redshift universe. We report the afterglow multi-wavelength observation and GTC spectroscopy follow up of GRB 140304A which was exploded at z=5.283. The spectrum was shown damped Lyman alpha features and a series of absorption lines S, Si, SiII*, Oi, CII, CII*, SiIV are clearly detected at common redshift. Clear optical flares are detected when X-ray flare happened and a possible gamma-ray excess also. At this conference, we report on implications for the GRB host and environments using its absorption features which place the results in context to other well studied high redshift GRBs and studies about the ejecta using its observed flaring activities.

• 대한원격탐사학회지
• /
• 제39권5_1호
• /
• pp.551-561
• /
• 2023

본 연구에서는 Pandora spectrometer system의 태양 직달광 관측 자료로부터 차등흡수분광법(differential optical absorption spectroscopy, DOAS)을 이용하여 포름알데히드(formaldehyde)의 경사칼럼농도(slant column density, SCD)를 산출할 때 스펙트럼 피팅(spectrum fitting) 파장 구간 및 흡수단면적이 산출에 미치는 영향을 조사하였다. 2022년 10월 12일에서 31일까지 서울 연세대학교에서 관측한 Pandora Level 1 자료를 사용하였다. The second Cabauw Intercomparison campaign for Nitrogen Dioxide measuring Instruments (CINDI-2)에서 사용하는 스펙트럼 피팅 파장 구간을 포함한 8가지 범위 및 흡수단면적 구성 7종을 기반으로 포름알데히드 칼럼농도를 산출하였다. 스펙트럼 피팅 파장 구간은 8가지 범위 중 336.5-359.0 nm 구간에서 피팅 후 잔여 신호와 포름알데히드 산출 오차가 최소로 확인되었다. 흡수단면적 구성 7종 중 CINDI-2 캠페인에서 사용하는 흡수단면적에 이산화질소 흡수단면적(220 K)을 추가하여 사용한 경우에 피팅 후 잔여 신호와 포름알데히드 산출 오차가 가장 작았으며 포름알데히드 농도가 안정적으로 산출되었다. 산출 정확도가 가장 높은 경우의 평균 포름알데히드 경사칼럼농도와 그 외 조건들에서 산출된 값들은 최소 4%에서 최대 40%까지 차이를 보였다.

• 조명전기설비학회논문지
• /
• 제29권6호
• /
• pp.27-34
• /
• 2015

There has been a critical issue in optical simulation of phosphors in LEDs due to their light-reabsorption properties. To improve the accuracy of optical modeling for a white LED package, we utilized the spectrum data of the phosphor-dispersed encapsulant film instead of the phosphor powder. By measuring white LED packages with green and red phosphors, the maximum difference between simulation and experimental results of a color temperature, a color rendition index number and a color coordinate corresponds to ${\Delta}T=95K$, ${\Delta}Ra=1.7$ and ${\Delta}xy=0.007$, respectively. Based on those results, the proposed method can well explain the change of emission spectra of white LEDs with more than two phosphors which introduce the complex optical phenomena such as absorption, reabsorption, light emission, reflection and scattering, etc.

• 해양환경안전학회:학술대회논문집
• /
• 해양환경안전학회 2006년도 추계학술발표회
• /
• pp.187-191
• /
• 2006

적조 종에 따라 해색이 다르다는 점에 착안해 해색 모델로부터 적조 종을 역 추정하는 기술을 개발하는데 있어 기본 입력 변수가 되는 적조 생물에 관한 광학적 특성(흡수, 역산란 특성)을 연구하였다. 실험실 수준에서의 적조 생물의 광특성을 조사하기 위해서 남해에서 채취 된 21종의 적조 생물을 배양하고 spectrophotometer를 이용해 광합성 색소에 의한 흡수계수(absorption coefficient, a)와 역산란 계수 (backscattering coefficient, $b_b$)를 측정하였다. 또한 spectrophotometer를 이용해 측정된 흡수 및 역산란 계수와 클로로필 농도를 이용하여 비 흡광계수 $(a^*)$와 비역산란계수$(b_b^*)$를 계산하였으며 이들 스펙트럼의 모양과 값을 비교하였다. 적조 생물 종에 따른 $a^*$은 파장대 440nm 에서 $0.005-0.06m^2/mg$의 값을 가지며, $b_b^*$의 범위는 $10^{-2}\sim10^{-4}m^2/mg$로 종간 약 100배의 차이가 있었다. 이와 같이 적조생물 종에 따라 스펙트럼의 모양과 값에서 차이를 나타냈으며 21종의 적조 생물 중에서 해색 스펙트럼으로 종간 구분이 가능한 종은 7-8 종이었다. 이 결과는 해색모델 개발에 있어 입력변수로 활용될 것이다.