• Title/Summary/Keyword: Non-Polarization

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Stability of TiN and WC Coated Dental Abutment Screw (TiN 및 WC코팅된 치과용 어버트먼트 나사의 안정성)

  • Son, M.K.;Lee, C.H.;Chung, C.H.;Jeong, Y.H.;Choe, H.C.
    • Journal of the Korean institute of surface engineering
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    • v.41 no.6
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    • pp.292-300
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    • 2008
  • Dental implant system is composed of abutment, abutment screw and implant fixture connected with screw. The problems of loosening/tightening and stability of abutment screw depend on surface characteristics, like a surface roughness, coating materials and friction resistance and so on. For this reason, surface treatment of abutment screw has been remained research problem in prosthodontics. The purpose of this study was to investigate the stability of TiN and WC coated dental abutment screw, abutment screw was used, respectively, for experiment. For improving the surface characteristics, TiN and WC film coating was carried out on the abutment screw using EB-PVD and sputtering, respectively. In order to observe the coating surface of abutment screw, surfaces of specimens were characterized, using field emission scanning electron microscope(FE-SEM) and energy dispersive x-ray spectroscopy(EDS). The stability of TiN and WC coated abutment screw was evaluated by potentiodynamic, and cyclic potentiodynamic polarization method in 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. The corrosion potential of TiN coated specimen was higher than those of WC coated and non-coated abutment screw. Whereas, corrosion current density of TiN coated screws was lower than those of WC coated and non-coated abutment screw. The stability of screw decreased as following order; TiN coating, WC coating and non-coated screw. The pitting potentials of TiN and WC coated specimens were higher than that of non-coated abutment screw, but repassivation potential of WC coated specimen was lower than those of TiN coated and non-coated abutment screws due to breakdown of coated film. The degree of local ion dissolution on the surface increased in the order of TiN coated, non-coated and WC coated screws.

An Overview of the Pretreatment Processes in Seawater Desalination Plants using Reverse Osmosis Membranes (역삼투막을 이용한 해수담수화 플랜트에서 전처리 공정 기술)

  • Ahn, Chang Hoon;Lee, Wonil;Yoon, Jeyong
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.6
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    • pp.811-823
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    • 2009
  • Seawater desalination process using a reverse osmosis (RO) membrane has been considered as one of the most promising technologies in solving the water scarcity problems in many arid regions around the world. To protect RO membrane in the process, a thorough understanding of the pretreatment process is particularly needed. Seawater organic matters (SWOMs) may form a gel layer on the membrane surface, which will increase a concentration polarization. As the SWOMs can be utilized as a substrate, membrane biofouling will be progressed on the RO membrane surface, resulting in the flux decline and increase of trans-membrane pressure drop and salt passage. In the middle of disinfection, an optimal chlorine dosage and neutralizer (sodium bisulfite, SBS) should be practiced to prevent oxidizing the surface of RO membranes. Additional fundamental research including novel non-susceptible biofouling membranes would be necessary to provide a guide line for the proper pretreatment process.

Estimation of Electric Properties of Insulating Silicone Rubbers Added Reinforcing Fillers (보강성 충전제를 첨가한 절연용 실리콘 고무의 전기 특성 평가)

  • Lee, Sung-Ill
    • Elastomers and Composites
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    • v.32 no.5
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    • pp.309-317
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    • 1997
  • Estimation of the dielectric properties of insulating silicone rubbers added reinforcing fillers $(SiO_2,\;0{\sim}140phr)$ are very important to investigate the polymer structure. The characteristies of the dielectric absorption in insulating silicone rubbers were studied in the frequency range from 30Hz to 1MHz at the temperature range from $0{\sim}170^{\circ}C$. In the case of non-filled specimen, the dielectric loss is due to the syloxane which is the main chain of silicone rubber at the low temperature below $50^{\circ}C$ and the frequency at 330Hz, and is due to methyl and vinyl radical over the frequency of 1MHz. It is confirmed that the methyl radical or the vinyl radical becomes thermal oxidation at the high temperature over $100^{\circ}C$ and then the dielectric disperssing owing to the carboxyl radical Is appeared. In the case of filled specimen, the dielectric constant is in creased with the additives of reinforcing fillers due to the effect of interfacial polarization explained by MWS(Maxwell-Wagner-Sillars)'s law. The dielectric loss is decreased by the disturbance of reinforcing fillers that is permeated between networks.

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Development of Integrated Corrosion Monitoring and Control System (통합 부식 모니터링 및 통합 제어 시스템의 개발)

  • Yoo, Nam-Hyun;Kim, Young-Hun
    • Journal of Ocean Engineering and Technology
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    • v.27 no.3
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    • pp.8-14
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    • 2013
  • Although there are various factors that threaten the security of ships, one of the most harmful is corrosion. It is not easy to find corroding areas and the status of corrosion, even though corrosion causes serious problems such as submergence and marine pollution as a result of leaking oil and polluted water. To monitor the corrosion of ships, non-destructive inspection, weight loss coupons, electrical resistance, linear polarization resistance, zero resistance ammeter, and electrochemical impedance spectroscopy have been developed. However, these methods require much time to detect corrosion, and most are not appropriate for real time monitoring. Coating, sacrificial anode, and impressed current cathodic protection (ICCP) methods have been developed to control corrosion. The ICCP and sacrificial anode methods are the most popular ways to prevent ship corrosion. However, ICCP is only appropriate for the outside of a ship and cannot be used for complex structures such as ballast tanks because these are composed of many separate chambers. Sacrificial anodes have to be replaced periodically. This paper proposes an integrated corrosion monitoring and control system (ICMCS) that can detect corrosion in real time and is appropriate for complex structures such as ballast tanks. Because the system uses titanium for an anode, exhausted anodes do not need to be replaced.

Effect of Cathode Materials (MS2, M=Fe, Ni, Co) on Electrochemical Properties of Thermal Batteries (열전지용(MS2, M=Fe, Ni, Co)계 양극의 전기화학적 특성 연구)

  • Lee, Jungmin;Im, Chae-Nam;Yoon, Hyun-Ki;Cheong, Hae-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.9
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    • pp.583-588
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    • 2017
  • Thermal batteries are used in military power sources that require robustness and long storage life for applications in missiles and torpedoes. $FeS_2$ powder is currently used as a cathode material because of its high specific energy density, environmental non-toxicity, and low cost. $MS_2$ (M = Fe, Ni, Co) cathodes have been explored as novel candidates for thermal batteries in many studies; however, the discharge characteristics (1, 2, 3 plateau) of single cells in thermal batteries with different cathodes have not been elucidated in detail. In this study, we independently analyzed the discharge voltage and calculated the total polarizations of single cells using $MS_2$ cathodes. Based on the results of this study, we propose $NiS_2$ as a potential cathode material for use in thermal batteries.

Femtosecond laser induced photo-expansion of organic thin films

  • Chae, Sang-Min;Lee, Myeong-Su;Choe, Ji-Yeon;Lee, Hyeon-Hwi;Kim, Hyo-Jeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.120.2-120.2
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    • 2015
  • We propose a novel direct writing technique with a femtosecond laser enabling selective modification of not only the morphology of conducting polymer thin films but also the orientation and alignment of the polymer crystal. Surface relief gratings resulting from photoexpansion on P3HT:PCBM and PEDOT:PSS thin films were fabricated by femtosecond laser direct writing. The photoexpansion was induced at laser fluence below the ablation threshold of the thin film. The morphology (size and shape) of photoexpansion could be quantitatively controlled by laser writing parameters such as focused beam size, writing speed, and laser fluence. GIWAX results showed that face-on P3HT crystals were largely increased in the photoexpansion in comparison with pristine region of the thin film. In addition, the face-on P3HTs in the photoexpansion were aligned with their orientation along the polarization of the laser. The micro-RAMAN spectra confirmed that neither chemical composition change nor the polymer chain breaking was observable after femtosecond laser irradiation. We believe that this laser direct writing technique opens a new door to the fabrication of more efficient OPVs via non-contact, toxic-free approach.

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The Electrical Properties of SBT Thin Film for Semiconductor Device (반도체 소자용 SBT 박막의 전기적특성)

  • Oh, Yong-Cheul;Cho, Choon-Nam;Kim, Jin-Sa;Shin, Chul-Ki;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05d
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    • pp.86-89
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    • 2003
  • SBT thin film for semiconductor device that is made by RF magnetron sputtering method studied electrical properties under various temperature condition. Dielectric constant who differ annealing condition appears highest in $750[^{\circ}C]$ and it is 213. Also, C-V properties by annealing temperature of SBT thin film for semiconductor device is no change almost to $600[^{\circ}C]$ and shows non-linear butterfly shape more than $650[^{\circ}C]$ Maximum capacitance and difference of smallest capacitance show the biggest difference in $750[^{\circ}C]$ as degree that domain wall motion contributes in ferrelectric polarization value in C-V characteristic curve of ferroelectric that this shows typical ferroelectric properties. Therefore, SBT thin film for semiconductor device that is annealing in $750[^{\circ}C]$ expressed the most superior electrical and ferroelectric properties.

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Static Characteristics of Micro Gas-Lubricated proceeding Bearings with a Slip Flow (미끄럼 유동을 고려한 초소형 공기 베어링의 정특성)

  • Kwak, Hyun-Duck;Lee, Yong-Bok;Kim, Chang-Ho;Lee, Nam-Soo;Choi, Dong-Hoon
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.05a
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    • pp.137-142
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    • 2002
  • The fluid mechanics and operating conditions of gas-lubricated proceeding bearings in micro rotating machinery such as micro polarization modulator and micro gas turbine are different from their larger size ones. Due to non-continuum effects, there is a slip of gas at the walls. Thus in this paper, the slip flow effect is considered to estimate the pressure distribution and load-carrying capacity of micro gas-lubricated proceeding bearings as the local Knudsen number at the minimum film thickness is greater than 0.01. Based on the compressible Reynolds equation with slip flow, the static characteristics of micro gas-lubricated proceeding bearings are obtained. Numerical predictions compare the pressure distribution and load capacity considering slip flow with the performance of micro proceeding bearings without slip f]ow for a range of bearing numbers and eccentricities. The results clearly show that the slip flow effect on the static characteristics is considerable and becomes more significant as temperature increases.

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Polarization Properties of J-aggregates by Mutual Mixing Effect in the LB Films of Merocyanine Dyes (메로시아닌 색소 LB막의 상호혼합효과에 의한 J-aggregates 편광특성)

  • Yang, Chang-Heon;Kim, Gyong-Chol;Kwon, Young-Soo;Shin, Hoon-Kyu
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.12
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    • pp.2245-2249
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    • 2010
  • The physical properties of the LB films with merocyanine dyes have been published and attract attention due to the possibility of molecular structure control. The evaluation of the thin films was focused for the purpose of molecular structure control. The molecular structure in the case of the thin films with dyes can be examine by optical absorption spectra measurements. In the result measured by optical absorption spectra, the $[DX]_{1-x}[DO]_x$ LB films shows a large in-plane anisotropy and the transition dipole moment of red-shifted band is preferentially oriented perpendicular to the dipping direction of the film, while that of the blue-shifted band prefers the dipping direction. The spectrum for $0_{\circ}$, $90_{\circ}$-polarized light coincides with the spectrum for non-polarized light and also with the spectrum was observed in the LB film deposited using a fresh solution. These results show that the aging process does not cause a structural change in chromophore but a change in the degree of molecular orientation. In the results, study of the merocyanine dyes LB films using optical absorption spectra would an interesting problem of absorbance peak shifts and mixed components.

Accelerated Thermal Aging Measurement and Analysis of CSPE Cable for Condition Monitoring (CSPE 케이블의 상태감시를 위한 가속열화 측정 분석)

  • Park, Joung-Ho;Cha, Wang-Cheol;Lee, Jung-Hoon;Cho, Uk-Rae;Kim, Jae-Chul
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.3
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    • pp.88-95
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    • 2015
  • The accelerated thermal aging of CSPE(Chloro Sulfonate Polyethylene) was carried out for 40.41, 121.22, 202.04 days, 16.82, 50.45, 84.09 days and 7.32, 21.96, 36.59 days at 100, 110, and $120^{\circ}C$, respectively, which are equivalent to 20, 60, 100 years of aging at $50^{\circ}C$. The permittivities and the apparent densities of the accelerated thermally aged CSPE samples are increased with accelerated thermal aging year but EAB(Elongation at Break) is decreased with that. The dielectric strength and the electric breakdown of the non-accelerated and accelerated thermally aged CSPE samples do not depend on accelerated thermal aging year and applied voltage rising time. density and EAB measures.