• Title/Summary/Keyword: Ocean Contamination

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Fecal Contamination Associated with Local Reclamation Activity in the Han River Estuary

  • Hyun, Jung-Ho;Ju, Se-Jong;Harvey, H.R.
    • Journal of the korean society of oceanography
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    • v.37 no.4
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    • pp.224-231
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    • 2002
  • Vertical distributions of coprostanol (5$\beta$-cholestan-3$\beta$-ol) and other sterols were investigated in the intertidal sediment of Shinbul island in the Han River estuary to estimate the short-term variations of fecal contamination in association with reclamation activity which caused a construction of tidal barrier and emigration of residents from the island. Quantitative contributions of coprostanol in total sterol (9.87-15.84%) and in total organic carbon (82.0-157.7 $\mu\textrm{g}$ g$^{-1}$ OC) implied that a substantial amount of organic matter associated with fecal pollutants was introduced into the sediment. The highest contribution of coprostanol to organic carbon that was observed between 0.3-0.9 cm depth seemed to be associated with increased human activities for the reclamation project of the island. The ratio of coprostanol to organic carbon decreased within 0.3 cm depth, which indicated decreased fecal contamination after the emigration of residents from the island. The results suggested that measurement of coprostanol could relevantly reflect short-term fluctuation of fecal contamination in the sediment of the Han River estuary.

Applicability of Resistivity/Capacitance Measurement on CPT Module for Investigation of Subsurface Contamination (지반 오염도 조사를 위한 전기비저항/정전용량 측정콘의 적용성 평가)

  • Oh, Myoung-Hak;Kim, Yong-Sung;Park, Jun-Boum
    • Journal of the Korean Geotechnical Society
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    • v.22 no.7
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    • pp.45-54
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    • 2006
  • Resistivity cone penetrometer test (RCPT) can be employed at a relatively low cost for in-situ delineation of subsurface contamination. While the resistivity measurement has a potential to investigate the subsurface contamination, resistivity measurements alone will lead to some degree of ambiguity in the results. In this study, capacitance measurement was incorporated into the RCPT to overcome the ambiguity inherent in electrical resistivity measurements. This study is focused on verifying the applicability of resistivity and capacitance measurements of CPT module to provide information on subsurface contaminated by heavy metal and petroleum hydrocarbon. Laboratory model tests were performed to evaluate the sensitivity of the measured resistivity and relative capacitance on the water content and different types of contaminants. Test results show that simultaneous measurement of electrical resistivity and capacitance can give more reliable information on subsurface contamination. Electrical measurements of the CPT module showed high applicability to be used in detecting saturated soils contaminated by heavy metal and diesel plume floating above the groundwater table.

A Study on the Influence of Al Alloy Sacrificial Anode Efficiency due to Marine Environmental Variation (해양환경 변화가 알루미늄합금 희생양극의 효율에 미치는 영향에 관한 연구)

  • 김도형
    • Journal of Ocean Engineering and Technology
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    • v.14 no.2
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    • pp.106-111
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    • 2000
  • Recently it was reported that the life of Al Sacrifical anode is being used in port piers has been significantly shortened compared with the original design life (e.g. average life shortened from 20 years to 13-15 year) Those factors involving these problems mentioned above were seemed to be a quality of anode material and diverse environmental factors such as pH flow rate temperature Dissolved oxygen Chemical oxygen demand and resistivity etcm In this study flow rate and contamination degree(pH) of sea water affecting to sacrificial anode life hve been investigated in terms of electrochemical characteristics of Al alloy sacrificial anode It was known that the lifetime of Al alloy anode was shortened not only by increasing of self-corrosion quantity by varying flow rate of sea water but also by increasing corrosion current density due to the potential difference increment between Al anode and steel structure cathode by varying contamination degree of sea water. Especially when anode current density is from 1mA/cm2 to 3mA/cm2 and flow rate of sea water is under 2m/s anode current efficiency is 90% above However flow rate is over 2m/s anode current efficiency fell down sharply due to erosion corrosion as well as galvanic corrosion.

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Spatial and Vertical Distribution of Polycyclic Aromatic Hydrocarbons in Sediment of the Shipyard Area in Gohyeon Bay (고현만 조선소 주변해역 퇴적물내 다환방향족탄화수소의 시공간적 분포특성)

  • Park, Pan-Soo;Kim, Nam-Sook;Yim, Un-Hyuk;Shim, Won-Joon;Kim, Gi-Beum
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.2
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    • pp.68-74
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    • 2009
  • Polycyclic aromatic hydrocarbons (PAHs), one of ubiquitous organic pollutants in marine environments, are major toxic components of petroleum and are produced during the incomplete combustion of organic materials. As shipyards are located inside of natural or artificial semi-enclosed bay, even a relatively weak environmental disturbance by ship-building activity can cause severe damage to marine ecosystem in the bay. Many studies of pollution in shipyard area have been focused on the antifouling agent, like tributyltin. This study aimed to investigate the effect of ship-building activity on PAH contamination. Total PAHs concentration was higher nearby and inside shipyard area than outside, implying that shipyard could be one of major source area of PAH contamination to pose harmful effects to surrounding environments. Through PAH profile and source recognition index, the source of PAHs inputs in this area was estimated to originate from both petrogenic and pyrogenic origin. PAH levels showed a significant correlation with total butyltins, indicating that ship-building activity influenced PAH concentration and distribution. Vertical distribution of PAHs historically confirmed the correlation between shipbuilding activity and PAHs contamination.

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Effect on Corrosion Characteristics of SS 400 Steel by Alkali Water pH from Electrolysis of City Water (수돗물의 전기분해에 의해서 생성된 알카리수의 pH가 SS 400강의 부식특성에 미치는 영향)

  • Moon, Kyung-Man;Ryoo, Hae-Jeon;Kim, Yun-Hae;Jeong, Jae-Hyun;Baek, Tae-Sil
    • Journal of Ocean Engineering and Technology
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    • v.31 no.3
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    • pp.248-255
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    • 2017
  • Many rivers and seas have been affected by environmental contamination. Therefore, city water supplies often require a high-degree purification treatment to provide safe drinking water. However, in order to achieve a high-degree purification treatment, a large amount of chlorine has to be added to sterilize city drinking water. The added chlorine reacts chemically with water and forms hypochlorous and chlorine ions. The hypochlorous ionizes with hypochlorous ions and hydrogen ions. As a result, the city water contains a large amount of chlorine ion. As such, when city water is used with domestic boilers, many kinds of heat exchangers, and the engines of vehicle and ships, there are often corrosion problems. In this study, alkali water was electrochemically made by electrolysis of city water, and corrosion properties between alkali and city water were investigated with an electrochemical method. Most of the chlorine ions are thought to not be contained in the alkali water because the alkali water is created in the cathodic chamber with an electrolysis process. In other words, the chlorine ion can be mostly removed by its migration from a cathodic chamber to an anodic chamber. Moreover, the alkali water also contains a large amount of hydroxide ion. The alkali water indicated relatively good corrosion resistance compared to the city water and the city water exhibited a local corrosion pattern due to the chlorine ion created by a high-degree purification treatment. In contrast, the alkali water showed a general corrosion pattern. Consequently, alkali water can be used with cooling water to inhibit local corrosion by chlorine ions in domestic boilers, various heat exchangers and the engine of ships and for structural steel in a marine structure.

Microbiological Pollution Investigation of Spring water in Seogwipo city of Jeju Island (제주도내 서귀포시 해안가 저지대용천수의 미생물학적 오염도 조사)

  • Han, Yong-Jae;Kim, Man-Chul;Moon, Yung-Gun;Heo, Moon-Soo
    • Proceedings of the KAIS Fall Conference
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    • 2010.11b
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    • pp.1025-1028
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    • 2010
  • The bacteriological examination of spring water in Seogwipo-city was conducted. A total 11 spring water samples were performed from January to April, 2010. During the study period, the range of temperature was from 0.7 to $15.4^{\circ}C$, and result of the analyses showed that hydrogen ion concentrations (pH) for spring water was 0.33 to 7.8. salinity levels for sample average of 0.5 to 1.04‰, as the result of measuring dissolved oxygen (DO) for spring water showed that water dissolved oxygen were 1.02 to 7.14 mg/${\ell}$. The range of total coliform of spring water sample at 11 stations located in the designated spring water were <1.8~>1,600 MPN/100mL. And the range of geometric mean of total coliform were 1.9~117.1 MPN/100mL, The range of fecal coliform of spring water sample at 11 stations located in the designated spring water were <1.8~>1,600 MPN/100mL. And the range of geometric mean of fecal coliform were 1.8~68.1 MPN/100mL, respectively. Level of microbial contamination was examined in 11 samples for indication of bacterial contamination such as heterophic bacteria, EscherichiacoliO157;H7, salmonella spp., Vibrio parahaemolyticus, Staphylococcus aureus, Shigella spp. Were frequently detected from the spring water. Salmonella spp., S.aureus were detected in the range of $0{\sim}1.0{\times}10^1$, $0{\sim}3.0{\times}10^1$ CFU/ml, respectively. And the Escherichia coli O157;H7, Vibrio parahaemolyticus, Shigella spp. Were not detected from the examined spring water samples.

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Subcellular Distribution of Heavy Metals in Organs of Bivalve Modiolus Modiolus Living Along a Metal Contamination Gradient

  • Podgurskaya, Olga V.;Kavun, Victor Ya.
    • Ocean Science Journal
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    • v.41 no.1
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    • pp.43-51
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    • 2006
  • Concentration and distribution of Fe, Zn, Cu, Cd, Mn, Pb, Ni among subcellular fractions (cellular membrane structures and cytosol) and Zn, Cu, Cd among cytoplasmic proteins in the kidney and digestive gland of mussel Modiolus modiolus living along a polymetallic concentration gradient were studied. It was found in the kidney of M. modiolus from contaminated sites that the Fe percent increased in the "membrane" fraction, whereas Zn, Pb, Ni and Mn percent increased in the cytosol compared to the kidney of the control mussel. Note kidney cytosol of M. modiolus from clean and contaminated sites sequestered major parts of Cu and Cd. In the digestive gland of M. modiolus from contaminated sites Fe, Zn, Cd, Mn, Ni percent increased in the "membrane" fraction, whereas Cu, Pb percent increased in the cytosol compared to digestive gland of control mussel. Gel-filtration chromatography shows kidney of M. modiolus contains increased metallothionein-like protein levels irrespective of ambient dissolved metal concentrations. It was shown that the metal detoxification system in the kidney and digestive gland of M. modiolus was efficient under extremely high ambient metal levels. However, under complex environmental contamination in the kidney of M. modiolus, the metal detoxification capacity of metallothionein-like proteins was damaged.

Delayed Mode Quality Control of Argo Data and Its Verification in the Pacific Ocean (태평양 Argo 자료의 지연모드 품질관리 및 검증연구)

  • Yang, Joon-Yong;Kang, Seong-Yun;Go, Woo-Jin;Suh, Young-Sang;Seo, Jang-Won;Suk, Moon-Sik
    • Journal of Environmental Science International
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    • v.17 no.12
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    • pp.1353-1361
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    • 2008
  • Quality control of Argo(Array for Real-time Geostrophic Oceanography) data is crucial by reason that salinity measurements are liable to experience some drift and offset due to biofouling, contamination of sensor and wash-out of biocide. The automated Argo real-time quality control has a limit of sorting data quality, so that WJO program is adopted as standardized method of Argo delayed mode quality control (DMQc) in the world that is a precise quality control method. We conducted DMQC on pressure, temperature and salinity measured by Argo floats in the Pacific Ocean including expert evaluation. Particularly, salinity data were corrected using WJO program. 4 salinity profiles of Argo delayed mode were compared with nearby in situ CTD data and other Argo data in deep layer where oceanographic conditions are stable in time and space. The differences of both salinities were lower than target accuracy of Argo. As compared with the difference of salinities before DMQC, those after DMQC decreased by 60-80 percent. Quality of delayed mode salinity data seemed to be improved correcting salinity data suggested by WJO program.

Screening of Differentially Expressed Genes in Diesel Oil-exposed Marine Fish Using DD-PCR

  • Woo, Seon-Ock;Yum, Seung-Shic;Yim, Un-Hyuk;Lee, Yaek-Kyun
    • Molecular & Cellular Toxicology
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    • v.2 no.4
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    • pp.251-256
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    • 2006
  • The exploration of genes which expressions are changed by exposure to ecotoxicants or pollutants can provide the important information about the reaction mechanisms in the body as well as adaptation to exterior stimulus or environmental changes. Also they can be developed as biomarkers for the detection of environmental pollution. Differential display polymerase chain reaction (DD-PCR) technique has been usefully used to hunt the clones which expressions are up-regulated or down-regulated by exterior changes and this study aimed to search for those clones in diesel oil-exposed rockfish (Sebastes schlegeli) using DD-PCR. The RNA isolated from liver of 20 ppb diesel oil-exposed rockfish was used for screening of the differentially displayed genes and total 44 differentially expressed genes (DEG) are detected then their nucleotide sequences were analyzed. The present data provided the general information about the effect of diesel oil contamination on marine organism and further more the primary step in development of new biomarkers for marine environmental pollution or ecotoxicological stresses.

Contemporary organic contamination levels in digested sewage sludge from treatment plants in Korea: (2) Non-alkylated Polycyclic Aromatic Hydrocarbons (우리나라 하수 및 폐수 처리 슬러지의 다환방향족탄화수소의 함량)

  • Lee Kang-Young;Chung Chang-Soo;Kim Young-Il;Lee Hyun-Kyung;Hong Gi-Hoon
    • Journal of Environmental Science International
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    • v.14 no.4
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    • pp.413-425
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    • 2005
  • The 16 priority PAHs (Polycyclic Aromatic Hydrocarbons) designated by US Environmental Protection Agency were analyzed for some digested sludges from wastewater treatment plants in Korea. PAHs are an important group of organic contaminants present in sewage sludge due to their persistence and toxic potential. PAHs were extracted from freeze-dried sludges using a methylene chloride-methanol (2:1) mixture in a soxhlet extractor. The extracts were cleaned-up by silica gel/alumina combination column and subsequently fed into gas chromatograph/mass spectrometer (GC/MS) for determining PAH contents. The sum of the 16 PAHs in the sewage sludge varied from 534.8 to $5754.5 {\cal}ug/{\cal}kg$, dry wt.. In the sewage sludge, phenanthrene appears as the most abundant PAHs, followed by naphthalene, pyrene, fluoranthene. Source of the investigated sewage sludges relatively predominated pyrogenic. PAHs levels of sewage sludges in Korea appeared to be lower than those in other countries.