• 제목/요약/키워드: Non-Polarization

검색결과 282건 처리시간 0.021초

해양환경 중에서 SS 400 강제의 간극부식거동에 관한 연구 (Study on the Crevice Corrosion Behavior of 55400 in Marine Environment)

  • 임우조;윤병두
    • Journal of Advanced Marine Engineering and Technology
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    • 제25권6호
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    • pp.1336-1340
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    • 2001
  • Due to increase of air pollution substance, such as $SO_2$,$SO_3$, H2S ,CO, HCI, $Cl_2$ and so on, the operating environment of mechanical equipment and facilities like generating plants, ships, metal structure etc., are acidified and corroded. In these environments, the crevice corrosion of marine facilities frequently occurs at crevice like jointed bolt, gasket or sealant, riveted plates, contact of metal with non-metallic solids etc. Therefore, this paper was studied on the crevice corrosion behavior of mild steel(SS 400) in marine environment. In a variety of NaCl solutions, the aspect of he .crevice corrosion and polarization behavior under the crevice corrosion was investigated. The main results obtained are as follows: 1) Under crevice corrosion, the open circuit potential become less treble as the concentration of NaCl solution increased. 2) The corrosion current density of mild steel was high drained as the concentration of NaCl solution increased by 3.5%, but in the concentration increased over 3.5%, the corrosion current density was low drained. 3) The crevice corrosion is more sensitive to the synergy effect of dissolved oxygen and NaCl.

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Ba 치환에 따른 PMW-PNN-PZT 세라믹스의 압전 및 전계유기왜형 특성 (Piezoelectric and Electric Field Induced Strain Properties of PMW-PNN-PZT Ceramics with the Substitution of Ba)

  • 윤광희;김규수;최병수
    • 한국전기전자재료학회논문지
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    • 제14권1호
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    • pp.20-25
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    • 2001
  • To develop the piezoelectric actuator, the structural, dielectric and piezoelectric properties and electric fieldinduced strain of the ceramics(Pb$\_$1-2/Ba$\_$x/)[Mg$\_$1/2/W$\_$1/2/)$\_$0.03/-Ni$\_$1/3/Nb$\_$2/3/)$\_$0.12/-(Zr$\_$0.5/Ti$\_$0.5/)$\_$0.85/]O$_3$(x=0, 0.01, 0.03, 0.05, 0.07, 0.1) were investigated with the substitution of Ba. The tetragonality of crystal structure and grain size decreased by the substitution of Ba. Curie temperature decreased due to the decrease of the tetragonality, and dielectric constants increased with the substitution of Ba. The coercive field, remnant polarization and electromechanical coupling factor also decreased, whereas the piezoelectric constatns d$\_$33/ and d$\_$31/ were showed the highest value of 430 and 209(x10$\^$-12/C/N), respectively, because of the increase of dielectric constant. The strain induced by 60Hz AC electric field had the maximum value of 204x10$\^$-6/Δℓ/ℓ at the substitution of Ba 3mol%. As the applied electric field approaches to the coercive field, the piezoelectric element is depolarized and the electric field induced strain revealed non-linearity.

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스핀 코팅법으로 증착한 $(Bi,La)_4Ti_3O_{12}$ 박막의 후속 열공정에 따른 입자 크기 및 결정 방향성 변화 (Thermal Process Effects on Grain Size and Orientation in $(Bi,La)_4Ti_3O_{12}$ Thin Film Deposited by Spin-on Method)

  • 김영민;김남경;염승진;장건익;류성림;권순용
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.192-193
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    • 2006
  • A 16Mb ITIC FeRAM device was fabricated with BLT capacitors. The average value of the switchable 2 polarization obtained m the 32k-array (unit capacitor size: 068 ${mu}m^2$) capacitors was about 16 ${\mu}C/cm^2$ at 3V and the uniformity within an 8-inch wafer was about 2.8%. But a lot of cells were failed randomly during the measuring the bit-line signal of each cell. It was revealed that the Grain size and orientation of the BLT thin film were severely non-uniform. Therefore, the uniformity of the grain size and orientation was improved by changing the process conditions of post heat treatment. The temperature of nucleation step was the very effective on varying the microstructure of the BLT thin film. The optimized temperature of the nucleation step was $560^{\circ}C$.

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실리콘 고무의 하전입자의 거동에 관한 연구 (A Study on the Behavior of Charged Particles of Silicone Rubbers)

  • 이성일
    • Elastomers and Composites
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    • 제31권5호
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    • pp.335-340
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    • 1996
  • In order to look into the internal structure and the properties in the silicone rubbers added reinforcing fillers; silica $additives(O{\sim}140phr)$, and to examine the behavior of charged particles, the properties of thermally stimulated current(TSC) and X-Ray diffraction are investigated, respectively. And then, from the TSC which are formed by applying the electric field of $2{\sim}5kV/mm$ to specimen at the temperature range from -150 to $260^{\circ}C$, the results are as follwing: In the case of non-filled specimen, four peaks of ${\delta},\;{\gamma},\;{\beta}\;and\;{\alpha}$ are obtained at the temperature of $-120^{\circ}C,\;-60^{\circ}C,\;20^{\circ}C\;and\;130^{\circ}C$, respectively and the case of filled specimen, three peaks of ${\delta},\;{\alpha}_2\;and\;{\alpha}_1$ are observed at the temperature of $-120^{\circ}C,\;80^{\circ}C\;and\;130^{\circ}C$, respectively. The origins of these peaks are that, the ${\delta}$ peak seems to the result from the contribution of side chain methyl radical, and the ${\gamma}$ peak from the depolarization of space charge polarization owing to be added impurity during manufacturing specimens, and the ${\beta}$ peak from the orientation of $Si-CH_3$ dipole, and the ${\alpha}_2$ near the temperature of $80^{\circ}C$ from hydroxyl in carboxylic radical, and finally, the ${\alpha}_1$ peak near the temperature of $130^{\circ}C$ from carboxyl acid that is formed by the thermal oxidation of high temperature.

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Ferroelectric and Structural Properties of Nd-substituted $Bi_4Ti_3O_{12}$ Thin Films Fabricated by MOCVD

  • Kang, Dong-Kyun;Park, Won-Tae;Kim, Byong-Ho
    • 한국반도체및디스플레이장비학회:학술대회논문집
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    • 한국반도체및디스플레이장비학회 2006년도 추계학술대회 발표 논문집
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    • pp.166-169
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    • 2006
  • A promising capacitor, which has conformable step coverage and good uniformity of thickness and composition, is needed to manufacture high-density non-volatile FeRAM capacitors with a stacked cell structure. In this study, ferroelectric $Bi_{3.61}Nd_{0.39}Ti_3O_{12}$ (BNT) thin films were prepared on $Pt(111)/Ti/SiO_2/Si$ substrates by the liquid delivery system MOCVD method. In these experiments, $Bi(ph)_3$, $Nd(TMHD)_3$ and $Ti(O^iPr)_2(TMHD)_2$ were used as the precursors and were dissolved in n-butyl acetate. The BNT thin films were deposited at a substrate temperature and reactor pressure of approximately $600^{\circ}C$ and 4.8 Torr, respectively. The microstructure of the layered perovskite phase was observed by XRD and SEM. The remanent polarization value (2Pr) of the BNT thin film was $31.67\;{\mu}C/cm^2$ at an applied voltage of 5 V.

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$YCa_4O(BO_3)_3$ 비선형광학 단결정 성장 및 Second Harmonic Generation 소자 제조에 관한 연구 (Crystal Growth of $YCa_4O(BO_3)_3$ and Preparation of Device for Second Harmonic Generation)

  • 유영문;;장석종;장원권;임기수
    • 한국결정학회지
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    • 제11권1호
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    • pp.16-21
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    • 2000
  • (Yb/sub x/Y/sub 1-x/)Ca₄O(BO₃)₃ single crystals where x=0.3,8,15,20% were grown by Czochralski Method. The crystals grown under the optimum conditions were transparent and colorless with good crystal form. Using polarizing microscope, crystal defects such as parasite crystals and bubbles were detected depending on the composition of melts and pulling rates. The optimum growth parameters for high quality of single crystals were 15∼20 rpm of rotation rate and 2mm/h of pulling rate at the flow rate of 2 l/min of Nitrogen gas. The relationship between crystal axes and optical axes was investigated by optical crystallographic method, polarization technique and single crystal X-ray method. From the spectroscopic measurements, it was confirmed that there were strong absorption bands at 900 and 976.4 nm and strong emission band at 976.4 nm in Yb/sup 3+/ ion doped YCa₄O(BO₃)₃ crystal. For the application of second harmonic generation of 1.064 ㎛ laser, non-linear optical devices with θ=32.32° and Ψ=0°, λ/10 of flatness and the size of 6x8x5.73 mm were fabricated from the grown YCa₄O(BO₃)₃ crystal.

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The Microstructure and Ferroelectric Properties of Ce-Doped Bi4Ti3O12 Thin Films Fabricated by Liquid Delivery MOCVD

  • Park, Won-Tae;Kang, Dong-Kyun;Kim, Byong-Ho
    • 한국세라믹학회지
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    • 제44권8호
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    • pp.403-406
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    • 2007
  • Ferroelectric Ce-doped $Bi_4Ti_3O_{12}$ (BCT) thin films were deposited by liquid delivery metal organic chemical vapor deposition (MOCVD) onto a $Pt(111)/Ti/SiO_2/Si(100)$ substrate. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to identify the crystal structure, the surface, and the cross-section morphology of the deposited ferroelectric flims. After annealing above $640^{\circ}C$, the BCT films exhibited a polycrystalline structure with preferred (001) and (117) orientations. The BCT lam capacitor with a top Pt electrode showed a large remnant polarization ($2P_r$) of $44.56{\mu}C/cm^2$ at an applied voltage of 5 V and exhibited fatigue-free behavior up to $1.0{\times}10^{11}$ switching cycles at a frequency of 1 MHz. This study clearly reveals that BCT thin film has potential for application in non-volatile ferroelectric random access memories and dynamic random access memories.

Molecular-dynamic simulation on the equilibrium and dynamical properties of fluids in a nano-channel

  • Hoang, H.;Kang, S.;Suh, Y.K.
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2008년도 학술대회
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    • pp.208-214
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    • 2008
  • The equilibrium molecular-dynamic simulations have been performed to estimate the properties of the three kinds of fluids (the Lennard-Jones fluid, water and aqueous sodium-chloride solution) confined between two plates that are separated by 1.086 nm; included in the equilibrium properties are the density distribution and the static structure, and the diffusivity in the dynamic property. Three kinds of fluids considered in this study are. The water molecules are modeled by using the SPC/E model and the ions by the charged Lennard-Jones particle model. To treat the water molecules, we combined the quaternion coordinates with Euler angles. We also proposed a plausible algorithm to assign the initial position and direction of molecules. The influence of polarization of water molecules as well as the presence of ions in the solution on the properties will be addressed in this study. In addition, we performed the non-equilibrium molecular-dynamic simulation to compute the flow velocity for the case with the gravitational force acting on molecules.

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$3.5\%$ NaCl수용액에서 SAE 5155의 부식거동에 미치는 쇼트피닝의 영향 (The Effect of Shot Peening on Corrosive Behavior of SAE 5155 in $3.5\%$ NaCl Solution)

  • 안재필;박경동
    • Journal of Advanced Marine Engineering and Technology
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    • 제29권6호
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    • pp.692-700
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    • 2005
  • In this study. investigated the effect of shot peening on the corrosion of SAE 5155 steel immersed in $3.5\%$ NaCl solution and corrosion characteristics by the heat treatment during shot peening process. The immersion test was Performed on the four kinds of specimens. Corrosion Potential, polarization curve, residual stress etc. were investigated from experimental results. From these test results, the effect of shot peening on the corrosion was evaluated The important results of the experimental study on the effects of shot peened SAE 5155 on the corrosion are as follows; Shot peened specimens show the low of corrosion current as compared with un peened specimens. In the case of corrosion potential, shot Peened specimen shows more negative Potential as compared with that of parent metal Surface of specimen, which is treated with shot peening Process. is Placed as more activated state against inner parent metal. Corrosion rate is shown that shot Peened specimens have less corrode than un peened specimens. But non heat treated shot peened specimens show the biggest weight loss owing to variable compressive residual stress layer by shot ball.

단일편파 레이더자료 품질관리기술 특성 분석 (Analysis of Quality Control Technique Characteristics on Single Polarization Radar Data)

  • 박소라;김헌애;차주완;박종서;한혜영
    • 대기
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    • 제24권1호
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    • pp.77-87
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    • 2014
  • The radar reflectivity is significantly affected by ground clutter, beam blockage, anomalous propagation (AP), birds, insects, chaff, etc. The quality of radar reflectivity is very important in quantitative precipitation estimation. Therefore, Weather Radar Center (WRC) of Korea Meteorological Administration (KMA) employed two quality control algorithms: 1) Open Radar Product Generator (ORPG) and 2) fuzzy quality control algorithm to improve quality of radar reflectivity. In this study, an occurrence of AP echoes and the performance of both quality control algorithms are investigated. Consequently, AP echoes frequently occur during the spring and fall seasons. Moreover, while the ORPG QC algorithm has the merit of removing non-precipitation echoes, such as AP echoes, it also removes weak rain echoes and snow echoes. In contrast, the fuzzy QC algorithm has the advantage of preserving snow echoes and weak rain echoes, but it eliminates the partial area of the contaminated echo, including the AP echoes.