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Microstructure and Dielectric Properties of (Ba0.86Ca0.14)(Ti0.85Zr0.12Sn0.03)O3 Ceramics ((Ba0.86Ca0.14)(Ti0.85Zr0.12Sn0.03)O3계 세라믹스의 미세구조와 유전 특성)

  • Shin, Sang-Hoon;Yoo, Ju-Hyun;Lee, Gwang-Min;Shin, Dong-Chan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.7
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    • pp.424-427
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    • 2015
  • In this study, in order to develop the capacitor composition ceramics with the good dielectric properties, $(Ba_{0.86}Ca_{0.14})(Ti_{0.85}Zr_{0.12}Sn_{0.03})O_3+xCuO$ (x= 0.006~0.010) ceramics were prepared by the conventional solid-state reaction method. The effects of CuO addition on the microstructure and dielectric properties was investigated. All specimens indicated rhombohedral phase without any secondary phase. As CuO addition increased, the variation width of TCC was increased at more than $40^{\circ}C$. Also, the specimen with x=0.007 sintered at $1,250^{\circ}C$ showed the high dielectric constant of 9,632 in spite of low temperature sintering temperature.

A study on ZnO varistor Design Prevented from Thermal Explosion (열폭주 방지 ZnO 배리스터 설계에 대한 연구)

  • Jung, Tae-Hun;Shin, Hee-Sang;Cho, Sung-Min;Choi, Sung-Wook;Kim, Jae-Chul
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1453_1454
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    • 2009
  • This paper examines the characteristics of ZnO varistor to prevent from thermal explosion. We carry out performance evaluation of electrical characteristics on ZnO varistor. we will develop ZnO varistor Prevented from thermal explosion using test result of this paper.

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High-temperature oxidation of Ti3(Al,Si)C2 nano-laminated compounds in air

  • Lee, Hwa-Shin;Lee, Dong-Bok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.147-148
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    • 2007
  • The compound, Ti3(Al,Si)C2, was synthesized by hot pressing a powder mixture of TiCX, Al and Si. Its oxidation at 900 and 1000 oC in air for up to 50 h resulted in the formation of rutile-TiO2, -Al2O3 and amorphous SiO2. During oxidation, Ti diffused outwards to form the outer TiO2 layer, and oxygen was transported inwards to form the inner mixed layer.

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Novel Synthesis of MnO2-SiC Fiber-TiO2 Ternary Composite and Effective Photocatalytic Degradation with Standard Dyes

  • Latiful Kabir;Yeon Woo Choi;Yun Seo Shin;Yeon Ji Shin;Geun Chan Kim;Jun Hyeok Choi;Jo Eun Kim;Young Jun Joo;Kwang Youn Cho;Hyuk Kim;Je-Woo Cha;Won-Chun Oh
    • Korean Journal of Materials Research
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    • v.34 no.6
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    • pp.275-282
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    • 2024
  • In this work, we investigated the photo-degradation performance of MnO2-SiC fiber-TiO2 (MnO2-SiC-TiO2) ternary nanocomposite according to visible light excitation utilizing methylene blue (MB) and methyl orange (MO) as standard dyes. The photocatalytic physicochemical characteristics of this ternary nanocomposite were described by X-ray diffraction (XRD), scanning electron microscopy (SEM), tunneling electron microscopy (TEM), ultraviolet-visible (UV-vis), diffuse reflectance spectroscopy (DRS), electrochemical impedance spectroscopy (EIS), photocurrent and cyclic voltammogram (CV) test. Photolysis studies of the synthesized MnO2-SiC-TiO2 composite were conducted using standard dyes of MB and MO under UV light irradiation. The experiments revealed that the MnO2-SiC-TiO2 exhibits the greatest photocatalytic dye degradation performance of around 20 % with MB, and of around 10 % with MO, respectively, within 120 min. Furthermore, MnO2-SiC-TiO2 showed good stability against photocatalytic degradation. The photocatalytic efficiency of the nanocomposite was indicated by the adequate photocatalytic reaction process. These research results show the practical application potential of SiC fibers and the performance of a photocatalyst composite that combines these fibers with metal oxides.

Combinatorial Synthesis and Screening of the Tb-activated Phosphors in the System $CaO-Y_{2}O_3-Al_{2}O_{3}$

  • Yoon, Ho-Shin;Kim, Chang-Hae;Park, Hee-Dong;Ryu, Seung-Kon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.836-839
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    • 2003
  • We have synthesized some phosphors in the system $CaO-Y_{2}O_3-Al_{2}O_{3}$ by combinatorial polymerized-complex method. Composition and synthetic temperature of phosphors in the liblary was screened from the emission intensities of individual samples under VUV excitation. In $Tb^{3+}$-activated $CaO-Y_{2}O_3-Al_{2}O_{3}$, green phosphors showing good intensity were found to be $CaYAl_{3}O_{7}$, $CaYalO_{4}$, $YAlO_{3}$, $Y_{3}Al_{5}O_{12}$, $Y_{4}Al_{2}O_{9}$, $Ca_{3}Al_{2}O6$.

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