• 한국물환경학회지
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• 제25권6호
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• pp.849-854
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• 2009

Pollutant unit load (unit-load) reported by Ministry of Environment (MOE) in 1995 has been a useful method for watershed management and environmental policy decision. The unit-load has been estimated using effective rainfall ratio method. However, reliability of unit-load determined by the method has been criticized especially for paddy field and upland conditions. In this paper the unit-load of paddy field estimated by effective rainfall ratio method was compared with continuous monitoring data. Annual loads was simulated by the method choosing 5~6 storm events randomly from whole events collected. Probability distribution of difference between results by the method and measured data was investigated. The results showed that unit-load derived by the method was generally lesser than measured unit-load and showed wide variations. Therefore, unit-load estimation of paddy fields by effective rainfall ratio method need caution.

• 한국물환경학회지
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• 제34권3호
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• pp.316-327
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• 2018

Liquid fertilizers made from livestock manure contain high concentrations of nitrogen and phosphorus and thus are used as a fertilizer. However, excessive use of liquid fertilizer causes eutrophication of agricultural land and nonpoint source pollution. In this study, as a means of lowering the nutrient concentrations, struvite ($MgNH_4PO_4{\cdot}6H_2O$) production from the liquid fertilizer was investigated. When liquid fertilizers produced in Gyeonggido were analyzed, its characteristics differed by region and season, but the phosphorus concentration was commonly lower than that of nitrogen. When $K_2HPO_4$ and $MgCl_2$ were added to the liquid fertilizers, the optimal pH for struvite formation was pH 9.5. For environmentally friendly sources of magnesium and phosphate, ferronickel slag (FNS) and sewage sludge ash (SSA) were suspended in deionized water and extracted by sulfuric acid with various mass ratios. The optimum conditions for extracting FNS and SSA were 4.0 M sulfuric acid and 0.35 mass ratio of sulfuric acid to sewage sludge ash, respectively. For forming struvite, 0.233 L of SSA leachate (SSAL) was added into 0.3 L of liquid fertilizer containing 2,586 mg/L of ammonia and 110 mg/L of phosphate, pH was then adjusted to pH 9.5 using 10 M of NaOH. Afterwards 0.333 L of FNS leachate (FNSL) was added to this mixed solution. After a reaction for 1 hr at room temperature, the remaining concentrations of magnesium, ammonium, and phosphate were less than 50 mg/L, 500 mg/L and 150 mg/L, respectively, and 30 g of precipitates were obtained, most of which were struvite.

• Journal of Applied Biological Chemistry
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• 제54권3호
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• pp.218-224
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• 2011

전라북도 서부해안지역(부안군)과 동부 산악지역(진안군, 장수군, 순창군)을 대상으로 328 지점의 농업용 지하수 수질특성을 비교 검토하였다. 조사항목은 지하수법에서 규정하고 있는 농업용수 관리항목인 일반오염물질 4개 항목과 특정유해물질 10개 항목이었다. 전라북도 서부 해안지역에서 일반오염물질의 일종인 염소이온이 기준치를 초과한 지점이 나타났으나, 모든 조사지점에서 농업용 지하수 수질기준을 충족하였다. 특정유해 물질은 거의 모든 조사지점에서 검출한계미만 또는 자연함유량 수준으로 검출되어 안전성이 확보되었다. 농업활동이 활발하고 논과 밭의 경지면적이 상대적으로 넓은 해안 인접 평야지가 중 산간지대 보다 농업용 지하수중 오염물질의 농도가 더 높게 나타나는 경향이었다.

• 한국농공학회논문집
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• 제56권6호
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• pp.85-91
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• 2014

In this study, the water quality purification of new medias which were NPS media, hyugato, mineral stone, charcoal for applying soil media of Integrated Management Practices (IMPs) of Low Impact Development (LID) were evaluated. The influent concentrations of COD, T-N, and T-P were 117.8 mg/L, 17.1 mg/L, and 2.062 mg/L, respectively. The infiltration capacities of NPS media, hyugoto, mineral stone, charcoal, and gravel were $7.1{\times}10m/s$, $7.3{\times}10^{-5}m/s$, $7.9{\times}10^{-5}m/s$, $6.0{\times}10^{-5}m/s$, respectively. All media meet criteria of infiltration capacity as surface soil layer at IMPs which is over $1.0{\times}10^{-5}m/s$. Maximum removal rates of COD, T-N, and T-P occurred at Charcoal with 98 % of COD removal rate, NPS with 78 % of T-N removal rate, and hyugato with 75 % fo T-P removal rate, respectively. For more high removal efficiency of all water quality item, the mixed media which is 4.5(NPS media): 1(charcoal) : 4.5 (hyugato) as volume ratio was evaluated. The infiltration capacity of mixed media was $7.9{\times}10^{-5}m/s$ and met the criteria of infiltration as surface soil layer. The water quality removal efficiencies of mixed media were very high with showing 70 % for COD, 85 % for T-N, and 71 % for T-P. The mixed media could purify the water quality of surface runoff and was recommended to used at the LID site of ground water quality problem.

• 한국농공학회지
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• 제44권4호
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• pp.139-148
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• 2002

Pilot study was performed to examine the feasibility of the pond system for further polishing of treatment wetland effluent from December 2000 to June 2001. The wetland system used for the experiment was highly effective to treat the sewage during the growing season, but it was less effective and its effluent was still high to discharge to the receiving water body. Therefore, the wetland effluent may need further treatment to prevent water quality degradation. Pond system could be used to hold and further polish the wetland effluent during the winter season and ots feasibility was evaluated in this study. Additional water quality improvement was apparent in the pond system during winter season, and the pond effluent could be good enough to meet the effluent water quality standards if it is properly managed. Timing of the pond effluent discharge appears to be critical for pond system management because it is a closed system and whole water quality constituents are affected by physical, chemical, and biological pond environments. Once algae started to grow in mid-April, constituents in the pond water column interact each other actively and its control becomes more complicated. Therefore, upper layer of the pond water column which is clearer than the lower layer my need be discharged in March right after ice cover melted. In the experiment, water quality of the upper water column was markedly clear in March than ant other times probably because of freezing-thawing effect. The remaining lower water column could be further treated by natural purification as temperature goes up or diluted with better quality of wetland effluent for appropriate water uses. This study demonstrated the feasibility of pond system for subsequent management of wetland effluent during the winter season, however, more study is needed for field application.

• 농업과학연구
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• 제43권3호
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• pp.424-431
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• 2016

The nutrients in livestock manure produced during fermentation processes in public livestock recycling centers are used as fertilizers. However, the large amounts of swine manure produced in intensive livestock farms can be a nonpoint source of pollution. In this experiment, we investigated the chemical properties, inorganic components, and heavy metal contents in 101 samples of liquid swine manure collected from 28 public livestock recycling centers throughout the nation. Results showed that the average pH of the samples was alkaline (pH range 5.18 to 9.54), and their maximum EC was $53.2dS\;m^{-1}$. The amounts of total nitrogen and total phosphorus were in the range of 1000 - 2000 and $200-800mg\;L^{-1}$ while potassium, which constituted 47% of the total inorganic ions recovered from the liquid swine manure, amounted to $1500mg\;L^{-1}$. The most distinctive heavy metals recovered from the liquid swine manure were copper and zinc although the amounts of both heavy metals were much lesser than those of the standards as livestock liquid fertilizer set by the Rural Development Administration. On the other hand, the amount of nitrogen decreased rapidly with an increasing fermentation period from immature to mature, assumed to be lost as volatile compounds, such as ammonia, which are the major odor components during the fermentation process.

• 한국수자원학회논문집
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• 제32권4호
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• pp.501-510
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• 1999

북한강 수계의 농업소유역에 대하여 하천수(2년)와 지하수(1년) 수질을 모니터링하여 분석하였다. 농업소유역의 주요한 비점원 오염물질인 총질소, 질산성 질소, 총인, BOD, TSS 및 대장균 농도를 주기적으로 측정하였다. 계절에 따른 수질의 변화 및 지하수와 하천수 수질과의 관계 비교를 통하여 토지이용이 수질에 미치는 영향을 분석하였다. 연구유역의 지하수 수위와 총질소, 질산성 질소의 농도의 벼농사와 밀접한 관련이 있었고 지하수와 하천수의 질소농도의 변화도 밀접한 관련이 있음이 나타나 벼농사가 하천의 질소농도에 많은영향을 주는 것으로 나타났다. 그러나 토지이용(벼농사)과 지하수 및 하천수의 총인, BOD, 대장균 농도 사이에는 일정한 관계를 발견할 수 없었다. 본 연구결과는 농업소유역의 수질변화를 이해하고 소하천의 수질관리정책을 개발하는데 유용하게 활용될 수 있을 것이다.

• 한국농공학회논문집
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• 제60권5호
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• pp.55-67
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• 2018

The objectives of this study were to monitor organic farming upland compared with conventional upland field and to evaluate nutrient loads reduction of surface cover effect with long-term historical climate data. APEX(Agricultural Policy Environmental eXtender) model was validated with experimental data and used for assessing surface cover scenarios for 30-year simulation periods. The validated values of RMSE(Root Mean Square Error), RMAE(Root Mean Absolute Error), $R^2$ and E(Nash-Sutcliffe efficiency) for runoff were 1.17-1.37 mm/day, 0.28-0.45 mm/day, 0.88-0.90 and 0.82-0.94 in two treatments, respectively. Those for water quality (nitrogen) were 0.05-0.16 kg/ha, 0.52-0.75 kg/ha, 0.67-0.72 and 0.32-0.70 in two treatments, respectively, and therefore the validated model showed good agreement with the observed runoff and nitrogen load for the study period. When decreasing the surface cover rate of organic farming field to 75%, 50%, 25%, and 0% (conventional field), average annual runoff increased by 7%, 15%, 23% and 31%, respectively. Under same condition of decreasing the surface cover rate, average annual nitrogen loads increased by 1.4 times, 1.7 times, 2.0 times, and 2.3 times compared with organic farming field, respectively. This study showed that it is possible to present an appropriate surface cover ratio to maintain conventional production and minimize nonpoint sources pollution for organic farming system, although long-term monitoring is needed to determine its effects on environmental concerns, crop competition, and other uncertainty.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2017년도 학술발표회
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• pp.89-89
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• 2017

유기농업은 저농약, 무농약, 자연농법과 함께 환경 친화적 농업으로 인식되어 세계적으로 유기농산물 생산량 및 재배면적이 급격하게 증가하고 있다. 국내 역시 안전한 먹거리 생산과 재배환경에서의 유해물질 관리방안 구축 등이 필요한 상황이다. 자가생산 유기농자재, 가축분을 이용한 축분 퇴비와 액비, 그리고 유박 등이 유기농업에 활용되고 있으나 사용 유기농자재의 양분가용화와 양분이용효율에 따른 비점오염원 형태로 토양 및 수질에 미치는 환경영향 등의 관측과 분석이 필요한 실정이다. 따라서 본 연구의 목적은 밭 포장에서의 유기농업 적용에 따른 유기농과 관행농에서의 대표적 비점오염원인 영양물질(T-N 및 T-P)에 대한 원단위를 평가하는데 있다. 시험포장은 전북 순장군 순창읍에 위치하고 있으며, 유기질비료시비 및 관행작물(고구마)의 3반복 1처리구(경사도 $6.6^{\circ}$)와 관행농관리 및 관행작물(고구마)의 1반복 1대조구(경사도 $6.8^{\circ}$)로 구성하였다. 현장에서 강우량과 유량을 실측하였으며, 강우 이벤트 시 T-N 및 T-P의 수질항목을 샘플링 후 분석하였다. 2016년 현재까지 총 6회의 강우 이벤트가 발생하였으며, 그 중 4회의 수질 샘플링을 실시하였다. 유출률은 평균 유기농에서 32%와 관행농에서 57%로 나타났다. 이는 토지피복 및 선행강우 등의 영향으로 다양한 분포를 보여주었다. 유기농 처리구에서 수질 부하량이 전체적으로 높게 나타났으며, T-N의 경우 4.4배와 T-P의 경우 1.8배로 나타났다. 이러한 경향은 유출수의 농도 영향보다 유출량의 영향이 큰 것으로 보인다. 유기농 처리구의 경우 제초제 등의 농작업이 제대로 이루어지지 않아 조도계수가 높았으며, 유기농 처리구에서 유출량이 31% 수준으로 상대적으로 낮게 나타났다. 본 연구의 경우 관행적으로 이루어지는 제초관리 형태를 벗어난 경우로 일반적인 결론 도출에는 한계가 있으나 유기농업 경작지에서 일반적으로 식생분포가 활발한 특성을 보여주고 있다. 향후 추가적인 모니터링 연구가 지속적으로 필요하며, 본 연구를 바탕으로 유기농업 최적관리방안 제시에 필요한 기초자료로 활용되기를 기대된다.

• 한국토양비료학회지
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• 제48권6호
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• pp.671-676
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• 2015

Control of surface runoff from upland soil is essential to reduce nonpoint source pollution. The use of non-woven fabric as a soil cover can be helpful to control surface runoff. The field experiment was conducted to evaluate the furrow cover effects of black non-woven fabric on the nutrient discharge from upland soil used for red pepper cultivation. The experimental plots consisted of chemical fertilizer (CF), cow manure compost (CMC), and pig manure compost (PMC) treatment. Each nutrient material treatment plot has control (no furrow cover (NFC)) and black non-woven fabric cover treatment, respectively. The amount of nutrient application was chemical fertilizer of $190-112-149(N-P_2O_5-K_2O)kgha^{-1}$, cow manure compost of $29.5tonha^{-1}$, and pig manure compost of $7.9tonha^{-1}$ as recommended amount after soil test for red pepper cultivation. Compared to control (NFC), furrow cover treatment with black non-woven fabric reduced the amount of T-N discharge by 50% at CF treatment, 36.9% at CMC treatment, and 44.8% at PMC treatment. Furrow cover treatment with black non-woven fabric reduced the amount of T-P discharge by 37.1% at CF treatment, 49.9% at CMC treatment, and 63.4% at PMC treatment compared to control (NFC). The production of red pepper did not show significant difference. There was no weed occurring in furrow cover treatment plots with black non-woven fabric. Results from this study showed that the furrow cover with black non-woven fabric could play a significant role in reduce nutrient discharge from upland soil used for red pepper cultivation.