• ALGAE
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• v.30 no.2
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• pp.139-146
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• 2015

Urchin barrens have been a major issue of rocky coastal ecosystems in temperate regions. In South Korea, the east coast and Jeju Island have especially been a focus because the area of barren ground increases in spite of continual efforts to install artificial reefs. This study approached the urchin barrens issue in South Korea, by focusing on a correlational analysis of urchin and macroalgal abundance. Urchin density and algal species coverage were obtained using a quadrat image analysis. Subtidal sites were then classified into three groups according to the average densities of urchins to evaluate the characterization of the macroalgal community: no urchin (NU) zone; transition (TR) zone, $4inds.\;m^{-2};$ and urchin (UR) zone, ${\geq}8inds.\;m^{-2}$. The average urchin density in the study site was $4.7inds.\;m^{-2}$ and 57 macroalgal species were found in the study site. From the NU zone to UR zone, total species number, species diversity index and evenness gradually decreased, whereas the dominance index increased. The algae species with negative correlations were Grateloupia divaricata, Polysiphonia morrowii, Chondracanthus intermedius, Delesseria violacea, Desmarestia viridis; and those with positive correlations were the crustose corallines, Sargassum horneri. Other species were not significantly correlated with urchin density. The significant correlations indicate that the abundance of some macroalgal species is proportionally regulated by sea urchin density. This study also shows how macroalgal vegetation changes in response to an urchin's density gradient in a natural condition; and there is a TR zone that existed with respect to an intermediate level of algal abundance.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.40 no.12
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• pp.1055-1060
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• 2016

Laser welding is a high-density energy welding method. Hence, deep penetration and high welding speed can be realized with lower heat input as compared with conventional welding. The heat input of a CW laser welding is determined by laser power and welding speed. In this study, bead and lap welding of $0.5mm^t$ pure titanium was performed using a fiber laser. Its weldability with laser power and welding speed was evaluated. Penetration, bead width, joining length, and bead shape were investigated, and the mechanical properties were examined through tensile-shear strength tests. Welds with sound joining length were obtained when the laser power and welding speed were respectively 0.5 kW and 2.5 m/min, and 1.5 kW and 6 m/min, and the weld obtained at low output presented better ductility than that obtained at high output.

• Journal of the Korean Chemical Society
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• v.17 no.2
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• pp.85-94
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• 1973

The stability constants of the charge-transfer complexes formed between three derivatives of nitrobenzene, i.e., 1,3,5-trinitrobenzene, m-dinitrobenzene, nitrobenzene and eleven organic molecules such as $\alpha-picoline$, pyridine, dimethylsulfoxide, N, N'-dimethylacetamide, tetrahydrofurane, 1, 4-dioxane, diethyl ether, acetonitrile, propylene oxide, epichlorohydrine, and methyl acetate, have been determined by ultraviolet absorption spectroscopy in carbon tetrachloride solution at 25.0$^{\circ}C$. The parameters of the electrostatic effect ($E_D$) and covalent effect ($C_D$) for the eleven organic compounds have been calculated from the modified equation of the double-scale enthalpy,$logK = E_AC_A+E_DC_D$ and also the shift of C=O vibrational frequency in infrared spectra for N,N'-dimethylacetamide have been measured from the solutions of above organic compounds. The empirical equation, ${\Delta}{\nu}_{C=O} = 37.4-5.47E_D+12.1C_D$, related to the parameters and the frequency shift has been derived. It seems that the stabilities of the complexes principally depend on the covalent effect. Especially it is found that $\pi$ orbitals in molecules, in addition to the parameters, play the important role in forming the charge-transfer complexes.

• Journal of the Korean Chemical Society
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• v.37 no.6
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• pp.612-617
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• 1993

Some vanadium(III) complexes have been prepared from the reaction of VC$l_3$ with N, P, O-donating ligands and characterized by elemental analysis, $^1$H-NMR infrared and UV-Visible spectroscopy. 3,5-Lutidine, 1,2-phenylenediamine, 8-hydroxyquinoline, 9,10-phenanthrenequinone, triphenylphosphine, 1,2-bis(diphenylphosphino)ethane, 1,3-bis(diphenylphosphino)propane and 1,1'-bis(diphenylphosphino)ferrocene were chosen as coordinating ligands. Stretching frequency ${\nu}g$(V-Cl) of complexes appears) at 298∼367 cm-1, which show octahedral geometries. Stretching frequency of ${\nu}g$(V-X) (X = N, P, O) indicates that ligands are coordinated to vanadium(III). Stretching frequency ${\nu}g(C{\equiv}N)$ of acetonitrile in these complexes are characteristically shifted to about 70 c$m^{-1}$ higher compared with that of a free ligand (2260 c$m^{-1}$). Bending frequency of $\delta(C{\equiv}N)$ is also shifted to about 60 c$m^{-1}$ higher compared with that of a free ligand (377 c$m^{-1}$). Finally each vanadium(III) complex showed the following formulation; [VC$l_3$(L)$_2$MeCN] or [VC$l_3$(L-L)MeCN].

• Bulletin of the Korean Chemical Society
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• v.26 no.9
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• pp.1395-1402
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• 2005

The reaction of cis-[Cr([14]-decane)$(OH)_2]^+$ ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) with auxiliary ligands {$L_a$ = acetylacetonate (acac), oxalate (ox) or malonate (mal)} leads to a new cis-[Cr([14]-decane)(acac)]$(ClO_4)_2{\cdot}(1/2)H_2O\;(1),\;cis-[Cr([14]-decane)(ox)]ClO_4{\cdot}(1/2)H_2O\;(2)\;or\;cis-[Cr([14]-decane)(mal)]ClO_4{\cdot}(1/4)H_2O\;(3)$. These complexes have been characterized by a combination of elemental analysis, conductivity, IR and Vis spectroscopy, mass spectrometry, and X-ray crystallography. Analysis of the crystal structure of cis-[Cr([14]-decane)(acac)]$(ClO_4)_2{\cdot}(1/2)H_2O$ reveals that central chromium(III) has a distorted octahedral coordination environment and two acetylacetonate-oxygen atoms are bonded to the chromium(III) ion in the cis positions. The angle $N_{axial}-Cr-N_{axial}$ deviates by $11^{\circ}$ from the ideal value of $180^{\circ}$ for a perfect octahedron. The bond angle O-Cr-O between the chromium(III) ion and the two acetylacetonate-oxygen atoms is close to $90^{\circ}$. The bond lengths of Cr-O between the chromium and the acetylacetonate-oxygen atoms are 1.950(3) and 1.954(2) $\AA$. They are shorter than those between chromium and nitrogen atoms of the macrocycle. The IR spectra of 1, 2 and 3 display bands at 1560 {ν (C=O)}, 1710 {${\nu}_{as}$(OCO)} and 1660 $cm^{-1}$ {${\nu}_{as}$(OCO)} attributed to the acac, ox and mal auxiliary ligands stretching vibrations, respectively.

• Journal of KIISE:Software and Applications
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• v.32 no.2
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• pp.108-118
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• 2005

The software of the nuclear power plant digital control system is a safety-critical system where many techniques must be applied to it in order to preserve safety in the whole system. Formal specifications especially allow the system to be clearly and completely specified in the early requirements specification phase, therefore making it a trusted method for increasing safety. In this paper, we discuss a systematic method, which generates PLC-based FBD programs from the requirements specification using NuSCR, a formal requirements specification method. This FBD programs takes an important position in design specification. The proposed method can reduce the possible errors occur in the manual design specification, and the software development cost and time. To investigate the usefulness of our proposed method, we introduce the fixed set-point rising trip example, a trip logic of BP in DPPS RPS, which is presently being developed at KNICS.

• Bulletin of the Korean Mathematical Society
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• v.42 no.1
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• pp.75-85
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• 2005

In this paper, the visco-Da-Rios equation; (0.1) ($$\frac{{\partial}{\gamma}}{{\partial}t}=\frac{{\partial}{\gamma}}{{\partial}s}{\bigwedge}\frac{D}{ds}\frac{{\partial}{\gamma}}{{\partial}s}+{\nu}\frac{{\partial}{\gamma}}{{\partial}s}$$) is investigated on 3-dimensional complete orientable Riemannian manifolds. The global existence of solution is discussed by trans-forming (0.1) into a cubic nonlinear Schrodinger equation for complete orient able Riemannian 3-manifolds of constant curvature.

• Ceramist
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• v.21 no.2
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• pp.83-88
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• 2018

There is close relation between the heat generation and the performance of electronic device. The durability and efficiency of the device are degraded due to heat generation. It is necessary to release the generated heat from an electronic device. Based on demands of the printed circuit board (PCB) manufacturing, the robust and reliable plating technique of PCB is necessary. In this study, we review various methods for improving the heat sink property. These methods were considered to enhance the adhesion between ceramic substrate as heat sink and metal layer as electrode.

• 한국IT서비스학회:학술대회논문집
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• 2009.11a
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• pp.384-388
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• 2009

본 연구는 소프트웨어 사업의 과업변경 제도의 효과성에 대하여 연구하였다. 먼저 과업변경 제도의 일반적인 운영현황과 현장사례을 분석하여 과업변경 관리의 핵심성공요인과 선결사항을 도출하였으며, 끝으로 관련 법 제도의 개선방안을 제시하였다.

• 한국지구물리탐사학회:학술대회논문집
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• 2011.10a
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• pp.117-118
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• 2011