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Performance of Magnesia Cement Using MgCO3 and Serpentine

  • Lee, Jong-Kyu;Soh, Jung-Sub
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.116-121
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    • 2016
  • The amount of carbon dioxide ($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical methods of reducing $CO_2$ in building materials is the addition of slag and fly ash, like pozzolan material another method is to reduce $CO_2$ production by developing carbon negative cement. MgO-based cement from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements can improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, basic research on magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as the main starting materials, as well as blast furnace slag for the mineral admixture, was carried out for industrial waste material recycling. In order to increase the overall hydration activity, $MgCl_2$ was also added. In the case of the addition of $MgCl_2$as accelerating admixture, there was a promoting effect on the compressive strength. This was found to be due to the production of needle-like dense Mg-Cl hydrates. Mgnesia cement has a high viscosity due to its high specific surface area therefore, when the PC-based dispersing agent was added at a level of more than 1.0%, it had the effect of improving fluidity. In particular, the addition of $MgCl_2$ in magnesia cement using $MgCO_3$and magnesium silicate ore (serpentine) as main starting materials led to a lower expansion ratio and an increase in the freeze-thaw resistance finally, the addition of $MgCl_2$ as accelerating admixture led to good overall durability.

Physical Properties of Artificial Interior stone Using Waste Resources (폐자원을 활용한 내장용 인조석재의 물리적 특성)

  • Yoo, Yong-Jin;Lee, Sang-Soo;Song, Ha-Young
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.3
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    • pp.237-243
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    • 2014
  • The environmental problem is serious due to global warming In a concrete industry, the effort to reduce the problem of the destruction of environment arising from the indiscriminate use of limestone that is the raw material of cement and aggregate and the exhaustion of resources are continually emphasized In this research, the waste porcelain and waste glass that are the natural aggregate substitute materials were mixed and were applied. In addition, the magnesia phosphate composite and fly ash are mixed with a cement substitute material and the properties of the artificial stone was examined. Density, water absorption, rate of aggregate on the surface, compressive strength, and flexural strength were performed. As a result of the test, it is that waste glass with 60% and waste porcelain with 70% are the most excellent mix to produce the artificial stone.

Effect of Initial Flexural Crack on Resistance to Chloride Penetration into Reinforced Concrete Members (초기 휨균열이 철근콘크리트 부재의 염화물침투저항성에 미치는 영향)

  • Yang, Eun Ik;Jin, Sang Ho;Kim, Myung Yu;Choi, Yoon Suk;Han, Sang Hun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.2
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    • pp.79-87
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    • 2011
  • In this study, the chloride penetration tests were performed for the initially cracked reinforced concrete members. The chloride diffusion characteristics and the critical crack width are compared, and the properties of self-healing are investigated. According to the test results, the chloride penetration resistance was greatly reduced as the surface crack width increased. When the mineral admixtures are added, the chloride penetration resistance of uncracked specimens were effectively increased, however, in case of the blast furnace slag and fly ash, the cracked specimens showed the more reduced resistance than OPC case, inversely. Also, the critical width was $29{\mu}m$, on average, for immersion test. The crack width with $4{\sim}15{\mu}m$ was restored by self-healing, The parts restored by self-healing were seemed to be visually restored, however, the chloride penetration resistance was not restored, perfectly.

Effect of magnesium sulphate solution on compressive strength and sorptivity of blended concrete

  • Jena, Trilochan;Panda, Kishor C.
    • Advances in concrete construction
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    • v.9 no.3
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    • pp.267-278
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    • 2020
  • This paper reports on the result of an experimental investigation carried out to study the compressive strength and sorptivity properties of blended cement concrete exposed to 5% and 10% MgSO4 solution using fly ash (FA) and silpozz. Usually in sulphate environment the minimum grade of concrete is M30 and the mix design is done for target mean strength of 39 MPa. Silpozz is manufactured by burning of agro-waste rice husk in designed furnace in between 600° to 700℃ which is one of the main agricultural residues obtained from the outer covering of rice grains during the milling process. There are four mix series taken with control mix. The control mix made 0% replacement of FA and silpozz with Ordinary Portland Cement (OPC). The first mix series made 0% FA and 10-30% replacement of silpozz with OPC. The second mix series made with 10% FA and 10-40% replacement of silpozz with OPC. The third mix series made 20% FA and 10-30% replacement of silpozz with OPC and the fourth mix series made 30% FA and 10-20% silpozz replaced with OPC. The samples (cubes) are prepared and cured in normal water and 5% and 10% MgSO4 solution for 7, 28 and 90 days. The studied parameters are compressive strength and strength deterioration factor (SDF) for 7, 28 and 90 days. The water absorption and sorptivity tests have been done after 28 days of normal water and magnesium sulphate solution curing. The investigation reflects that the blended cement concrete incorporating FA and silpozz showing better resistance against MgSO4 solution when compared to normal water curing (NWC) samples.

A New Method on the Prediction of Corrosion Resistance of Reinforced Concrete Using Accelerated Potentiometric Corrosion Method (전위차 부식촉진법을 이용한 철근 콘크리트의 내부식성 예측을 위한 새로운 기법 연구)

  • 오병환;조윤구;차수원;정원기
    • Magazine of the Korea Concrete Institute
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    • v.8 no.5
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    • pp.201-209
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    • 1996
  • Recently, large scale concrete structures exposed to severe environment are increasingly built in various locations. The corrosion may severely affect the durability and service life of such a concrete structure. It is, therefore, necessary to develop durable concrete to enhance the corrosion resistance. The corrosion resistance of concrete can be identified through accelerated corrosion test. The purpose of the present paper is, therefore, to devise a reasonable and accurate method to predict the amount of corrosion of reinforcing steels. The proposed method which is basically based on the concept of Faraday's Law, determines the corroded amount of a rebar according to accelerated corrosion time. The corrosion is accelerated by employing the potentiometric corrosion test arrangement. The effects of admixtures in concrete including fly ash and silica fume have been also studied to explore the relative corrosion resistance of concrete.

Evaluation of Accuracy and Effectiveness of Real-Time Kinematic GPS Surveying Technology Using Carrier Phase Observations (반송파 위상관측을 이용한 실시간 Kinematic GPS 측량기법의 정확도와 효용성 평가)

  • 이진덕;정한상
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.17 no.3
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    • pp.301-309
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    • 1999
  • Real-time kinematic (RTK) GPS surveying which allows centimeter level accuracy of three-dimensional coordinates without post-processing has become recognized as a major advance in GPS technology. Employing On-The-Fly initialization technique, the RTK system can escape from cycle slip problems that have affected as a main obstacle factor in traditional kinematic and static approaches. The objective of this research was to evaluate accuracy and effectiveness of the RTK-GPS surveying. First, the continuous RTK observation of a base line was conducted for the purpose of finding out the repeatability of the RTK surveying and the results which were then compared against results from static surveying showed RMS errors of $\pm{3mm}\;and\;\pm{13mm}$ for their respective horizontal and vertical components. On a test network of 30 stations covering the small area, the results of RTK testing were compared against those from not only post-processing kinematic and rapid-static surveyings but conventional surveyings and also the efficiency of RTK were analyzed. In addition, geoid heights which were derived by combination of GPS and spirit leveling about all of the points within the network were compared against those derived by the PNU95 and EGM96 models respectively.

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A Study on the Basic Properties of Concrete and Low Heat-Blended Cement with Bottom Ash (바텀애시를 이용한 저발열 혼합시멘트 및 콘크리트의 기초물성에 관한 연구)

  • Kim, Won-Ki;Kim, Hoon-Sang;Kim, Hong-Joo;Lee, Won-Jun;Shin, Jin-Ho
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.685-688
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    • 2008
  • This study has examined the effect of bottom ash(BA) on the properties of low heat-blended cement(LHC) and concrete. A number of binders were prepared by the replacement of LHC with BA in range of 5$^{\sim}$20wt%. The results showed that the final setting time of cement paste were delayed when the BA replaced part of the cement. However, The heat of hydration increased narrowly with adding BA in a early hydration period. The results also showed the inclusion of BA at replacement levels of 5$^{\sim}$10wt% resulted in an increase in compressive strength of the specimens compared with that of the control concrete and improved a resistance of concrete against the sulfate and chlorine ion.

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Experimental Study on the Properties of Concrete by the Kinds of Admixture and the Replacement Ratios of Activated Hwangtoh (혼화재 종류 및 활성황토 대체율별 콘크리트의 공학적 특성에 관한 실험적 연구)

  • 최희용;김무한;김문한;황혜주;최성우
    • Journal of the Korea Concrete Institute
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    • v.13 no.2
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    • pp.123-129
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    • 2001
  • Pozzolan is to improve the strength and the durability of concrete as a result of the pozzolanic reaction, Broadly speaking, pozzolanic materials can be artificial materials, such as slica fume and fly ash, and natural material, such as rice husk ash, clay, volcanic ash, clayish pozzolan. Hwangtoh is a mineral which belongs to a group of matakaolin, especially halloysite, and the main elements is SiO$_2$, Al$_2$O$_3$, Fe$_2$O$_3$. The purpose of this study is to examine the application of Hwangtoh for the concrete admixtures, the composition of this study is shown as follows. Chapter I is analysis for properties of concrete as the kinds of admixture, and Chapter H is analysis for properties of concrete as the replacement ratio of activated Hwangtoh. As a result of this study, Hwangtoh is found to have high practical use as pozzolanic material, and the pertinent range of replacement ratios of Hwangtoh on cement are 10∼20 %.

The Chloride Ion Diffusivity of Ready-Mixed Concrete Depending on Specified Compressive Strength (레디믹스트 콘크리트의 설계기준 압축강도별 염소이온 확산특성)

  • Park, Dong-Cheon;Kim, Yong-Ro
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.6
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    • pp.543-550
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    • 2018
  • The RC buildings which are constructed on the seaside are followed by KBC(2016) to achieve the minimization of durability damage. To control the corrosion of the reinforcing steel bar by salt attack, W/C should be under 0.4 and specified concrete strength is higher than 35MPa in the concrete/building construction standard specification. Even though it has been proved that the concrete mixed with mineral admixture such as blast furnace slag and fly ash etc. have high strength and durability in previous researches, the beneficial informations are not applied to the codes. Ready-mixed concretes which usually include the admixtures in Busan were tested to certify the salt attack durability. In the same specified concrete strength, remarkable salt attack durability was evaluated in comparison to OPC. For economical and reliable durability design, chloride ion diffusivity should be measured before applying to new building construction.

Prediction Model on Autogenous Shrinkage of High Performance Concrete (고성능 콘크리트의 자기수축 예측모델에 관한 연구)

  • Yoo, Sung-Won;Soh, Yang-Sub;Cho, Min-Jung;Koh, Kyung-Taek;Jung, Sang-Hwa
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.3
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    • pp.97-105
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    • 2006
  • The autogenous shrinkage of high-performance concrete is important in that it can lead the early cracks in concrete structures. The purpose of the present study is to explore the autogenous shrinkage of high-performance concrete with admixture and to derive a realistic equation to estimate the autogenous shrinkage model of that. For this purpose, comprehensive experimental program has been set up to observe the autogenous shrinkage for various test series. Major test variables were the type and contents of admixture and water-cement ratio is fixed with 30%. The autogenous shrinkage of HPC with fly ash slightly decreased than that of OPC concrete, but the use of blast furnace slag increased the autogenous shrinkage. Also, the autogenous shrinkage of HPC is found to decrease with increasing shrinkage reduction agent and expansive additive. A prediction equation to estimate the autogenous shrinkage of HPC with admixture was derived and proposed in this study. The proposed equation show reasonably good correlation with test data on autogenous shrinkage of HPC with mineral and chemical admixture.