• Journal of the Korean Institute of Gas
• /
• v.18 no.4
• /
• pp.56-62
• /
• 2014

The present study investigated numerically heat and mass transfer characteristics of a fixed bed reactor by using a computational fluid dynamics (CFD) code of Fluent (ver. 13.0). The temperature and species fraction were estimated for different porosities. For modeling of the catalyst in a fixed bed tube, catalysts were regarded as the porous material, and the empirical correlation of pressure drop based on the modified Eugun equation was used for simulation. In addition, the averaged porosities were taken as 0.545, 0.409, and 0.443 and compared with non-porous state. The predicted results showed that the temperature at the tube wall became higher than that estimated along the center line of tube, leading to higher hydrogen generation by the endothermic reaction and heat transfer. As the mean porosity increases, the hydrogen yield and the outlet temperature decreased because of the pressure drop inside the reformer tube.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.11 no.3
• /
• pp.1027-1034
• /
• 2010

Effects of inorganic nano-powders on the polymerization and thermal degradation kinetics as well as the mechanical properties of polyurethane nano-composites were studied by both the measurement of polymerization temperature as a function of time and non-isothermal thermogravimetric analysis (TGA) as well as the Instron test. As the results from polymerization studies, the reaction rates of MMT-filled PU composites were faster than those of Ce500-filled ones, and moreover, the activation energies using Kissinger method for the thermal degradation of composites were calculated as 139.34 kJ/mol for the Ce500-filled PU composites and 91.12 kJ/mol for MMT-filled one, respectivel, exhibiting that MMT nano-powder seemed to be acting as the catalyst for both polymerization and degradation of PU composites. UTM result, however, showed that tensile strength at break of MMT-filled composites was much higher than that of Ce500-filled ones above the concentrations range of 5 phr in the composites.

• Applied Chemistry for Engineering
• /
• v.23 no.2
• /
• pp.190-194
• /
• 2012

10 wt% Mn supported on various commercial $TiO_2$ catalysts were prepared by wet-impregnation method for the low temperature selective catalytic reduction (SCR) of NO with $NH_3$. A combination of various physico-chemical techniques such as BET, XRD, XPS and TPR were used to characterize these catalysts. MnOx surface densities on MnOx/$TiO_2$ catalyst were related to surface area. As MnOx surface density lowered with high dispersion, the SCR activity for low temperature was increased and the reduction temperature ($MnO_2$ ${\rightarrow}$ $Mn_2O_3$) of surface MnOx was lower. For a high SCR, MnOx could be supported on a high surface area of $TiO_2$ and should be existed a high dispersion of non-crystalline species.

• Journal of Sensor Science and Technology
• /
• v.31 no.5
• /
• pp.343-347
• /
• 2022

Recently, the problem of global warming caused by greenhouse gases is getting serious due to the development of industry and the increase in transportation means. Accordingly, the need for a technology to reduce carbon dioxide, which accounts for most of the greenhouse gas, is increasing. Among them, a catalyst for converting carbon dioxide into fuel is being actively studied. Catalysts for reducing carbon dioxide are classified into thermal catalysts and photocatalysts. In particular, the photocatalyst has the advantage that carbon dioxide can be reduced only by irradiating ultraviolet rays at room temperature without high temperature or additional gas. TiO₂ is widely used as a photocatalyst because it is non-toxic and has high stability, but has a disadvantage of low carbon dioxide reduction efficiency. To increase the reduction efficiency, 1-propanol was used in the synthesis process. This prevents agglomeration of the catalyst and increases the specific surface area and pores of TiO₂, thereby increasing the surface area in contact with carbon dioxide. As a result of measuring the CO₂ reduction efficiency, it was confirmed that the efficiency of TiO₂ with 1-propanol and TiO₂ without 1-propanol was 19% and 12.3%, respectively, and the former showed a 1.5 times improved efficiency.

• Bulletin of the Korean Chemical Society
• /
• v.26 no.5
• /
• pp.713-714
• /
• 2005

• Journal of the Korean Chemical Society
• /
• v.10 no.2
• /
• pp.76-90
• /
• 1966

Ammonium sulfate synthesized by the air oxidation methods without catalyst using the reaction vessel which was fitted with fritted glass at the bottom of it and introducing, through the bottom, ammonia and air with constant flow rates to sulfurous acid solution of constant concentrations at the given temperatures. The experiment showed that the oxidation process was accelerated in accord with the increase of the air flow rates when the ammonia flow rate was constantly kept at ca. 100ml/min. in high temperatures. When the pH of the solution reached 9.0, the oxidation was nearly completed. It is assumed that in the process of reaction, $[O_{2}{\to}HSO_{3}^-]^{\neq}$ would be produced as an activated complex and the reaction was thought to be first order. The experiment indicated that the 0.5M sulfurous solution could be oxidized up to 98.54% at the flow rates of ammonia and air, 100ml/min., and 4l/min., respectively at $50^{\circ}C$.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2012.11a
• /
• pp.217-219
• /
• 2012

In this study, the experiment was conducted in the level of mortar as one of the basic studies on pre-cast concrete which acceleration curing is not done. This study has the purpose to develop the strength of mortar into 20MPa within 6 hours in the condition of room temperature using admixtures which can accelerate C3S hydration reaction. In this experiment, W/C was fixed into 20%, PCE which can stimulate C3S was used as an accelerating admixture. From the results of this experiment, maximum content of accelerating admixture was 1%. Also, as more than 20MPa was measured through 6-hour compressive strength, it can be known that strength can be developed without steam-curing.

• 한국신재생에너지학회:학술대회논문집
• /
• 2006.11a
• /
• pp.340-343
• /
• 2006

In this paper, heat and mass transfer characteristics through experimental and numerical study are extensively investigated in steam reform ins reactor under given operating conditions. In order to get simulated data at outlet of the reformer, heterogeneous reactor model is incorporated. As the reaction also takes place in porous media, two medium approach is used to take into account thermally non-equilibrium phenomena between catalyst and bulk gas. In steam reforming reaction, heat transfer issue is so significant that geometrical configuration study is also conducted.

• Journal of the Korean Applied Science and Technology
• /
• v.17 no.1
• /
• pp.15-21
• /
• 2000

The catalytic hydroxylation of several cycloalkanes in dichloromethane have been investigated using In(Ⅲ)-, Tl(Ⅲ)-porphyrin complexes as a catalyst and NaClO, $NaClO_{2}$, $H_{2}O_{2}$ as a terminal oxidant. Porphyrins were TPP and ($F_{20}$)TPP (TPP = tetraphenylporphyrin) and substrates were cyclopentane, cyclohexane, cycloheptane and cyclooctane. The substrate conversion yield was discussed according to the substituent effect and hinderance effect of metalloporphyrin and the radius effect of non-redox metal ion. The conversion yield of cycloalkane followed the order of $ C_{5} $ < $ C_{6}$ < $ C_{7}$ = $ C_{8}$. In this experimental condition $NaClO_2$ was rather efficient terminal oxidant than NaClO and $H_{2}O_{2}$.

• Transactions on Electrical and Electronic Materials
• /
• v.11 no.6
• /
• pp.243-248
• /
• 2010

The emergence of different and disparate materials together with the convergence of both the 'old' and 'emerging' technologies is paving the way for integration of heterogeneous technologies that are likely to extend the limitations of silicon technology beyond the roadmap envisaged for complementary metal-oxide semiconductor. Formulation of new information processing concepts based on novel aspects of nano-scale based materials is the catalyst for new nanoarchitectures driven by a different perspective in realization of novel logic devices. The memory technology has been the pace setter for silicon scaling and thus far has pave the way for new architectures. This paper provides an overview of the inevitability of heterogeneous integration of technologies that are in their infancy through initiatives of material physicists, computational chemists, and bioengineers and explores the options in the spectrum of novel non-volatile memory technologies considered as forerunner of new logic devices.