• 제목/요약/키워드: OTF

검색결과 108건 처리시간 0.019초

α-케토안정화된 일리드화 인의 수은(II) 및 은(I) 착물에 대한 X-선 및 분광학적 연구 (X-ray and Spectroscopy Studies of Mercury (II) and Silver (I) Complexes of α-Ketostabilized Phosphorus Ylides)

  • Karami, K.;Buyukgungor, O.;Dalvand, H.
    • 대한화학회지
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    • 제55권1호
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    • pp.38-45
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    • 2011
  • 전이금속 이온인 수은(II) 및 은(I)에 대한 $\alpha$-케토안정화된 일리드화 인 $Ph_3P$=CHC(O) $C_6H_4$-X (X=Br, Ph)의 착물 반응 행동을 연구하였다. 수은(II) 착물 {$HgX_2$ [Y]} 2 ($Y_1$=4-bromo benzoyl methylene triphenyl phosphorane; X=Cl(1), Br(2), I(3), $Y_2$=4-phenyl benzoyl methylene triphenyl phosphorane; X=Cl(4), Br(5), I(6))는 $Y_1$$Y_2$$HgX_2$ (X=Cl, Br, I)와 각각 반응시켜 제조하였다. $\alpha$-케토안정화된 일리드화 인($Y_2$)의 은(I) 착물 [Ag$(Y_2)_2$] X(X=$BF_4$(7), OTf(8))는 이러한 일리드와 AgX(X=$BF_4$, OTf)를 아세톤에서 반응시켜 얻었다. 착물 (1)과 (4)의 결정구조를 고찰하였다. 일리드의 C-배위 이핵착물과 트랜스-구조의 착물$[Y_1HgCl_2]_2$. $CHCl_3$ (1) 및 $[Y_2HgCl_2]_2$ (4)를 형성하는 이들 반응에 대해 단결정 X-선 분석을 통해 고찰하였다. 모든 착물(1-3)은 IR, $^1H$$^{31}P$ NMR 뿐만아니라 $^{13}$CNMR을 통하여 확인하였다.

Synthesis of 2,5-Disubstituted Pyrrolidines from N-Alkenyl and Alkynyl N-Benzoyloxysulfonamides Catalyzed by (CuOTf)2・C6H6

  • Liu, Wei-Min;Liu, Zhen-Hong;Cheong, Wei-Wen;Priscilla, Lu-Yi Teo;Li, Yongxin;Narasaka, Koichi
    • Bulletin of the Korean Chemical Society
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    • 제31권3호
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    • pp.563-569
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    • 2010
  • A new synthetic method of 2,5-disubstituted pyrrolidines is developed by the cyclization of unsaturated N-benzoyloxysulfonamides by $(CuOTf)_2{\cdot}C_6H_6$ in refluxing dichloroethane. Various N-4- and N-5-alkenyl and alkynyl N-benzoyloxysulfonamides are cyclized to give pyrrolidines. The cyclization proceeds via addition of sulfonamidoyl radicals to intramolecular unsaturated bonds or allylic hydrogen abstraction with the radical intermediates.

OTF계산값을 이용한 ERF계산 (Computation of the ERF from the OTF)

  • 심상현
    • 한국광학회지
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    • 제4권2호
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    • pp.140-144
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    • 1993
  • Optical Transfer Function(OTE)으로부터 Edge Response Function(ERF)을 계산하는 computer program을 작성하였다. 이 program을 사용하여 무수차 광학계와 몇가지 형태의 수차를 포함하는 광학계의 ERF를 계산하였다. 왜곡수차, 촛점이동, 비점수차, 코마 또는 구면수차 등의 단일수차 및 이들이 조합된 몇가지 형태의 복합수차 등을 포함하는 광학계를 고려하였다. 계산의 결과로부터 sagital case의 경우, 촛점이동이나 구면수차가 코마에 비하여 ERF에 나쁜 영향을 미치며, tangential case의 경우, 코마가 촛점이동과 구면수차보다 나쁜 영향을 미침을 알았다. 한편 코마는 tangential case의 ERF의 형태와 위치를 변화시키지만 왜곡수차는 상의 위치만을 변화시킨다는 것도 확인 할 수 있었다. 또한 코마와 왜곡수차를 포함하는 광할계의 tangential case의 ERF는 이들중 하나의 수차만 포함하는 경우보다 오히려 좋은 형태를 나타내어 두 수차가 상호 보완적인 영향을 미침을 알았다.

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Efficient Implementation of Simeck Family Block Cipher on 8-Bit Processor

  • Park, Taehwan;Seo, Hwajeong;Bae, Bongjin;Kim, Howon
    • Journal of information and communication convergence engineering
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    • 제14권3호
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    • pp.177-183
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    • 2016
  • A lot of Internet of Things devices has resource-restricted environment, so it is difficult to implement the existing block ciphers such as AES, PRESENT. By this reason, there are lightweight block ciphers, such as SIMON, SPECK, and Simeck, support various block/key sizes. These lightweight block ciphers can support the security on the IoT devices. In this paper, we propose efficient implementation methods and performance results for the Simeck family block cipher proposed in CHES 2015 on an 8-bit ATmega128-based STK600 board. The proposed methods can be adapted in the 8-bit microprocessor environment such as Arduino series which are one of famous devices for IoT application. The optimized on-the-fly (OTF) speed is on average 14.42 times faster and the optimized OTF memory is 1.53 times smaller than those obtained in the previous research. The speed-optimized encryption and the memory-optimized encryption are on average 12.98 times faster and 1.3 times smaller than those obtained in the previous studies, respectively.

실시간 정밀측위를 위한 AFM 알고리즘의 성능개선에 관한 연구 (The advanced Algorithm of Ambiguity Function Method far Realtime Precise GPS Positioning)

  • 김용일;김동현
    • 한국측량학회지
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    • 제14권2호
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    • pp.167-179
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    • 1996
  • AFM은 반송파 위상을 이용하는 GPS 정밀측위에서 일반적으로 문제가 되는 초기미지정수와 cycle-slip에 영향을 받지 않는 기법이다. 그러나 기존의 AFM알고리즘에는 두 가지의 어려움이 있다. 첫째, 최적의 수신기 위치를 구하기 위한 계산시간이 너무 길다는 점이다. 둘째, 검색공간 내에 최적의 수신기 위치로 선정이 가능한 후보가 많을 수 있다는 점이다. 따라서 기존의 AFM 알고리즘이 갖는 단점을 개선하여 OTF의 환경에 적용할 수 있도록 계산시간을 획기적으로 단축시키는 새로운 알고리즘이 본 논문에서 제시되었다. 또한 결정된 최적의 수신기 위치의 진위 여부를 통계적으로 검정하는 알고리즘이 제시되었다.

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A Study on the Coast Topography using Real-Time Kinematics GPS and Echo Sounder

  • Park, Woon-Yong;Kim, Jin-Soo;Kim, Cheon-Yeong
    • International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
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    • 제6권1호
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    • pp.22-29
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    • 2003
  • This research aims at investigation of accuracy potential of RTK(Real-Time Kinematic) GPS in combination with Echo Sounder(E/S) for the coastal mapping. Apart from this purpose, the accuracy of ambiguity resolution with the OTF(On The Fly) method was tested with respect to the initialization time. The result shows that the accuracy is better than 1cm with 5-minute initialization in the distance of 10km baseline. The seaside topography was measured by the RTK GPS only, on the other hand the seafloor topography was surveyed in combination of RTK GPS and E/S. Comparing to the volume of seaside measured by RTK GPS and digital topographical map, the difference of only 2% was achieved. This indicates that the coastal mapping. As a result, it has been revealed that every possible noise in surveying could be corrected and the accuracy could be improved. The accuracy of GPS data acquired in real time was as good as that acquired by post processing. It is expected that it will be useful for the analysis of coastal geographic characteristics because DTM(Digital Terrain Model) can be also constructed for the harbor reclamation, the dredging, and the variation of soil movement in a river.

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A Study on the Coast Topography using Real-Time Kinematics GPS and Echo Sounder

  • PARK WOON-YONG;KIM JIN-SOO;KIM CHEON-YEONG
    • 한국해양공학회지
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    • 제17권3호
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    • pp.13-20
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    • 2003
  • This research aims at investigation of accuracy potential of RTK(Real-Time Kinematic) GPS in combination with Echo Sounder(E/S) for the coastal mapping. Apart from this purpose, the accuracy of ambiguity resolution with the OTF(On The Fly) method was tested with respect to the initialization time. The result shows that the accuracy is better than 1cm with 5-minute initialization in the distance of 10km baseline. The seaside topography was measured by the RTK GPS only, on the other hand the seafloor topography was surveyed in combination of RTK GPS and E/S. Comparing to the volume of seaside measured by RTK GPS and digital topographical map, the difference of only $2\%$ was achieved. This indicates that the coastal mapping. As a result, it has been revealed that every possible noise in surveying could be corrected and the accuracy could be improved. The accuracy of GPS data acquired in real time was as good as that acquired by post processing. It is expected that it will be useful for the analysis of coastal geographic characteristics because DTM(Digital Terrain Model) can be also constructed for the harbor reclamation, the dredging, and the variation of soil movement in a river.

적외선 광학계통 성능평가를 위한 간섭계 개발 (Development of Interferometer for Performance Assessment of IR Optical System)

  • 홍경희;고재준;이성태;장세안;오명호
    • 한국광학회지
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    • 제2권4호
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    • pp.179-185
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    • 1991
  • 적외선 광원으로 $CO_2$ 레이저를 사용하였고 광속을 2.5 cm의 직경으로 확대하여 Twyman-Green 간섭계를 구성하였다. 각종 렌즈는 Ge 렌즈로, 광속분리기는 ZnSe 평행판으로 택하였다. Pyro-electric vidicon camera에 의해 CRT monitor에 간섭무늬를 제시하며 image card에 의해 digitize되고 PC로 강도분포가 입력되어 data처리된다. 여기서, 적외선 간섭무늬는 thermal paper 상에 기록하였다. 가시영역에서는 He-Nefp이저를 광원으로 하고 CCD 카메라로 검출하여 CRT monitor에 제시하였다. 파면수차함수, PSF, OTF가 계산되어 3차원 그래프로 제시되며 프린트 된다.

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