• Title/Summary/Keyword: Nuclear waste

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5kg $U_{3}O_{8}$ Batch Scale Mock-up Test for the Electrochemical Reduction of Spent Oxide Fuel (사용후핵연료의 전기화학적 금속전환을 위한 5kg $U_{3}O_{8}$ Batch 규모의 Mock-up 시험)

  • 오승철;허진목;홍순석;이원경;서중석;박승원
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.47-53
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    • 2003
  • An electrochemical reduction technology which can reduce the decay heat, volume, and radioactivity of spent fuel by a factor of quarter through converting oxide type spent fuel to a metallic form in a molten salt was developed and tests in a scale of g (3- 40g $U_{3}O_{8}$ batch) have been carried out by Korea Atomic Energy Research Institute. In this research, the reaction apparatus in a scale of 5kg $U_{3}O_{8}$ batch was designed and manufactured for the mock-up test to obtain design data of the apparatus which will be used for the hot test in a scale of 20kg $U_{3}O_{8}$ batch. The electrochemical reduction behavior of $U_{3}O_{8}$ was analyzed regarding the operational factors and fresh $U_{3}O_{8}$ powder was metallized with a more than 99% yield verifying the process validity of electrochemical reduction process in a kg scale.

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Development of the Maintenance Process Based on Graphic Simulation for the Parts of the Equipment at the outside of the MSM′s Workspace in a Hot Cell (그래픽 전산모사를 이용한 핫셀 사각지역 내 장치부품 유지보수공정 개발)

  • 이종열;김승현;송태길;박병석;윤지섭
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.55-64
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    • 2003
  • In this study, the maintenance process by the servo manipulator has been developed for the parts of the equipment, which we unable to reach out by the Master-Slave Manipulator(MSM) in a hot cell. To do this, a virtual mock-up is implemented using the iか prototyping technology. Using this mock-up, the workspace of the manipulators in the hot cell and the operator's view through the wall-mounted lead glass have been analyzed. In addition, the path planning of the servo manipulator using the collision detection function of the virtual mock-up has been established. From these, the maintenance process for the parts of the equipment, which are located at the outside of the MSM's workspace using the servo manipulator has been proposed and verified through the graphic simulation. It is revealed that the proposed remote maintenance process of the equipment can effectively be used in the real hot cell operation. It is also believed that the implemented virtual mock-up of the hot cell can effectively be applied in analyzing the various hot cell operation and enhancing the reliability and safety in a hot cell remote handling for the spent fuel management.

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Dependence Evaluation of the Self-Absorption Correction Factor for p-type High Purity Germanium Detector Characteristics (p-type HPGe 검출기 특성에 따른 밀도 보정인자 의존도 평가)

  • Jang, Mee;Ji, Young-Yong;Kim, Chang-Jong;Lee, Wanno;Kang, Mun Ja
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.4
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    • pp.295-300
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    • 2015
  • The precise determination of the activity for each radionuclide in environmental samples requires the self-absorption correction factor. In this research, we derived the self-absorption correction factor for three p-type high purity germanium detectors using the Monte Carlo code MCNPX. These detectors have different characteristics such as crystal diameter, height and size of the core. We compared the calculated full-energy peak efficiency with the experimental value using a standard sample with $1g/m^3$ density and verified the modeling. We simulated the dependency of the full-energy peak efficiency on the 0.3, 0.6, 0.9, 1.0, 1.2 and $1.5g/m^3$ samples and obtained the corresponding self-absorption correction factor. The self-absorption correction factors calculated for the three detectors differ by less than 1% over most of the energy range and sample densities considered. This indicates that the self-absorption correction factors are independent of the crystal characteristics of HPGe detector.

A study on dehydration of rare earth chloride hydrate (염화 희토류 수화물의 탈수화에 관한 연구)

  • Lee, Tae-Kyo;Cho, Yong-Zun;Eun, Hee-Chul;Son, Sung-Mo;Kim, In-Tae;Hwang, Taek-Sung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.2
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    • pp.125-132
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    • 2012
  • The dehydration schemes of rare earth (La, Ce, Nd, Pr, Sm. Eu, Gd, Y) chloride hydrates was investigated by using a dehydration apparatus. To prevent the formation of the rare earth oxychlorides, the operation temperature was changed step by step ($80{\rightarrow}150{\rightarrow}230^{\circ}C$) based on the TGA (thermo-gravimetric analysis) results of the rare earth chloride hydrates. A vacuum pump and preheated Ar gas were used to effectively remove the evaporated moisture and maintain an inert condition in the dehydration apparatus. The dehydration temperature of the rare earth chloride hydrate was increased when the atomic number of the rare earth nuclide was increased. The content of the moisture in the rare earth chloride hydrate was decreased below 10% in the dehydration apparatus.

An Electrochemical Reduction of TiO2 Pellet in Molten Calcium Chloride (CaCl2 용융염에서 TiO2 펠렛의 전기화학적 환원반응 특성)

  • Ji, Hyun-Sub;Ryu, Hyo-Yeol;Jeong, Ha-Myung;Jeong, Kwang-Ho;Jeong, Sang-Mun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.2
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    • pp.97-104
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    • 2012
  • A porous $TiO_2$ pellet was electrochemically converted to the metallic titanium by using a $CaCl_2$ molten salt system at $850^{\circ}C$. Ni-$TiO_2$ and graphite electrodes were used as cathode and anode, respectively. The electrochemical behaviour of $TiO_2$ pellet was determined by a constant voltage control electrolysis. Various reaction intermediates such as $CaTiO_3$, $Ti_2O$ and $Ti_6O$ were observed by XRD analysis during electrolysis of the pellet. Once $TiO_2$ pellet was converted to a porous metallic structure, the porous structure disappeared by sintering and shrinking with increasing the reaction time at high temperature.

Influence of Water Salinity on the Hydraulic Conductivity of Compacted Bentonite (물의 염도가 압축벤토나이트의 수리전도도에 미치는 영향)

  • Cho, Won-Jin;Kim, Jin-Seop;Choi, Jong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.4
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    • pp.199-206
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    • 2011
  • The influence of water salinity on the hydraulic conductivities of compacted bentonites with several dry densities were studied. The hydraulic conductivity increases with increasing salinity only when the dry density of bentonite is relatively low. The degree of increase becomes more remarkable at a lower dry density of bentonite. For bentonite with the density of 1.0 $Mg/m^3$ and 1.2 $Mg/m^3$, the hydraulic conductivity of the 0.4 M NaCl solution increases up to about 7 times and 3 times, respectively higher than that of freshwater. However, for the bentonite with a dry density higher than 1.4 $Mg/m^3$, the salinity has an insignificant effect on the hydraulic conductivity, and the hydraulic conductivity is nearly constant within the salinity range of 0.04 to 0.4 M NaCl. The pre-saturation of the bentonite specimen with freshwater has no significant influence on the hydraulic conductivity.

Arrangement of Disposal Holes According to the Features of Groundwater Flow (지하수 유동 특성을 이용한 심층처분의 처분공 배치 방안)

  • Ko, Nak-Youl;Baik, Min-Hoon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.4
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    • pp.321-329
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    • 2016
  • Based on the results of groundwater flow system modeling for a hypothetical deep geological repository site, quantitative and spatial distributions of groundwater flow rates at the positions of deposition holes, groundwater travel length and time from the positions to the surface environment were analyzed and used to suggest a method for determining locations of deposition holes. The hydraulic head values at the depth of the deposition holes and a particle tracking method were used to calculate the ground-water flow rates and groundwater travel length and time, respectively. From the results, an approach to designing a layout of deposition holes was suggested by selecting relatively favorable positions for maintaining performance of the disposal facility and screening some positions of deposition holes that did not comply with specific constraints for the groundwater flow rates, travel length and time. In addition, a method for determining a geometrical direction for extension of the disposal facility was discussed. Designing the layout of deposition holes with the information of groundwater flow at the disposal depth can contribute to secure performance and safety of the disposal facility.

Visualization of Virtual Slave Manipulator Using the Master Input Device (주 입력장치를 이용한 가상 슬레이브 매니퓰레이터의 시각화)

  • 김성현;송태길;이종열;윤지섭
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.388-394
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    • 2003
  • To handle the high level radioactive materials such a spent fuel, the master-slave manipulators (MSM) are widely used as a remote handling device in nuclear facilities such as the hot cell with sealed and shielded space. In this paper, the Digital Mockup which simulates the remote operation of the Advanced Conditioning Process(ACP) is developed. Also, the workspace and the motion of the slave manipulator, as well as, the remote operation task should be analyzed. The process equipment of ACP and Maintenance/Handling Device are drawn in 3D CAD models using IGRIP. Modeling device of manipulator is assigned with various mobile attributes such as a relative position, kinematics constraints, and a range of mobility, The 3D graphic simulator using the external input device of space ball displays the movement of manipulator. To connect the external input device to the graphic simulator, the interface program of external input device with 6 DOF is deigned using the Low Level Tele-operation Interface(LLTI). The experimental result shows that the developed simulation system gives much-improved human interface characteristics and shows satisfactory response characteristics in terms of synchronization speed. This should be useful for the development of work's education system in the virtual environment.

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Evaluation of Time Dependent Tritium Concentration for Safety Analysis in Wolsong Tritium Removal Facility (월성 삼중수소 저장 시설 안전성 평가를 위한 시간에 따른 삼중수소 농도 평가)

  • 육대식;이건재;정흥석
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.539-543
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    • 2003
  • The objective of this to improve the reliability of the safety evaluation code for Wolsong Tritium Removal Facility(WTRF) which is on the development for environmental assessment. To achieve this, tritium concentrations calculated in the Wolsong Units of this study are compared with that of the existing reference. As the result, the tritium concentration in each Wolsong nuclear power plant unit just before operating WTRF is 60.9Ci/kg, 36.3Ci/kg, 30.0Ci/kg, 26.5Ci/kg under the assumption that the WTRF begins operation in 2005, respectively. This result is almost same with that of the existing reference. But the reducing rate of tritium concentration in the moderator is faster than that of the reference result Finally it is expected to drop below 10Ci/kg after WTRF operation. And this result is also similar with that of the existing reference.

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Removal Efficiency of Organic Iodide on Silver Ion-Exchanged Zeolite and TEDA-AC at High Temperature Process (고온공정에서 은교환 제올라이트 및 TEDA 첨착활성탄의 유기요오드 제거성능)

  • 최병선;박근일;윤주현;김성훈;배윤영;지성균;양호연;유승곤
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.207-214
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    • 2003
  • Removal efficiency of methyl iodide at high temperature process by TEDA-impregnated activated carbon used for radioiodine retention in nuclear facility was experimentally compared with that of silver ion-exchanged synthetic zeolite(AgX), In temperature ranges of$30^{\circ}C$ to $400^{\circ}C$, adsorption capacity of un-impregnated carbon was sharply decreased, but TEDA-impregnated carbon showed similar values of adsorption capacity of AgX even around $100^{\circ}C$. Especially, loading amount of methyl iodide on TEDA carbon up to$250^{\circ}C$ represented higher values compared to un-impregnated carbon. Breakthrough curves of methyl iodide in fixed bed packed with AgX and TEDA-impregnated carbon at high temperature was compared. Removal mechanism of methyl iodide on AgX was proposed, based on analysis of by-product gas generated from adsorption reaction.

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