• Title/Summary/Keyword: Non-$CO_2$

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Effect of Cathode Materials (MS2, M=Fe, Ni, Co) on Electrochemical Properties of Thermal Batteries (열전지용(MS2, M=Fe, Ni, Co)계 양극의 전기화학적 특성 연구)

  • Lee, Jungmin;Im, Chae-Nam;Yoon, Hyun-Ki;Cheong, Hae-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.9
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    • pp.583-588
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    • 2017
  • Thermal batteries are used in military power sources that require robustness and long storage life for applications in missiles and torpedoes. $FeS_2$ powder is currently used as a cathode material because of its high specific energy density, environmental non-toxicity, and low cost. $MS_2$ (M = Fe, Ni, Co) cathodes have been explored as novel candidates for thermal batteries in many studies; however, the discharge characteristics (1, 2, 3 plateau) of single cells in thermal batteries with different cathodes have not been elucidated in detail. In this study, we independently analyzed the discharge voltage and calculated the total polarizations of single cells using $MS_2$ cathodes. Based on the results of this study, we propose $NiS_2$ as a potential cathode material for use in thermal batteries.

Morphological Analysis of Engineered PCC by Gas-Liquid Mixing Conditions (기체-액체 혼합조건에 따른 Engineered PCC의 형태학적 분석)

  • Lee, Tai-Ju;Seo, Jin-Ho;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.113-120
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    • 2011
  • Precipitated calcium carbonate(PCC), particularly calcite crystal, is extensively used as a pigment, filler or extender in various industries such as paper, paint, textile, detergents, adhesives, rubber and plastics, food, cosmetics, and biomaterials. PCC is conventionally produced through the gas-liquid carbonation process, which consists on bubbling gaseous $CO_2$ through a concentrated calcium hydroxide slurry. This study is aimed to find some factors for controlling the morphology of engineered PCC in lab-scaled mixing batch. The experimental designs were based on temperature variables, $Ca(OH)_2$ concentration, $CO_2$ flow rate, and electrical conductivity. The model of engineered PCC morphology was finally controlled by adjustment of electrical conductivity(6.0~7.0 mS/cm) and $Ca(OH)_2$ concentration(10 g/L). Orthorhombic calcite crystals were mostly created at high concentration and electrical conductivity conditions because the increased ratio of $Ca^{2+}$ and $CO{_3}^{2-}$ ions affects the growth rate of orthorhombic faces. Excess calcium spices were contributed to the growth of faces in calcium carbonate crystal, and the non-stoichiometric reaction was occurred between $Ca^{2+}$ and $CO{_3}^{2-}$ ions during carbonation process.

Decomposition of Trichloroethylene by Using a Non-Thermal Plasma Process Combined with Catalyst (저온 플라즈마·촉매 복합공정을 이용한 트리클로로에틸렌의 분해에 관한 연구)

  • Mok, Young-Sun;Nam, Chang-Mo
    • Journal of the Korean Society of Industry Convergence
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    • v.6 no.4
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    • pp.269-275
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    • 2003
  • A non-thermal plasma process combined with $Cr_2O_3/TiO_2$ catalyst was applied to the decomposition of trichloroethylene (TCE). A dielectric barrier discharge reactor operated with AC high voltage was used as the non-thermal plasma reactor. The effects of reaction temperature and input power on the decomposition of TCE and the formation of byproducts including HCl, $Cl_2$, CO, NO, $NO_2$ and $O_3$ were examined. At an identical input power, the increase in the reaction temperature from 373 K to 473 K decreased the decomposition of TCE in the plasma reactor. The presence of the catalyst downstream the plasma reactor not only enhanced the decomposition of TCE but also affected the distribution of byproducts, significantly. However, synergistic effect as a result of the combination of non-thermal plasma with catalyst was not observed, i.e., the TCE decomposition efficiency in this plasma-catalyst combination system was almost similar to the sum of those obtained with each process.

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Comparison of N2O Emissions by Greenhouse Gas Emission Estimation Method (온실가스 배출량 산정 방법에 따른 N2O 배출량 비교)

  • Kang, Soyoung;Cho, Chang-Sang;Kim, Seungjin;Kang, Seongmin;Yoon, Hyeongi;Jeon, Eui-Chan
    • Journal of Climate Change Research
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    • v.6 no.3
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    • pp.175-184
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    • 2015
  • In this study GC and PAS were used to calculate $N_2O$ concentration of exhaust gas from Wood Chip combustion system. Fuel supplied to the incinerator was collected and analyzed and then the analysis result was used to calculate $N_2O$ emissions. Tier 3 and Tier 4 Method were used to calculate the $N_2O$ emissions. Plant's Specific emission factor of $N_2O$ by Tier 3 Method was 0.35 kg/TJ, while default emission factor of Wood?Wood Waste proposed by 2006 IPCC G/L was 4 kg/TJ. So the $N_2O$ emission factor of this study was 3.65 kg/TJ lower compared to the IPCC G/L. The total emissions calculated by Plant's specific emission factor was 4.22 kg during the measuring period, but by Tier 4 Method it was 7.88 kg. This difference in emissions was caused by the difference of continuous measuring and intermittent sampling. It would be necessary to apply continuous measuring to calculate emissions of $Non-CO_2$ gas whose the density distribution is relatively high. However currently, according to the target management guideline of greenhouse gas and energy, the continuous measuring method to calculate greenhouse gas emission is applied only to $CO_2$. Therefore for reliable greenhouse gas emission calculation it would be necessary to apply continuous measuring to calculate $Non-CO_2$ gas emission.

Evaluation of Greenhouse Gas Emissions from Animal Manure Treatment Systems with Life Cycle Assessment : A Case Study (전과정평가를 이용한 가축분뇨 처리시설의 온실가스 배출량 평가 : 사례 연구)

  • Park, K.H.;Choi, D.Y.;Cho, S.B.;Yang, S.H.;Hwang, O.H.
    • Journal of Animal Environmental Science
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    • v.17 no.sup
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    • pp.1-6
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    • 2011
  • Korean Government announced 'The Roadmap to realize a low carbon green society on year 2020' on July 12, 2011 in order to mitigate greenhouse gas (GHG) emissions. Non-energy category of Food, Agriculture, Forestry and Fishery (FAFF) should mitigate 1,349 kilo $CO_2$-equivalent ($CO_2$-eq.) tonnes which is 7.1% of Business-As-Usual on year 2020. The mitigation from animal manure treatment system (AMTS) comprises ca. 45% of the total mitigated amount of Non-energy category of FAFF. Hence, the precise evaluation of GHG emissions from AMTS is important to find effective mitigation measures. Life cycle assessment was used to evaluate GHG emissions from AMTS. The most GHG emitter was a composting/liquid fertilizer/activated sludge system (1,649.45 kg $CO_2$-eq./head/year) and the least GHG emitter was a activated liquid fertilizer system (1,024.46 kg $CO_2$-eq./head/year). Thermophilic oxic process showed the highest ratio (34.9%) of GHG emissions by the use of electricity to total GHG emissions from systems. Energy efficiency should be considered to mitigate GHG emissions from AMTS.

An Experimental Study on the Mechanical Behavior of Concrete Using Non-Sintered Cement (비소성 시멘트 콘크리트의 역학적 거동에 대한 실험 연구)

  • Yoo, Sung-Won;Min, Gyeong-Oan
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.1
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    • pp.115-121
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    • 2012
  • If cement could be manufactured with industrial byproducts such as granulated blast furnace slag, phosphogypsum, and waste lime rather than clinker, there would be many advantages, including the maximization of the use of these industrial byproducts for high value-added resources, the conservation of natural resources and energy by omitting the use of clinker, the minimization of environmental pollution problems caused by $CO_2$ discharge, and the reduction of the production cost. For this reason, in this study, mechanical behavior tests of non-sintered cement concrete were performed, and elasticity modulus and stress-strain relationship of non-sintered cement concrete were proposed. Nine test members were manufactured and tested according to reinforcement ratio and concrete compressive strength. According to the test results, there was no difference between general cement concrete and non-sintered cement concrete in terms of flexure and shear behavior.

Lateral-Torsional Post-Buckling Analyses of Thin-Walled Space Frames with Non-symmetric Sections (비대칭단면을 갖는 박벽 공간뼈대구조의 횡-비틂 후좌굴 유한요소해석)

  • Park, Hyo Gi;Kim, Sung Bo;Kim, Moon Young;Chang, Sung Pil
    • Journal of Korean Society of Steel Construction
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    • v.11 no.2 s.39
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    • pp.153-165
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    • 1999
  • In order to trace the lateral-torsional post-bucking behaviors of thin-walled space frames with non-symmetric cross sections, a geometrically non-linear finite element formulation is presented by applying incremental equilibrium equations based on the updated Lagrangian formulation and introducing Vlasov's assumption. The improved displacement field for non-symmetric thin-walled cross sections is introduced based on inclusion of second order terms of finite rotations, and the potential energy corresponding to the semitangential rotations and moments is consistently derived. For finite element analysis, tangent stiffness matrices of thin-walled space frame element are derived by using the Hermition polynomials as shape functions. A co-rotational formulation in order to evaluate the unbalanced loads is presented by separating the rigid body rotations and pure deformations from incremental displacements and evaluating the updated direction cosines and incremental member forces.

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Study of Non Sintered Cement Mortar Using Nanoslag and Alkali Activator (나노슬래그와 알칼리 자극제를 활용한 비소성 시멘트 모르타르에 관한 연구)

  • Jeong, Sung-Wook;Lim, Nam-Gi
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.6
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    • pp.61-66
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    • 2010
  • As global warming has had harmful effects on the environment, the construction industry has made efforts to reduce the amount of $CO_2$ generated in the process of cement production. There is an urgent need for an alternative material that can replace cement. To improve the initial strength and economical efficiency pointed out as problems, this research was conducted for Blast Furnace Slag (BFS), an industrial byproduct. Non-sintering cement (NSC) was used by minimizing the amount of high-priced alkali activators. By using Nano-technology, fineness has been maximized, to enhance the initial strength of BFS. This research is based on non-sintered cement replaced by nano-slag using alkali activators, and the fundamental properties and quality of the non-sintered cement were investigated. A variety of activators were used, up to 10 percent of the slag weight. This research aims to present fundamental data through a comparative analysis of flexural strength, compressive strength, time of setting, diabetic temperature, and rising heat.

Hemodynamic effects of Chunwangbosim-dan - A 3-dimensional radial pulse tonometry device study (3차원 맥영상 검사로 살펴본 천왕보심단이 심혈관계에 미치는 영향)

  • HeeJung KANG;YoungSang KUN;Tae Hun KU;Gyeung Cheul KIM
    • Journal of Convergence Korean Medicine
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    • v.6 no.1
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    • pp.5-20
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    • 2024
  • Objectives: This study was aimed to evaluate the hemodynamic feasibility using pulse parameters as a way to establish safe dose guidelines for Chunwangbosim-dan, and to provide a foundation for developing evidence-based guidelines for clinical use. Methods: Forty-one volunteers were recruited to participate in a study examining the changes in pulse wave characteristics following the ingestion of Chunwangbosim-dan, over a period of 2 weeks, and pulse wave measurements were taken before and after the administration. Pulse wave parameters were measured in this study using a 3-dimensional radial pulse tonometry device(DMP-Lifeplus). In addition, questionnaire, blood pressure, temperature, and body composition were also measured as secondary measures. Results: Fifteen minutes after administration of Chunwangbosim-dan, the non-adverse event group(non-AE) exhibited a statistically significant increase in several power and pressure-related parameters, including h1, h3, h4, h5, SA, PA and PW, while the adverse event group(AE) showed a trend of decreasing stroke volume and increasing Systemic Vascular Resistance Index(SVRI) and applied pressure. After 2 weeks of administration, non-adverse event group(non-AE) exhibited significant changes in standard deviation of pulse rate and HRV_LH ratio. Notably, there are significant differences between AE group and non-AE group in h4/h1, w/t, applied pressure, SV and pulse rate. Conclusion: These findings suggest that pulse parameters may be a useful way to establish safe dosing guidelines for Chunwangbosim-dan. Further research is needed to confirm these results and to develop evidence-based guidelines for clinical use.

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Non-isothermal Crystallization Behavior of Poly(glycolide-co-ε-caprolactone-co-L-lactide) Block Copolymer (생체분해성 Poly(glycolide-co-ε-caprolactone-co-L-lactide) 블록 공중합물의 비등온 결정화 거동에 관한 연구)

  • Choi, Sei-Young;Song, Seung-Ho
    • Elastomers and Composites
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    • v.49 no.1
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    • pp.13-23
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    • 2014
  • In this work, glycolide, L-lactide and ${\varepsilon}$-caprolactone monomers were polymerized into the triblock copolymers by two step polymerization method and their non-isothermal crystallization behaviors were studied by combination of modified Avrami and Ozawa formula for further analysis of their behaviors. The result showed that PGCLA21 gave the highest value for supercooling analysis and super cooling degree increased with L-lactide content. Crystallization velocity constant, however, showed no significant change. The result of cooling function in specific relative crystallization degree showed that the increase of L-lactide content made an effect on the more enhancement of crystallization velocity of the PGCLA than PGCL. The result of big logF(T) value with the L-lactide content above critical point for PGCLA41 and PGCLA21 showed that bigger cooling velocity needed to gain same crystal size compared with PGCL. This means that it gives negative effect in the increase of crystallization velocity.