• Title/Summary/Keyword: Operation layer

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Investigating the Au-Cu thick layers Electrodeposition Rate with Pulsed Current by Optimization of the Operation Condition

  • Babaei, Hamid;Khosravi, Morteza;Sovizi, Mohamad Reza;Khorramie, Saeid Abedini
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.172-179
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    • 2020
  • The impact of effective parameters on the electrodeposition rate optimization of Au-Cu alloy at high thicknesses on the silver substrate was investigated in the present study. After ensuring the formation of gold alloy deposits with the desired and standard percentage of gold with the cartage of 18K and other standard karats that should be observed in the manufacturing of the gold and jewelry artifacts, comparing the rate of gold-copper deposition by direct and pulsed current was done. The rate of deposition with pulse current was significantly higher than direct current. In this process, the duty cycle parameter was effectively optimized by the "one factor at a time" method to achieve maximum deposition rate. Particular parameters in this work were direct and pulse current densities, bath temperature, concentration of gold and cyanide ions in electrolyte, pH, agitation and wetting agent additive. Scanning electron microscopy (SEM) and surface chemical analysis system (EDS) were used to study the effect of deposition on the cross-sections of the formed layers. The results revealed that the Au-Cu alloy layer formed with concentrations of 6gr·L-1 Au, 55gr·L-1 Cu, 24 gr·L-1 KCN and 1 ml·L-1 Lauryl dimethyl amine oxide (LDAO) in the 0.6 mA·cm-2 average current density and 30% duty cycle, had 0.841 ㎛·min-1 Which was the highest deposition rate. The use of electrodeposition of pure and alloy gold thick layers as a production method can reduce the use of gold metal in the production of hallow gold artifacts, create sophisticated and unique models, and diversify production by maintaining standard karats, hardness, thickness and mechanical strength. This will not only make the process economical, it will also provide significant added value to the gold artifacts. By pulsating of currents and increasing the duty cycle means reducing the pulse off-time, and if the pulse off-time becomes too short, the electric double layer would not have sufficient growth time, and its thickness decreases. These results show the effect of pulsed current on increasing the electrodeposition rate of Au-Cu alloy confirming the previous studies on the effect of pulsed current on increasing the deposition rate of Au-Cu alloy.

A Study on the Characteristics of Wastewater Treatment by Rapid Infiltration Using Sand Soil (사토(砂土)를 이용(利用)한 급속토양삼투법(急速土壤滲透法)의 폐수처리(廢水處理) 특성(特性)에 관한 연구(研究))

  • Yang, Sang Hyon;Cho, Woong Hyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.23-31
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    • 1987
  • In land treatment systems for organic waste removal, especially rapid intiltration method is well known as less climatic restrictions and less field area requirements as against the others. Therefore the present study on rapid infiltration is aimed to survey the waste removal rate, infiltration rate, variation of dissolved oxygen due to biological oxygen absorption and pH decrement using pilot infiltration column filled with permeable soil(sand) as media, also to find the waste load(COD) per unit area and nitrate conversion ratio from TKN. The results obtained here are as follows. 1) When the depth of sand layer is more than 1 meter, the COD removal would be reached steadly to 90% or more under the infiltration rate below 15~20cm/day, and would be no problem due to leached organic pollutants considering the depth of ground water table. 2) The COD removal per unit area($m^2$) can readily be expected to 10~14g/day with proper operation, and the decomposition of substrate would be attained mostly at the surface layer of the media. 3) Generally the conversion of TKN to the $NO_3{^-}$-N is seemed to be proportional to the COD removal rate if provided proper retention time.

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Study on Concrete Activation Reduction in a PET Cyclotron Vault

  • Bakhtiari, Mahdi;Oranj, Leila Mokhtari;Jung, Nam-Suk;Lee, Arim;Lee, Hee-Seock
    • Journal of Radiation Protection and Research
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    • v.45 no.3
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    • pp.130-141
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    • 2020
  • Background: Concrete activation in cyclotron vaults is a major concern associated with their decommissioning because a considerable amount of activated concrete is generated by secondary neutrons during the operation of cyclotrons. Reducing the amount of activated concrete is important because of the high cost associated with radioactive waste management. This study aims to investigate the capability of the neutron absorbing materials to reduce concrete activation. Materials and Methods: The Particle and Heavy Ion Transport code System (PHITS) code was used to simulate a cyclotron target and room. The dimensions of the room were 457 cm (length), 470 cm (width), and 320 cm (height). Gd2O3, B4C, polyethylene (PE), and borated (5 wt% natB) PE with thicknesses of 5, 10, and 15 cm and their different combinations were selected as neutron absorbing materials. They were placed on the concrete walls to determine their effects on thermal neutrons. Thin B4C and Gd2O3 were placed between the concrete wall and additional PE shield separately to decrease the required thickness of the additional shield, and the thermal neutron flux at certain depths inside the concrete was calculated for each condition. Subsequently, the optimum combination was determined with respect to radioactive waste reduction, price, and availability, and the total reduced radioactive concrete waste was estimated. Results and Discussion: In the specific conditions considered in this study, the front wall with respect to the proton beam contained radioactive waste with a depth of up to 64 cm without any additional shield. A single layer of additional shield was inefficient because a thick shield was required. Two-layer combinations comprising 0.1- or 0.4-cm-thick B4C or Gd2O3 behind 10 cm-thick PE were studied to verify whether the appropriate thickness of the additional shield could be maintained. The number of transmitted thermal neutrons reduced to 30% in case of 0.1 cm-thick Gd2O3+10 cm-thick PE or 0.1 cm-thick B4C+10 cm-thick PE. Thus, the thickness of the radioactive waste in the front wall was reduced from 64 to 48 cm. Conclusion: Based on price and availability, the combination of the 10 cm-thick PE+0.1 cmthick B4C was reasonable and could effectively reduce the number of thermal neutrons. The amount of radioactive concrete waste was reduced by factor of two when considering whole concrete walls of the PET cyclotron vault.

Properties analysis of environment friendly calcareous deposit films electrodeposited at various temperature conditions in natural seawater (천연해수 중 온도 변화에 따라 전착한 환경친화적인 석회질 피막의 특성 분석)

  • Lee, Chan-Sik;Kang, Jun;Lee, Myeong-Hoon
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.7
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    • pp.779-785
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    • 2015
  • Cathodic protection is recognized as the most cost-effective and technically appropriate corrosion prevention method for the submerged zone of offshore structures, ships, and deep-sea facilities. When cathodic protection is applied, the cathodic currents cause dissolved oxygen reduction, generating hydroxyl ions near the polarized surface that increase the interfacial pH and result in enhanced carbonate ion concentration and precipitation of an inorganic layer whose principal component is calcium carbonate. Depending on the potential, magnesium hydroxide can also precipitate. This mixed deposit is generally called "calcareous deposit." This layer functions as a barrier against the corrosive environment, leading to a decrease in current demand. Hence, the importance of calcareous deposits for the effective, efficient operation of marine cathodic protection systems is recognized by engineers and scientists concerned with cathodic protection in submerged marine environments. Calcareous deposit formation on a marine structure depends on the potential, current, pH, temperature, pressure, sea-water chemistry, flow, and time; deposit quality is significantly influenced by these factors. This study determines how calcareous deposits form in sea water, and assesses the interrelationship of formation conditions (such as the sea water temperature and surface condition of steel), deposited structure, and properties and the effectiveness of the cathodic protection.

Acoustic Target Strength of the Pelagic Fish in the Southern Waters of Korea I. In situ Measurement of Target Strength of Anchovy (Engraulis japonica) (한국 남해안 부어류의 음향반사강도에 관한 연구 I. 멸치 (Engraulis japonica)의 in situ 반사강도 측정)

  • YOON Gab Dong;KIM Zang Geun;CHOI Young Min
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.29 no.1
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    • pp.107-114
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    • 1996
  • The in situ target strength for the anchovy (Engraulis japonica) were measured by the split beam echo sounder system at 38 kHz. This study allowed us to detect the single echos from anchovy shoals which were dispersed during trawling operation in day time. The results of our study were as fellows: We found that the anchouy occupied about $95\%$ of the total catch from the detected shoals from which target strength data were collected. Length distribution of anchovy showed a mode and ranged from 13.6 to 15.4cm with a mean of 14.4cm and a standard deviation of 0.45cm, and weight distribution showed a mode and ranged from 16 to 28 g witha mean of 21.9 g and a standard deviation of 2.7 g. The target strength distribution of anchovy ranged from -40.7 dB to -69.2 dB in the water layer of ,$10\~30\;m$ -42.19 to -67.7 dB in the $30\~50\;m$ and -42.2 to -67.7 dB in $10\~50\;m$, showing 2 modes in each layer, respectively. Overall mean target strengths were -49.7 dB/fish and -33.1 dB/kg, averaged by area backscattering cross section $(\sigma)$, and the confidence interval for target strength was less than 1 dB. With the mean total length and the mean target strength, we drived the target strength-length relationship as $TS(\sigma)=20\;Log\;L-72.9$.

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A Study on the Silica Removal in Primary System using the Membrane Process (막 분리 공정을 이용한 1차 계통 실리카 제거에 관한 연구)

  • Kim Bong-Jin;Lee Sang-Jin;Yang Ho-Yeon;Kim Kyung-Duk;Jung Hee-Chul;Jo Hang-Rae
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.137-144
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    • 2005
  • Silica in primary system combines with an alkali grammatical particle metal and forms the zeolite layer which is hindering the heat transfer on the surface of the cladding. Zeolite layer becomes the cause of the damage in this way. The problems of the NPP's primary system have been issued steadily by EPRI. Through a series of experiments of the laboratory scale, we confirmed the applicability of NF membrane for silica removal, as silica rejection rate of NF membrane is about $60\;{\sim}\;70\%$ and boron rejection rate is about $10\;{\sim}\;20\%$. We accomplished a site experiment about four NF membranes manufactured by FilmTec and Osmonics Inc. In experiment using 400L of SFP water, when operation pressure is $10kg_{f}/cm^2$, we confirmed that the silica rejection rate of NF90-2540 manufactured by FilmTec Inc. is about $98\%$, boron rejection rate is about $43\%$. The silica rejection rate of NF270-2540 is about $38\%$, boron rejection rate is about $3.5\%$. Afterward, through additional experiments, such as long term characteristic experiments, we are going to design a optimum NF membrane system for silica removal.

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COMPARISON OF DIFFUSION COEFFICIENTS AND ACTIVATION ENERGIES FOR AG DIFFUSION IN SILICON CARBIDE

  • KIM, BONG GOO;YEO, SUNGHWAN;LEE, YOUNG WOO;CHO, MOON SUNG
    • Nuclear Engineering and Technology
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    • v.47 no.5
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    • pp.608-616
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    • 2015
  • The migration of silver (Ag) in silicon carbide (SiC) and $^{110m}Ag$ through SiC of irradiated tristructural isotropic (TRISO) fuel has been studied for the past three to four decades. However, there is no satisfactory explanation for the transport mechanism of Ag in SiC. In this work, the diffusion coefficients of Ag measured and/or estimated in previous studies were reviewed, and then pre-exponential factors and activation energies from the previous experiments were evaluated using Arrhenius equation. The activation energy is $247.4kJ{\cdot}mol^{-1}$ from Ag paste experiments between two SiC layers produced using fluidized-bed chemical vapor deposition (FBCVD), $125.3kJ{\cdot}mol^{-1}$ from integral release experiments (annealing of irradiated TRISO fuel), $121.8kJ{\cdot}mol^{-1}$ from fractional Ag release during irradiation of TRISO fuel in high flux reactor (HFR), and $274.8kJ{\cdot}mol^{-1}$ from Ag ion implantation experiments, respectively. The activation energy from ion implantation experiments is greater than that from Ag paste, fractional release and integral release, and the activation energy from Ag paste experiments is approximately two times greater than that from integral release experiments and fractional Ag release during the irradiation of TRISO fuel in HFR. The pre-exponential factors are also very different depending on the experimental methods and estimation. From a comparison of the pre-exponential factors and activation energies, it can be analogized that the diffusion mechanism of Ag using ion implantation experiment is different from other experiments, such as a Ag paste experiment, integral release experiments, and heating experiments after irradiating TRISO fuel in HFR. However, the results of this work do not support the long held assumption that Ag release from FBCVD-SiC, used for the coating layer in TRISO fuel, is dominated by grain boundary diffusion. In order to understand in detail the transport mechanism of Ag through the coating layer, FBCVD-SiC in TRISO fuel, a microstructural change caused by neutron irradiation during operation has to be fully considered.

Relationship between the Catch of Squid, Todarodes pacificus STEENSTRUP, According to the Jigging Depth of Hooks and Underwater Illumination in Squid Jigging Boat (소형 오징어 채낚기 어선의 낚시 깊이별 조획량과 수중 조도)

  • CHOI Sok-Jin;ARAKAWA Hisayuki
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.6
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    • pp.624-631
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    • 2001
  • The relationship between the catch of squid, Todarodes pacificus, according to the jigging depth and underwater illumination by fishing lamps was investigated during nighttime operations off-Tusima Islands in November 1994 and off-Oki Islands in November 1995. We used echo sounder to observe the distribution of squid. Echo images on the echo sounder showed the distribution of squid at the water layer of 50 meter depth at the beginning of jigging operation. After the time elapsed, a continuous dense image had moved to the layer of 60-80 meters jigging depth. A larger number of squid were caught by jigging machines set at a lowest depth of 90 meters, when it compared with machines set at a 60 meters. However, Catch increased around 60 meters jigging depth, when fishing lamps output were switched to 24 kW halogen lights:.The underwater illumination, under the each light power of fishing lamps of squid jigging boat was continuously measured with an underwater illuminometer. Values of the underwater illumination, when schools were distributed from 60 to 80 meters, ranged from $3.0\times10^{-2}lx\;to\;3.4\times10^{-3}lx$ in average at $80\~360$ kW fishing lamps output of squid jigging boat.

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Index Management Method using Page Mapping Log in B+-Tree based on NAND Flash Memory (NAND 플래시 메모리 기반 B+ 트리에서 페이지 매핑 로그를 이용한 색인 관리 기법)

  • Kim, Seon Hwan;Kwak, Jong Wook
    • Journal of the Korea Society of Computer and Information
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    • v.20 no.5
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    • pp.1-12
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    • 2015
  • NAND flash memory has being used for storage systems widely, because it has good features which are low-price, low-power and fast access speed. However, NAND flash memory has an in-place update problem, and therefore it needs FTL(flash translation layer) to run for applications based on hard disk storage. The FTL includes complex functions, such as address mapping, garbage collection, wear leveling and so on. Futhermore, implementation of the FTL on low-power embedded systems is difficult due to its memory requirements and operation overhead. Accordingly, many index data structures for NAND flash memory have being studied for the embedded systems. Overall performances of the index data structures are enhanced by a decreasing of page write counts, whereas it has increased page read counts, as a side effect. Therefore, we propose an index management method using a page mapping log table in $B^+$-Tree based on NAND flash memory to decrease page write counts and not to increase page read counts. The page mapping log table registers page address information of changed index node and then it is exploited when retrieving records. In our experiment, the proposed method reduces the page read counts about 61% at maximum and the page write counts about 31% at maximum, compared to the related studies of index data structures.

A Design of AES-based WiBro Security Processor (AES 기반 와이브로 보안 프로세서 설계)

  • Kim, Jong-Hwan;Shin, Kyung-Wook
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.44 no.7 s.361
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    • pp.71-80
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    • 2007
  • This paper describes an efficient hardware design of WiBro security processor (WBSec) supporting for the security sub-layer of WiBro wireless internet system. The WBSec processor, which is based on AES (Advanced Encryption Standard) block cipher algorithm, performs data oncryption/decryption, authentication/integrity, and key encryption/decryption for packet data protection of wireless network. It carries out the modes of ECB, CTR, CBC, CCM and key wrap/unwrap with two AES cores working in parallel. In order to achieve an area-efficient implementation, two design techniques are considered; First, round transformation block within AES core is designed using a shared structure for encryption/decryption. Secondly, SubByte/InvSubByte blocks that require the largest hardware in AES core are implemented using field transformation technique. It results that the gate count of WBSec is reduced by about 25% compared with conventional LUT (Look-Up Table)-based design. The WBSec processor designed in Verilog-HDL has about 22,350 gates, and the estimated throughput is about 16-Mbps at key wrap mode and maximum 213-Mbps at CCM mode, thus it can be used for hardware design of WiBro security system.