• Title/Summary/Keyword: Nitrogen cycle

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A Study on the Improvement of LNGC Re-liquefaction System (LNG선 재액화 시스템의 성능 개선에 관한 연구)

  • Oh, Cheol;Song, Young-Uk
    • Journal of Navigation and Port Research
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    • v.33 no.10
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    • pp.659-664
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    • 2009
  • LNG carriers have, up to 2006, mainly been driven by steam turbines. The Boil-Off Gas from the LNG cargo tanks has so far been used as fuel. This is a costly solution that requires special skills during construction and operation. Alternative propulsion systems offer far better fuel economical efficiency than steam turbines. Instead of previous practice using Boil-Off Gas as a fuel, the Re-liquefaction system establishes a solution to liquefy the Boil-Off Gas and return the LNG to the cargo tanks. This Re-liquefaction of Boil-Off Gases on LNG carriers results in increased cargo deliveries and allows owners and operators to choose the most optimum propulsion system. In this study, thermodynamic cycle analysis has been performed on two type of LNG Re-liquefaction system which was designed and adopted for the Q-Flex(216,000$m^3$) and Q-Max(266,000$m^3$) LNG carrier under construction at Korea ship yards and variable key factor was simulated to compare efficiency, power and nitrogen consumption of each Re-liquefaction system.

Evaluation of Mechanical Properties and Fatigue Behavior of STS 304L due to Plastic Working (소성가공에 따른 STS 304L 재료의 기계적 특성 및 피로평가)

  • Shim, Hyun-Bo;Kim, Young-Kyun;Suh, Chang-Min
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.7
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    • pp.635-643
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    • 2017
  • The purpose of this study is to investigate the influence of the cold reduction rate and an ultrasonic fatigue test (UFT) on the fatigue behaviors of STS 304L. The tensile strength, yield strength, hardness value and fatigue limit in the UFT fatigue test linearly increased as thickness decreased from 1.5 mm to 1.1 mm, as the cold reduction rate of STS 304L increased. As a result of the UFT fatigue test (R = -1) of four specimens, the fatigue limit of the S-N curve formed a knee point in the region of $10^6$, and the 2nd fatigue limit caused by giga cycle fatigue did not appeared. In the case of t = 1.1 mm, the highest fatigue limit was 345 MPa, which was 64.3% higher than the original material (t = 1.5 mm). As a result of the UFT fatigue test of STS 304L, many small surface cracks occurred, grown, coalesced while tearing.

HIPIMS Arc-Free Reactive Deposition of Non-conductive Films Using the Applied Material ENDURA 200 mm Cluster Tool

  • Chistyakov, Roman
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.96-97
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    • 2012
  • In nitride and oxide film deposition, sputtered metals react with nitrogen or oxygen gas in a vacuum chamber to form metal nitride or oxide films on a substrate. The physical properties of sputtered films (metals, oxides, and nitrides) are strongly influenced by magnetron plasma density during the deposition process. Typical target power densities on the magnetron during the deposition process are ~ (5-30) W/cm2, which gives a relatively low plasma density. The main challenge in reactive sputtering is the ability to generate a stable, arc free discharge at high plasma densities. Arcs occur due to formation of an insulating layer on the target surface caused by the re-deposition effect. One current method of generating an arc free discharge is to use the commercially available Pinnacle Plus+ Pulsed DC plasma generator manufactured by Advanced Energy Inc. This plasma generator uses a positive voltage pulse between negative pulses to attract electrons and discharge the target surface, thus preventing arc formation. However, this method can only generate low density plasma and therefore cannot allow full control of film properties. Also, after long runs ~ (1-3) hours, depends on duty cycle the stability of the reactive process is reduced due to increased probability of arc formation. Between 1995 and 1999, a new way of magnetron sputtering called HIPIMS (highly ionized pulse impulse magnetron sputtering) was developed. The main idea of this approach is to apply short ${\sim}(50-100){\mu}s$ high power pulses with a target power densities during the pulse between ~ (1-3) kW/cm2. These high power pulses generate high-density magnetron plasma that can significantly improve and control film properties. From the beginning, HIPIMS method has been applied to reactive sputtering processes for deposition of conductive and nonconductive films. However, commercially available HIPIMS plasma generators have not been able to create a stable, arc-free discharge in most reactive magnetron sputtering processes. HIPIMS plasma generators have been successfully used in reactive sputtering of nitrides for hard coating applications and for Al2O3 films. But until now there has been no HIPIMS data presented on reactive sputtering in cluster tools for semiconductors and MEMs applications. In this presentation, a new method of generating an arc free discharge for reactive HIPIMS using the new Cyprium plasma generator from Zpulser LLC will be introduced. Data (or evidence) will be presented showing that arc formation in reactive HIPIMS can be controlled without applying a positive voltage pulse between high power pulses. Arc-free reactive HIPIMS processes for sputtering AlN, TiO2, TiN and Si3N4 on the Applied Materials ENDURA 200 mm cluster tool will be presented. A direct comparison of the properties of films sputtered with the Advanced Energy Pinnacle Plus + plasma generator and the Zpulser Cyprium plasma generator will be presented.

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Relationship between Transferable Embryos and Major Metabolite Concentrations in Holstein Donor Cows

  • Son, Jun-Kyu;Jung, Yeon-Sub;Cho, Sang-Rae;Baek, Kwang-Soo;Yoon, Ho-Beak;Lim, Hyun-Joo;Kwon, Eung-Gi;Kim, Sang-Bum;Choe, Changyong
    • Journal of Embryo Transfer
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    • v.27 no.4
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    • pp.229-235
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    • 2012
  • This research was investigated the relationship, in high-producing Holstein donor cows, between the number of the transferable embryos and the blood serum concentrations of Blood Urea Nitrogen (BUN), glucose and cholesterol, which affect the nutritional state of cows. CIDRs were inserted into the vaginas of twenty two heads of Holstein cows, regardless of estrous cycle. Superovulation was induced using folliclar stimulating hormone (FSH). For artificial insemination, donor cows were injected with $PGF_{2{\alpha}}$ and estrus was checked about 48 hours after the injection. Then they were treated with 4 straws of semen 3 times, with 12-hour intervals. Embryos were collected by a non-surgical method 7 days after the first artificial insemination. The total numbers of ova collected from 3 experimental groups whose blood BUN concentrations were <10 mg/dl, 11~18 mg/dl and ${\geq}19$ mg/dl were 8.9, 12.5 and 19.0, respectively; whereas the numbers of transferable embryos were 5.8 + 1.9, 7.9 + 2.8 and 5.2 + 1.4, respectively. When glucose concentration was <60 mg/dl, the total number of collected ova was 9.9, which was smaller than when the concentration was 60~70 mg/dl or ${\geq}70$ mg/dl. When glucose concentration was 60~70 mg/dl, the number of transferable embryos was 7.1 + 2.4, which was slightly larger than the numbers 6.4 + 2.1 and 6.1 + 1.7 that were obtained when the concentrations were <60 mg/dl and ${\geq}70$ mg/dl, respectively ; however, the differences were not significant (p>0.05). When cholesterol concentrations were <150 mg/dl, 150~200 mg/dl and ${\geq}200$ mg/dl, the total numbers of collected ova were 11.2, 11.3 and 8.6, respectively. Whereas the numbers of transferable embryos were 7.1 + 2.1, 7.3 + 1.9 and 5.6 + 1.3, respectively ; however, the differences were again not significant (p>0.05). The result of this research showed no significant difference in ovum recovery rate and the number of transferable embryos according to major metabolite concentrations in high-producing Holstein donor cows. However, it is considered that the failure of maintaining proper nutritional status would cause the fall in in vivo embryo productivity.

Relationship between Nutritional Status and Transferable Embryos in Hanwoo Donors (한우 공란우의 영양 상태와 이식 가능 수정란과의 관계)

  • Jung, Yeon-Sub;Choe, Chang-Yong;Cho, Sang-Rae;Lim, Hyun-Joo;Yoon, Ho-Baek;Baek, Kwang-Soo;Kwon, Eung-Gi;Son, Dong-Soo;Son, Jun-Kyu
    • Journal of Embryo Transfer
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    • v.27 no.1
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    • pp.15-20
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    • 2012
  • The objective of this study was to investigate the relationship between body weight, body condition score (BCS), blood urea nitrogen (BUN), glucose, cholesterol and number of transferable embryos for the purpose of improving reproductive performance in Hanwoo donors. Seventy five cows, at random stages of the estrous cycle, received a CIDR together with injection of 1mg estradiol benzoate and 50 mg progesterone, and gonadotropin treatment begann. Four days later, the animals were superovulated with a total of 28AU FSH (Antorin, 2AU = 1 ml) administered twice daily in constant doses over 4 days. On the 3rd administration of FSH, CIDR was withdrawn and 25 mg $PGF_2{\alpha}$ was administered. Cows were artificially inseminated twice after estrous detection at 12 hr intervals. The cows received $100{\mu}g$ GnRH at the time of 1st insemination. Embryos were recovered 7 days after the 1st insemination. In conclusion, cows with body weight < 400, 400~450 and > 450kg had number of transferable embryos of $4.2{\pm}1.7$, $6.1{\pm}2.7$ and $4.8{\pm}2.6$, cows with BCS <2.25, 2.25~2.75 and ${\geq}2.75$ had number of transferable embryos of $4.6{\pm}1.6$, $5.7{\pm}2.4$ and $5.1{\pm}2.7$ respectively. These data indicate that a body weight and BCS for superovulation of CIDR-treated Korean native cows does not affect the embryo yield.

Quality Characteristics of Gamma Irradiated-Grain Shape Improved Meju (감마선 조사된 개량메주의 보존 중 품질특성)

  • Kim, Dong-Ho;Lee, Kyong-Haeng;Yook, Hong-Sun;Kim, Jae-Hoon;Shin, Myung-Gon;Byun, Myung-Woo
    • Korean Journal of Food Science and Technology
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    • v.32 no.3
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    • pp.640-645
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    • 2000
  • The effect of gamma-irradiation on the quality changes of the grain shape improved Meju was studied. Meju was prepared, irradiated at 0, 5, 10 and 20 kGy, and then stored at $25^{\circ}C$ for six months. The results showed that the fungi and acid producing bacteria were completely eliminated by gamma-irradiation with dose of 10 kGy or higher and the Bacillus was decreased by 5 log cycles with dose of 10 kGy. The $D_{10}$ values of the fungi, Bacillus and acid producing bacteria were 0.79, 2.28 and 1.17 kGy, respectively. Also, the microorganisms that survived irradiation was decreased significantly with the duration of storage period. The $NH_3-nitrogen$, negative factors of quality of Meju, and browning were repressed and the protease activity and pH were not affected by gamma-irradiation. Therefore, it was considered that the Meju treated with gamma-irradiation maintained better quality than that of the control with storage.

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Utilization of Various Electron Acceptors in Shewanella putrefaciens DK-l (Shewanella putrefaciens DK-1의 Fe(III) 환원 특성)

  • 조아영;이일규;전은형;안태영
    • Korean Journal of Microbiology
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    • v.39 no.3
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    • pp.175-180
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    • 2003
  • Microbial Fe(III) reduction is an important factor for biogeochemical cycle in anaerobic environments, especially sediment of freshwater such as lakes, ponds and rivers. In addition, the Fe(III) reduction serves as a model for potential mechanisms for the oxidation of organic compounds and the reduction of toxic heavy metals, such as chrome or uranium. Shewanella putrefaciens DK-1 was a gram-negative, facultative anaerobic Fe(III) reducer and used ferric ion as a terminal electron acceptor for the oxidation of organic compounds to $CO_{2}$ or other oxidized metabolites. The ability of reducing activity and utilization of various electron acceptors and donors for S. putrefaciens DK-1 were investigated. S. putrefaciens DK-1 was capable of using a wide variety of electron acceptor, including $NO_{3}^{-}$, Fe(III), AQDS, and Mn(IV). However, its ability to utilize electron donors was limited. Lactate and formate were used as electron donors but acetate and toluene were not used. Fe(III) reduction of S. putrefaciens DK-l was inhibited by the presence of either $NO_{3}^{-}$ or $NO_{2}^{-}$. Further S. putrefaciens DK-1 used humic acid as an electron acceptor and humic acid was re-oxidized by nitrate. Environmental samples showing the Fe(III)-reducing activity were used to investigate effects of the limiting factors such as carbon, nitrogen and phosphorus on the Fe(III) reducing bacteria. The highest Fe (III) reducing activity was measured, when lactate as a carbon source and S. putrefaciens DK-1 as an Fe(III) reducer added in untreated sediment samples of Cheon-ho and Dae-ho reservoirs.

The Study of Modified Sequencing Batch Reactor Process for Small Advanced Wastewater Treatment (소규모 고도하수처리를 위한 변형 연속회분식공정에 관한 연구)

  • Han, Woonwoo;Kim, Kyuhyoung
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.3
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    • pp.35-43
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    • 2008
  • This study was carried out to estimate the performance of modified sequencing batch reactor (SBR) process by the application of SBR process for small advanced wastewater treatment plant. Organic, nitrogen and phosphorus were able to remove in the unit reactor by SBR process and it would be able to select the suitable operation method. The plant was operated to achieve high performance with influent control, optimum anoxic/oxic condition using intermediate aeration method, and solid (sludge) /liquid (effluent) separation by modified decanter. The optimum operating mode was 3Cycles a day and intermediate input and aeration. Under these conditions, the treatment efficiencies were good with 60% of designed flow rate and low influent quality. When the influent concentrations of BOD and CODMn were 120.4 mg/L and 95.7 mg/L, respectively. The effluent concentrations of BOD and CODMn were 6.8 mg/L and 11.0 mg/L, respectively. The average removal efficiencies of BOD and CODMn were 94.4% and 88.5%, respectively. The removal efficiencies of T-N and T-P were 69.6% and 73.6%, respectively when the average T-N and T-P concentrations were 32.2mg/L and 4.65mg/L, respectively. The T-N and T-P removal efficiencies were slightly decreased to 58.8% and 68.5%, respectively in the winter season but its were also stable efficiencies. BOD, T-N and T-P were removed by 90%. 67% and 46% respectively in the first anoxic/oxic condition, in addition to T-P was removed by 70% in the second anoxic/oxic condition. From the results, modified sequencing batch reactor (SBR) process is suitable for small advanced wastewater treatment.

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Effect of Circulation Cycle of Nutrient Solution on the Dissolved Oxygen Concentration, and the Growth and Phytonutrient Contents of Leafy Vegetables Grown in DFT Systems (양액의 순환주기가 담액수경 엽채류의 용존산소 농도, 생육 및 식물영양소의 함량에 미치는 영향)

  • Seo, Tae-Cheol;Rhee, Han-Cheol;Rho, Mi-Young;Choi, Kyeong-Lee;Yun, Hyung-Kwon;Chun, Chang-Hoo
    • Journal of Bio-Environment Control
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    • v.18 no.2
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    • pp.112-118
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    • 2009
  • To determine the effects of circulation frequency of nutrient solution, three frequencies of 10min. on/10min. off; 10min. on/110min. off; and 10min. on/1,430min. off. treatments were applied to leafy vegetable production using deep flow technique (DFT) systems and their growth and phytonutrient content were investigated. In the 10min. on/I,430min. off treatment, dissolved oxygen concentration (DOC) 17 days after treatment decreased to 2.8mg. $L^{-1}$, known to be a low DOC that causes hypoxia, and thereafter decreased to 1.5mg. $L^{-1}$ 20 days after treatment. Fresh weight of 7 leafy vegetables in the 10min. on/1,430min. off treatment was lower by 0${\sim}$24% than those in the 10min. on/110min. off treatment, and those in the 10min. on/10min. off was higher by -2${\sim}$34% than those in the 10min. on/110min. off treatment as control. As the more frequent circulation was applied, the higher phosphorous content and the lower carbon to nitrogen ratio (C/N ratio) and total ascorbic acid contents were resulted. Results indicate that the circulation frequency of 110min, on/110min. off could be recommended for the production of the tested leafy vegetables in DFT systems.

Analysis on Retrofit Method to Improve TP treatment efficiency in Air-vent SBR process installed MWTP and RCSTP during winter based on Modeling (모델링 기반의 선회와류식 SBR 공법이 적용된 하수처리장 및 마을하수도 동절기 총인 개선방안 연구)

  • Lee, Hyunseop;Im, Jiyeol;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.21 no.4
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    • pp.251-256
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    • 2019
  • In the upstream and nearby areas of the water source, there are many areas where the sewerage penetration rate is relatively low due to development restrictions. This has been continuously affecting the pollution of the water source. As a measure to prevent this, method of distributing sewage and improving existing facilities are suggested. In this study, A MWTP(Municipal Watewater Treatment Plant) using the Air-vent SBR process located at upstream of An-dong and Im-ha Dam was selected as a modeling facility. And, the retrofit method to improve the effluent from RCSTP(Rural Community Sewage Tratment Plant) was induced based on A MWTP modeling result. The model construction and verification were carried out based on the operating data for 5 years (2012 ~ 2016). As a result, it was analyzed that the water quality of the effluent during the winter could be improved through control of cycle time in Air-vent SBR process and decreasing SRT (BOD: 1.8%, COD: 54.5%, SS: 4.3%, T-N; 0.8% and T-P: 7.7%). This research suggests that result of this research can be utilized as a retrofit method to improve the effluent overall treatment efficiency of the MWTP and the RCSTP which have similar operation process.