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화학양론 조성의 뮬라이트 합성거동과 입자형상에 미치는 전구체 pH의 영향 (Effects of Precursor pH on Synthesizing Behavior and Morphology of Mullite in Stoichiometric Composition)

  • 이재언;김재원;정연길;장중철;조창용
    • 한국재료학회지
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    • 제12권7호
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    • pp.573-579
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    • 2002
  • Stoichiometric mullite ($3Al_2$$O_3$. $2SiO_2$) precursor sol has been prepared by sol-gel method. The effects of the precursor pH and sintering temperature on the synthesizing behavior and morphology of mullite have been studied. Mullite precursor sol was prepared by dissolution of aluminum nitrate enneahydrate (Al($NO_3$)$_3$.9H$_2O) into the mixture of silica sol. Precursor pH of the sols was controlled to acidic condition ($PH\leq$ 1~1.5) and to basic condition ($pH\geq$8.5~9). The synthesized aluminosilicate sols were formed under 20 MPa pressure after drying at $150^{\circ}C$ for 24 hours, and then sintered for 3hours in the temperature range of $1100~1600^{\circ}C$. From TGA/DTA analysis, total weight loss in the aluminosilicate gel of the acidic sample was (equation omitted) 56% and that of the basic sample was (equation omitted) 85%, indicating that the synthesizing temperature of mullite phase for acidic and basic samples was above $1200^{\circ}C$ and $1300^{\circ}C$, respectively. The morphologies of the synthesized mullite were fine and needle-like (or rod-like) for acidic sample, and granular for basic sample that has been sintered above $1300^{\circ}C$. It was found that the morphology of mullite particle was predominantly governed by precursor pH and sintering temperature.

PHOTOCHEMISTRY AND PHOTOBIOLOGY OF PSORALENS

  • Shim, Sang-Chul;Jeon, Young Hee;Kim, DongWon;Han, GyuSeok;Yoo, Dong Jin
    • Journal of Photoscience
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    • 제2권1호
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    • pp.37-45
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    • 1995
  • INTRODUCTION : Psoralens are planar tricyclic furocoumarins present in numerous plants and fungi found throughout the world.' Naturally occurring and synthesized psoralen derivatives(see Figure 1) are photosensitizers of UVA especially from 320 nm to 400 nm, a range at which cellular nucleic acids and proteins are weakly absorbing if any at all. Because of their skinphotosensitizing properties, these compounds have been used in the photochemotherapy of psoriasis and vitiligo. However, undesirable side effects such as carcinoma development in hairless mice as well as possible liver damage from the use of 8-methoxypsoralen(8-MOP) have been reported. The other photobiological effects include inactivation of DNA viruses, killing and mutagenesis of bacteria, inhibition of tumor transmitting capacity of various cells, and hyperpigmentation on human and guinea pig skin. PUVA(psoralen+UVA) photochemotherapy is in fact thousands of years old, having been used in Egypt and India since B.C. 1200-2000. Photochemotherapy for a common disfiguring disease, vitiligo, was practiced in the ancient world by physicians and herbalists who used boiled extracts of the fruits of certain umbelliferous plants, e.g. Ammi majus Linnaeus in Egypt or the leguminous plants, Psoralea corylifolia L. in India. It was first described by Kuske in 19388 that photosensitization of skin by plants was related to the presence of psoralen. He identified natural psoralens in plants as photosensitizers and isolated bergapten(5methoxypsoralen) from the oil of bergamot. The scientific interest in photosensitizing psoralens, however, has grown considerably after the introduction into clinics of the psoralen photochemotherapy for the treatment of psoriasis and of other skin (abbreviation)

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Variation of the Hemispheric Asymmetry of the Equatorial Ionization Anomaly with Solar Cycle

  • Kwak, Young-Sil;Kil, Hyosub;Lee, Woo Kyoung;Yang, Tae-Yong
    • Journal of Astronomy and Space Sciences
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    • 제36권3호
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    • pp.159-168
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    • 2019
  • In solstices during the solar minimum, the hemispheric difference of the equatorial ionization anomaly (EIA) intensity (hereafter hemispheric asymmetry) is understood as being opposite in the morning and afternoon. This phenomenon is explained by the temporal variation of the combined effects of the fountain process and interhemispheric wind. However, the mechanism applied to the observations during the solar minimum has not yet been validated with observations made during other periods of the solar cycle. We investigate the variability of the hemispheric asymmetry with local time (LT), altitude, season, and solar cycle using the electron density taken by the CHAllenging Minisatellite Payload satellite and the global total electron content (TEC) maps acquired during 2001-2008. The electron density profiles provided by the Constellation Observing System for Meteorology, Ionosphere, and Climate satellites during 2007-2008 are also used to investigate the variation of the hemispheric asymmetry with altitude during the solar minimum. During the solar minimum, the location of a stronger EIA moves from the winter hemisphere to the summer hemisphere around 1200-1400 LT. The reversal of the hemispheric asymmetry is more clearly visible in the F-peak density than in TEC or in topside plasma density. During the solar maximum, the EIA in the winter hemisphere is stronger than that in the summer hemisphere in both the morning and afternoon. When the location of a stronger EIA in the afternoon is viewed as a function of the year, the transition from the winter hemisphere to the summer hemisphere occurs near 2004 (yearly average F10.7 index = 106). We discuss the mechanisms that cause the variation of the hemispheric asymmetry with LT and solar cycle.

Low-Temperature Sintering Behavior of Aluminum Nitride Ceramics with Added Copper Oxide or Copper

  • Hwang, Jin-Geun;Oh, Kyung-Sik;Chung, Tai-Joo;Kim, Tae-Heui;Paek, Yeong-Kyeun
    • 한국세라믹학회지
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    • 제56권1호
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    • pp.104-110
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    • 2019
  • The low-temperature sintering behavior of AlN was investigated through a conventional method. $CaF_2$, CuO and Cu were selected as additives based on their low melting points. When sintered at $1600^{\circ}C$ for 8 h in $N_2$ atmosphere, a sample density > 98% was obtained. The X-ray data indicated that eutectic reactions below $1200^{\circ}C$ were found. Therefore, the current systems have lower liquid formation temperatures than other systems. The liquid phase showed high dihedral angles at triple grain junctions, indicating that the liquid had poor wettability on the grain surfaces. Eventually, the liquid was likely to vaporize due to the unfavorable wetting condition. As a result, a microstructure with clean grain boundaries was obtained, resulting in higher contiguity between grains. From EDS analysis, oxygen impurity seems to be well removed in AlN lattice. Therefore, it is believed that the current systems are beneficial for reducing sintering temperature and improving oxygen removal.

Feasibility Study for an Optical Sensing System for Hardy Kiwi (Actinidia arguta) Sugar Content Estimation

  • Lee, Sangyoon;Sarkar, Shagor;Park, Youngki;Yang, Jaekyeong;Kweon, Giyoung
    • 농업생명과학연구
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    • 제53권3호
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    • pp.147-157
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    • 2019
  • In this study, we tried to find out the most appropriate pre-processing method and to verify the feasibility of developing a low-price sensing system for predicting the hardy kiwis sugar content based on VNIRS and subsequent spectral analysis. A total of 495 hardy kiwi samples were collected from three farms in Muju, Jeollabukdo, South Korea. The samples were scanned with a spectrophotometer in the range of 730-2300 nm with 1 nm spectral sampling interval. The measured data were arbitrarily separated into calibration and validation data for sugar content prediction. Partial least squares (PLS) regression was performed using various combinations of pre-processing methods. When the latent variable (LV) was 8 with the pre-processing combination of standard normal variate (SNV) and orthogonal signal correction (OSC), the highest R2 values of calibration and validation were 0.78 and 0.84, respectively. The possibility of predicting the sugar content of hardy kiwi was also examined at spectral sampling intervals of 6 and 10 nm in the narrower spectral range from 730 nm to 1200 nm for a low-price optical sensing system. The prediction performance had promising results with R2 values of 0.84 and 0.80 for 6 and 10 nm, respectively. Future studies will aim to develop a low-price optical sensing system with a combination of optical components such as photodiodes, light-emitting diodes (LEDs) and/or lamps, and to locate a more reliable prediction model by including meteorological data, soil data, and different varieties of hardy kiwi plants.

Backsheet 반사율에 따른 Shingled Mini Module 출력변화에 대한 연구 (A Study on the Output Power of Shingled Mini Module Depending on Reflectance of Backsheets)

  • 조성현;문지연;손형진;전다영;김성현
    • Current Photovoltaic Research
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    • 제8권4호
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    • pp.129-133
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    • 2020
  • It is very important to optimize the reflectance of incident light in solar modules for improving output power and reducing loss of cell-to-module (CTM). It is assumed that a higher reflectance backsheet may improve optical efficiency. However how much output power is related to optical properties by reflectance property of backsheets have not been revealed clearly yet. A total of 3 types of industrial backsheets with 3 type of industrial encapsulants (EVA or POE) were analyzed as fabricated mini modules used shingled cells. According to the type of backsheets, the difference between the highest and lowest average reflectance in the range of 400 nm to 1200 nm was found to be 13.08% by UV-visible spectroscopy. Also, when using the same encapsulant, the maximum gap value of the output power increase was measured by about 3.755 mW% (166.02 mW). The correlation between reflectance and output power was experimentally found by measuring the output property of the fabricated shingled mini modules.

Radiation risk perception and its associated factors among residents living near nuclear power plants: A nationwide survey in Korea

  • Sung, Hyoju;Kim, Jung Un;Lee, Dalnim;Jin, Young Woo;Jo, Hyemi;Jun, Jae Kwan;Park, Sunhoo;Seo, Songwon
    • Nuclear Engineering and Technology
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    • 제54권4호
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    • pp.1295-1300
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    • 2022
  • There has been increased interest in researching risk perception of radiation to implement successful risk communication, particularly given the recent worldwide nuclear policy movement regarding nuclear energy. This study aimed to investigate characteristics of risk perception among residents living near normally operating nuclear power plants in South Korea by identifying factors associated with risk perception. A survey was conducted with face-to-face interviews for 1200 residents aged 20e84 years by gender- and age-stratified random sampling. Risk perception was associated with trust perception in nuclear safety, but was not highly correlated with benefit perception for utilizing nuclear power. Relatively high risk perception was observed in women, older age groups, and residents not having experience of nuclear-related education or work. This association remained after adjusting for other factors including benefit perception, trust perception, and psychological distress. In addition to these individual characteristics, risk perception was also associated with a residential district's own unique context, indicating that a strategy of risk communication should be developed differently for residents facing nuclear-related circumstances. Given that risk perception can be changed, depending on social values such as safety culture and economic setting, further studies are required to understand the changing characteristics of radiation risk perception.

산화물이 Doping된 YSZ의 고온 열처리에 따른 Monoclinic 상변화 및 미세구조 분석 (Analysis of Monoclinic Phase Change and Microstructure According to High-temperature Heat Treatment of Oxide-doped YSZ)

  • 이계원;최용석;전창우;이인환;오윤석
    • 한국분말재료학회지
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    • 제29권6호
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    • pp.468-476
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    • 2022
  • Yttria-stabilized zirconia (YSZ) has a low thermal conductivity, high thermal expansion coefficient, and excellent mechanical properties; thus, it is used as a thermal barrier coating material for gas turbines. However, during long-time exposure of YSZ to temperatures of 1200℃ or higher, a phase transformation accompanied by a volume change occurs, causing the YSZ coating layer to peel off. To solve this problem, YSZ has been doped with trivalent and tetravalent oxides to obtain coating materials with low thermal conductivity and suppressed phase transformation of zirconia. In this study, YSZ is doped with trivalent oxides, Nd2O3, Yb2O3, Al2O3, and tetravalent oxide, TiO2, and the thermal conductivity of the obtained materials is analyzed according to the composition; furthermore, the relative density change, microstructure change, and m-phase formation behavior are analyzed during long-time heat treatment at high temperatures.

Dynamic Contrast Enhanced MRI and Intravoxel Incoherent Motion to Identify Molecular Subtypes of Breast Cancer with Different Vascular Normalization Gene Expression

  • Wan-Chen Tsai;Kai-Ming Chang;Kuo-Jang Kao
    • Korean Journal of Radiology
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    • 제22권7호
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    • pp.1021-1033
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    • 2021
  • Objective: To assess the expression of vascular normalization genes in different molecular subtypes of breast cancer and to determine whether molecular subtypes with a higher vascular normalization gene expression can be identified using dynamic contrast-enhanced (DCE) magnetic resonance imaging (MRI) and intravoxel incoherent motion (IVIM) diffusion-weighted imaging (DWI). Materials and Methods: This prospective study evaluated 306 female (mean age ± standard deviation, 50 ± 10 years), recruited between January 2014 and August 2017, who had de novo breast cancer larger than 1 cm in diameter (308 tumors). DCE MRI followed by IVIM DWI studies using 11 different b-values (0 to 1200 s/mm2) were performed on a 1.5T MRI system. The Tofts model and segmented biexponential IVIM analysis were used. For each tumor, the molecular subtype (according to six [I-VI] subtypes and PAM50 subtypes), expression profile of genes for vascular normalization, pericytes, and normal vascular signatures were determined using freshly frozen tissue. Statistical associations between imaging parameters and molecular subtypes were examined using logistic regression or linear regression with a significance level of p = 0.05. Results: Breast cancer subtypes III and VI and PAM50 subtypes luminal A and normal-like exhibited a higher expression of genes for vascular normalization, pericyte markers, and normal vessel function signature (p < 0.001 for all) compared to other subtypes. Subtypes III and VI and PAM50 subtypes luminal A and normal-like, versus the remaining subtypes, showed significant associations with Ktrans, kep, vp, and IAUGCBN90 on DEC MRI, with relatively smaller values in the former. The subtype grouping was significantly associated with D, with relatively less restricted diffusion in subtypes III and VI and PAM50 subtypes luminal A and normal-like. Conclusion: DCE MRI and IVIM parameters may identify molecular subtypes of breast cancers with a different vascular normalization gene expression.

광도, 온도, $\textrm{CO}_2$ 농도 및 엽중 질소농도의 변화에 따른 양액재배 오이의 광합성속도에 관한 수리적 모형 (Mathematical Models of Photosynthetic Rate of Hydroponically Grown Cucumber Plants as Affected by Light Intensity, Air Temperature, Carbon Dioxide and Leaf Nitrogen Content)

  • 임준택;백선영;정현희;현규환;권병선
    • 생물환경조절학회지
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    • 제9권3호
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    • pp.171-178
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    • 2000
  • 시설 오이재배에서 조절가능한 환경요인들, 즉 광도, $CO_2$ 농도, 온도 그리고 엽중 질소 농도의 변화에 따른 양액재배 오이 엽의 총광합성 속도를 측정하였다. 광보상점은 10~20$\mu$mol.m$^{-2}$ .s$^{-1}$ 정도로 낮았고 광포화점은 1000$\mu$mol.m$^{-2}$ .s$^{-1}$ 이상이었으며, 오이의 총광합성 속도는 온도가 상승할수록 증가속도는 감소하지만 지속적인 증가를 보였으나 24~32$^{\circ}C$ 사이에서 광합성 속도는 큰 차이를 보이지 않아 이 범위가 오이 생육에 대한 적정온도인 것으로 나타났다. $CO_2$ 보상점은 20-40$\mu$mol.mol$^{-1}$ 사이에 위치하였고 $CO_2$포화점은 1200$\mu$mol.mol$^{-1}$이상으로 나타났으며 엽중은 질소함량의 증가에 따른 잎의 총광합성 속도의 변화는 sigmoid형의 증가추세를 보였다. 요인들간의 상호작용 효과에서는 모든 경우 상승적으로 나타나, 한 요인의 수준이 증가함에 따라 타 요인의 수준의 증가에 따른 총광합성 속도도 상승적을 증가하였다. 각환경요인의 변화와 요인들간의 상호작용에 따른 총광합성 속도의 변화에 대한 수리적 모형을 개발하였다. 이들 모형은 시설 내 환경변이에 따른 오이의 생육 내지는 수량에서의 차이를 밝히는데 이용될 수 있으며 오이의 식물생장 모형이나 더 나아가 경영합리화를 위한 오이 생산 전문가 시스템의 개발에 필요한 기초 자료로 이용될 수 있을 것이다.

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