• Title/Summary/Keyword: OH Spectrum Band

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The study on the spectroscopic and electrical properties of Azomethine compounds (Azomethine계 화합물의 분광학적 특성과 전기적 특성에 관한 연구)

  • Baek, Dae-Jin;Oh, Won-Chun;Ko, Young-Shin
    • Analytical Science and Technology
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    • v.8 no.3
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    • pp.249-258
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    • 1995
  • The polymers, polyazine, polyazomethine ( I ) and polyazomethine ( II ) were prepared by the condensation of p-benzoquinone with hydrazine hydrate, p-phenylenediamine and diaminomaleonitrile in DMSO, respectively. The IR spectra of these polymers showed a characteristic peak of schiff base (-C=N-) at about $1600cm^{-1}$. These polymers dissolved in concentrated sulfuric acid showed UV/VIS absorption near 300nm indicatiog the presence of iminium ion(>$C\limits^{\small\oplus}=NH-$). Another UV/VIS absorption band in the region of 350~415nm was shown presumably due to the charge transfer transition in the molecule. The electrical conductivities of polyazine, polyazomethine ( I ) and ( II ) were measured. The self-electrical conductivity of these was found to be about $10^{-14}{\sim}10^{-11}{\Omega}^{-1}cm^{-1}$ and these polymers doped with $I_2$ showed the maximum conductivity of about $10^{-2}{\Omega}^{-1}cm^{-1}$.

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Analysis of Adjacent Channel Interference for WCDMA ATC Service Frequency Allocation Operating in MSS Band (MSS 대역 WCDMA ATC 서비스 주파수 할당을 위한 인접 채널 간섭 분석)

  • Kang, Young-Heung;Jeong, Nam-Ho;Oh, Dae-Sub
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.23 no.11
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    • pp.1288-1296
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    • 2012
  • A candidate hybrid satellite and terrestrial network architecture, MSS/ATC(Mobile Satellite Service/Ancillary Terrestrial Component), is proposed for utilizing efficiently the exist MSS bands. Studies on the adjacent channel interference from the existing terrestrial mobile services and MSS/ATC itself are important to allocate a new ATC service frequency in MSS band. In this paper, we have analyzed the minimum permission power of terrestrial base station and the capacity loss with parameters of ACIR, number of MS(mobile Station) and MES(Mobile Earth Station) in uplink, and also, the capacity performance based on 1 beam and 1 cell assumption for MSS/ATC in downlink. The ACIR requirements are estimated in two MSS/ATC frequency allocation scenarios for 5 MHz and 10 MHz guard band to share spectrum with adjacent systems, and according to these ACIR requirements the service coverage and the receiver filter for ATC system should be designed in near future.

Speech enhancement system using the multi-band coherence function and spectral subtraction method (다중 주파수 밴드 간섭함수와 스펙트럼 차감법을 이용한 음성 향상 시스템)

  • Oh, Inkyu;Lee, Insung
    • The Journal of the Acoustical Society of Korea
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    • v.38 no.4
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    • pp.406-413
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    • 2019
  • This paper proposes a speech enhancement method through the process of combining the gain function with spectrum subtraction method in the two microphone array with close spacing. A speech enhancement method that uses a gain function estimated by the SNR (Signal-to Noise Ratio) based on the multi frequency band coherence function causes the performance degradation in high correlation between input noises of two channels. A new speech enhancement method is proposed where the weighted gain function is used by combining the gain function from the spectral subtraction. The performance evaluation of the proposed method was shown by comparison with PESQ (Perceptual Evaluation of Speech Quality) value which is an objective quality evaluation test provided by the ITU-T (International Telecommunications Union Telecommunication). In the PESQ tests, the maximum 0.217 of PESQ value is improved in the various background noise environments.

Identification of C3G(cyanidin-3-glucoside) from Mulberry Fruits and Quantification with Different Varieties (오디에서 C3G(cyanidin-3-glucoside)의 분리, 동정 및 계통별 함량분석)

  • 김현복;김선림
    • Journal of Sericultural and Entomological Science
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    • v.45 no.2
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    • pp.90-95
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    • 2003
  • This study was carried out to identify of C3G (cyanidin-3-glucoside) from mulberry fruits and quantify with different varieties. C3G of mulberry fruits was extracted with 1% HCl-MeOH and purified with open column (5${\times}$90cm) which filled with Amberlite IRC-50 ion exchange resin. The $\lambda$max ranges of the purified C3G on UV/vis spectrum were 516nm and 280nm. Also, molecular weight of C3G from mulberry fruits by LC-Mass was determined as 449. From above results, we concluded that anthocyanin pigment of mulberry fruits was C3G only. The cyanidin-3-glucoside (C3G) was separated and quantified by High Performance Liquid Chromatography (HPLC) system using a Nova-Pack C$\_$18/ column. Mean content of the 35 tested accessions was 0.89%. Also fruity characteristics as well as C3G content to select the desirable mulberry varieties for the production of fruit were researched and analyzed. We selected three suitable varieties such as 'Susungppong', 'Kangsun', and 'Jeolgokchosaeng(Chungpuk)'.

A Study on the Characteristics of Humic Materials Extracted from Decomposing Plant Residues -I. Chemical Properties of Humic Acids from Plant Residues Characterized by IR Spectra (식물성(植物性) 유기물질(有機物質)의 부숙과정중(腐熟過程中) 부식특성(腐植特性)에 관(關)한 연구(硏究) -1. 분광분석(分光分析)에 의(依)한 식물잔해(植物殘骸) 부식산(腐植酸)의 화학적(化學的) 성질규명(性質糾明))

  • Kim, Jeong-Je;Shin, Young-Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.3
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    • pp.251-259
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    • 1987
  • Humic acids extracted from decomposing plant residues were characterized by infrared(IR) spectra. The IR spectra were further interpreted by chemical analyses for oxygen-containing functional groups such as carboxyl, phenolic, alcoholic, carbonyl, and quinionic groups. 1. The IR spectra obtained in this study were divied into three categories: spectra of humic acids from grain crop straws of rice, barley, wheat and rye produced Type I, while that from wild grass hay yielded Type II, and those from forest tree litter of the deciduous and conifers were led to give Type III. 2. There were no significant changes in the absorption bands observed among humic acids extracted at various stages of decomposition of a given Plant material. 3. The absorption band at about $3,430cm^{-1}$ represents the presence of hydrogen-bonded hydroxyl groups, phenolic-OH groups being the major component. 4. A close relationship was found between the total acidity and the content of phenolic-OH groups of humic acids. The content of carboxyl groups maintains a direct relationship with the content of total hydroxyl groups, and such a close relationship also exists between the content of alcoholic hydroxyls and that of total hydroxyl groups. 5. Overlapping of the absorption bands of carbonyl groups and quinones renders it difficult to make differentiation between the two. 6. A variety of non-armoatic cyclic hydrocarbons appears to be a structural component as evidenced by a sharp absorption peak near $995-1000cm^{-1}$.

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Electronic Spectroscopy of Protonated Tyr-Ala Dipeptide Ions (Tyr-Ala 펩타이드 이온의 전자전이 분광 연구)

  • Choi, Chang-Min;Kwon, Jang-Sook;Kim, Hwan-Jin;Yoon, Tae-Oh;Yang, Min-O;Kim, Nam-Joon
    • Journal of the Korean Chemical Society
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    • v.51 no.4
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    • pp.318-323
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    • 2007
  • Electronic photofragmentation spectrum of protonated tyrosine-alanine dipeptide ions(YAH+) was obtained in the wavenumber region of 34500~36700 cm-1 using a quadrupole ion trap time-of-flight mass spectrometer (QIT-TOFMS). YAH+ ions were produced by electrospray ionization, stored in the ion trap and then irradiated by ultraviolet laser pulses which induced photofragmentation of the ions. The electronic photofragmentation spectrum was obtained by monitoring the photodissociation yields of YAH+ ions as a function of the laser wavelength. The spectrum exhibited two broad peaks which were assigned as S1 and S2 by theoretical calculations using a time-dependent density functional method. The broad widths of the peaks in the spectrum were explained by the overlaps of the peaks originated from various conformers of YAH+ ions which were present in the gas phase at room temperature and also by the contributions of the hot bands.

Characteristics of Kenaf Fibers Treated by Alkali (알칼리 처리에 따른 케나프 섬유의 특성 변화 연구)

  • Yoo, Hye-Ja;Lee, Hye-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.8
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    • pp.982-990
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    • 2011
  • Kenaf fiber can be obtained by decortications of the kenaf plant stem. The properties of the kenaf fiber treated by alkali (NaOH) were investigated by spectrocolorimeter, SEM, X-ray diffractometer, FT-IR and TGA. The kenaf fibers treated by alkali became darker and their Munsell color values changed from Y (yellow) to YR (yellowred) according to an increased NaOH concentration. SEM observation of the kenaf fibers showed that their crimps were developed and their surfaces were cleaned by the removal of protruding ends and impurities after alkali treatments. In the x-ray diffraction analysis, the structures of the fibers were found in the form of cellulose I when treated with a 0-16% alkali concentration and cellulose II when treated with over 20%. It was also confirmed that the crystallinity was lowered according to an increased NaOH concentration. The change of fiber compositions was investigated in FT-IR analysis. Strong band of $1,738cm^{-1}$ and asymmetrical stretching strong bands of $1,630-1,600cm^{-1}$ in spectrum (which represent pectin) were not found in the samples because the pectin was removed by the alkali treatment. Weak bands of $1,728-1,730cm^{-1}$ and peaks of $1,245-1,259cm^{-1}$ (which represent hemicellulose) and peaks of $1,592cm^{-1}$, $1,504cm^{-1}$, $1,462cm^{-1}$ and $1,429cm^{-1}$ (which are related to lignin) were not found or reduced in the samples treated with a concentration over 20%. TGA indicated that the kenaf fiber had the better hydrophilic properties by alkali treatment. The higher Tmax in TGA and the higher thermal stability when treated by alkali with the higher concentration. The fibers treated with an alkali concentration over 30% did not show any changes in Tmax.

A Study on Frequency Spectrum Allocation for the Next-Generation Terrestrial Broadcasting Service (차세대 지상파 방송을 위한 주파수 배분 연구)

  • Oh, Jai-Pil;Kim, Min-Ki;Kim, Dong Ho
    • Journal of Satellite, Information and Communications
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    • v.9 no.1
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    • pp.79-84
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    • 2014
  • Increasing demand for realistic media and improvement of transmission and device techniques accelerate ultra-high definition(UHD) service realization. In Korea, the cable TV broadcasting companies are planning to commercialize in Apr. 2014. For the terrestrial TV broadcasting service, technical issues are considered for the specification of UHD broadcasting system. However, the frequency bands and the system bandwidth for the terrestrial UHD broadcasting system have not been decided. In this paper, we propose required spectrum bandwidth for the next-generation terrestrial broadcasting service considering source coding, error correcting codes and modulation techniques. Also, we propose frequency management plan for terrestrial UHD broadcasting system in which we divide all parts of the country into 9 frequency zones and allocate 4 frequency band to each frequency zone considering single frequency network (SFN).

Design of Maritime Satellite Communication Systems Sharing Frequency with DVB-S2 (DVB-S2와 주파수 공유하는 해양 위성 통신 시스템 설계)

  • Ryu, Joon-Gyu;Oh, Deock-Gil;Yu, Heejung
    • Journal of Satellite, Information and Communications
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    • v.8 no.4
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    • pp.75-80
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    • 2013
  • In this paper, the Ka-band maritime satellite communication systems for mobile terminals are proposed. The design includes the link budget analysis, determination of modulation and coding schemes and the overall structure of a transmitter. To avoid the harmful effects on the existing DVB-S2 services, the proposed maritime satellite system using the same spectrum with DVB-S2 at the same time employs the very wideband spreading transmission. Additionally, omni-directional low-gain antennas should be equipped in a mobile terminal to reduce the system cost. These two considerations limit the maximum transmission rate of the proposed system. Due to the limitations, the proposed system includes 36 dB or 39 dB spreading gain depending on the modulation scheme and a link-adaptive repetition method depending on the level of rain attenuation. To support short packets with minimal performance loss, the turbo code used in 3GPP instead of LDPC(low density parity check code) is adopted. By combining them, the overall structure of low-rate maritime satellite communication system is designed.

A Study on Interference Analysis between FHSS and DSSS Short Range Radio Devices (FHSS 및 DSSS 방식 소출력 무선기기간 간섭 분석에 관한 연구)

  • Kim, Jin-Young;Kim, Eun-Cheol;Yang, Jae-Soo;Ryu, Chung-Sang;Oh, Seong-Taek
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.19 no.2
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    • pp.271-279
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    • 2008
  • In this paper, we investigate interference between short-range radiocommunication devices(SRDs) with frequency hopping spread spectrum(FHSS) and direct sequence spread spectrum(DSSS) methods when they are in the same frequency bands. In order to analyze interference from unwanted emission of SRD with DSSS to that of FHSS, Monte-carlo(MC) simulation method is employed and interference probabilities are calculated. We simulate interference scenarios in accordance with several duty cycles and bandwidths. It is also assumed that the propagation model is free space. The effect of distance between interfering transmitter and victim receiver is analyzed and bit error rate(BER) is simulated. From the interference analysis results, it is shown that duty cycle affects compatibility more than band-width does. Also, we can make sure of the separation distance which satisfies BER criterion when there are only one interfering transmitter and multiple interfering transmitters.