• Journal of the Korean Magnetics Society
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• v.24 no.1
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• pp.1-10
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• 2014

$Co_2Z$-type barium ferrites ($Ba_3Co_2Fe_{24}O_{41}$) were synthesized using variation method. First, M-type, $Co_2Y$-type and $Co_2Z$-type synthesized by hydrothermal method. Second, M- and Y-type precursors for synthesis of $Co_2Z$ hexaferrite by hydrothermal and ball milling method. the morphology, structure and magnetic properties of the barium ferrite particles were characterized using XRD, FESEM, VSM, impedance. As a result, Single phase of M-type and $Co_2Y$-type were obtained. Manufactured powders of M+Y ball milling, M+Y hydrothermal were similar to single phase of $Co_2Z$-type hexaferrite, all powders were obtained theoretical magnetization (50 emu/g). The largest initial permeability were obtained $Co_2Z$ hexaferrite synthesized by reagent precusor, With increasing calcination temperature was lowered the initial permeability. In another synthesis didn't almost that little change could be found.

• The Journal of the Petrological Society of Korea
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• v.1 no.1
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• pp.1-24
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• 1992

Precambrian metamorphic rocks of the Gapyeong-Cheongpyeong area consist of banded gneiss, augen gneiss, leucocratic gneiss, quartz schist and quartzite, together with minor intercalations of serpentinite, amphibolite and marble. Mineral assemblages of meta-sedimentary rocks are classified into three types: sillimanite-free; sillimanite-bearing; and sillimanite+K-feldspar-bearing assemblages. Compositions of metamorphic phases depend on the type of mineral assemblages. In particular, the Ca contents of plagioclase and garnet are high in sillimanite-free assemblges. Kyanite occurs in three samples, and coexists with sillimanite in one sample. The presence of kyanite indicates that metamorphic rocks of the study area have experienced the Barrovian type metamorphism. Peak metamorphic conditions estimated from various geothermobarometers and phase equilibria are 618-674$^{\circ}C$ and 6.5${\pm}$2.0 kbar for sillimanite-free assemblages, and 701-740$^{\circ}C$ and 4.4${\pm}$0.8 kbar for sillimanite-bearing assemblages, respectively. Furthermore, a clockwise P-T-time path is deduced for the study area, based on the following observations: (1) the polymorphic transition of kyanite to sillimanite, (2) the occurrence of sillimanite and K-feldspar belonging to the upper amphibolite facies, and finally (3) the retrograde metamorphism characterized by muscovite-, chlorite-, and actinolite-bearing assemblages.

• Journal of Soil and Groundwater Environment
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• v.21 no.1
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• pp.28-39
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• 2016

Struvite (MgNH₄PO₄ ⋅ 6H₂O) and hydroxyapatite (HAP, Ca₁₀(PO₄)₆(OH)₂) precipitation in urine-separating toilets (NoMix toilets) causes severe maintenance problems and also reduce the phosphate and calcium content. Application of urine separating technique and extraction of by-products from human urine is a cost effective technique in waste water treatment. In this study, we extract urine calcite from human urine by batch scale method, using urease producing microbes to trigger the precipitation and calcite formation process. Extracted urine calcite (calcining at 800℃) is a potential adsorbent for removal of heavy metal(loid)s like (Cd²⁺, Cu²⁺, Ni²⁺, Pb²⁺, Zn²⁺ and As³⁺) along with additional leaching analysis of total nitrogen (T-N), phosphate (T-P) and chemical oxygen demand (COD). The transformations of calcite during synthesis were confirm by characterization using XRD, SEM-EDAX and FT-IR techniques. In additional, the phosphate leaching potential and adsorbate (nitrate) efficiency in aqueous solution was investigated using the calcinedurine calcite. The results indicate that the calcite was effectively remove heavy metal(loid)s lead up to 96.8%. In addition, the adsorption capacity (q_e) of calcite was calculated and it was found to be 203.64 Pb, 110.96 Cd, 96.02 Zn, 104.2 As, 149.54 Cu and 162.68 Ni mg/g, respectively. Hence, we suggest that the calcite obtain from the human urine will be a suitable absorbent for heavy metal(loid)s removal from aqueous solution.

• Korean Journal of Soil Science and Fertilizer
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• v.4 no.1
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• pp.101-107
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• 1971

1. 수도(水稻)의 생육기간(生育其間)만이라도 심수하(甚水下)에 있어야하는 논은 투수성(透水性)의 영향(影響)을 받아야 하고, 동영향(同影響)은 수도생육(水稻生育)과 관련(關聯)을 갖는다. 즉(卽) 투수성(透水性)이 클 경우(境遇)에는 물의 소비(消費)가 많을 뿐만이 아니라 영양분(營養分)의 유실(流失) 및 유효화(有效化)가 억제(抑制)되고, 투수성(透水性)이 적을 경우(境遇)에에는 심(甚)한 환원상태(還元狀態)의 발달(發達)로 유해성분(有害成分)이 집적(集積)되어 수도(水稻)의 생육(生育)은 해(害)를 입게된다. 이렇게 생각하면 투수성(透水性)으로 본 벼 생육(生肉)에 가장 적합(適合)한 토양조건(土壤條件)이 있을 것인바 이 조건(條件)은 토양(土壤)의 종류외(種類外)에도 수도(水稻)의 품종(品種)이나 생육시기(生育時期)에 따라 다른것이다. 2. 투수성(透水性)이 큰 토양(土壤)에는 잘 유거(流去)되지 않는 비료(肥料)(유기물비료(有機物肥料)나 용성연비(熔成憐肥) 등(等))를 쓸것이며, 투수성(透水性)이 적고 유해성분(有害成分)이 집적(集積)되기 쉬운 토양(土壤)에는 류산근(류硫酸根)이나 유기질(有機質) 비료등(肥料等) 유해성분(有害成分)의 집적(集積)을 증가(增加)할 우려가 있는 비료(肥料)의 시용(施用)을 삼가야 한다. 3. 기왕(旣往) 국내(國內)에서 실시(實施)한 시험결과(試驗結果)에 의(依)하면 중점토(重粘土)에서는 연산(憐酸), 중점토(重粘土)와 퇴화염토(退化鹽土)에서는 가리결핍(加里缺乏)을 일으키기 쉬운것 같으나 그 밖의 토양(土壤)에서는 뚜렷한 경향(傾向)이 인정(認定)되지 않는다. 4. 투수성(透水性)이 큰 토양(土壤)에서는 산적토(山赤土)를 객토(客土)하는 경우(境遇)가 많은 바 이때에는 금비(金肥) 특(特)히 질소질비료(窒素質肥料)를, 객토(客土)하지 않았을때 보다 많이 써야 하는것이 일반적(一般的)이다. 5. 투수성(透水性)이 약(弱)하고 유해성분(有害成分)이 집적(集積)되기 쉬운 논에는 우선(于先) 석회(石灰)(소석회(消石灰))를 시용(施用)하여 토양반응(土壤反應)을 높여야 하며 심(甚)한 노후답(老朽畓)이나 퇴화염토(退化鹽土)에는 석회(石灰)와 아울러 규산질(珪酸質) 비료(肥料)를 시용(施用)한 연후(然後)에 비료(肥料) 삼요소(三要素) 시용(施用)을 고려(考慮)해야 할 것이다. 산성(酸性)으로 기울어져있는 많은 우리나라 논 토양(土壤)에는 알칼리성(性) 비료(肥料)인 용성연비(熔成憐肥)를 시용(施用)하는 것이 효과적(效果的) 일것이다. 6. 소석회(消石灰)와 규산(珪酸)의 시용(施用)은 연산(憐酸)과 가리(加里)의 요구량(要求量)을 증가(增加) 할것이며 비료(肥料) 삼요소(三要素)에 대(對)한 수도(水稻)의 응수곡선(應酬曲線)의 모습을 기왕(旣往)의 것과 달리 할것이다.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.6
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• pp.744-750
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• 2015

The objectives of this study were to investigate soil chemical characteristics for forest rehabilitation and suggest management in abandoned coal mine areas in Boryeong City, Chungcheongnam-do. Total study sites were seven sites, and soil properties analyzed were soil pH, total organic carbon (TOC), total-N, C/N ratio, and available $P_2O_5$ (A.v. P). Average soil pH (range) was 5.9 (4.5~7.0). Three study sites (Samgwang, Shinsung1, and Shimwon1) showed lower soil pH than standard (pH 5.6~7.3) of Korea Industrial Standards (KS) for abandoned coal mine forest rehabilitation. Average contents of TOC, and total-N were 1.5% (0.1~4.7%), and 0.10% (0.03~0.23%), respectively. Five study sites where the collapsed time was less than 10 years (Wangjashingang, Wonpoong, Samgwang, Shinsung1, and Shinsung2) showed lower TOC level than standard of KS (more than 1.2%). Wangjashingang, Wonpoong, Samgwang, and Shinsung1 showed lower level of total-N than standard of KS (more than 0.09%). C/N ratio of six study sites except Shimwon1 was out of proper range (15:1~30:1). Average A.v. P (range) was $20.7mgkg^{-1}$ (4.8~63.1), less than other abandoned coal mine fores rehabilitation areas in Mungyong City, and Hwasun-gun. TOC, total N and A.v. P increased with elapsed time from forest rehabilitation, while other soil properties did not show distinct pattern. Betula platyphylla was planted in Samkwang and Sinsung where soil pH was less than KS standard. Because the growth of Betula platyphylla can be limited in acid soil, it is necessary to neutralize soil pH to proper level with some soil amendment such as lime or shell of oyster. Furthermore, TOC, total-N and A.v. P in early stage of forest rehabilitation showed lower level than proper to vegetation growth. Therefore it needs continuous monitoring of soil characteristics and fertilization for vegetation growth and influx from surrounding forest in early stage of rehabilitation.

• Korean Journal of Soil Science and Fertilizer
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• v.48 no.5
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• pp.397-403
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• 2015

Heavy metals reduce the photosynthetic efficiency and disrupt metabolic reactions in a concentration-dependent manner. Moreover, by replacing the metal ions in metalloproteins that use essential metal ions, such as Cu, Zn, Mn, and Fe, as co-factors, heavy metals ultimately lead to the formation of reactive oxygen species (ROS). These, in turn, cause destruction of the cell membrane through lipid peroxidation, and eventually cause the plant to necrosis. Given the aforementioned factors, this study was aimed to understand the physiological responses of rice to cadmium (Cd) and arsenic (As) toxicity and the effect of essential metal ions on homeostasis. In order to confirm the level of physiological inhibition caused by heavy metal toxicity, hydroponically grown rice (Oryza sativa L. cv. Dongjin) plants were exposed with $0-50{\mu}M$ cadmium (Cd, $CdCl_2$) and arsenic (As, $NaAsO_2$) at 3-leaf stage, and then investigated malondialdehyde (MDA) contents after 7 days of the treatment. With increasing concentrations of Cd and As, the MDA content in leaf blade and root increased with a consistent trend. At 14 days after treatment with $30{\mu}M$ Cd and As, plant height showed no significant difference between Cd and As, with an identical reduction. However, As caused a greater decline than Cd for shoot fresh weight, dry weight, and water content. The largest amounts of Cd and As were found in the roots and also observed a large amount of transport to the leaf sheath. Interestingly, in terms of Cd transfer to the shoot parts of the plant, it was only transported to upper leaf blades, and we did not detect any Cd in lower leaf blades. However, As was transferred to a greater level in lower leaf blades than in upper leaf blades. In the roots, Cd inhibited Zn absorption, while As inhibited Cu uptake. Furthermore, in the leaf sheath, while Cd and As treatments caused no change in Cu homeostasis, they had an antagonist effect on the absorption of Zn. Finally, in both upper and lower leaf blades, Cd and As toxicity was found to inhibit absorption of both Cu and Zn. Based on these results, it would be considered that heavy metal toxicity causes an increase in lipid peroxidation. This, in turn, leads to damage to the conductive tissue connecting the roots, leaf sheath, and leaf blades, which results in a reduction in water content and causes several physiological alterations. Furthermore, by disrupting homeostasis of the essential metal ions, Cu and Zn, this causes complete heavy metal toxicity.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1080-1084
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• 2011

Predictive model for estimating total contents of cadmium (Cd) and lead (Pb) was developed by stepwise multiple-regression analysis using chemical properties and extractable contents of metal in paddy soil adjacent to abandoned mines in 2009 and 2010. Soil properties, e.g. pH, electrical conductivity (EC), organic matter (OM), available phosphorus ($P_2O_5$), and exchangeable cations (i.e. Ca, Na, K, Mg) were measured. Total contents of Cd and Pb as well as extractable contents of metals were analyzed by ICP-OES. Results showed that the total and extractable contents were estimated to be 3.55 and $0.27mg\;kg^{-1}$ in Cd and 83.38 and $24.32mg\;kg^{-1}$ in Pb on the average. From stepwise analysis, it was found that the contents of extractable Cd, Zn, Cu, as well as exchangeable Na were significantly influenced on estimation of the total contents of Cd in soil. Moreover, it also showed that the contents of extractable Pb, Zn, and Cu significantly affected estimation of the total contents of Pb in soil. More significant relationship between estimated and measured value in total contents of Pb was observed than those of Cd ($R^2$=0.87, p<0.0001). This demonstrates that extractable contents of metal are influenced more on estimation of total contents of Cd and Pb in soil than soil properties.

• Journal of Ginseng Research
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• v.45 no.5
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• pp.583-590
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• 2021

Background: Gintonin, isolated from ginseng, acts as a ginseng-derived lysophosphatidic acid (LPA) receptor ligand and elicits the [Ca²⁺]_i transient through six LPA receptor subtypes (LPARSs). However, the long-term effects of gintonin-enriched fraction (GEF) on the gene expression of six LPARSs remain unknown. We examined changes in the gene expression of six LPA receptors in the mouse whole brain, heart, lungs, liver, kidneys, spleen, small intestine, colon, and testis after long-term oral GEF administration. Methods: C57BL/6 mice were divided into two groups: control vehicle and GEF (100 mg/kg, p.o.). After 21-day saline or GEF treatment, total RNA was extracted from nine mouse organs. Quantitative-real-time PCR (qRT-PCR) and western blot were performed to quantify changes in the gene and protein expression of the six LPARSs, respectively. Results: qRT-PCR analysis before GEF treatment revealed that the LPA6 RS was predominant in all organs except the small intestine. The LPA2 RS was most abundant in the small intestine. Long-term GEF administration differentially regulated the six LPARSs. Upon GEF treatment, the LPA6 RS significantly increased in the liver, small intestine, colon, and testis but decreased in the whole brain, heart, lungs, and kidneys. Western blot analysis of the LPA6 RS confirmed the differential effects of GEF on LPA6 receptor protein levels in the whole brain, liver, small intestine, and testis. Conclusion: The LPA6 receptor was predominantly expressed in all nine organs examined; long-term oral GEF administration differentially regulated LPA3, LPA4, and LPA6 receptors in the whole brain, heart, lungs, liver, kidneys, small intestine, and testis.

• Journal of The Korean Society of Agricultural Engineers
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• v.63 no.6
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• pp.1-16
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• 2021

Global warming due to climate change is expected to significantly affect the hydrological cycle of agriculture. Therefore, in order to predict the magnitude of climate impact on agricultural water resources in the future, it is necessary to estimate the water demand for irrigation as the climate change. This study aimed at evaluating the future changes in water demand for irrigation under two Shared Socioeconomic Pathways (SSPs) (SSP2-4.5 and SSP5-8.5) scenarios for paddy rice in Gimje, South Korea. The APEX-Paddy model developed for the simulation of paddy environment was used. The model was calibrated and validated using the H₂O flux observation data by the eddy covariance system installed at the field. Sixteen General Circulation Models (GCMs) collected from the Climate Model Intercomparison Project phase 6 (CMIP6) and downscaled using Simple Quantile Mapping (SQM) were used. The future climate data obtained were subjected to APEX-Paddy model simulation to evaluate the future water demand for irrigation at the paddy field. Changes in water demand for irrigation were evaluated for Near-future-NF (2011-2040), Mid-future-MF (2041-2070), and Far-future-FF (2071-2100) by comparing with historical data (1981-2010). The result revealed that, water demand for irrigation would increase by 2.3%, 4.8%, and 7.5% for NF, MF and FF respectively under SSP2-4.5 as compared to the historical demand. Under SSP5-8.5, the water demand for irrigation will worsen by 1.6%, 5.7%, 9.7%, for NF, MF and FF respectively. The increasing water demand for irrigating paddy field into the future is due to increasing evapotranspiration resulting from rising daily mean temperatures and solar radiation under the changing climate.

• Biomolecules & Therapeutics
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• v.29 no.3
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• pp.321-330
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• 2021

Oxidative stress plays a crucial role in the development of neuronal disorders including brain ischemic injury. Thioredoxin 1 (Trx1), a 12 kDa oxidoreductase, has anti-oxidant and anti-apoptotic functions in various cells. It has been highly implicated in brain ischemic injury. However, the protective mechanism of Trx1 against hippocampal neuronal cell death is not identified yet. Using a cell permeable Tat-Trx1 protein, protective mechanism of Trx1 against hydrogen peroxide-induced cell death was examined using HT-22 cells and an ischemic animal model. Transduced Tat-Trx1 markedly inhibited intracellular ROS levels, DNA fragmentation, and cell death in H2O2-treatment HT-22 cells. Tat-Trx1 also significantly inhibited phosphorylation of ASK1 and MAPKs in signaling pathways of HT-22 cells. In addition, Tat-Trx1 regulated expression levels of Akt, NF-κB, and apoptosis related proteins. In an ischemia animal model, Tat-Trx1 markedly protected hippocampal neuronal cell death and reduced astrocytes and microglia activation. These findings indicate that transduced Tat-Trx1 might be a potential therapeutic agent for treating ischemic injury.