• Title/Summary/Keyword: Nitrogen loads

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Computation and Assessment of Delivery Pollutant Loads for the Streams in the Nakdong River Basin (낙동강 소수계별 유달부하량 산정 및 평가)

  • Yoon, Young-Sam;Yu, Jae-Jeong;Kim, Moon-Su;Lee, Hae-Jin
    • Journal of Korean Society on Water Environment
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    • v.22 no.2
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    • pp.277-287
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    • 2006
  • Production loads of the contaminants near the Nakdong-river are, BOD : $1,006ton{\cdot}day^{-1}$, TN : $117ton{\cdot}day^{-1}$, and TP : $21ton{\cdot}day^{-1}$. Among the sources of contamination, the biggest contribution to the production load was shared by the human population, which maintains 40.7% of BOD, 44.2% of TN, and 52.5% of TP production. Similarly, among the sources of discharge load, the human population contributed 45.0% of BOD, 34.5% of TN, and 45.8% of TP. Results of flow investigation in 2001 and 2002 indicate that among the side streams, Nam-river showed the greatest average flow. In case of main stream flow, it was increased in the downstream due to the increase of the influents from the side streams. In case of BOD, COD, TOC and SS, high values were detected at Keumho-river where industrial wastewater was discharged as high level concentration. In case of the main stream, Koryoung point where direct influence of Keumho-river and Seongseo industrial complex is evident showed high BOD, COD and TOC. Oxidized nitrogen compounds and total nitrogen showed similar patterns of BOD, COD, and TOC. Especially, nitrate nitrogen was relatively high at all points. However, in case of Chlorophyll-a, relatively high values were observed at mid- and downstream areas such as Koryoung, Namjee, Soosan, Moolkeum and Hakooeun. This could be caused by the slow flow rate and the abundant nutrient salts attributed by the side streams. Relatively better water quality was observed in 2002 when the flow was relatively abundant than that in 2001. Results of investigation during 2001-2002 showed that delivery load increased as the flow reaches downstream. In 2001, delivery loads at the downstream Soosan-bridge were BOD $22,152ton{\cdot}day^{-1}$, COD $45,467ton{\cdot}day^{-1}$, TN $22,062ton{\cdot}day^{-1}$, TP $926ton{\cdot}day^{-1}$. Delivery loads in 2002 were increased due to the increase of the rainfall. They are BOD $25,876ton{\cdot}day^{-1}$, COD $64,200ton{\cdot}day^{-1}$, TN $41,101ton{\cdot}day^{-1}$, and TP $1,362ton{\cdot}day^{-1}$.

Sliding Wear Mechanism of the High-Nitrogen Austenitic 18Cr-l8Mn-2Mo-0.9N Steel (고질소 Fe-l8Cr-l8Mn-2Mo-0.9N 강의 미끄럼 마멸 기구)

  • Kim, S.D.;Kim, S.J.;Kim, Y.S.
    • Transactions of Materials Processing
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    • v.15 no.2 s.83
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    • pp.112-117
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    • 2006
  • Sliding wear mechanism of a high nitrogen austenitic 18Cr-18Mn-2Mo-0.9N steel has been investigated. Dry sliding wear tests of the steel were carried out at various loads of IN-10N under a constant sliding speed condition of 0.15m/s against AISI 52100 bearing steel balls. Solution ($1050^{\circ}C$) and isothermal aging ($900^{\circ}C$) heat treatments were performed on the steel and the effect of the heat treatments on the wear was investigated. Wear rates of the solution-treated steel specimen remained low until 5N load, and then increased abruptly at loads above 5N. The rates of isothermally aged specimens were low and increased gradually with the applied load. Worn surfaces, their cross sections, and wear debris of the steel specimens were examined with a scanning electron microscopy. Phases of the heat-treated specimen and the wear debris were identified using XRD. The transformed phase underneath a sliding track was investigated and analyzed using a TEM. Effects of the phase transformation during the wear and $Cr_{2}N$ precipitates formed during the isothermal aging on the wear of the austenitic steel were discussed.

Sliding wear mechanism of the high-nitrogen austenitic 18Cr-18Mn02Mo-0.9N steel (고질소 Fe-18Cr-18Mn-2Mo-0.9N강의 미끄럼 마멸 기구)

  • Kim S. D.;Kim S. J.;Kim Y. S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.10a
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    • pp.105-108
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    • 2005
  • Sliding wear mechanism of a high nitrogen austenitic 18Cr-18Mn-2Mo-0.9N steel has been investigated. Dry sliding wear tests of the steel were carried out at various loads of 1N-10N under a constant sliding speed condition of 0.15m/s against AISI 52100 bearing steel balls. Solution $(1050^{\circ}C)$ and isothermal aging $(900^{\circ}C)$ heat treatments were performed on the steel and the effect of the heat treatments on the wear were investigated. Wear rates of the solution-treated steel specimen remained low until 5N, and then increased abruptly at loads above 5N. The rates of isothermally aged specimens were low and increased gradually with the applied load. Worn surfaces, their cross sections, and wear debris of the steel specimens were examined with a scanning electron microscopy. Phases of the heat-treated specimen and the wear debris were identified using XRD. Phases transformed underneath the sliding track during the wear were investigated and analyzed using TEM. Effects of the phase transformation during the wear and $Cr_2N$ precipitates formed during the isothermal aging on the wear of the austenitic steel were discussed.

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Combined effect of nitrogen- and oxygen functional groups on electrochemical performance of surface treated multi-walled carbon nanotubes (표면처리된 탄소나노튜브의 질소 및 산소관능기 도입에 따른 전기화학적 특성)

  • Kim, Ji-Il;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.214.1-214.1
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    • 2011
  • In this work, the electrochemical properties of the surface treated multi-walled carbon nanotubes (MWNTs) are investigated for supercapacitors. Nitrogen- and oxygen functional groups containing MWNTs are prepared by nitrogen precursors and acidic treatment, respectively. The surface properties of the MWNTs are confirmed by X-ray photoelectron spectroscopy (XPS) and Zeta-potential measurements. The electrochemical properties of the MWNTs are investigated by cyclic voltammetry, impedance spectra, and charge-discharge cycling performance in 1 M $H_2SO_4$ at room temperature. As a result, these functionalized MWNTs lead to an increase in the specific capacitance as compared with the pristine MWNTs. It proposes that the pyridinic and pyridinic-N-oxides nitrogen species influence on the specific capacitance due to their positive charges, and thus an improved electron transfer at high current loads, since they are the most important functional groups affecting capacitive behaviors.

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Estimation of LOADEST coefficients according to watershed characteristics (유역특성에 따른 LOADEST 회귀모형 매개변수 추정)

  • Kim, Kyeung;Kang, Moon Seong;Song, Jung Hun;Park, Jihoon
    • Journal of Korea Water Resources Association
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    • v.51 no.2
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    • pp.151-163
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    • 2018
  • The objective of this study was to estimate LOADEST (LOAD Estimator) coefficients for simulating pollutant loads in ungauged watersheds. Regression models of LOADEST were used to simulate pollutant loads, and the multiple linear regression (MLR) was used for coefficients estimation on watershed characteristics. The fifth and third model of LOADEST were selected to simulate T-N (Total-Nitrogen) and T-P (Total-Phosphorous) loads, respectively. The results and statistics indicated that regression models based on LOADEST simulated pollutant loads reasonably and model coefficients were reliable. However, the results also indicated that LOADEST underestimated pollutant loads and had a bias. For this reason, simulated loads were corrected the bias by a quantile mapping method in this study. Corrected loads indicated that the bias correction was effective. Using multiple regression analysis, a coefficient estimation methods according to the watershed characteristic were developed. Coefficients which calculated by MLR were used in models. The simulated result and statistics indicated that MLR estimated the model coefficients reasonably. Regression models developed in this study would help simulate pollutant loads for ungauged watersheds and be a screen model for policy decision.

INTEGRATED LIFE-CYCLE COST ANALYSIS CONSIDERING ENVIRONMENTAL COSTS: A HIGHWAY PROJECT CASE

  • Woo-Sik Jang;Heedae Park;Sungmin Kim;Seung Heon Han;Jong Seo Jeon
    • International conference on construction engineering and project management
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    • 2011.02a
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    • pp.273-279
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    • 2011
  • Concerns over the environment have spawned a number of research studies in the construction industry, as the construction of built environments and large infrastructures involves diverse environmental impacts and loads of hazardous emissions. Many researchers have attempted to quantify these environmental loads, including greenhouse gases, carbon dioxide, nitrogen dioxide, and sulfur dioxide, to name a few. However, little research has been conducted regarding integrating the life-cycle assessment (LCA) of environmental loads with the current life-cycle cost analysis (LCCA) approach. This study aims to estimate the environmental loads as a monetary value using the European Climate Exchange (ECX) rate and, then, to integrate those impacts with the pure construction cost. Toward this end, this study suggests an integrated approach that takes into account the environmental effect on the evaluation of the life-cycle cost (LCC). The bill of quantity (BOQ) data of a real highway project are collected and analyzed for this purpose. As a result, considering the environmental loads in the pavement process, the total LCC increased 16% from the traditional LCC cost. This study suggests an integrated approach that will account the environmental effect on the LCC. Additionally, this study is expected to contribute to better decision-making, from the perspective of more sustainable development, for government as well as for contractors.

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Characteristics of Pollution Source Structures and Temporal and Spatial Discharge from the Drainage Basin of a Reclaimed Area (간척지 담수호유역의 오염물질 배출구조 및 시공간적 유출특성)

  • 엄명철;공동수;정동일;권순국
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 1999.10c
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    • pp.739-746
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    • 1999
  • Discharge characteristics of organic materials and nutrients were estimated in the catchment area of relaimed area-Saemankeum-. Discharge load of BOD5 was high in the domestic system, while nitrogen and phosphorous were discharged mainly from the livestock system and the land . Load was so dependent on the precipitation that it increased in the rainy season, particulary in nitrogen and phosphorus. Loads from nonpoint sources in this area were higher compared with others.

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Outflow Loads of Total Nitrogen, Total Phosphorus, and COD in Mountain Stream Water (산지 계류수에서의 총질소, 총인 및 COD의 유출부하)

  • Kim, Jin-Soo;Kim, Sun-Jong;Oh, Kwang-Young;Oh, Seung-Young;Kim,Je-Su;Jeong, Young-Ho
    • Journal of Korea Water Resources Association
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    • v.36 no.5
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    • pp.787-797
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    • 2003
  • The characteristics of concentrations and loads of Total Nitrogen(T-N), Total Phosphorus(T-P), and Chemical Oxygen Demand (COD) in mountain stream water were examined from September 2000 through August 2001. The 92.5-ha study watershed in Chungbuk Province consists of 59% mixed forest and 30% coniferous forest. Streamflow was measured and water samples were collected at about 10 day intervals for dry days and at 2-6 hour intervals for a storm event at the study watershed outlet. The mean concentration of COD in streamflow for rainy days was significantly (p < 0.05) higher than for dry days. The mean concentrations of T-N and T-P in vegetation growing season (May to October) were lower than those in vegetation dormant season (November to April). Low concentrations of pollutants during vegetation growing season are likely due to the heavy demand for nutrients by the vegetation and biological activity associated with a warming of soil. The ratios of pollutants loads during storm periods to annual pollutants loads were 87% for T-N, 83% for T-p, and 87% for COD. The unit loads of pollutants for study area were estimated at 5.9 kg/ha $\cdot$ yr for T-N, 0.15 kg/ha $\cdot$ yr for T-p, and 23.9 kg/ha $\cdot$ yr for COD. The removal efficiency of pollutants in study area were 24% for T-N, 58% for T-P and 66% for COD, indicating that a study area shows water purification function.

Simultaneous Estimation of Diffuse Pollution Loads and Model Parameters for River Water Quality Modeling (하천 수질모형에 의한 비점 오염 부하량과 모형 매개변수의 동시 추정)

  • Jun, Kyung-Soo;Kang, Ju-Whan
    • Journal of Korea Water Resources Association
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    • v.37 no.12
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    • pp.1009-1018
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    • 2004
  • A systematic method using an optimal estimation algorithm is presented for simultaneous estimation of diffuse pollution distributed along a stream reach and model parameters for a stream water quality model. It was applied with the QVAL2E model to the South Han River for optimal estimation of kinetic constants and diffuse loads along the river. Initial calibration results for kinetic constants selected from a sensitivity analysis reveal that diffuse source inputs for nitrogen and phosphorus are essential to satisfy the system mass balance. Diffuse loads for total nitrogen and total phosphorus were estimated solving the expanded inverse problem. Comparison of kinetic constants estimated simultaneously with diffuse sources to those estimated without diffuse loads, suggests that diffuse sources must be included in the optimization not only for its own estimation but also for adequate estimation of the model parameters. Application of optimization method to river water quality modeling is discussed in terms of the sensitivity coefficient matrix structure.