• Title/Summary/Keyword: Non-Formation

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Characteristics of Time Variations of PM10 Concentrations in Busan and Interpreting Its Generation Mechanism Using Meteorological Variables (부산 지역 미세먼지 농도의 시간변동 특성 및 기상인자 분석을 통한 먼지생성 해석)

  • Kim, Ji-A;Jin, Hyung-Ah;Kim, Cheol-Hee
    • Journal of Environmental Science International
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    • v.16 no.10
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    • pp.1157-1167
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    • 2007
  • In an effort to interpret the characteristics of fine particle concentrations in Busan, time variations of hourly monitored concentrations $PM_{10}$ (Particulate Matter with aerodynamic Diameter ${\le}10\;{\mu}m$) in Busan are analyzed for the period from 2000 to 2005. The characteristics of aerosol second generation formation process is also interpreted qualitatively, by using the statistical analysis of the meteorological variables including temperature, wind speed, and relative humidity. The result shows some significant annual, seasonal, weekly and diurnal variations of $PM_{10}$ concentrations. In particular, seasonal(i.e., spring) variations are governed by frequency of yellow sand events even for the non-yellow sand cases where yellow-sand days are eliminated in our analysis. However, in seasonal variation, summer season predominate lower $PM_{10}$ concentrations due to the frequent precipitation, and weekly and diurnal variations are both found to be reflecting the emission rate from traffic amount. Correlation coefficients between $PM_{10}$ concentration and meterological variables for non-yellow sand days show overall negative correlation with visibility, wind speed, cloud amounts, and relative humidity. However for non-precipitation days, during non-yellow sand period positive correlation are found clearly with relative humidity, suggesting the importance of secondary aerosol formation in Busan that can be achieved by both homogeneous aerosol formation and heterogeneous transformations resulting from hygroscopic aerosol characteristics.

Numerical Analysis of Effects of Mold Cavity Shape on Bubble Defect Formation in UV NIL (UV NIL공정에서 몰드 중공부 형상과 기포결함에 대한 수치해석)

  • Lee, Hosung;Kim, Bo Seon;Kim, Kug Weon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.1
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    • pp.596-602
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    • 2018
  • Nanoimprint lithography (NIL) is an emerging technology that enables cost-effective and high-throughput nanofabrication. In ultraviolet (UV) NIL, low-cost and high-speed production can be achieved using a non-vacuum environment at room temperature and low pressure. However, there are problems with the formation of bubble defects in such an environment. This paper investigates the shape of the mold cavity and the bubble defect formation in UV NIL in a non-vacuum environment. The bubble defect formation was simulated using two-dimensional flow analysis and the VOF method for commonly used cavity mold shapes (rectangular, elliptical, and triangular). The characteristics of the resist flow front and various contact angles were also analyzed. The shape of the mold cavity had a very significant effect on the bubble defect formation. For all cavity shapes, a smaller contact angle with the mold and larger contact angle with the substrate decreased the possibility of bubble defect formation. The elliptical shape was the most effective for preventing bubble defect formation.

Analysis on cause of failure of guided bone regeneration during implant placement : A retrospective study (임플란트 시술 시 GBR의 실패 원인분석에 관한 후향적 연구)

  • Ko, Sun-Young;Oh, Jun-Ho;Lee, Seung-Jae;Kim, Hyung-Seop
    • Journal of Periodontal and Implant Science
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    • v.38 no.3
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    • pp.535-542
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    • 2008
  • Purpose: The aim of this retrospective study is to evaluate survival rate of implant and bone formation, to analyze failure contribution factor. Material and Methods: A total of 52 consecutive patients(35 male, 17 female, mean age 49 years) with 104 osseous defects were treated during the period from October 2004 to June 2007 with a simultaneous or staged GBR approach using non-resorbable or resorbable membranes combined with autogenous bone grafts or xenograft(Bio-Oss, Bio-cera, BBP). Result: A total of 32(30,8%) of 104 GBR-treated sites failed the bone formation and a total of 5(5.6%) of 89 implants were removed. Early exposure of the membrane has significantly affected bone formation(p<0.05). Non-resorbable membrane showed more exposure of the membrane and low success rate of bone formation than resorbable membrane(p<0.05). There were no difference between success rate of bone formation and using autogenous bone or graft materials. There were no statistically significant difference between success rate of bone formation and smoking or using PRP. Mandible showed more success rate of bone formation than maxilla(p<0.05). Conclusion: Early exposure of the membrane, membrane type and maxilla/mandible type have influence on success rate of bone formation during GBR.

A Study on the Formation of Air Bubble by the Droplet Volume and Dispensing Method in UV NIL (UV NIL공정에서 액적의 양과 도포방법에 따른 기포형성 연구)

  • Lee, Ki Yeon;Kim, Kug Weon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.9
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    • pp.4178-4184
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    • 2013
  • Nanoimprint lithography (NIL) is an emerging technology enabling cost-effective and high-throughput nanofabrication. Recently, the major trends of NIL are high throughput and large area patterning. UV curable type NIL (UV NIL) can be performed at room temperature and low pressure. And one advantage of UV NIL is that it does not need vacuum, which greatly simplifies tool construction, so that vacuum oprated high-precision stages and a large vacuum chamber are no longer needed. However, one key issue in non-vacuum environment is air bubble formation problem. Namely, can the air bubbles be completely removed from the resist. In this paper, the air bubbles formation by the method of droplet application in UV NIL with non-vacuum environment are experimentally studied. The effects of the volume of droplet and the number of dispensing points on air bubble formation are investigated.

The Formation Behavior of Non-metallic Inclusion in the Ba-added Hyper Duplex STS (Hyper Duplex STS 중 Ba 첨가 시 비금속개재물 생성거동)

  • Joo, S.W.;Hong, S.H.;Park, Y.M.;Kim, K.T.;Kim, J.S.;You, B.D.
    • Transactions of Materials Processing
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    • v.20 no.7
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    • pp.504-511
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    • 2011
  • The alkaline earth metal Ba has a relatively low melting point. Because of its significantly high affinity to oxygen, nitrogen and sulfur, it is highly functional as a steel refining agent. But Ba can adversely affect the properties of steel especially the workability, because it can form a variety of inclusions. So, understanding of these inclusions is needed for improvement of the properties of steel. Thus a fundamental study in the formation behavior of non-metallic inclusions in Ba added Hyper Duplex STS melts was investigated. The amount of Ba, holding time and temperature were considered as experimental variables. The number of non-metallic inclusions decreased and the large particle size of non-metallic inclusions increased as the amount of Ba increased. The number of non-metallic inclusions also decreased and the large particle size increased with increased holding times and temperatures of molten steel.

Electrochemical Behavior of Poly 8-(3-Acetylimino-6-methyl 2,4-dioxopyran)-1-aminonaphthaline in Aqueous and Non Aqueous Media

  • Hathoot, A.A.
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1609-1612
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    • 2003
  • The electrooxidation of 8-(3-acetylimino-6-methyl 2,4-dioxopyran)-1-aminonaphthaline (AMDAN) in aqueous and non aqueous media led to the formation of polymeric films, poly (AMDAN). The monomer, undergo anodic oxidation through the formation of a monocation radical irrespective of the nature of the medium. In aqueous medium, the monocation radical undergoes, through its resonance structures, dimerisation involving tail-to-tail, head-to-tail and even head-to-head coupling. The products formed, being more easily oxidisable than the parent substance, undergo further oxidation at the same potential so that the overall oxidation involves a one-step (i.e., a single wave), two-electron process. In non-aqueous medium, the monocation radical does not undergo dimerisation through coupling reactions. Retaining its identity, monomer oxidise in two steps involving one electron in each step. The fact that the cathodic peaks corresponding to these anodic peaks are rarely observed indicates fast consumption of the electrogenerated monocation radicals and dications by follow-up chemical reactions to produce polymeric products (poly AMDAN). The electrochemical behavior of the formed polymer films was investigated in both non aqueous and aqueous media. The films prepared in non aqueous medium were found to be more electroactive than that the films prepared in aqueous medium. This is confirmed with the results in litreature which illustrate that the film prepared in aqueous solution hold water in its structure via hydrogen bonding, which causes decomposition reactions.

Physiological Response of a White Mutant of Ganoderma lucidurn Induced by Light and Temperature (영지버섯 백색변이주의 광 및 온도에 의한 생리적 반응)

  • Cho, Soo-Muk;Seo, Geon-Sik;Yoo, Ick-Dong;Shin, Gwan-Chull
    • Microbiology and Biotechnology Letters
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    • v.22 no.2
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    • pp.115-119
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    • 1994
  • White mutant of Ganoderma lucidum(G4142) induced the non-basediocarpous basidiospores(NBB) from the aerial mycelia on agar media by the light illumination. Light was found to be necessary for NBB formation, but it also inhibited the growth of mycelium. The best sporulation was obtained at the periodic exposure of 16 hour light and 8 hour dark. Blue and yellow light were the most effective on sporulation, however, near UV and red light did not induce any spores. Effective light intensity for NBB bearing was about 1,000 lux as white light. Even after 16 days of culture, this strain did not form the pinhead nor chlamydospore. Optimum temperature for the mycelial growth and NBB formation were 30$\circ $C. Ganoderma lucidum G4142 exhibited the formation of stroma after five days of incubation at 30$\circ $C.

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An Improved Convergent Approach for Synthesis of Erlotinib, a Tyrosine Kinase Inhibitor, via a Ring Closure Reaction of Phenyl Benzamidine Intermediate

  • Asgari, Davoud;Aghanejad, Ayuob;Mojarrad, Javid Shahbazi
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.909-914
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    • 2011
  • An improved convergent and economical method has been developed for the synthesis of erlotinib, a 4-anilinoquinazoline and an EGFR-tyrosine kinase inhibitor for treatment of non-small-cell lung cancer. The final two steps for the formation of this 4-anilinoquinazoline from suitable 2-aminobenzonitrile intermediate and 3-ethynylaniline were modified and were performed in a simple one-pot reaction. The ring-closing mechanism for the formation of erlotinib from the suitable formamidine intermediate and 3-ethynylaniline was investigated and determined to proceed via the formation of phenyl benzamidine intermediate rather than involving Dimroth rearrangement reported earlier. The new benzamidine intermediate was isolated for the first time and characterized.

Effects of Oxygen Concentration on the NOx Emission of Non-premixed Flame in Hot Exhaust Gas (고온 배기가스의 산소농도가 비예혼합화염의 NOx 발생에 미치는 영향)

  • Sohn, Hwa-Seung;Kim, Ho-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.6
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    • pp.833-841
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    • 2002
  • The present study examined the possibility of NOx reduction in the high temperature industrial furnaces, duct burner of gas turbine cogeneration and two-stage gas turbine combustor. The experimental study was carried out for the non-premixed flame of second stage combustor with the variations of oxygen concentration in the hot exhaust gas of first stage combustor. It also examined the flammability range, temperature and NOx, $CO_2$, $O_2$formation in the combustor with respect to oxygen concentration in which the fuel(natural gas) is supplying into the hot exhaust gas. The results show that the inner temperature of flame reaches 1,20$0^{\circ}C$ at EGR $O_2$23% and that 15ppm of NOx at EGR $O_2$15.5% increases up to 60ppm at EGR $O_2$23%. It is believed that Fenimore's prompt NOx mechanism is more influential on the NOx formation than Zeldovich's thermal NOx mechanism does.

A New Protein Factor in the Product Formation of Non-Reducing Fungal Polyketide Synthase with a C-Terminus Reductive Domain

  • Balakrishnan, Bijinu;Chandran, Ramya;Park, Si-Hyung;Kwon, Hyung-Jin
    • Journal of Microbiology and Biotechnology
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    • v.25 no.10
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    • pp.1648-1652
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    • 2015
  • Azaphilone polyketides are synthesized by iterative non-reducing fungal polyketide synthases (NR-fPKSs) with a C-terminus reductive domain (-R). Several azaphilone biosynthetic gene clusters contain a putative serine hydrolase gene; the Monascus azaphilone pigment (MAzP) gene cluster harbors mppD. The MAzP productivity was significantly reduced by a knockout of mppD, and the MAzP NR-fPKS-R gene (MpPKS5) generated its product in yeast only when co-expressed with mppD. Site-directed mutations of mppD for conserved Ser/Asp/His residues abolished the product formation from the MpPKS5/mppD co-expression. MppD and its homologs are thus proposed as a new protein factor involved in the product formation of NR-fPKS-R.