• Korean Journal of Environmental Biology
• /
• v.36 no.1
• /
• pp.90-97
• /
• 2018

This study assessed the effect of ozone to control pathogenic bacteria in inlet water flowing to flounder farms, establishing operational parameters of ozonation at seawater conditions. Hydraulic retention time in a reaction pipeline after ozonation was fixed at 3 minutes in a flow through system. Concentrations of total residual oxidant (TRO) by ozonation were measured according to different ozonation intensities. The oxidant reduction potential (ORP), which is indirect but enables real-time measurement, was measured in relation to TRO values. TRO values were $0.01{\pm}0.01mg\;L^{-1}$ at an ORP range of 320-410 mV, $0.07{\pm}0.02mg\;L^{-1}$ at 600 mV, and $0.16{\pm}0.03mg\;L^{-1}$ at 700 mV. A heterotrophic marine bacteria colony was reduced by 80.6-97.9%, showing the suppression effect of ozonation on total bacteria in inlet water. At an ORP range of 400-500 mV, colonies of heterotrophic marine bacteria, Vibrio spp., and gram negative bacteria were significantly reduced in outlet water from a culture tank with ongrowing flounder (230 g) at a stocking density of $8kg\;m^{-2}$. Especially, Vibrio spp. and gram negative bacteria were seldom found at 400-500 mV. The daily feeding rate was from over 0.7% to total body weight at 300-500 mV, showing better performance than that in the control. The pathogenic bacteria entering the flounder farm were effectively removed when the ORP range to 400 mV or less.

• Korean Chemical Engineering Research
• /
• v.40 no.6
• /
• pp.746-751
• /
• 2002

Fluidized bed combustion is a coal combustion technology that can reduce both SOx and NOx emission; SOx is removed by limestone that is fed into the combustion chamber and the NOx is reduced by low temperature combustion in a fluidized bed combustor and air stepping, but $N_2O$ generation is quite high. $N_2O$ is not only a greenhouse gas but also an agent of ozone destruction in the stratosphere. The calcium oxide(CaO) is known to be a catalyst of $N_2O$ decomposition. This study of $N_2O$ decomposition reaction in fixed bed reactor packed over CaO bed has been conducted. Effects of parameters such as concentration of inlet $N_2O$ gas, reaction temperature, CaO bed height and effect of $CO_2$, NO, $O_2$ gas on the decomposition reaction have been investigated. As a result of the experiment, it has been shown that $N_2O$ decomposition reaction increased with the increasing fixed bed temperature. While conversion of the reaction was decreased with increasing $CO_2$ concentration. Also, under the present of NO, the conversion of $N_2O$ decomposition is decreased. From the result of kinetic study gained the heterogeneous reaction rate on $N_2O$ decomposition. In the case of $N_2O$ decomposition over CaO, heterogeneous reaction rate is. $\frac{d[N_2O]}{dt}=\frac{3.86{\times}10^9{\exp}(-15841/R)K_{N_2O}[N_2O]}{(1+K_{N_2O}[N_2O]+K_{CO_2}[CO_2])}$. In this study, it is found that the calcium oxide is a good catalyst of $N_2O$ decomposition.

• Advances in environmental research
• /
• v.4 no.4
• /
• pp.233-246
• /
• 2015

High amounts of air pollution in crowded urban areas are always considered as one of the major environmental challenges especially in developing countries. Despite the errors in air pollution prediction, the forecasting of future data helps air quality management make decisions promptly and properly. We studied the air quality of the Aqdasiyeh location in Tehran using factor analysis and the Box-Jenkins time series methods. The Air Quality Control Company (AQCC) of the Municipality of Tehran monitors seven daily air quality parameters, including carbon monoxide (CO), Nitrogen Monoxide (NO), Nitrogen dioxide ($NO_2$), $NO_x$, ozone ($O_3$), particulate matter ($PM_{10}$) and sulfur dioxide ($SO_2$). We applied the AQCC data for our study. According to the results of the factor analysis, the air quality parameters were divided into two factors. The first factor included CO, $NO_2$, NO, $NO_x$, and $O_3$, and the second was $SO_2$ and $PM_{10}$. Subsequently, the Box- Jenkins time series was applied to the two mentioned factors. The results of the statistical testing and comparison of the factor data with the predicted data indicated Auto Regressive Integrated Moving Average (0, 0, 1) was appropriate for the first factor, and ARIMA (1, 0, 1) was proper for the second one. The coefficient of determination between the factor data and the predicted data for both models were 0.98 and 0.983 which may indicate the accuracy of the models. The application of these methods could be beneficial for the reduction of developing numbers of mathematical modeling.

• Journal of the Korea Institute of Information and Communication Engineering
• /
• v.26 no.2
• /
• pp.294-305
• /
• 2022

Recently, drones have been widely used to solve environmental problems such as environmental protection and natural disaster monitoring. This study focuses on the problem of the search altitude of drones when using drones to search for air pollution in order to maintain the urban air environment. In particular, when exploring air pollution in cities using drones, various experiments are conducted to determine the appropriate search altitude for each air pollution source and each communication module. Through the experiment, the maximum measurable altitude for the most common air pollutants, such as CO (carbon monoxide), NO₂ (nitrogen dioxide), O₃ (ozone), and P10, P2.5 (fine dust), was identified, and the effective search altitude for each air pollution source was determined. As a result of the experiment, three types of drone search altitudes including legally measurable altitudes were suggested. The communication module measurable altitude was 60m to 120m depending on the communication module, and the effective measurable altitude was analyzed from 10m to 100m.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2008.05a
• /
• pp.1452-1456
• /
• 2008

우리나라 주요 상수원인 낙동강, 금강 등의 수질이 급격히 악화됨에 따라, 기존의 정수방법에 어려움이 발생되고 있다. 과거 염소에 의존한 수처리방법이 많이 사용되어 왔으나, 1989년 이후 중금속, THM(Trihalomethane), 페놀사건, 벤젠 등 각종 수돗물 유기물질 오염사고가 다발하면서, 활성탄 및 오존$(O_3)$ 등을 이용한 다양한 처리 시설들이 도입되기 시작했다. 이중 강력한 산화력을 지니고 있는 오존의 경우, 상수처리, 폐 배수처리, 식품의 살균 및 보관, 나아가 반도체 제조공정중의 포토레지스터의 제거에 이르기까지 폭넓게 사용되고 있다. 그러나 오존이 가지는 뛰어난 정화능력에도 불구하고, 막대한 설치비용 및 운전비용의 문제로 하수처리장과 같은 대규모 시설에서는 도입되지 못하고 있었다. 이러한 문제점을 극복하고자 본 연구에서는 재생 가능한 에너지를 오존시스템의 전력원으로 대용시킴으로써, 그 효과를 극대화시키고자 하는데 목적이 있다. 에너지 밀도가 낮지만, 지역 의존성이 적고, 청정한 무한 에너지인 수력, 풍력 및 태양에너지를 혼용한 오존 발생시스템은 소규모의 연못이나 농촌의 저수지 같은 유역뿐만 아니라, 농촌폐수로 인해 오염된 지하수의 국소지역에 대한 수처리에 사용될 수 있다.

• Journal of Environmental Science International
• /
• v.21 no.2
• /
• pp.165-179
• /
• 2012

Indirect $CO_2$ effect due to non-methane volatile organic compound (NMVOC) emissions from solvent and product use and fugitive NMVOC emissions from fuels in the Republic of Korea and 13 Annex I countries under United Nations Framework on Climate Change were estimated and the proportions of them to total greenhouse gas (GHG) emissions ranged from 0.092% to 0.45% in 2006. Indirect greenhouse effect ($CO_2$, $CH_4$, and $O_3$) were estimated at 13 photochemical assessment monitoring sites in the Republic of Korea using concentrations of 8 NMVOCs of which indirect global warming potential (GWP) were available. The contribution of toluene to mixing ratio was highest at 11 sites and however, the contribution of toluene to indirect greenhouse effect was highest at nine sites. In contrast to toluene, the contributions of ethane, butane, and ethylene were enhanced. The indirect greenhouse effects of ethane and propane, of which ozone formation potentials are the lowest and the third lowest respectively among targeted 10 NMVOCs, ranked first and fourth highest respectively. Acetaldehyde has relatively higher maximum incremental reactivity and is classified as probable human carcinogen however, its indirect GWP ranked second lowest.

• Journal of the Korean Data and Information Science Society
• /
• v.21 no.6
• /
• pp.1117-1124
• /
• 2010

The PM10 (Promethium 10) data is one of the important environmental data for measurement of the atmospheric condition of the country. In this article, the Autoregressive Error (ARE) model has been considered for analyzing the monthly PM10 data at the southern part of the Gyeonggi-Do, Suwon monitoring site in Korea. In the ARE model, six meteorological variables and four pollution variables are used as the explanatory variables for the PM10 data set. The six meteorological variables are daily maximum temperature, wind speed, relative humidity, rainfall, radiation, and amount of cloud. The four air pollution explanatory variables are sulfur dioxide ($SO_2$), nitrogen dioxide ($NO_2$), carbon monoxide (CO), and ozone ($O_3$). The result showed that the monthly ARE models explained about 13-49% for describing the PM10 concentration.

• Journal of Environmental Science International
• /
• v.14 no.6
• /
• pp.555-563
• /
• 2005

This study presents the characteristics of nocturnal inversion layer and their effect on the concentration variations of surface air pollutants using tethersonde and automatic weather station (AWS, 2 layer tower) system in Ulsan during 2003, The method for the distinction of inversion intensity was decided based on the sum of nocturnal temperature gradient. As the results, there was a close correlation (correlation coefficient of 0,76) between the maximum inversion height obtained from tethersonde and the sum of nocturnal temperature gradient. The air pollutant concentration was also directly proportional to the inversion intensity. When the inversion intensity was strong in the nighttime, ozone $(O_3)$ concentration was lower, while nitrogen dioxide $(NO_2)$ concentration was higher. The carbon monoxide (CO) concentration was gradually higher according to the nocturnal inversion intensity, whereas sulfur dioxide $(SO_2)$ concentration was relatively constant. In addition, we found that there was no correlation between the inversion intensity and TSP concentration.

• Transactions of the Society of Information Storage Systems
• /
• v.9 no.2
• /
• pp.42-47
• /
• 2013

In this study, we have experimentally analyzed how the surface properties of transparent electrode layer influence the photovoltaic performance of bulk heterojunction organic solar cell by the contact angle measurement and X-ray photoelectron spectroscopy(XPS) observation. As a result, the power conversion efficiency of test devices improved from 0.64% to 1.83% and 2.15% by UV-ozone exposure and $O_2$ plasma treatment, respectively. Thus, we conclude that the surface activation process is very important for better performance and stability in addition to the cleaning process of carbonate residue on the surface.

• Journal of Korean Society of Environmental Engineers
• /
• v.35 no.12
• /
• pp.889-896
• /
• 2013

Advanced Oxidation Processes (AOP) have been interested for removing micropollutants in water. Most of water treatment plants (WTPs) located along the lower part of Nakdong River have adopted the $O_3/BAC$ process and have interesting in peroxone process a kind of AOP. This study evaluated the removal characteristics of residual hydrogen peroxide ($H_2O_2$) combining with the biofiltration process in the next BAC process when the hydrogen peroxide is applied for the WTP operating $O_3/BAC$ process. In the experiment, changing the temperature and the concentration of $H_2O_2$ of influent, the biofiltration process showed rapidly dropped the biodegradability when the $H_2O_2$ concentration was increased and lowered water temperature while BAC process maintained relatively stable efficiency. The influent fixed at $20^{\circ}C$ and the concentration of $H_2O_2$ at 300 mg/L was continuously input for 78 hours. Most of the $H_2O_2$ in the influent did not remove at the biofiltration process controlled 5 to 15 minutes EBCT condition after 24~71 hours operating time while BAC process controlled 5 to 15 minutes EBCT showed 38~91% removal efficiency condition after 78 hours operating time. Besides, after 78 hours continuously input experiment, the biomass and activity of attached bacterial on the biofilter and BAC were $6.0{\times}10^4CFU/g$, $0.54mg{\cdot}C/m^3{\cdot}hr$ and $0.4{\times}10^8CFU/g$, $1.42mg{\cdot}C/m^3{\cdot}hr$ respectively. These biomass and activity values were decreased 99% and 72% in biofilter and 68% and 53% in BAC compared with initial condition. The biodegradation rate constant ($k_{bio}$) and half-life ($t_{1/2}$) in BAC were decreased from $1.173min^{-1}$ to $0.183min^{-1}$ and 0.591 min to 3.787 min respectively according to increasing the $H_2O_2$ concentration from 10 mg/L to 300 mg/L at $5^{\circ}C$ water temperature and the $k_{bio}$ and $t_{1/2}$ were $1.510min^{-1}$ to $0.498min^{-1}$ and 0.459 min to 1.392 min at $25^{\circ}C$ water temperature. By increasing the water temperature from $5^{\circ}C$ to $15^{\circ}C$ or $25^{\circ}C$, the $k_{bio}$ were increased 1.1~2.1 times and 1.3~4.4 times. If a water treatment plant operating $O_3/BAC$ process is considering the hydrogen peroxide for the peroxone process, post BAC could effectively decrease the residual $H_2O_2$, moreover, in case of spilling the $H_2O_2$ into the water process line, these spilled $H_2O_2$ concentration can be able to decrease by increasing the EBCT at the BAC process.