• 한국결정성장학회지
• /
• 제12권6호
• /
• pp.323-328
• /
• 2002

The model of the shortest chemical bonds is applied for the classification of acentric simple and binary Mo(VI) and W(VI) oxides. It is shown that on the plane of the shortest chemical bonds the compounds are located into the rosette of three intersected ellipses. The correlation between the optical nonlinearity and combination of the bond lengths is discussed.

• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 1994년도 Proceedings of the Korea Automatic Control Conference, 9th (KACC) ; Taejeon, Korea; 17-20 Oct. 1994
• /
• pp.725-730
• /
• 1994

A sodium chloride crystallizer shows oscillatory and nonlinear characteristics under its nucleating and growing process. Because these characteristics vary with operational condition, we can't control the product crystal size exactly with a PID controller or a sequence controller. Then, we make a model with threefold neural networks for the laboratory equipment that is a jet mixing crystallizer. We try to control the product crystal size with its neuro-model, and we reach the conclusion that our neuro-model is applicable to the practical crystallizer.

• 한국결정성장학회지
• /
• 제5권2호
• /
• pp.181-188
• /
• 1995

3차 비선형광학 재료를 설계하기 위해 단성분 산화물에서의 산소의 평균 전자분극률과 광학 염기도를 굴절율, 에너지 갭의 각기 다른 물성을 통해 산출하였다. Lorentz-Lornez식과 Duffy 의 반실험식을 도입하여 산소의 평균 전자분극율과 광학 염기도를 두가지 다른 물성으로부터 계산하여 비교하였다. 처음으로 독립적인 초기값에서 계산한 각각의 산소의 평균 전자분극률과 광학 염기도 사이에 좋은 상응관계가 있음을 확인하였다.

• 한국결정성장학회지
• /
• 제6권2호
• /
• pp.166-176
• /
• 1996

새로운 비선형 광학결정으로 유망시되는 $CsLiB_{6}O_{10}$ 결정을 육성하기 위한 기초 조건을 조사하였다. 화학양론적으로 혼합된 $CsLiB_{6}O_{10}$ 조성으로부터 $600^{\circ}C$ 이상의 온도에서 같은 조성의 결정이 형성되었고, 이 결정은 $800^{\circ}C$까지 상변화를 나타내지 않았으며, $850^{\circ}C$에서 합치용융하였다. $CsLiB_{6}O_{10}$ 조성을 용융시킨 뒤, 융액을 $1~150^{\circ}C/hr$의 냉각 속도로 냉각시키면, 냉각 속도에 관계없이 유리가 생성되었다. 그러나 융액중에 $CsLiB_{6}O_{10}$ 결정 seed가 존재하는 경우에는 융액으로부터 $CsLiB_{6}O_{10}$ 결정이 직접 석출되었다. Seed 결정을 이용하여 온도 구배가 $100^{\circ}C/cm$인 일방향 전기로에서 0.06 mm/hr의 응고 속도로 투명한 $CsLiB_{6}O_{10}$ 단결정을 육성하였다. 육성된 결정의 구조 해석 결과, 이결정은 noncentrosymmetric tetragonal space group 142d에 속하고, unit cell dimensions은 $a=10.467(1)\;{\AA},\;c=8.972(1)\;{\AA}과\;V=983.0(2)\;{\AA}^3$이었다. 이 결정의 광학적 특성은 180mm에서 absorption edge를 가지고 300 nm이상의 파장 영역에서 70%의 광투과율(두께 0.5 mm)을 나타내었다.

• 한국결정성장학회지
• /
• 제16권4호
• /
• pp.133-140
• /
• 2006

The growth characteristics and properties of large size $SrAlF_5$ single crystals are described and compared with those of $BaMgF_4$. Transmission spectra in the vacuum ultraviolet wavelength region indicate a high transparency of $SrAlF_5$ (about 90% without considering surface reflection loses) down to 150 nm, on contrast to the optical loses observed for $BaMgF_4$. The ferroelectric character of $SrAlF_5$ is evidenced by the reversal of the spontaneous polarization in a hysteresis loop. The higher potential of $SrAlF_5$ in comparison with $BaMgF_4$ for the realization of all-solid-state lasers in the ultraviolet wavelength region by the quasi-phase matching (QPM) technique is pointed out. $SrAlF_5$, besides a higher grade of transparency, shows a nonlinear effective coefficient similar to that of quartz and uniaxial nature, on contrast to the one order smaller nonlinear coefficient and biaxial character of $BaMgF_4$. The refractive index of $SrAlF_5$ from the ultraviolet to the near-infrared wavelength region is measured by the minimum deviation method. The Sellmeier and Cauchy coefficients are obtained from the fits to the curves of the ordinary and extraordinary refractive indices, and the grating period for the first order QPM is estimated as a function of the wavelength. The poling periodicity for 193 nm SHG from 386 nm is $4{\mu}m$.

• Bulletin of the Korean Chemical Society
• /
• 제23권1호
• /
• pp.98-102
• /
• 2002

The structure of a single crystal, grown by a slow cooling a melt of $Ca_{1.29}Bi_{0.14}VO_4$ composition, was analyzed. The crystals belong to the rhombohedral space group R3c and the dimensions of the unit cells are a = 10.848(1)${\AA}$, c = 38.048(6)${\AA}$, V = 3877.6(8)${\AA}^3$ for the pale yellow crystal, and a = 10.857(1), c = 38.063(6)${\AA}$, V = 3885.6(8)${\AA}^3$ for the yellow crystal, respectively. Unit cell dimensions of the crystal were larger than those of the host crystal, $Ca_3(VO_4)_2$, owing to the Bi that replaced Ca in the unit cell. Ca in the unit cell formed six, eight and nine coordinated polyhedra with O atoms and Bi replacing Ca entered the eight or nine coordinated Ca sites with different crystallographic environments in the unit cell. All the V in the unit cell formed four coordinated tetrahedra with O atoms, however V-O bond lengths in the tetrahedra were different from one another.

• Journal of the Optical Society of Korea
• /
• 제13권1호
• /
• pp.158-165
• /
• 2009

We present cross-correlation frequency-resolved optical gating (XFROG) measurements of supercontinuum pulses generated by using a photonic crystal fiber (PCF), and ultraviolet (UV) pulses generated by frequency doubling of infrared ultra-short pulses. Since supercontinuum pulses have broad spectra, XFROG measurement typically requires using an extremely thin nonlinear crystal which has a thickness of sub-ten microns. Instead of using such a thin crystal, we employed a relatively thick crystal which was mounted on a galvanometer in order to achieve a phase-matching over the whole spectral bandwidth of the supercontinuum pulses by a crystal-dithering technique. Experimental results of the retrieved phase and intensity were in fair agreement with the independently measured data.

• 한국결정성장학회지
• /
• 제13권4호
• /
• pp.153-156
• /
• 2003

Pure and Ethylenediaminetetraacetic acid (EDTA) doped L-arginine phosphate (LAP) single crystals were grown from the aqueous solution by temperature lowering method. The effect of EDTA additive on the solubility and metastable zone width of LAP solution has been investigated. Addition of EDTA has enhanced the metastable zone width of LAP and hence bulk crystals could be grown. The growth rate along the [100] direction increases with EDTA additive. Powder X-ray diffraction and FTIR studies reveal the absence of EDTA in the lattice of LAP, This reveals that the addition of EDTA to LAP doesn't influence the crystallinity. However, the transmittance and NLO properties significantly increase with EDTA additive and hence bulk LAP crystals are useful for laser fusion experiments.

• 한국결정성장학회지
• /
• 제7권3호
• /
• pp.514-520
• /
• 1997

진공급냉법을 이용하여 단성분계 $Sb_2O_3$ 유리를 제조하였다. 선형굴절율은 500-1000 nm 범위내에서 측정하였으며, 굴절율은 633 nm에서 2.0이었다. 에너지갭은 3.38 eV 이었으며, 3차 비선형 광학 감수율을 THG법을 이용하여 측정하였으며 단성분계 Silica 유리보다도 20배 큰 $5.68{\times}10^{-13}$ esu의 측정값을 얻었다.

• 한국광학회지
• /
• 제18권1호
• /
• pp.14-18
• /
• 2007

실리카 코어 주변에 주기적인 공기층을 가지는 광자결정 광섬유는 넓은 파장 영역을 통한 단일모드의 구현 또는 1옥타브 이상의 광대역 연속광 발생과 같은 기존의 광섬유로는 불가능한 독특한 특성을 갖도록 유연하게 설계할 수 있다. 광자결정 광섬유의 설계에 사용되는 변수로는 공기층의 직경과 간격이 있으며 이러한 변수의 조절을 위한 공정을 도입하여 넓은 파장영역을 통한 단일모드 구현과 높은 비선형 특성을 가지는 광자결정 광섬유를 각각 제작 하였고 수치적 계산과 실험을 통해 그 특성을 살펴보았다.