• Bulletin of the Korean Chemical Society
• /
• v.34 no.6
• /
• pp.1823-1828
• /
• 2013

Tetraoxanes (1,2,4,5-tetraoxanes) have been reported to exhibit potent antimalarial activity. In the present study, the three dimensional-quantitative structure activity relationship (3D-QSAR) studies were performed on a series of tetraoxanes derivatives using comparative molecular field analysis (CoMFA) and comparative molecular similarity indices analysis (CoMSIA) techniques. The best predictive CoMFA model with atom fit alignment resulted in cross-validated coefficient ($q^2$) value of 0.719, non-cross-validated coefficient ($r^2$) value of 0.855 with standard error of estimate (SEE) 0.335. Similarly, the best predictive CoMSIA model was derived with $q^2$ of 0.739, $r^2$ of 0.847 and SEE of 0.344. The generated models were externally validated using test sets. The final QSAR models as well as the information gathered from 3D contour maps should be useful for the design of novel tetraoxanes having improved antimalarial activity.

• Journal of the Society of Naval Architects of Korea
• /
• v.47 no.2
• /
• pp.225-232
• /
• 2010

The requirement of design of High-Pressure/High-Temperature(HP/HT) pipelines on an seabed increases in recent years. The need of research on the analysis method to improve the design capacity is increasing. The purpose of this study is the development of the analysis method of thermal buckling of subsea pipeline structures. The analysis method of thermal buckling was established by using the commercial FEM code(ABAQUS) which shows the outstanding performance in non-linear static FE analysis. The developed method has been applied to the installation of subsea pipeline on the offshore project. For a validation, the comparative study has been carried out. This application to offshore project demonstrates the superiority of the analysis method of thermal buckling of subsea pipeline structures and testifies the application to detail design.

• Journal of The Korean Society of Clinical Toxicology
• /
• v.19 no.1
• /
• pp.17-23
• /
• 2021

Purpose: Alcohol ingestion enhances impulsivity and aggression, and has been proven to have a close relationship with suicide. This study investigates whether alcohol co-ingestion affects the Poisoning Severity Score (PSS) grade in patients with intentional poisoning. Methods: We conducted a retrospective analysis of intentional poisoning patients who visited the emergency department (ED) from January 1 to December 31, 2020. Patients were divided into non-drunken and drunken groups. We collected the data based on the medical records of the patients and serum ethanol level results recorded during initial blood tests at the ED. To grade the PSS, the highest score was assessed through clinical signs and test results during the hospital stay. A comparative analysis was conducted between the two groups. Results: A total of 277 patients were included in the study. 163 (58.8%) were in the non-drunken group, and 114 (41.2%) were in the drunken group. The PSS grade showed a significant difference between the two groups (p=0.002). While grade 1 (mild) was observed more in the non-drunken group, grade 2 (moderate) and grade 3 (severe) were seen more in the drunken group. In an ordinal logistic regression analysis, alcohol co-ingestion (adjusted odds ratio [aOR] 2.557, 95% confidence interval [CI] 1.554-4.208, p<0.001) was considered to be a risk factor for a higher PSS grade. There was no significant correlation between the serum ethanol level and the PSS grade. (p=0.568) Conclusion: Intentional poisoning patients with alcohol co-ingestion had a higher PSS. Hence close observation and aggressive treatment in the ED is warranted in such cases.

• Environmental and Resource Economics Review
• /
• v.13 no.3
• /
• pp.441-468
• /
• 2004

We estimate carbon embodied in the export goods of Korea. A commodity-by-industry IO model ($CO_2$ hybrid IO model) is constructed for the estimation. In the model, all monetary units of energy commodities are converted to physical unit, carbon tons. Results show that total $CO_2$ embodied in the exports of non-energy goods of Korea equals 51.18 million carbon ton or 44% of total $CO_2$ emissions in Korea in 2000. Overall carbon intensity of export goods is estimated as 0.227 carbon ton per million Won. These findings suggest Korea's responsibility on global warming may be imputed to the countries who import and consume Korean goods. It is in accordance with the user pay principle. It is also argued that if UNFCCC impose the burden of $CO_2$ mitigation on importing countries rather than exporting countries, we can prevent '$CO_2$ emission leakages' effectively.

• Journal of Applied Biological Chemistry
• /
• v.64 no.4
• /
• pp.351-356
• /
• 2021

Changing environmental conditions can affect plant growth by influencing water and nutrient transport and photosynthesis. Plant physiological responses under changing environmental conditions can be non-destructively monitored using electrodes as plant induced electrical signal (PIES). Objective of the study was to monitor PIES in response to increased CO₂ and decreased photosynthetic photon flux density (PPFD). The PIES increased during day time when transpiration and photosynthesis occurs and monitored CO₂ concentration was negatively correlated to the PIES. Enhanced CO₂ concentration slightly reduced PIES, but the effect of increased CO₂ was limited by light intensity. The effect of reduced PPFD was not appeared immediately because water and nutrient transport was not promptly affected by the light. The study was conducted to evaluate short-term effect of increasing CO₂ and decreasing PPFD, hence proline content and chlorophyll fluorescence was not significantly affected by the conditions.

• Proceedings of the KIEE Conference
• /
• 2004.07c
• /
• pp.1954-1956
• /
• 2004

Nowadays, $CO_2$ lasers are used widely in many applications such as materials fabrication, communications, remote sensing and military purpose etc. Especially, $CO_2$ lasers are in the spotlight at surface handling and heat processing. It is important to control the laser output power and beam Quality in those fields. And those are studied the important parameters deciding the fluctuation of laser beam are smoothing capacitor, frequency and the characteristics of laser resonator. But the study of plasma parameters of $CO_2$ lasers are little. So we detect the $CO_2$ laser from emitted $CO_2$ laser discharge plasma using a non-contact photo tansistor sensor and Low pass filter. In this study, The relativity of the emitted light of discharge plasma and CO2 laser output.

• Korean Chemical Engineering Research
• /
• v.47 no.3
• /
• pp.373-379
• /
• 2009

Cesium carbonate was used as an adsorbent to capture carbon dioxide from gaseous stream of carbon dioxide, nitrogen, and moisture in a fixed-bed to obtain the breakthrough data of $CO_2$. The deactivation model in the non-catalytic heterogeneous reaction systems is used to analyze the sorption kinetics among carbon dioxide, carbonate, and moisture using the experimental breakthrough data. The experimental breakthrough data are fitted very well to the deactivation model than the adsorption isotherm models in the literature.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2023.05a
• /
• pp.115-116
• /
• 2023

This study aims to investigate and improve the carbon dioxide sequestration capability and the mechanical properties of non-hydraulic low calcium silicate cement especially designed for CO₂ reaction and ordinary Portland cement subjected to the carbonation curing facilitating pH swing method. Nitric acid (HNO₃) was utilized as an liquid for the mixing of cement paste to enhance the initial dissolution of Ca ions from the cements by promoting low pH environment and prevent the direct precipitation of Ca with the anion, owing to the high solubility of Ca(NO₃)₂ in water. The results presented that the higher the concentration of HNO₃, the higher the compressive strength and CO₂ sequestration (until 0.1 M). Ca dissolution caused by the harsh acid attack onto the anhydrous cement particle lead to the higher carbonation reaction degree, forming abundant CaCO₃ crystals after the reaction. However, cement paste mixed with excessively high concentration of HNO₃ presented deterioration due to the too harsh pH environment and abundant NO₃- ions which are known to retard the reaction of cement.

• Journal of Environmental Science International
• /
• v.13 no.9
• /
• pp.767-777
• /
• 2004

This study evaluated the technical feasibility of the application of $TiO_2$ photocatalysis for the removal of volatile hydrocarbons(VHC) at low ppb concentrations commonly associated with non-occupational indoor air quality issues. A series of experiments was conducted to evaluate five parameters (relative humidity (RH), hydraulic diameter (HD), feeding type (FT) of VHC, photocatalytic oxidation (PCO) reactor material (RM), and inlet port size (IPS) of PCO reactor) for the PCO destruction efficiencies of the selected target VHC. None of the target VHC presented significant dependence on the RH, which are inconsistent with a certain previous study that reported that under conditions of low humidity and a ppm toluene inlet level, there was a drop in the PCO efficiency with decreasing humidity. However, it is noted that the four parameters (HD, RM, FT and IPS) should be considered for better VHC removal efficiencies for the application of $TiO_2$ photocatalytic technology for cleansing non-occupational indoor air. The PCO destruction of VHC at concentrations associated with non-occupational indoor air quality issues can be up to nearly 100%. The amount of CO generated during PCO were a negligible addition to the indoor CO levels. These abilities can make the PCO reactor an important tool in the effort to improve non-occupational indoor air quality.

• Journal of Korean Society for Atmospheric Environment
• /
• v.19 no.E4
• /
• pp.157-168
• /
• 2003

This study evaluated the technical feasibility of the application of titanium oxide (TiO$_2$) photocatalysis for the removal of VOCs in low ppb concentrations commonly associated with non -occupational indoor air quality issues. A series of experiments were conducted to evaluate four parameters (relative humidity (RH), hydraulic diameter (HD), photocatalytic oxidation (PCO) reactor material (RM), and inlet port size (IPS) of PCO reactor) for the PCO destruction efficiencies of the selected target VOCs. None of the target VOCs presented significant dependency on the RH, which is inconsistent with a few previous studies. However, it is noted that the three parameters (HD, RM and IPS) should be considered for better VOCs removal efficiencies for the application of TiO$_2$ photocatalytic technology for cleansing non -occupational indoor air. The PCO destruction of VOCs at concentrations associated with non-occupational indoor air quality issues can be up to nearly 100％. The amount of CO generated during PCO would be negligible in comparison to the indoor CO levels. These results can make the PCO reactor an important tool in the effort to improve non-occupational indoor air quality.