• 공업화학
• /
• 제29권6호
• /
• pp.746-752
• /
• 2018

본 연구에서는 마이크로웨이브 에너지를 이용하여 폐식용유로부터 바이오디젤을 제조하고, Box-Behnken 설계를 이용하여 공정의 최적화를 설계하였다. Box-Behnken 설계의 계량인자는 메탄올/유지 몰비, 마이크로웨이브 조사세기, 반응시간으로 설정하였고, 계측인자는 FAME 함량이다. 기초실험 결과 산가에 관계없이 계량인자인 메탄올/유지 몰비(8~10)와 반응시간(4~6 min)의 범위는 동일하게 설정하였으며, 마이크로웨이브 조사세기의 경우 산가 1.30 mg KOH/g (8~12 W/g)와 2.00 mg KOH/g (10~14 W/g)로 설정하였다. Box-Behnken 설계에 의해 예측된 바이오디젤 제조공정의 최적조건은 산가 1.30 mg KOH/g인 폐식용유의 경우 메탄올/유지 몰비(7.58), 마이크로웨이브 조사세기(10.26 W/g), 반응시간(5.1 min)이었고, 산가 2.00 mg KOH/g의 경우 메탄올/유지 몰비(7.78), 마이크로웨이브 조사세기(12.18 W/g), 반응시간(5.1 min)로 산출되었다. 이때 예측 FAME 함량은 각각 98.4, 96.3%로 나타났으며, 실제 실험을 통한 오차율은 0.3% 이하로 나타났다. 따라서 마이크로웨이브를 이용한 바이오디젤의 제조공정에 Box-Behnken 설계를 적용할 수 있을 것으로 사료된다.

• International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
• /
• 제3권1호
• /
• pp.1-7
• /
• 2000

A new alternative for large deepwater field development is described. This "Oil Box" (aka "Box Spar") is a multifunction vessel capable of floating drilling, production, storage and offloading (FDPSO). It is distinguished from other Floating Production, Storage and Offloading (FPSO) vessels by its unique hull form and oil storage system. It's main advantages are flexibility derived from the floatover deck option, use of proven top tensioned riser technology, and motion characteristics which make it operable in a wide range of environmental conditions.

• Biotechnology and Bioprocess Engineering:BBE
• /
• 제6권4호
• /
• pp.284-288
• /
• 2001

Lipid emulsions with saturated triacylglycerols (TAGs) with 4 to 10 carbons in each acyl chain were prepared to study how the oil component alters the stability of the lipid emul-sions when phosphatidylcholines were used as emulsifiers. The average droplet size of the emul-sions became smaller as the chain length of the TAG increased. For a given oil emulsion with smaller droplets was formed with an emulsifier having higher HLB value. The influence of HLB values on the droplet size was biggest for the tributyrin (C4) emulsion. For the tricaprylin(C8) emulsions, droplet size was identical at given emulsifier concentrations regardless of HLB values. The HLB value and the concentration of the emulsifiers also affect the droplet size of the emul-sions. The emulsions with smaller average droplet size were more stable than with bigger size for 20 days. The oil and water (o/w) interfacial tension in inversely proportional to the initial droplet size of the emulsion.

• 기술사
• /
• 제45권6호
• /
• pp.28-32
• /
• 2012

Namhae chemical is one of the largest fertilizer manufacturing company in Korea which company has operating 4 unit agitator gear boxes and producing variety kinds of fertilizer production. The gearbox operating temperature of agitator is approximated in $55^{\circ}C{\sim}90^{\circ}C$ and required to keep operating continuous without stopping. The system required high performance oil and longer oil drain interval as limited workforce in maintenance team. It was lubricated by mineral gear oil of ISO VG 320 and also need to change to new oil frequently. Namhae Chemical would expect to keep stable operating condition without shut down and consider, lower cost of operation and equipment protection.

• Environmental Engineering Research
• /
• 제24권4호
• /
• pp.711-717
• /
• 2019

The application of advanced oxidation for the treatment of oil refinery wastewater under UV radiation by using nanoparticles of titanium dioxide was investigated. Synthetic wastewater prepared from phenol crystals; Power Glide SAE40 motor vehicle oil and water was used. Response surface methodology (RSM) based on the Box-Behnken design was employed to design the experimental runs, optimize and study the interaction effects of the operating parameters including catalyst concentration, run time and airflow rate to maximize the degradation of oil (SOG) and phenol. The analysis of variance and the response models developed were used to evaluate the data obtained at a 95% confidence level. The use of the RSM demonstrated the graphical relationship that exists between individual factors and their interactive effects on the response, as compared to the one factor at time approach. The obtained optimum conditions of photocatalytic degradation are the catalyst concentration of 2 g/L, the run time of 30 min and the airflow rate of 1.04 L/min. Under the optimum conditions, a 68% desirability performance was obtained, representing 81% and 66% of SOG and phenol degradability, respectively. Thus, the hydrocarbon oils were readily degradable, while the phenols were more resistant to photocatalytic degradation.

• Tribology and Lubricants
• /
• 제26권1호
• /
• pp.61-67
• /
• 2010

The purpose of this paper is to study and analyze the failure examples on tribological characteristics of an automotive steering system. In this failure study, the grease leakage may stick leaked grease, dust, and wear particles between pinion and rack gears in mechanical steering system. In the case of seal failures such as a rod seal, o-ring and oil seals, the gear box and oil pump do not operate properly due to lack of oils. This means that oil pump does not supply a working fluid and produce a normal oil pressure of the steering system. This leads to leak a working fluid from the seals and produce a wear between pinion and rack gears. Especially, the leaked oil is usually mixed with internal wear particles and foreign dust/fine sands. Thus no leakage of working oils is very important design concepts, which is strongly related to the sealing components and smoothly operating of the mechanical friction parts of power steering system.

• 한국기계가공학회지
• /
• 제15권2호
• /
• pp.46-50
• /
• 2016

When rotating the clutch drum in the power take-off (PTO) gear box of an armored recovery vehicle, lots of inner oil is drained through the adapter by centrifugal force. Therefore, a lack of lubrication is caused by inner oil loss, and the bearing is damaged by overheating. This study, therefore, aims to design an oil-controlling adapter by using shape alteration to prevent oil loss. Both the original and improved adapters were tested at 1,800rpm by using an operational test machine. When applying the original adapter to the gear box, the bearing was damaged by overheating, which was caused by the lack of lubrication. When applying the improved oil-controlling adapter, on the other hand, it prevented the loss of inner oil. Applying the improved adapter is expected to prevent the overheating caused by lack of lubrication.

• 자원ㆍ환경경제연구
• /
• 제30권4호
• /
• pp.535-555
• /
• 2021

본 연구는 국내 주식시장 변동성에 대한 국제유가의 영향을 실증적으로 분석한다. 분석을 위해 사용된 자료는 2015년 1월 2일부터 2021년 7월 30일까지 KOSPI 지수와 WTI 선물가격의 10분 주기 고빈도 자료이다. 이를 사용하기 위해서는 이질적 자기회귀(HAR) 모형을 사용하였다. 분석 모형에서는 고빈도 자료의 장점을 살려 국제유가의 영향을 수익률뿐 아니라 실현 변동성, 실현 왜도 및 첨도를 통해 확인한다. 추정에는 큰 왜도를 갖는 실현 변동성 분포를 감안하여 Box-Cox 변환을 적용하였다. 추정 결과, WTI 가격의 일간 수익률 변동은 KOSPI 수익률의 변동성에 통계적으로 유의한 양(+)의 영향을 미치는 것으로 나타났다. 하지만 WTI 수익률의 변동성, 왜도, 첨도는 KOSPI 수익률의 변동성에 영향을 주지 않는 것으로 나타났다. 이와 같은 결과는 KOSPI 수익률의 변동성이 거래 시간의 시차를 갖는 WTI 수익률의 일간 변화는 반영하지만 투자자의 일중 거래 행태까지는 반영하지 않기 때문으로 판단된다.

• Environmental Engineering Research
• /
• 제23권2호
• /
• pp.175-180
• /
• 2018

Box-Behnken Design (BBD) under response surface methodology (RSM) was implemented to optimization the operating parameters and assess the removal and recovery efficiencies of crude oil from contaminated soil using subcritical water extraction. The effects of temperature, extraction time and water flow rate were explored, and the results indicate that temperature has a great impact on crude oil removal and recovery. The correlation coefficients for oil removal ($R^2=0.74$) and recovery ($R^2=0.98$) suggest that the proposed quadratic model is useful. When setting the target removal and recovery (>99%), BBD-RSM determined the optimum condition to be a temperature of $250^{\circ}C$, extraction time of 120 min, and water flow rate of 1 mL/min. An experiment was carried out to confirm the results, with removal and recovery efficiencies of 99.69% and 87.33%, respectively. This result indicates that BBD is a suitable method to optimize the process variables for crude oil removal and recovery from contaminated soil.

• Korean Chemical Engineering Research
• /
• 제56권4호
• /
• pp.435-440
• /
• 2018

Nyamplung (Calophyllum inophyllum Linn) is one of the most widely grown plants in Indonesia. In addition, nyamplung oil has a future competitive advantage in that it can be processed into biodiesel. However, conventional methods for transesterification of nyamplung oil have been less effective. Therefore, in this study biodiesel was produced using microwaves as one of the alternative methods that can improve the shortcomings of conventional methods. In addition, optimization of parameters such as microwave power, catalyst concentration and transesterification time was done using Box-Behnken design. The combination of microwave with CaO catalyst and treated with Box-Behnken design are considered as a new and modern method for production of biodiesel from nyamplung oil and optimizing the factors that affected the transesterification process. The results showed that factors such as microwave power of 449.29 W, concentration of catalyst of 4.86% and transesterification time of 10.07 min can produce optimal yield of biodiesel of 92.73% with reliability of 93.22%.