• 대한설비공학회지:설비저널
• /
• 제17권2호
• /
• pp.150-158
• /
• 1988

On a refrigeration compressor, damage of a discharge valve is one of the annoying troubles for an engineer. Small size compressors, having ring plate type discharge valve are recently used. Therefore, it is very important for engineers to measure and analyze strains of discharge valve. The purpose of this study is to obtain the basic data of the strain of the flexible ring valve. Measurements were performed by the strain gauge bonded on the surface of the flexible ring valve. Stress and strain of the valve were calculated by the method of uniformly loaded circular plates with a central hole. The results obtained are as follows; (1) the strain of flexible ring discharge valve in refrigeration compressor was influenced by tension and compression strain simultaneously. (2) for a given discharge pressure, the tangential and radial strains was increased with increasing discharge pressure. (3) the valve of radial strain was larger than that of tangential strain.

• 천문학논총
• /
• 제27권4호
• /
• pp.257-258
• /
• 2012

With AKARI, we carried out near-infrared spectroscopy of the nearby barred spiral galaxy, NGC 1097, categorized as Seyfert 1 with a circumnuclear starburst ring. Our observations mapped the galactic center region. As a result, we obtain the spatial distributions of the polycyclic aromatic hydrocarbon $3.3{\mu}m$ and the aliphatic hydrocarbon $3.4-3.6{\mu}m$ emission. The former is detected from all the observed regions and the latter is enhanced near the bar connecting the ring with the nucleus. In addition, we detect absorption features due to $H_2O$ ice and CO/SiO at the ring and the galactic center, while we detect the hydrogen recombination line $Br{\alpha}$ only from the ring. Hence the observed spectra change dramatically within the central 1 kpc region.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2009년도 제33회 추계학술대회논문집
• /
• pp.119-122
• /
• 2009

본 연구는 친환경 추진제인 과산화수소($H_2O_2$)와 케로신을 추진제로 하는 액체 로켓 엔진에서의 막냉 각 장치 개발을 목적으로 이를 위하여 막냉각링을 설계/제작하고, 수류 시험을 통해 분무 특성과 공급 유량을 확인하였다. 또한 설계/제작된 막냉각링의 성능 예측을 위하여 열해석을 수행하였다. 수류 실험 결과 설계 유량(42.25g/s)이 공급됨을 확인하였고, 상대적으로 유속이 빠르고 홀 개수가 많은 막냉각링이 더 좋은 분무패턴을 보임을 확인하였다. 또한 열해석 결과 설계된 막냉각링이 충분한 냉각 성능을 가짐을 확인하였다.

• 한국전기전자재료학회논문지
• /
• 제17권2호
• /
• pp.171-177
• /
• 2004

Voltage step-down characteristics in Ring/Dot type piezoelectric transformer were examined as a function of the area of input electrode when the area of output electrode is fixed. The effects of driving frequency and load resistance on the voltage step-down characteristics were also examined. Voltage gain was greatly dependent on the driving frequency and load resistance, and showed a maximum gain at resonance frequency of the step-down transformer. The frequency where the maximum cutout voltage appears increased about 0.2％ as the load resistance increased from 10 to 150 Ω. As the area of input electrode increased, the voltage gain and the efficiency of the transformer increased. Frequency dependence of efficiency of the step-down transformer revealed a similar tendency with the voltage gain curves. The maximum efficiency remarked 94% when the input voltage and the load resistance were 20 Vpp and 120 Ω, respectively.

• Bulletin of the Korean Chemical Society
• /
• 제35권9호
• /
• pp.2717-2722
• /
• 2014

The reaction mechanism between azacyclopropenylidene and epoxypropane has been systematically investigated employing the second-order M${\o}$ller-Plesset perturbation theory (MP2) method to better understand the reactivity of azacyclopropenylidene with four-membered ring compound epoxypropane. Geometry optimization, vibrational analysis, and energy property for the involved stationary points on the potential energy surface have been calculated. It was found that for the first step of this reaction, azacyclopropenylidene can insert into epoxypropane at its C-O or C-C bond to form spiro intermediate IM. It is easier for the azacyclopropenylidene to insert into the C-O bond than the C-C bond. Through the ring-opened step at the C-C bond of azacyclopropenylidene fragment, IM can transfer to product P1, which is named as pathway (1). On the other hand, through the H-transferred step and subsequent ring-opened step at the C-N bond of azacyclopropenylidene fragment, IM can convert to product P2, which is named as pathway (2). From the thermodynamics viewpoint, the P2 characterized by an allene is the dominating product. From the kinetic viewpoint, the pathway (1) of formation to P1 is primary.

• 한국연소학회:학술대회논문집
• /
• 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
• /
• pp.125-130
• /
• 2003

본 논문에서는 액체로켓엔진에서 터보펌프의 160kW급 터빈을 구동하고, 액체산소와 케로신을 추진제로 사용하는 가스발생기의 설계점 연소성능시험 결과에 대해 논의하였다. 충돌형 F-O-F 인젝터, 물냉각 채널을 가진 연소실, torch ignitor, turbulence ring 그리고 측정 링을 갖는 가스발생기에 대해 기술하였고, 점화, 연소, 종료 등의 시험 cyclogram에 대해 언급하였다. 설계점에서의 연소시험 및 turbulence ring 장착여부, 연소실 길이 변화에 따른 연소시험의 결과들에 대해 기술하였다. 연소시험 결과 가스발생기는 설계점에서 안정된 작동성을 보여주었고, 연소압력 및 온도 등의 성능이 예측치에 근접하는 결과를 보여 주었다. Turbulence ring은 출구에서의 가스온도를 균일하게 분포시켜 효과적인 혼합 장치임을 보여 주었고, 4-6msec 정도에서의 잔류시간에서는 연소효율의 차이가 크지 않음을 알 수 있었다. 가스발생기 출구에서의 온도는 공급되는 추진제의 O/F ratio에 따라 매우 민감하게 반응함을 알 수 있었다.

• Journal of Applied Biological Chemistry
• /
• 제43권1호
• /
• pp.37-43
• /
• 2000

1,3,2-Dioxaphosphorinanes are suitable compounds for studying the stereochemistry of substitution at phosphorus. Cis- and trans-5-hydroxymethl-5-methyl-2-thiono-2ethoxy-1,3,2-dioxaphosphorinane were prepared, and their structures and stereochemistry unambiguously assigned by NMR and X-ray crystallography with acetoxy and 3,5-dinitrobenzoyloxy derivatives, respectively. Trans isomer gave $^{31}P$ NMR signal at higher field than cis isomer, and the ring proton Spectrum of cis isomer showed characteristic pattern for identifying its geometry. In X-ray crystallography they adopted a chair conformation with the ethoxy groups in the axial positions, and the sulfide groups in the equatorial positions. A flattening of the ring around the phosphorus center was noted, the POC bond angles were about $120^{\circ}$, and the C-O bonds in the ring were significantly longer than the C-O bond for the ethoxy group or the C-O bond for hydroxyl group.

• Archives of Pharmacal Research
• /
• 제28권10호
• /
• pp.1114-1121
• /
• 2005

Flavonoids are polyphenols composed of two aromatic rings (A, B) and a heterocyclic ring (C). In order to determine the effects of the number of hydroxyl groups in the B-ring of the flavonoids on human cytochrome P450 (CYP) 1 family enzymes, we evaluated the inhibition of CYP1A-dependent 7-ethoxyresorufin O-deethylation activity by chrysin, apigenin and luteolin, using bacterial membranes that co-express human CYP1A1, CYP1A2, or CYP1B1 with human NADPH-cytochrome P450 reductase. Chrysin, which possesses no hydroxyl groups in its B-ring, exhibited the most pronounced inhibitory effects on CYP1A2-dependent EROD activity, followed by apigenin and luteolin. On the contrary, CYP1A1-mediated EROD activity was most potently inhibited by luteolin, which is characterized by two hydroxyl groups in its B-ring, followed by apigenin and chrysin. However, all of the 5,7-dihydroxyflavones were determined to similarly inhibit CYP1B1 activity. Chrysin, apigenin, and luteolin exhibited a mixed-type mode of inhibition with regard to CYP1A2, CYP1B1, and CYP1A1, with apparent Ki values of 2.4, 0.5, and 2.0 ${\mu}M$, respectively. These findings suggested that the number of hydroxyl groups in the B-ring of 5,7-dihydroxyflavone might have some influence on the degree to which CYP1A enzymes were inhibited, but not on the degree to which CYP1B1 enzymes were inhibited.

• Bulletin of the Korean Chemical Society
• /
• 제23권12호
• /
• pp.1790-1800
• /
• 2002

The DNA nucleosides(dA, dC, dG, dT)bound to gold nanoparticles (~13 nm) in aqueous solution has been studied as a probe by the SERS and their coordination structures have been proposed on the basis of them. According to UV-Visible absorption of gold nanoparticles after modifying with DNA nucleosides, the rates of absorption of dA, dC, and dG were much faster than that of dT as monitored by the aggregation kinetics at 700 nm. These data indicated that the nucleosides dA, dC, and dG had a higher affinity for the gold nanoparticles surface than nucleoside dT. As the result of SERS spectra, the binding modes of each of the nucleosides on gold nanoparticles have been assigned. A dA binds to gold nanoparticles via a N(7) nitrogen atom of the imidazole ring, which the C(6)-$NH_2$ group also participates in the coordination process. In the case of dC, it binds to the gold surface via a N(3) nitrogen atom of the pyrimidine ring with a partial contribution from the oxygen of C(2)=O group. A coordination of dG to the gold surfaces is also proposed. Although the dG has the two different nitrogens of a pyrimidine ring and the amino group, the N(1) nitrogen atom of a pyrimidine ring has a higher affinity after the hydrogen migrates to the amino group. Conversely, dT binds via the oxygen of the C(4)=O group of the pyrimidine ring. Accordingly, these data suggest that the nitrogen atom of the imidazole or the pyrimidine ring in the DNA nucleosides will bind more fast to the gold nanoparticles surfaces than the oxygen atom of the carbonyl group.

• Tribology and Lubricants
• /
• 제34권5호
• /
• pp.197-207
• /
• 2018

Thermal deterioration of fuel due to long-term storage influences engine performance and causes malfunctions. Fuel stability is usually evaluated via heat resistance and thermal stability during a brief heat shock at high temperature; storage stability in this scenario means that there is very little change in the quality of the fuel during long-term storage. In addition, rubber-based products such as oil seals, O-rings, and rubber hoses can influence the quality of the fuel. When these rubber products are in contact with fuel, they can swell, mechanically weaken, and occasionally crack, thus leaking low molar weight rubber and additives including plasticizer and antioxidant into the fuel to degrade its properties and shorten its useful lifetime. This study determines the thermal stabilities of three kinds of synthetic fuels by evaluating their low temperature kinematic viscosities, chemical composition changes via GC analyses, gross heat of combustion, and color changes. We evaluate the compression set of O-rings by immersing one NBR and two FKM rubber O-rings in the three synthetic fuel samples in airtight containers at variable storage temperatures for six months; from this, we estimate the lifetimes of the O-rings using the Power law model. There were very little changes in the chemical compositions and gross heat of combustion after six months of the experiment. The lifetimes are thus dependent on the materials of the rubber products, and in particular, the FKM O-ring was calculated to have a theoretical lifetime of 200 to 5,700 years. These results indicate that the synthetic fuels maintain their physical properties even after long-term storage at high temperatures, and the FKM O-ring is suitable for long-term sealing of these fuels.