• 제목/요약/키워드: Nonlinear spectroscopy

검색결과 74건 처리시간 0.024초

Fatigue Crack Localization Using Laser Nonlinear Wave Modulation Spectroscopy (LNWMS)

  • Liu, Peipei;Sohn, Hoon;Kundu, Tribikram
    • 비파괴검사학회지
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    • 제34권6호
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    • pp.419-427
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    • 2014
  • Nonlinear features of ultrasonic waves are more sensitive to the presence of a fatigue crack than their linear counterparts are. For this reason, the use of nonlinear ultrasonic techniques to detect a fatigue crack at its early stage has been widely investigated. Of the different proposed techniques, laser nonlinear wave modulation spectroscopy (LNWMS) is unique because a pulse laser is used to exert a single broadband input and a noncontact measurement can be performed. Broadband excitation causes a nonlinear source to exhibit modulation at multiple spectral peaks owing to interactions among various input frequency components. A feature called maximum sideband peak count difference (MSPCD), which is extracted from the spectral plot, measures the degree of crack-induced material nonlinearity. First, the ratios of spectral peaks whose amplitudes are above a moving threshold to the total number of peaks are computed for spectral signals obtained from the pristine and the current state of a target structure. Then, the difference of these ratios are computed as a function of the moving threshold. Finally, the MSPCD is defined as the maximum difference between these ratios. The basic premise is that the MSPCD will increase as the nonlinearity of the material increases. This technique has been used successfully for localizing fatigue cracks in metallic plates.

Nonlinear Time Reversal Focusing and Detection of Fatigue Crack

  • Jeong, Hyun-Jo;Barnard, Dan
    • 비파괴검사학회지
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    • 제32권4호
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    • pp.355-361
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    • 2012
  • This paper presents an experimental study on the detection and location of nonlinear scattering source due to the presence of fatigue crack in a laboratory specimen. The proposed technique is based on a combination of nonlinear elastic wave spectroscopy(NEWS) and time reversal(TR) focusing approach. In order to focus on the nonlinear scattering position due to the fatigue crack, we employed only one transmitting transducer and one receiving transducer, taking advantage of long duration of reception signal that includes multiple linear scattering such as mode conversion and boundary reflections. NEWS technique was then used as a pre-treatment of TR for spatial focusing of reemitted second harmonic signal. The robustness of this approach was demonstrated on a cracked specimen and the nonlinear TR focusing behavior is observed on the crack interface from which the second harmonic signal was originated.

OLED Power Driving Simulation Using Impedance Spectroscopy

  • Kong, Ung-Gul;Hyun, Seok-Hoon;Yoon, Chul-Oh
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.32-35
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    • 2003
  • Nonlinear parameterization of OLED device from measurements of bias dependence of impedance spectra and parameter extraction using Levenberg-Marquardt complex nonlinear least square regression algorithm based on resistor-capacitor equivalent circuit model enables computer simulation of OLED power driving characteristics in forms of square-wave or sinusoidal output signal at arbitrary conditions. We introduce developed OLED power driving simulation software and discuss transient responses in voltage-or current-controlled operations as well as nonlinear characteristics of OLED, by presenting both the simulation and experimental results. This OLED simulation technique using impedance spectroscopy is extremely useful in predicting performance of the nonlinear device, especially in time-domain analysis of device operation.

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Polymer surfaces studied by sum-frequency vibrational spectroscopy

  • Kim, D.;J. Sung;H. M. Cheong;C. N. Whang;Y. Ouchi;T. limori;N. Matsuie;K. Seki
    • 한국진공학회지
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    • 제12권S1호
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    • pp.70-73
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    • 2003
  • Sum-frequency vibrational spectroscopy has recently been used to investigate the surface of the various polymers and was able to find the chemical compositions and structures specific to the surface. Here we report our studies on two specific polymer samples to demonstrate its capability. Polyimide thin films were made by spin coating on fused quartz and $CaF_2$ substrates. The sum-frequency signal originating mainly from the air/polymer interface showed markedly different spectra, indicating the structural change of the polymer surface depending on the underlying substrate. Various polyethylene surfaces were also investigated by sum-frequency vibrational spectroscopy. The surface of polyethylene samples in the CH-region showed different sum-frequency spectra, presumably due to the trace amount of additives having much higher concentration at the air/polymer interface. These examples demonstrate the surface and interface of the polymer could have different structure and chemical composition from those of a bulk, which can be studied effectively by surface nonlinear optical spectroscopy.

Application of Nonlinear Ultrasonic Method for Monitoring of Stress State in Concrete

  • Kim, Gyu Jin;Park, Sun Jong;Kwak, Hyo Gyoung
    • 비파괴검사학회지
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    • 제36권2호
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    • pp.121-129
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    • 2016
  • As the lifespan of concrete structures increases, their load carrying capacity decreases owing to cyclic loads and long-term effects such as creep and shrinkage. For these reasons, there is a necessity for stress state monitoring of concrete members. Particularly, it is necessary to evaluate the concrete structures for behavioral changes by using a technique that can overcome the measuring limitations of usual ultrasonic nondestructive evaluation methods. This paper proposes the use of a nonlinear ultrasonic method, namely, nonlinear resonant ultrasonic spectroscopy (NRUS) for the measurement of nonlinearity parameters for stress monitoring. An experiment compared the use of NRUS method and a linear ultrasonic method, namely, ultrasonic pulse velocity (UPV) to study the effects of continuously increasing loads and cyclic loads on the nonlinearity parameter. Both NRUS and UPV methods found a similar direct relationship between load level and that parameter. The NRUS method showed a higher sensitivity to micro-structural changes of concrete than UPV method. Thus, the experiment confirms the possibility of using the nonlinear ultrasonic method for stress state monitoring of concrete members.

Nonlinear Response of Classical Dynamical Systems to Short Pulses

  • Dellago, Christoph;Mukamel, Shaul
    • Bulletin of the Korean Chemical Society
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    • 제24권8호
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    • pp.1107-1110
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    • 2003
  • Valuable insight into the nonlinear dynamics of a system can be gleaned from its response to a single intense short pulse. We derive expressions for the corresponding nonlinear response functions and show that the fluctuation-dissipation theorem may be extended beyond the linear response limit to an arbitrary pulse intensity. As an illustrative example, we calculate response functions up to 11th order for the regular Lorentz gas in two dimensions.

Two-color Transient Grating Spectroscopy of a Two-level System

  • Kwak, Kyoung-Won;Cho, Min-Haeng;Fleming, Graham R.;Agarwal, Ritesh;Prall, Bradley S.
    • Bulletin of the Korean Chemical Society
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    • 제24권8호
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    • pp.1069-1074
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    • 2003
  • A theoretical description and experimental demonstration of homodyne-detected two-color transient grating (2-C TG) signal are presented. By treating the coupled bath degrees of freedom as a collection of harmonic oscillators and using a short-time expansion method, approximated nonlinear response functions were obtained. An analytic expression for the two-color transient grating signal was obtained by carrying out relevant Gaussian integrals. The initial rising and decaying parts of the 2-C TG signal is shown to be critically dependent on the ultrafast inertial component of the solvation correlation function. The experimental results confirm the predictions of the theoretical model.

Coherent Absorption Spectroscopy with Supercontinuum for Semiconductor Quantum Well Structure

  • Byeon, Ciare C.;Oh, Myoung-Kyu;Kang, Hoon-Soo;Ko, Do-Kyeong;Lee, Jong-Min;Kim, Jong-Su;Choi, Hyoung-Gyu;Jeong, Mun-Seok;Kee, Chul-Sik
    • Journal of the Optical Society of Korea
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    • 제11권3호
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    • pp.138-141
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    • 2007
  • We suggest that supercontinuum can be used for absorption spectroscopy to observe the exciton levels of a semiconductor nano-structure. Exciton absorption spectrum of a GaAs/AlGaAs quantum well was observed using supercontinuum generated by a microstructrured fiber pumped by a femtosecond (fs) pulsed laser. Significantly narrower peaks were observed in the absorption spectrum from 11 K up to room temperature than photoluminescence (PL) spectrum peaks. Because supercontinuum is coherent light and can readily provide high enough intensity, this method can provide a coherent ultra-broad band light source to identify exciton levels in semiconductors, and be applicable to coherent nonlinear spectroscopy such as electromagnetically induced transparency (EIT), lasing without inversion (LWI) and coherent photon control in semiconductor quantum structures.

비선형 초음파공명 특성을 이용한 미세균열 탐지 (Detection of Micro-Crack Using a Nonlinear Ultrasonic Resonance Parameters)

  • 정용무;이덕현
    • 비파괴검사학회지
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    • 제32권4호
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    • pp.369-375
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    • 2012
  • 기존 비파괴평가 기술의 결함 탐지 한계를 극복하기 위하여 비선형 초음파공명 특성을 이용한 미세 균열 진단 기술을 개발하였다. 가진 전압에 따른 초음파공명 주파수의 천이현상과 정규화 공명 진폭 감소 현상을 비선형 초음파공명 특성 파라미터로 제안하였으며 이를 실험적으로 확인하였다. CT 시편에 피로시험을 통하여 미세한 자연 균열을 생성하였으며 피로 사이클 단계마다 초음파공명주파수와 정규화 공명진폭의 변화를 측정하였다. 무결함 또는 10 ${\mu}m$ 정도의 매우 미세한 균열이 존재하는 시편에서는 초음파공명 주파수 천이현상이나 정규화 공명 진폭의 변화가 나타나지 않는 반면에 30 ${\mu}m$급 이상의 미세 균열 시편에서는 균열 크기가 증가함에 따라 초음파공명주파수의 천이 현상이나 정규화 공명 진폭의 감소량이 증가함을 확인하였다.

Reagentless Determination of Human Serum Components Using Infrared Absorption Spectroscopy

  • Hahn, Sang-Joon;Yoon, Gil-Won;Kim Gun-Shik;Park Seung-Han
    • Journal of the Optical Society of Korea
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    • 제7권4호
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    • pp.240-244
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    • 2003
  • Simultaneous determination of concentrations for four major components in human blood serum was investigated using a Fourier-transform mid-infrared spectroscopy. Infrared spectra of human blood serum were measured in 8.404 ∼ 10.25 ${\mu}m$ range where the highest absorption peaks of glucose are located. A partial least square (PLS) algorithm was utilized to establish a calibration model for determining total protein, albumin, globulin and glucose levels which are commonly measured metabolites. The standard error of cross validation obtained from our multivariate calibration model was 0.24 g/dL for total protein, 0.15 g/dL for albumin, 0.17 g/dL for globulin, and 6.68 mg/dL for glucose, which are comparable with or meet the criteria for clinical use. The results indicate that the infrared absorption spectroscopy can be used to predict the concentrations of clinically important metabolites without going through a chemical process with a reagent.