• 제목/요약/키워드: Non-isothermal

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유동 해석을 이용한 평판형 고체 산화물 연료전지의 성능 특성 분석 (II) - 비등온 모델 - (Performance Predictions of the Planar-type Solid Oxide Fuel Cell with Computational Flow Analysis (II) - Non-isothermal Model -)

  • 현희철;손정락;이준식;노승탁
    • 대한기계학회논문집B
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    • 제27권7호
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    • pp.963-972
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    • 2003
  • Performance characteristics of the planar-type solid oxide fuel cell (SOFC) are investigated by the analysis of flow fields coupled with heat and mass transfer phenomena in anode and cathode channels. For these purposes, performance analysis of the SOFC is conducted based on electrochemical reaction phenomena in electrodes and electrolyte coupled with flow fields in anode and cathode channels. In the present study, the isothermal model adopted in the previous paper prepared by the same authors is extended to the non-isothermal model by solving energy equation additionally with momentum and mass transfer equations using CFD technique. It is found that the difference between isothermal and non-isothermal models come from non-uniform temperature distribution along anode and cathode electrodes by solving energy equation in non-isothermal model. Non-uniform temperature distribution in non-isothermal model contributes to the increase of average temperature of the fuel cell and influences its performance characteristics.

변온 하중하에 있는 재료의 이력거동 예측을 위한 다층 모델에 관한 연구 (A Study on the Overlay Model for Description of Hysteresis Behavior of a Material under Non-isothermal Loading)

  • 김상호;서동훈;여태인
    • 한국자동차공학회논문집
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    • 제18권3호
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    • pp.133-142
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    • 2010
  • The present work focuses on the characterization of material parameters of the Overlay(multilinear hardening) model for analyzing the non-isothermal cyclic deformation. In the previous study, all the parameters were especially based on the Overlay theories, and a simple method was suggested to find out the best material parameters for the isothermal cyclic deformation analysis. Based on the previous research this paper f dther improves the isothermal parameters and suggests how to apply the isothermal parameters to the non-isothermal conditions especially for the description of TMF(Thermo-Mechanical Fatigue) hysteresis behavior. The parameters are determined and calibrated using 400 series stainless steel test data in the reference papers. For the implementation into ABAQUS, a user subroutine is developed by means of ABAQUS/UMAT. The finite element results show good agreement with test for the case of uniaxial non-isothermal cyclic loading, signifying the proposed method can be used in the TMF analysis of the converter-inserted heavy duty muffler system and the stainless steel exhaust-manifold system which are to be done in our future research.

알루미늄 합금박판 비등온 성형공정의 유한요소 해석 및 실험적 연구 (제2부:해석) (Finite Element Analysis and Experimental Investigation of Non-isothermal Forming Processes for Aluminum-Alloy Sheet Metals (Part2:Analysis))

  • 김성민;구본영;금영탁;김종호
    • 소성∙가공
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    • 제8권3호
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    • pp.252-261
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    • 1999
  • The 3-dimensional finite element program is developed to analyze the non-isothermal forming processes of aluminum-alloy sheet metals. Bishop's method is introduced to solve the heat balance and force equilibrium equations. Also, Barlat's non-quadratic anisotropic yield function depicts the planar anisotropy of the aluminum-alloy sheet. To find an appropriate constitutive equation, four different forms are reviewed. For the verification of the reliability of the developed program, the computational try-outs of the non-isothermal cylindrical cupping processes of AL5052-H32 and Al1050-H16 are carried out. As results, the constitutive equation relating to strain and strain-rate, in which the constants are represented by the 5th-degree polynomials of temperature, is in good agreement with measurement. The computational try-outs can predict optimal forming conditions in non-isothermal forming processes.

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Pyrolysis Properties of Lignins Extracted from Different Biorefinery Processes

  • Lee, Hyung Won;Jeong, Hanseob;Ju, Young-Min;Youe, Won-Jae;Lee, Jaejung;Lee, Soo Min
    • Journal of the Korean Wood Science and Technology
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    • 제47권4호
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    • pp.486-497
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    • 2019
  • The non-isothermal and isothermal pyrolysis properties of H lignin and P lignin extracted from different biorefinery processes (such as supercritical water hydrolysis and fast pyrolysis) were studied using thermogravimetry analysis (TGA) and pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS). The lignins were characterized by ultimate/proximate analysis, FT-IR and GPC. Based on the thermogravimetry (TG) and derivative thermogravimetry (DTG) curves, the thermal decomposition stages were obtained and the pyrolysis products were analyzed at each thermal decomposition stage of non-isothermal pyrolysis. The isothermal pyrolysis of lignins was also carried out at 400, 500, and $600^{\circ}C$ to investigate the pyrolysis product distribution at each temperature. In non-isothermal pyrolysis, P lignin recovered from a fast pyrolysis process started to decompose and produced pyrolysis products at a lower temperature than H lignin recovered from a supercritical water hydrolysis process. In isothermal pyrolysis, guaiacyl and syringyl type were the major pyrolysis products at every temperature, while the amounts of p-hydroxyphenyl type and aromatic hydrocarbons increased with the pyrolysis temperature.

에틸렌-테트라플르오르에틸렌 공중합체의 비등온 결정화 거동 (Non-isothermal Crystallization Behaviors of Ethylene-Tetrafluoroethylene Copolymer)

  • 이재훈;김효갑;강호종
    • 폴리머
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    • 제36권6호
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    • pp.803-809
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    • 2012
  • 에틸렌-테트라플르오르에틸렌(ETFE) 공중합체의 비등온 결정화 거동을 DSC와 imaging FTIR을 이용하여 살펴보았다. 변형 비등온 Avrami 분석 결과, DSC에 의한 열분석의 경우 상대적으로 적은 결정화 엔탈피 변화로 인하여 Avrami 식에 의한 ln[-ln(1-X(t))] vs. ln(t) 곡선이 선형을 이루지 못하는 반면, 결정화에 의한 IR 흡수 강도 image의 변화에 의한 분석 방법인 imaging FTIR의 경우보다 선형적인 결과를 얻음에 따라 imaging FTIR이 ETFE 비등온 결정화 연구에 보다 효과적임을 알 수 있었다. 이와 함께 비등온 결정화에 의한 ETFE의 광학특성을 살펴본 결과, 서냉에 의하여 형성된 ETFE 결정의 빛 산란에 의하여 haze가 증가하며 따라서 투명도가 감소함을 알 수 있으며 비등온 결정화에 의하여 최대 8%의 투과도 감소가 일어남을 확인할 수 있었다. 이상의 결과로부터 결정화를 조절하는 냉각속도가 유리 대체 소재로 사용되고 있는 ETFE 필름의 광투과도 조절에 주요한 가공 변수임을 확인할 수 있었다.

Layered System의 아웃도어 의류에의 적용 - 수분전달 특성을 중심으로 - (Application of Layered System to the Outdoor Clothing - Through Water Vapor Permeability -)

  • 오애경
    • 한국의류산업학회지
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    • 제8권6호
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    • pp.709-712
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    • 2006
  • The aim of this study is to find out comfortable combinations of layered system for outdoor activities through water vapor permeability. Layering fabrics is an effective way of controlling water transport properties in fabric systems for outdoor activities and analysis of these systems may be useful for designing comfortable clothing. Seven fabrics were chosen for the experiments: two fabrics for base layer, two for the middle layer and three for the shell layer. A total of 12 different layered systems, which are all possible combinations were established using selected fabrics. The water vapor permeability was measured using JIS L1099 under isothermal and non-isothermal conditions. It was found that layered system was working together as a whole having influence on each layer, though every layer offers varying degree of water vapor permeability. Furthermore, it was also found that an optimal combination of the three layered system does exist although the combination may differ according to the ways. The shell layer is the greatest effect of water vapor permeability under isothermal and non-isothermal conditions within layered system.

단조하중 감소를 위한 열간 형단조공정 해석 (An Analysis of Hot Closed-Die Forging to Reduce Forging Load)

  • 김헌영;김중재;김낙수
    • 대한기계학회논문집
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    • 제17권12호
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    • pp.2970-2981
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    • 1993
  • In hot closed-die forging the load increases rapidly near the final stage. Preforming operation is important to both the sound final forging and die-service life. In this study, the material flows during preforming and final forging are investigated. The physical modeling with Plasticine as a model material showed clear flow patterns. The forging process were numerically simulated by the finite element method with the isothermal and the non-isothermal models. The flow patten of the isothermal simulation showed good agreements with the experiments. Temperature changes and pressure distributions on the die surfaces during one cycle of the forging process were obtained from the non-isothermal simulation. High pressure and temperature were developed at certain areas of the die surfaces. It was concluded that those areas usually coincide with each other and should be distributed by the preforming operations to enhance the die life.

Loop-mediated isothermal amplification (LAMP)법을 이용한 Streptococcus parauberis 의 신속 진단 (Loop-mediated Isothermal Amplification (LAMP) for Detection of Streptococcus parauberis)

  • 문경미;김동휘;허문수
    • 생명과학회지
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    • 제24권4호
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    • pp.428-436
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    • 2014
  • Loop-mediated isothermal amplification (LAMP)법은 등온에서 DNA 주형을 변성시키지 않고 실시하기 때문에, autocycling 가닥 변위 DNA 합성에 의존한다. 그래서 고가의 PCR 장비를 필요로 하지 않고 등온 유지가 가능한 저가의 장비인 항온 수조, 오븐, 온장고 등에서 증폭이 가능하다. 본 연구진은 Streptococcus parauberis의 random primer중에서 5개를 선정하여, 신장도가 높은 2개의 primer를 이용하여 최적 반응온도 및 최적 반응시간, 최적 반응 조건들을 확립하였다. 그리고 기존의 PCR과 LAMP의 민감도의 비교 분석을 측정한 결과, LAMP의 높은 검출 한계를 확인할 수 있었다. 본 논문에서는 non-target DNA의 영향을 받지 않고 등온 조건 하에서 DNA를 증폭시킬 수 있는 LAMP법과 SYBR-green I를 이용하여 시각화시켰으며, 기존의 PCR과 비교 분석함으로써, S. parauberis에 대한 신속하고 정확한 진단법을 확립하였다.

비등온 난류 제트의 이상유동에 대한 수치모델 (Numerical Modeling of Two-Phase Non-Isothermal Turbulent Jet)

  • 황득리엔;김명관;권오붕
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집E
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    • pp.783-788
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    • 2001
  • Choosing the most suitable mathematical model and relating this to turbulent tangential tensions model are very important in the investigations of turbulent two-phase flow. This paper considers two-fluid scheme. According to it, two phases have their own densities, velocities, and temperatures at any spatial point and at any moment. The equations of motion and heat transfer for each phase are linked with the forces of interaction between two phases. These forces are considered as predominant for the flow. As a closure in the system of motion equations, one modification of $K - {\epsilon}$ turbulent model is worked out. The modification uses two equations for turbulent kinetic energy of the phases and one - for the turbulent energy loss of main phase. This model can be set as a $K_g - K_p -{\epsilon}$ model. The modified model has been tested for both a two-phase non-isothermal flat jet and axially symmetrical jet. The numerical results are compared with the reference data revealing a good agreement between them.

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Non-isothermal pyrolysis of cashew shell cake-bituminous coal blends

  • Park, Yoon Hwa;Park, Ho Young;Kim, Hyun Hee;Park, Sang Bin
    • Environmental Engineering Research
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    • 제23권2호
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    • pp.121-128
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    • 2018
  • This paper describes the non-isothermal pyrolysis of cashew shell cake (CSC) - bituminous coal blends. The blends exhibit two distinct stages in the thermogravimetric curves, which the first stage stems from CSC and the second one from the superposition of CSC and coal pyrolysis. The pyrolysis behavior of the blend was linearly proportional to the blending ratios. The overall behavior of the blends was evaluated in terms of the maximum rate of weight loss, characteristic temperatures, char yields, and the calculated and experimental thermogravimetric curves. The activation energies ranged up to 49 kJ/mol for the blends were obtained and used to evaluate the interaction in the blends. The present thermogravimetric study shows that there is no significant interaction between CSC and coal in the blends, and it was supported by the characteristic values which are linearly proportional to the weight percentages of cashew cake-shell in the blends. The no-interaction might be due to the fact that the main reaction zones are distinctively different for two constituents, so the additive rule is acceptable for describing pyrolysis behavior of the present blends.