• Title/Summary/Keyword: Nucleation behavior

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Bending Creep and Creep Fracture of Sintered Alumina under High-Temperature (알루미나의 고온 굽힘크리프 및 크리프 파괴)

  • 김지환;권영삼;김기태
    • Journal of the Korean Ceramic Society
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    • v.31 no.5
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    • pp.543-551
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    • 1994
  • The creep behavior and creep fracture of sintered alumina at high temperature were investigated under four point flexural test. Steady-state creep behavior was observed at low bending stress and primary creep until fracture was observed at hish bending stress. The loading history of bending stress did not affect on steady-state creep rate. Intergranular fracture was dominant for fracture of alumina at room and high temperature. However, transgranular fracture was dominant on creep of alumina under high temperature by nucleation and growth of microcracks due to residual flaws or cavities in the material.

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Particle Contamination in PCVD Reactor for Semiconductor Processing (반도체 제조용 PCVD 반응기에서의 미립자 오염)

  • Kim, Dong-Joo;Kim, Kyo-Seon
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1492-1494
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    • 1996
  • We have studied the generation, growth and behavior of chemical species and particles in silane PCVD. We included the plasma chemistry of silane, particle nucleation by homogeneous formation, acrosol dynamics and transport phenomena of chemical species and particles. The concentration profile of chemical species and particles were shown as a function of reactor length. The effects of process variables such as reactor pressure, total gas flow rate and electrical field strength on the behavior of chemical species and particles were analyzed.

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Effect of Grain Size on Corrosion Resistance and High Temperature Oxidation Behavior of 22Cr-15Ni-5W Super Austenitic Stainless Steels (22Cr-15Ni-5W 슈퍼 오스테나이트계(系) 스테인리스강(鋼)의 고온산화(高溫酸化) 및 내식성(耐蝕性)에 미치는 결정립(結晶粒) 크기의 영향(影響))

  • Kim, H.J.;Lee, H.W.;Lee, J.M.;Kang, C.Y.
    • Journal of Power System Engineering
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    • v.10 no.3
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    • pp.51-57
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    • 2006
  • The effect of grain size on corrosion resistance and high temperature oxidation behavior was studied in 22Cr-15Ni-5W super austenitic stainless steels for desulfurization equipment as a heat power station. In the high temperature oxidation test, oxidation rate was increased as the temperature increased from $600^{\circ}C\;to\;800^{\circ}C$. In vapor, oxidation rate was faster than that in air. Because the vapor was inhibited nucleation of $Cr_2O_3$ film. And the high temperature oxidation resistance at $600^{\circ}C{\sim}800^{\circ}C$ was excellent from all specimens and specimen of the smallest grain size was the most excellent. Because increasing of diffusion course through the grain-boundary was promoted nucleation and growth of $Cr_2O_3$ film. In the test temperature at $600^{\circ}C{\sim}800^{\circ}C$, Cr rich round particle oxide was formed in air, whereas Fe rich needle type oxide was developed in vapor.

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Effects of Wheel Condition on Solidification Characteristics of Al-Cu Polycrystalline Ribbon (Al-Cu 다결정 리본의 응고거동에 미치는 휠조건의 영향)

  • Kim, Ju-Hyung;Lee, Sang-Mok;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.17 no.3
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    • pp.276-285
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    • 1997
  • The effect of wheel surface condition on solidification behavior of Al-Cu ribbon was investigated in order to establish extreme levels of heat extraction. The condition of wheel surface was changed either by heating the wheel surface up to $200^{\circ}C$ or by coating boron nitride(BN) onto the the rim of a wheel. Heating the wheel surface up to $200^{\circ}C$ improved the wetting behavior between the molten metal and the rotating wheel, leading to an increase in the ratio of columnar structure to the entire thickness of Al-4.3wt%Cu and Al-33.2wt%Cu ribbons. For Al-4.3wt%Cu ribbon, assuming one grain as a single heterogeneous nucleation event at the contact point, the nucleation density with the wheel surface heated to $200^{\circ}C$, was $4{\times}10^6/mm^2$, and in the cases of BN coating with thin and thick layers, $10^5/mm^2$ and $5{\times}10^4/mm^2$, respectively. The largest cooling capacity of the wheel corresponded to the heated wheel surface, and as the thickness of BN coating layer increased, the cooling capacity of the wheel gradually decreased.

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Grain Growth Behavior of (K0.5Na0.5)NbO3 Ceramics Doped with Alkaline Earth Metal Ions

  • Il-Ryeol Yoo;Seong-Hui Choi;Kyung-Hoon Cho
    • Korean Journal of Materials Research
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    • v.33 no.4
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    • pp.135-141
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    • 2023
  • The volatilization of alkali ions in (K,Na)NbO3 (KNN) ceramics was inhibited by doping them with alkaline earth metal ions. In addition, the grain growth behavior changed significantly as the sintering duration (ts) increased. At 1,100 ℃, the volatilization of alkali ions in KNN ceramics was more suppressed when doped with alkaline earth metal ions with smaller ionic size. A Ca2+-doped KNN specimen with the least alkali ion volatilization exhibited a microstructure in which grain growth was completely suppressed, even under long-term sintering for ts = 30 h. The grain growth in Sr2+-doped and Ba2+-doped KNN specimens was suppressed until ts = 10 h. However, at ts = 30 h, a heterogeneous microstructure with abnormal grains and small-sized matrix grains was observed. The size and number of abnormal grains and size distribution of matrix grains were considerably different between the Sr2+-doped and Ba2+-doped specimens. This microstructural diversity in KNN ceramics could be explained in terms of the crystal growth driving force required for two-dimensional nucleation, which was directly related to the number of vacancies in the material.

Formation Behavior of Precipitated Calcium Carbonate Polymorphs by Supersaturation (과포화도에 의한 침강성 탄산칼슘 다형체의 생성거동)

  • Ahn, Young jun;Jeon, ong Hyuk;Lee, Shin Haeng;Yu, Young Hwan;Jeon, Hong Myeong;Ahn, Ji Whan;Han, Choon
    • Resources Recycling
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    • v.24 no.4
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    • pp.22-31
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    • 2015
  • From results obtained by adjusting experimental variables based on the kinetic, the nucleation rate for formation of precipitated calcium carbonate (PCC) was investigated. Formation behavior of PCC was investigated for various concentrations of NaOH solution and $Na_2CO_3$ addition methods in the $Ca(OH)_2$ slurry. The range of nucleation rate was investigated for dissolution rates of major ion concentrations, $Ca^{2+}$ and $CO{_3}^{2-}$. In case of high concentration of major ions, vaterite and calcite were synthesized. The high nucleation rate was achieved for lower either $Ca^{2+}$ or $CO{_3}^{2-}$ ion concentration, calcite was mainly synthesized and when concentration of major ions was low, aragonite was synthesized. Furthermore, the formation of calcite was decreased with increasing concentration of NaOH. homogeneous aragonite could be obtained by addition 5 M NaOH. Therefore, in this study, specific shape of polymorphs could be prepared through controlling supersaturation.

Nano-behavior of material beneath an indenter in nanoindentation (나노 인덴테이션에 의한 나노재료의 경도예측 (1) 나노 인덴테이션에서 압자 밑 재료의 나노거동)

  • Kim, J.;Park, J.W.;Kim, Y.S.;Lee, S.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.05a
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    • pp.111-115
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    • 2003
  • Nanoindentation is simply an indentation test in which the length scale of the penetration is measured in nanometres rather than microns or millimetres, the latter being common in conventional hardness tests. Three-dimensional molecular dynamics simulations have been conducted to evaluate the nanoindentation test. Molecular dynamics simulations were carried out on single crystal copper by varying crystal orientations to investigate nano-behavior of material beneath an indenter in nanoindentation. Morse potential function was used as an interatomic force between indenter and thin film. The result of the simulation shows that crystal orientation significantly influenced the slip system, dislocation nucleation and dislocation behavior.

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Numerical approach to fracture behavior of CFRP/concrete bonded interfaces

  • Lin, Hai X.;Lu, Jian Y.;Xu, Bing
    • Computers and Concrete
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    • v.20 no.3
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    • pp.291-295
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    • 2017
  • Tests on the fracture behavior of CFRP-concrete composite bonded interfaces have been extensively carried out. In this study, a progressive damage model is employed to simulate the fracture behaviors. The crack nucleation, propagation and more other details can be captured by these models. The numerical results indicate the fracture patterns seem to depend on the relative magnitudes of the interface cohesive strength and concrete tensile strength. The fracture pattern transits from the predominated adhesive-concrete interface debonding to the dominated concrete cohesive cracking as the interface cohesive strength changes from lower than concrete tensile strength to higher than that. The numerical results have an agreement with the experimental results.

Investigation on Behavior of HAN-based Propellant Droplet at High Temperature (고온에서 HAN 계열 추진제 액적의 거동에 대한 연구)

  • Hwang, Chang Hwan;Baek, Seung Wook;Han, Cho Young;Kim, Su Kyum;Jeon, Hyung Yeol
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.329-332
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    • 2012
  • The droplet behavior of 83.9 wt.% HAN water solution was investigated experimentally with various ambient temperature and nitrogen environment. At the initial stage of evaporation under thermal decomposition temperature of HAN, gradual decreasing of droplet diameter was observed. After that, the droplet started to expand due to the internal pressure build up by water nucleation inside the droplet. The micro explosion was observed at higher temperature than the decomposition temperature of HAN and the remaining droplet showed similar behavior of single composition droplet. The decreasing rate was augmented as the ambient temperature increasing.

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