• Bulletin of the Korean Chemical Society
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• 제33권12호
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• pp.4122-4126
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• 2012

Cellulose-graft-poly (L-lactide) (cellulose-g-PLLA) was successfully prepared via ring-opening polymerization (ROP) by using 4-dimethylaminopyridine (DMAP) as an organic catalyst in an ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). The structure and morphology of the polymer was characterized by nuclear magnetic resonance (NMR) and transmission electron microscope (TEM). From wide-angle X-ray powder diffraction (WAXD) and degradation test (by acid, alkaline, PBS and enzyme solution), changes in the crystalline structure as a result of degradation was also investigated. The results indicated that materials which have low degree of crystallinity showing higher degradability, however, in acid liquor, enzyme solution, alkaline liquor and PBS system, the degradation rate of the polymer decreased by the above sequence. Moreover, with the further increase of graft degree of this material, its degradation degree decreased.

• 교육시설
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• 제16권1호
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• pp.59-68
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• 2009

In the knowledge-base 21st century, schools are required functions as a place of education for student as well as a place of life-long education for community. Therefore schools are needed to be open and to be multiple. The purpose of this study is to analysis of open-facilities to community of twenty elementary schools in Busan and to suggest a design guideline for open -facilities of school plan at the base of this analysis. The main contents of this study are as follows: 1) Study for general ideals and necessity of opening school facilities to community. 2) Establish the study objects of the opening facilities by existing studies and a questionnaire. 3) Focused on twenty elementary schools in Busan, analysis of the characteristics of opening facilities in terms of the using efficiency, that is, the approachability, the recognition and the territoriality. 4) At the base of 1) 2) 3), results are as follows: $\circ$ In consideration of approachability, the block plan of the open-facilities should be designed at making a circulation system without interruption of the student's educational area. $\circ$ In consideration of recognition, the form and detail of external and internal of the open-facilities should be designed at making distinction with the student's educational area. $\circ$ In consideration of territoriality, the zone of the open-facilities should be designed at composing exclusive hall, staircase and sanitation.

• Macromolecular Research
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• 제16권2호
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• pp.155-162
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• 2008

We report the successful synthesis of poly(NBECOOH-b-NBEPOSS) copolymers, taking advantage of the sequential, living ring opening metathesis polymerization of NBETMS and NBEPOSS using the $RuCl_2(=CHPh)(PCY_3)_2$/$CH_2Cl_2$/$20^{\circ}C$ system, followed by the hydrolysis of trimethylsilyl groups in poly(NBETMS-b-NBEPOSS) copolymers. The living behavior of ROMP of NBETMS was first investigated using two diagnostic plots, a first order kinetic plot and a $\bar{M}_n$ vs. conversion plot. The plots confirmed that no termination and chain transfer reaction had occurred during polymerization. Poly(NBECOOH-b-NBEPOSS) copolymers were prepared using the sequential monomer addition of NBEPOSS to living poly(NBETMS) chain ends, followed by the hydrolysis of trimethylsilyl groups in the poly(NBETMS-b-NBEPOSS) copolymers. The high structural integrity of poly(NBE-COOH-b-NBEPOSS) copolymers was confirmed by $^1H$-NMR, $^{13}C$-NMR spcctroscopy and GPC.

• 한국추진공학회지
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• 제9권2호
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• pp.70-77
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• 2005

축소-팽창 디퓨저가 장착된 초음속 이젝터를 제작하여, 다양한 위치에서의 측정된 압력으로 부유동의 초음속 시동조건을 찾아내었다. 우선 부유동 흡입구의 크기의 영향을 알아내기 위하여 다양한 흡입구 직경으로 실험하였으며, 부유동의 초음속 시동은 흡입구 직경과 축소-팽창 디퓨저 직경의 비, d/D가 0.306 미만인 경우에만 일어났다. 이보다 큰 d/D에서는, 아음속 시동이 먼저 시작되고, 흡입구를 막으면서 주유동의 유입이 전 유동장을 채우게 되어 수직 충격파를 축소-팽창 디퓨저의 하류로 내려보내게 된다 이러한 상황에서 다시 흡입구를 열어도 히스테리시스의 영향으로 초음속 시동이 유지된다.

• 한국구조물진단유지관리공학회 논문집
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• 제24권6호
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• pp.138-145
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• 2020

본 연구는 강재 단순보의 유공보 시스템에서 개구부를 지지점 에 근접한 위치에 설치하는 경우에 대하여 구조성능을 파악하고자 실험을 실시하였다. 또한 수직·수평 강판을 이용한 개구부 보강에 대하여도 실험을 통하여 구조성능을 파악하였다. 강재 단순보에서 개구부가 지지점에 근접한 위치인 강재보 높이의 절반(D/2)인 경우에 강재보 높이(D)인 경우보다 적절한 개구부 위치인 것을 알 수 있었다. 또한 보강방법으로는 수직강판 보강보다는 수평강판 보강이 보강효과가 크며, 개구부와 강판의 간격이 없는 것이 구조성능이 더 큰 결과를 얻을 수 있었다.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2011년도 정기총회 및 추계학술대회 논문집
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• pp.517-544
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• 2011

Promote competition in local government and the construction of a subway construction in the vicious cycle of debt due to the operating deficit as a greater burden on local finances was leave. This government policy of public transport in the center of the metro construction costs affordable and to respond appropriately to public transport demand new transit LRT(Light rail Transit) by introducing the current Busan was the opening of Line 4, yongin line, Busan - Gimhae line, parliamentary and barge construction or ready for the opening. What is light rail, compared to the existing subway and cheaper construction cost, the existing road or bridge that runs along the track is installed, etc. Manless system construction cost and operating expenses as a possible new railway transportation has been a leading state-of-the-art mad. However, the domestic business system engineering of light rail-related companies in the developed countries are doing to advance to the national to the local engineering skills of the self-free, hurry will have to be secured. Therefore, this paper applies local light rail project on the status of the systems engineering analysis and based on this source of the latest engineering technology-intensive systems engineering to provide direction to the development of technology.

• 한국수소및신에너지학회논문집
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• 제31권3호
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• pp.307-313
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• 2020

The 3.9 liter diesel engine with a mechanical fuel injection system was converted to di-methyl ether (DME) engine and performance optimized. In order to switch to the DME engine, the plunger of the high pressure fuel pump was replaced and the diameter of the injector nozzle was increased. Through this, the disadvantage of DME having low calorific value per volume can be compensated. To optimize the performance, the number of injector nozzle holes, injector opening pressure, and fuel injection timing were changed. As a result, the optimum number of injector nozzle holes was 5, the injector opening pressure was from 15 MPa to 18 MPa, and the injection timing was 15 crank angle degree before top dead center (CAD BTDC). The power was at the same level as the base diesel engine and nitrogen oxides (NOx) emissions could be reduced.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.1-4
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• 2008

Fuel cells have the potential of providing several times higher energy storage densities than those possible using current state-of-the-art lithium-ion batteries, but current energy density of fuel cell system is not better than that of lithium-ion batteries. To achieve the high energy density, volume and weight of fuel cell system need to be reduced by miniaturizing system components such as stack, fuel tank, and balance-of-plant. In this paper, the thin flexible PCB (Printed circuit board) is used as a current collector to reduce the stack volume. Two end plates are made from light weight aluminum alloy plate. The plate surface is wholly oxidized through the anodizing treatment for electrical insulation. The opening rate of cathode plate hole is optimized through unit cell performance measurement of various opening rates. The performances are measured at room temperature and ambient pressure condition without any repulsive air supply. The active area of MEA is 10.08 $cm^2$ and active area per a unit cell is 1.68 $cm^2$. The peak power density is about 210 mW/$cm^2$ and the air-breathing planar stack of 2 Wis achieved as a small volume of 18 cc.

• 한국화재소방학회논문지
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• 제23권5호
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• pp.84-89
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• 2009

본 연구에서는 미분무수 노즐을 이용하여 소화시간에 영향을 미치는 인자들을 변화시키며 소화실험을 수행하였다. 주요 인자는 화염의 위치와 노즐 중심으로부터의 거리, 미분무 입자의 크기, 노즐의 설치 높이, 개구부 여부 등이었다. 소화실험 결과로부터 각 인자들 간의 상호작용과 소화에 대한 민감도를 Mini tab을 이용하여 분석하여 미분무수 소화시스템의 최적 소화모델을 도출하였다. 소화시간에 가장 큰 영향을 미치는 인자는 노즐 중심으로부터의 거리이며 개구부의 여부는 다른 인자들에 비하여 소화시간에 미치는 영향도가 적게 나타났다.

• 설비공학논문집
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• 제23권8호
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• pp.562-570
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• 2011

In this research, an experimental study is performed to investigate the effects of system operating variables on the cooling and heating characteristics of heat pump system using geothermal heat source and carbon dioxide as a refrigerant. System variables analyzed include compressor frequency, electronic expansion valve opening, refrigerant charge, secondary fluid temperature and flow rate. Results show that optimum refrigerant charge and electronic expansion valve opening position exist at the maximum point of COP curve, and both cooling and heating capacity increase but COPs decrease with the increase of compressor frequency. The change of a secondary fluid temperature leads to variation of overheat area and enthalpy difference in the evaporator and gas cooler. which again results in considerable variations of cooling and heating capacity and COP. In the case of effects of secondary water fluid flow rate, both cooling capacity and COP increase with the increase of secondary flow in evaporator or gas cooler, whereas heating capacity and COP decrease with the increase of flow rate in gas cooler.