• 전기화학회지
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• 제17권1호
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• pp.26-29
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• 2014

The corrosion behavior of stainless steel 304 (SS 304), titanium, nickel and aluminium is studied by immersion and anodic polarization tests in non-aqueous electrolytes. Tetraethyl ammonium tetrafluoroborate is used as a supporting electrolyte in the three kinds of solvents. The immersion test shows that chemical corrosion rate in propylene carbonate-based electrolyte is lower than those in acetonitrile- or ${\gamma}$-butyrolactone-based electrolytes. Surface analyses do not reveal any corrosion product formed after the immersion test. In the anodic polarization tests, a higher concentration of supporting electrolyte gives a higher current density. In addition, a higher temperature increases the current density in the active region and reduces the potential range in the passive region. SS 304 shows the highest corrosion potential while Al shows the lowest corrosion potential and the highest current density in all studied conditions. Based on the conducted corrosion tests, the corrosion resistance of metal substrates in the organic solvents can be sorted in descending order as follows: SS 304 - Ti - Ni - Al.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.211.2-211.2
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• 2014

Epitaxial complex oxide thin film heterostructures have attracted a great attention for their multifunctional properties, such as ferroelectricity, and ferromagnetism. Two dimensional electron gas (2DEG) confined at the interface between two insulating perovskite oxides such as LaAlO3/SrTiO3 interface, provides opportunities to expand various electronic and memory devices in nano-scale. Recently, it was reported that the conductivity of 2DEG could be controlled by external electric field. However, the switched conductivity of 2DEG was not stable with time, resulting in relaxation due to the reaction between charged surface on LaAlO3 layer and atmospheric conditions. In this report, we demonstrated a way to control the conductivity of 2DEG in non-volatile way integrating ferroelectric materials into LAO/STO heterostructure. We fabricated epitaxial Pb(Zr0.2Ti0.8)O3 films on LAO/STO heterostructure by pulsed laser deposition. The conductivity of 2DEG was reproducibly controlled with 3-order magnitude by switching the spontaneous polarization of PZT layer. The controlled conductivity was stable with time without relaxation over 60 hours. This is also consistent with robust polarization state of PZT layer confirmed by piezoresponse force microscopy. This work demonstrates a model system to combine ferroelectric material and 2DEG, which guides a way to realize novel multifunctional electronic devices.

• Corrosion Science and Technology
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• 제21권2호
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• pp.89-99
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• 2022

A versatile method for performing non-cyanide electroless gold plating using thiomalic acid (TMA) as a complexing agent and 2-aminoethanethiol (AET) as a reducing agent was investigated. It was found that TMA was an excellent complexing agent for gold. It can be used in electroless gold plating baths at a neutral pH with a high solution stability, makes it a potential candidate to replace conventional toxic cyanide complex. It was found that one gold atomic ion could bind to two TMA molecules to form the [2TMA-Au⁺] complex in a solution. AET can be used as a reducing agent in electroless gold plating solutions. The highest current density was obtained at electrode rotation rate of 250 to 500 rpm based on anodic and cathodic polarization curves with the mixed potential theory. Increasing AET concentration, pH, and temperature significantly increased the anodic polarization current density and shifted the plating potential toward a more negative value. The optimal gold ion concentration to obtain the highest current density was 0.01 M. The cathodic current was higher at a lower pH and a higher temperature. The current density was inversely proportional to TMA concentration.

• 대한기계학회논문집A
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• 제22권1호
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• pp.177-189
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• 1998

The contents of this paper include a non-destructive technique for evaluating the degradation of the boiler superheater tube in a fossil power plant through an electrochemical polarization test. Correlation between Ip of polarization parameter and SP-DBTT for the superheater tubes in long-term use was obtained. 1.0Cr-0.5Mo steel was degraded by softening, and the degree of degradation was dependent upon carbides with Cr and Mo elements. Since brittle fracture at low temperature and ductile fracture mode at high temperature were shown, similarity between standard Charpy and small punch tests could be found. In addition, SP-DBTT showing the degree of degradation was higher, as the time-in use of the materials got longer. Electrolyte including picric acid of 1.3 g in distilled water of 100ml at 25.deg. C temperature and sodium tridecylbenzene sulfonate with 1g could be applied to evaluate the degradation of 1.0Cr-0.5Mo steel by means of the electrochemical polarization test. Ip and Ipa values measured through the electrochemical test are the appropriate parameters for representing the degradation of the superheater tube(1.0Cr-0.5Mo steel) for the fossil power plant. It is poassible to evaluate the degradation of materials with different time histories electrochemically, by Ip value only, at field test.

• 한국광학회지
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• 제8권6호
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• pp.486-491
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• 1997

액정표시소자(LCD:Liquid Crystal Display Device)의 핵심부분인 액정셀의 광학적 동특성을 잴 수 있는 진폭분할방식의 측광식 편광계측기를 만들었다. 이 장치는 편광상태를 결정할 빛살을 비편광빛살분할기를 써서 밝기가 거의 같은 세 줄기의 빛살로 나누고, 나누어진 각각의 빛살을 편광빛살분할기 또는 사반파장판과 편광빛살분할기를 써서 직교하는 두 편광성분으로 나눈 다음, 각 성분의 밝기를 6개의 광다이오드를 써서 잰다. 이렇게 얻은 6개의 광신호의 비를 바탕으로 들어오는 빛살의 편광상태를 결정한다. 이 장치의 시간분해능은 80.mu.s, 정확도는 뽀앙카레 공(Poincare sphere)표현에서 나타낼 때 .+-.0.3.deg.이다. LCD에 쓰이는 전형적인 네마틱 액정의 반응시간은 수십 ms이므로 이 장치를 쓰면 액정셀의 광학적 동특성을 분석할 수 있다.

• 열처리공학회지
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• 제19권4호
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• pp.200-207
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• 2006

In addition to the basic properties of the base and top coating agents, corrosion resistance of non-chrome magni 565 coating and characteristics of coating film when coated to steel substrate were studied. The system had a good wettability at room temperature. Moreover, both the contact angle and surface tension were affected little by the viscosity of coating agent and surface roughness of the steel substrate. And the samples coated with optimal conditions showed a great corrosion resistance in salt spray test with 1500 hours or longer of initial appearance time of rust. The coating film was composed of overlapping layer of zinc and aluminium flakes, and the thickness of base coat increased with an increase of base coat viscosity. Based on the C-F peaks of 1,1-Difluoroethaen homo-polymer, it was thought that the base coat was an inorganic polymer bond layer. Meanwhile, the top coat showed C-F peaks of polytetrafluoroethylene with C-H peaks of phenol in FT-IR analysis. From the lower weight loss of base coat in TG analysis, it was thought that cross linking density of base coat was larger than that of top coat. It was thought that the small exothermic reactions observed in DSC curves were due to the thermosetting resins contained in the coating agents. Compared to the non-coated specimen, the coated sample showed more higher polarization resistance and corrosion potential with lower corrosion current density.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 하계학술대회 논문집 C
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• pp.1366-1368
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• 2001

In this study it can be confirmed that the formula by the free-rotational dipole theory is similiar with that by the phenomenological theory and the non-linear permittivity is determined only with the third harmonic conponent of polarization. Various parameters of VDCN copolymers were obtained from fitting results with the related formula.

• 대한환경공학회지
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• 제33권8호
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• pp.598-605
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• 2011

본 연구의 주 목적은 다층 다단 다공성 시스템에 편극전하 방식을 부가하여 본 시스템의 집진특성을 실험적으로 해석하는데 있다. 본 시스템의 압력손실 및 집진효율 특성 해석을 위해 실험은 인가전압, 시스템 유입유속, 유입농도 및 stage 수 등의 실험적 변수들에 의해 수행된다. 실험결과, 기류유입 시 유입유속 $v_{in}$ = 3.11 m/s에서 단(stage) 수 변화($1{\rightarrow}5$단)에 따라 압력손실은 $18{\sim}134mmH_2O$를 나타낸다. 인가전압 0 kV 및 기류유입이 없을 때, 시스템 유입유속 $v_{in}$ = 2.58 m/s인 경우 5 stage에서 집진효율은 92.5% 인 데 비해, 동일 유속에서 플레이트 별 편극전하(alternating polarization charge-applied voltage 2.5 kV) 및 기류유입 시스템인 경우 5 stage 효율은 98.5%로 전자에 비해 6% 정도 매우 높은 효율 상승을 보인다.

• 천문학회지
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• 제29권spc1호
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• pp.209-211
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• 1996

Recent surveys at Parkes, in particular the 70 cm survey of the southern sky, have discovered many pulsars, including 17 miilisecond pulsars in the Galactic disk. Timing and polarization observations of some of these pulsars are described. The only two pulsars known to be in orbit around massive non-degenerate stellar compamons were also discovered at Parkes, and some recent observational results for these pulsars are also presented.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 추계총회 및 연구발표회 초록집
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• pp.19.2-19
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• 2003