• Bulletin of the Korean Chemical Society
• /
• v.33 no.3
• /
• pp.775-778
• /
• 2012

The potential energy surfaces of ammonia molecule adsorptions on the symmetrically chlorinated Si(100)-$2{\times}1$ surface were explored with SIMOMM:MP2/6-31G(d). It was found that the initial nucleophilic attack by ammonia nitrogen to the surface Si forms a $S_N2$ type transition state, which eventually leads to an HCl molecular desorption. The second ammonia molecule adsorption requires much less reaction barrier, which can be rationalized by the surface cooperative effect. In general, it was shown that the surface Si-Cl bonds can be easily subjected to the substitution reactions by ammonia molecules yielding symmetric surface Si-$NH_2$ bonds, which can be a good initial template for subsequent surface chemical modifications. The ammonia adsorptions are in general more facile than the corresponding water adsorption, since ammonia is better nucleophile.

• Journal of the Korean Ceramic Society
• /
• v.32 no.2
• /
• pp.183-188
• /
• 1995

The properties of the glasses are not dominantly dependent on the chemical composition, temperature, and pressure but also on the thermal history. For example, electrical, thermal, optical, and mechanical properties are all known to be strongly dependent on the thermal history. Fluoride glasses have received a great deal of attention as candidate materials for an infra-red transmitting medium. A series of fluoride glasses and fibers were prepared under a nitrogen atmosphere. Thermal history effects of the fluoride glass fibers associated with the fast cooling rate employed during the fiber drawing process were discussed in terms of the glass temperatures and the fictive temperatures on the basis of the results obtained from the Differential Scanning Calorimeter (DSC) measurements of the fiber and bulk forms of the same chemical composition.

• Journal of the Korean Ceramic Society
• /
• v.19 no.2
• /
• pp.121-126
• /
• 1982

This paper deals with the $Si_3N_4$-bonded SiC refractory in terms of its microstructure development during nitridation. When mixture of SiC grains and fine Si power is fired under nitrogen atmosphere, an interlocking network of $Si_3N_4$ whiskers is formed by nitridation of Si. It is found that the strength of $Si_3N_4$-bonded SiC refractory is soley due to the physical nature of this interlocking whiskers. At the initial stage of nitridation, $Si_3N_4$ whisker forms in very thin and long shape and, with further nitridation, it becomes thicker with diameters up to 0.35$\mu\textrm{m}$. It is found that the mechanical strength of $Si_3N_4$-bonded SiC refractory depends on the degree of nitridation and the development of microstructure.

• Progress in Superconductivity and Cryogenics
• /
• v.5 no.1
• /
• pp.133-135
• /
• 2003

Cryogenic systems are requirement for the operation of HTS power cables. In general, HTS power cables require temperature below 77K, a temperature that can be achieved from the liquid nitrogen at latm or sub-cooled LN2 above latm. HTS power cable needs sufficient refrigeration to overcome its low temperature heat loading. This loading typically cones in two forms : (1) heat leaks from the surroundings and (2) internal heat generation. This paper explains the cooling test system of 10m HTS power cable. This system is composed of storage dewar, auto fill system, core cryostat and cold-box. Storage dewar is a LN2 storage tank and auto fill system is a LN2 supply device to the sub-cooler, Core cryostat is a LN2 flow line. Cold box is a control unit of temperature and flow rate. It is composed of control valve, flow meter, sub-cooler and circulation pump, etc..

• Proceedings of the KSME Conference
• /
• 2002.08a
• /
• pp.529-532
• /
• 2002

In coflow jets with relatively large size nozzle and low fuel jet velocity, the buoyancy effect arises from the density difference between fuel and air streams. The present study investigated the behavior of such a buoyant cold Jet both numerically and experimentally, especially when the fuel stream has higher density than air. It has been demonstrated that the cold jet has a circular cone shape since upwardly injected fuel jet decelerates and forms a stagnation region, when the fuel jet was composed of propane highly diluted with nitrogen. When the fuel was moderately diluted, numerical results showed the Kelvin-Helmholtz type instability along the mixing layer of the jet. The stagnation height increases nonlihearly with fuel jet velocity with the power of approximately 1.64.

• Advances in nano research
• /
• v.4 no.3
• /
• pp.157-165
• /
• 2016

The photocatalytic (PC) activity of anatase titania nanoparticles can be improved through codoping with transition metals and nitrogen. In addition, the PC activity can also be improved by creating monodisperse, mesoporous nanoparticles of titania. The question naturally arose as to whether combining these two characteristics would result in further improvement in the PC activity or not. Herein, we describe the synthesis and photocatalytic characteristics of codoped, monodisperse anatase titania. The transition metals tested in the polydisperse and the monodisperse forms were Mn, Co, Ni, and Cu. In each case, it was found that the monodisperse version had a higher PC activity compared to the corresponding polydisperse version.

• Journal of the Korean Chemical Society
• /
• v.22 no.4
• /
• pp.195-201
• /
• 1978

Configuration and conformation of nicotine and its protonated form have been studied by MO theoretically using EHT and CNDO/2 methods. The form with angle of rotation ${\theta}\;=\;280^{\circ}$ of pyrrolidine ring was shown to be most stable and this was interpreted in terms of conjugative, electrostatic and seric effects. It was predicted that protonation occurs on the nitrogen atom of pyridine ring and forms a ${\pi}$-complex.

• Korean Journal of Microbiology
• /
• v.29 no.1
• /
• pp.40-48
• /
• 1991

Two malonate-specific enzymes, malonyl-CoA synthetase and malonamidase, were found in free-living cultures of Rhizobium japonicum, Rhizobium meliloti, and Rhizobium trifolii, that infect plant roots where contain a high concentration of malonate. Malonyl-CoA synthetase catalyzes the formation of malonyl-CoA, AMP, and PPi directly from malonate, coenzyme A, and ATP in the presence of $Mg^{2+}$ Malonamidase is a novel enzyme that catalyzes hydrolysis and malonyl transfer of malonamate, and forms malonohydroxamate from malonate and hydroxylamine. Both enzymes are highly specific for malonate. These results show that Rhizobia have enzymes able to metabolize malonate and suggest that malonate may be used in symbiotic carbon and nitrogen metabolism.

• Progress in Superconductivity and Cryogenics
• /
• v.13 no.2
• /
• pp.5-8
• /
• 2011

This paper shows results of a design work of a program that is to develop a large power single phase high temperature superconducting (HTS) transformer. The program forms a part of a national project in Korea. A target of the design work is an HTS power transformer with rated voltages of 154 kV/22.9 kV and material for windings is supposed to be coated conductor. The design results presents in this paper will include: 1)HTS winding structures for high voltage in liquid nitrogen, 2)design result of continuously transposed coated conductor (CTCC), 3)conceptual design of high voltage bushings, 4)cooling system. A feasibility study will succeed to this design work for construction of a prototype HTS power transformer with capacity/voltage of 33 MVA/154 kV.

• Magazine of the Korean Society of Agricultural Engineers
• /
• v.42 no.2
• /
• pp.63-70
• /
• 2000

The present study was carried out for 7-months (from October 1.1997 to April 30. 1998) at a rice cultivation area blocked from livestock farming, farmstead and industrial complex to investigate the runoff loading of nitrogen and phosphorus in a plot(5,000$m^2$) paddy field areas. The runoff loading of total-N, amminia-N nitrate-N and total-P were 12.96kg/ha, 5.42kg/ha, 1.52kg/ha and 1.41kg/ha , respectively. When the runoff loading of nutrients was compared by dissolved and adsorbed forms, about 66% of total-N by dissolved form and the rest 34% by adsorbed form were flowed into streams. But 56% of total-P by adsorbed form and the rest 44% by dissolved form were flowed into streams. The phosphrous compounds , which were flowed into streams by runoff sediments and then sedimented, keep exchanging with water at water body in undelivered condition. And it moves gradually into water layer. This process can cause eutrophication continually and repeatedly in water environment . So, a sound program is needed to reduce soil erosion from farmlands.