• 한국진공학회지
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• 제7권s1호
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• pp.149-155
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• 1998

The linear electro-optic (EO) effect is one of the second-order nonlinear optical effects existing in a noncentrosymmetric macroscopic system. In a polymer thin film, the noncentrosymmetry is achieved by electric field poling. The magnitude of the linear EO response is determined through the orientational distribution function of hyperpolarizable molecular dipoles. The relation between the linear EO coefficient and the second-order nonlinear optical susceptibility is explained. Three different methods of measuring the linear EO coefficient of a poled nonliner optical polymer thin film are introduced and discussed. All of them make use of the interferometric technique, the difference being in the optical parameters which are interfering.

• Current Optics and Photonics
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• 제7권6호
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• pp.721-731
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• 2023

This paper studies various roughness parameters, besides waviness, texture, and nonlinear parameters of Bismarck brown Y (BBY)-doped Poly(methyl methacrylate) (PMMA) films based on the computed values of optical limiting (OL) threshold power and nonlinear refractive index. The films' morphology, grain size, and absorption spectra were investigated using atomic force microscopy in conjunction with ultraviolet-visible (UV-Vis) spectrophotometer. The particle size of the films ranged between 4.11-4.51 mm and polymer films showed good homogeneity and medium roughness, ranging from 1.11-4.58 mm. A polymer film's third-order nonlinear optical features were carried out using the Z-scan methodology. The measurements were obtained by a continuous wave produced from a solid-state laser with a 532 nm wavelength. According to the results, BBY has a nonlinear refractive index of 10^-6 cm²/W that is significantly negative and nonlinear. The optical limiting thresholds are roughly 10.29, 13.52, and 18.71 mW, respectively. The shift of nonlinear optical features with the film's concentration was found throughout the experiment Additionally, we found that the polymer samples have outstanding capabilities for restricting the amount of optical power that may be transmitted through them. We propose that these films have the potential to be used in a wide variety of optoelectronic applications, including optical photodetectors and optical switching.

• 한국광학회:학술대회논문집
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• 한국광학회 2007년도 동계학술발표회 논문집
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• pp.117-118
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• 2007

• 대한전기학회:학술대회논문집
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• 대한전기학회 1994년도 추계학술대회 논문집 학회본부
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• pp.225-227
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• 1994

The second-order nonlinear optical effect, especially the second harmonic generation, in Langmuir-Blodgett(LB) films have get much attention over the past few years. For second harmonic generation(SHG) of the ultrathin organic films, the multilayer structure of the film should have the noncentrosymmetric arrangements of molecules. The Langmuir-Blodgett technique can result in the production of thin films of precisely controlled dimensions and structure. In this paper, n-octadecyl 4-(4'-nitrophenylazo)-1-naphthyl ether, ONNE(azohenzene derivative), was synthesized and the optical properties of ONNE was studied. Nonccntrosymmctric Z-type LB films of ONNE were prepared and SHG intensity of the film were measured. The structural characteristics of floating monolayer(L film) and LB film of ONNE were discussed with $\pi$-A isotherm. UV-visible absorption spectroscopy and spectroscopic ellipsometry. The polarized UV-visible absorption spectroscopy and SHO intensity suggest the molecular orientation in LB film.

• 한국광학회:학술대회논문집
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• 한국광학회 1998년도 제15회 광학 및 양자전자 학술발표회 논문집
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• pp.146-147
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• 1998

• 한국광학회:학술대회논문집
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• 한국광학회 1999년도 제16회 광학 및 양자전자 학술발표회Proceedings of 16th Optics and Quantum Electronics Conference, 1999
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• pp.190-191
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• 1999

• 한국광학회:학술대회논문집
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• 한국광학회 1999년도 제16회 광학 및 양자전자 학술발표회Proceedings of 16th Optics and Quantum Electronics Conference, 1999
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• pp.192-193
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• 1999

• 한국광학회지
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• 제5권1호
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• pp.18-24
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• 1994

전도성 고분자 박막의 스펙트럼, 가간섭 길이 및 3차 비선형 광학 감수율의 측정방법을 연구했다. 시료박막의 대한 Maker fringe를 용융석영에 대한 것과 비교하고 선형 굴절률에 의한 효과를 보정하여 3차 비선형 광학 감수율값을 계산했다. 선형 굴절률값의 계산을 위하여는 투과율 스펙트럼에서 투과율의 극대(극소) 값의 포락선이 사용되었다. Spin coating 방법을 사용하여 제작된Poly((1,4-phenylenevinylene$)_{0.34}$-co-(2-methoxy-1,4-phen ylene vinylene$)_{0.66}$) [PP$V_{0.34}$-PMP$V_{0.66}$] 박막에 대해서 투과율 스텍트럼과 Maker fringe를 측정한 후, 이들 data로부터 구한 1907 nm 펌프 파장에 대한 굴절률, 가간섭길이 및 3차 비선형 광학 감수율 값은 각각 1.786, 17.86 ${\mu}m$ 및 5.8${\times}10^{12}$esu였다.

• 한국광학회:학술대회논문집
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• 한국광학회 2005년도 하계학술발표회
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• pp.284-285
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• 2005

• 한국결정성장학회지
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• 제8권2호
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• pp.315-323
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• 1998

$Ti(i-OC_3H_7)_4$알콕사이드를 출발원료로 사용한 sol-gel법을 이용하여 Rutle, Anatase 결정상의 $TiO_2$박막을 제조하였다. 결정화 정도란 관점에서 $TiO_2$ 박막의 결정상에 미치는 첨가물의 영향을 조사하였다. 3차 비선형 광학 감수율을 THG법을 이용하여 측정하였으며, Rutle 과 Anatase 결정상의 $TiO_2$ 박막의 3차 비선형 광학 감수율은 각각 $1.4{\times}10^{-12}$과 $9.7{\times}10^{-13}$ esu의 값을 얻었다.