• Title/Summary/Keyword: Nitrates

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Vitrification of Highly Active Liquid Waste(I) (Thermal Decomposition of Nitrates and Additives for Glass-making)

  • Chun, Kwan-Sik;Lee, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.9 no.4
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    • pp.211-222
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    • 1977
  • The decomposition of all the individual chemicals used in the Harwell inactive vitrification pilot plant has been studied by means of a thermal balance. Weight loss curves to 110$0^{\circ}C$ have been obtained. The four materials (sodium nitrate, cesium nitrate, lithium nitrate and ruthenium nitroso-nitrate solution) showed a greater weight loss than that based on an oxide yield, and hence these compounds of their products of decomposition are volatile below 110$0^{\circ}C$. The remaining materials suffered a weight loss no more than that corresponding to a full yield of the oxide, and hence they were not volatile below 110$0^{\circ}C$. Most of chemicals begin to decompose at less than 75$^{\circ}C$ but the nitrates of cesium, strontium, barium and sodium not until 295$^{\circ}C$ to 59$0^{\circ}C$. The results obtained can be used in the analysis of process conditions in the vitrification and calcination of highly radioactive wastes and also of the thermal decomposition behaviour of mixtures containing those materials.

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The Change of Nitrites and Nitrates in Carrot Juice (당근즙(汁)중의 질산염(窒酸鹽) 및 아질산염(亞窒酸鹽)의 소장(消長)에 관한 연구)

  • Suh, Hong-Kyl
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.8 no.1
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    • pp.15-20
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    • 1979
  • The nitrite and nitrate levels of carrot juice at various temperature and periods were studied. The nitrite level of carrot juice at high temperature increased rapidly as the bacterial level increased. When carrot juice was held at $30^{\circ}C$, nitrite concentration began to decline after 14 hours, although there was no decrease in bacterial population, The nitrate level of carrot juice at high temperature decreased rapidly. The bacteria in carrot juice were supposed to reduce nitrates to nitrites, No increase in nitrite and no decrease in nitrate occured when bacterial growth was prevented by holding the juice at $5^{\circ}C$ or by adding potassium dehydroacetate.

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The Reduction Properties of Nitrate in Water with Palladium and Indium on Aluminum Pillared Montmorillonite Catalyst (팔라디움과 인디움을 담지한 Al 층간가교 몬모릴로나이트 촉매의 수중 질산성질소 환원 특성)

  • Jeong, Sangjo
    • Journal of Korean Society on Water Environment
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    • v.34 no.6
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    • pp.621-631
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    • 2018
  • In this study, catalyst was made through incipient wetness method using palladium (Pd) as noble metal, indium (In) as secondary metal, and montmorillonite (MK10) and Al pillared montmorillonite (Al-MK10) as supporters. The nitrate reduction rate of the catalysts was measured by batch experiments where H2 gas was used as reducing agent and formic acid as pH controller. Transmission electron microscopy (TEM) equipped with energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) were all used to determine the elemental distribution of Pd, In, Al, and Si on catalysts. It was observed that Al pillaring increased the Al/Si elemental composition ratio and point of zero charge of MK10, but decreased its BET specific surface area and pore volume. The nitrate reduction rate of Al-MK10 Pd/In was 2.0 ~ 2.5 times higher than that of MK10 Pd/In using artificial groundwater (GW) in ambient temperature and pressure. Nitrate reduction rates in GW were 1.2 ~ 1.7 times lower than those in distilled deionized water (DDW). Nitrate reduction rates in acidic conditions were higher than those in neutral condition in both GW and DDW. The amount of produced NH3-N over degraded NO3- at acid conditions was lower than that of neutral condition. Even though the leaching of Pd after reaction was measured in DDW it was not detected when both Al-MK10 Pd/In and MK10 Pd/In were used in GW. The modification of montmorillonite as a supporter significantly increased the reductive catalytic activities of nitrates. However, the ratio of producing ammonia by-products to degraded nitrates in ambient temperature and pressure was similar.

Multicomponent IGZO Ceramics for Transparent Electrode Target Fabricated from Oxides and Nitrates (산화물과 질산염으로 제조한 투명전극 타깃용 다성분계 IGZO 세라믹스)

  • Lee, Hyun-Kwun;Yoon, Ji-Hye;Cho, Kyeong-Sik
    • Journal of Powder Materials
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    • v.26 no.5
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    • pp.375-382
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    • 2019
  • Homogeneous multicomponent indium gallium zinc oxide (IGZO) ceramics for transparent electrode targets are prepared from the oxides and nitrates as the source materials, and their properties are characterized. The selected compositions were $In_2O_3:Ga_2O_3:ZnO$ = 1:1:2, 1:1:6, and 1:1:12 in mole ratio based on oxide. As revealed by X-ray diffraction analysis, calcination of the selected oxide or nitrides at $1200^{\circ}C$ results in the formation of $InGaZnO_4$, $InGaZn_3O_6$, and $InGaZn_5O_8$ phases. The 1:1:2, 1:1:6, and 1:1:12 oxide samples pressed in the form of discs exhibit relative densities of 96.9, 93.2, and 84.1%, respectively, after sintering at $1450^{\circ}C$ for 12 h. The $InGaZn_3O_6$ ceramics prepared from the oxide or nitrate batches comprise large grains and exhibit homogeneous elemental distribution. Under optimized conditions, IGZO multicomponent ceramics with controlled phases, high densities, and homogeneous microstructures (grain and elemental distribution) are obtained.

Nutrients And Chlorophyll $\alpha$ Variations At A Fixed Station During The Red Tides In The Jinhae Bay

  • Yang, Dong-Beom;Hong, Gi-Hoon
    • 한국해양학회지
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    • v.17 no.1
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    • pp.19-26
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    • 1982
  • 12 or 25 hours continuous observations were made for the variations of nutrients and chlorophyll ${\alpha}$ with tidal cycle at a fixed station located at a mid-channel of the Masan Bay. High nitrate concentrations were observed at the time of low tides whereas high phosphate concentrations at the time of high tides. It is suggested that anoxic bottom waters could also be the possible source of high phosphates in the outer bay. Chlorophyll ${\alpha}$ concentrations were related to the nitrates in April and to the phosphates in June and August. The possible role of growth stimulators in causing the extensive blooms of red tide organisms is suggested.

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Effect of Amaranthus Pigments on Quality Characteristics of Pork Sausages

  • Zhou, Cunliu;Zhang, Lin;Wang, Hui;Chen, Conggui
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.10
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    • pp.1493-1498
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    • 2012
  • The objective of this investigation was to evaluate the possibility of substituting Amaranthus pigments for nitrates in the of manufacture pork sausage. Five treatments of pork sausages (5% fat) with two levels of sodium nitrite (0 and 0.015%), or three levels (0.1%, 0.2% and 0.3%) of pigments extracted from red Amaranthus were produced. The addition of Amaranthus pigments resulted in the significant increase of $a^*$ values, sensory color, flavor and overall acceptance scores, but the significant reduction of $b^*$ values, TBA values and VBN values (p<0.05). Based mainly on the results of overall acceptance during 29 d storage, it could be concluded that Amaranthus pigments showed a potential as nitrite alternative for pork sausage manufacture.

Effect of annealing on the magnetic behavior and microstructures of spherical NiZn ferrite particle prepared by ultrasonic spray pyrolysis

  • Nam, Joong-Hee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.1
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    • pp.11-17
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    • 2007
  • The spherical NiZn ferrite particles were prepared by ultrasonic spray pyrolysis with mixed solution of aqueous metal nitrates. The NiZn ferrite particle was observed with nano-sized primary particles of about 10 nm or less before annealing which represented as paramagnetic behavior measured at 77 K and room temperature. The typical abnormal growth of primary particles like polyhedral primary particles was observed by annealing at 1273 K with Zn-concentration dependency. The XRD patterns showed good crystallinity of NiZn ferrite powder after annealing. In annealing process, the intra-particle sintering phenomenon was observed and the spherical particle morphology was collapsed at 1673 K. The saturation magnetization of NiZn ferrite powder for each annealing temperature was decreased with measuring temperature of $77{\sim}$300K.

Studies on Nitrosamine(I) - Contents of Nitrite and Nitrate in Korean Foods(Kimchi) and Human Saliva - (Nitrosamine에 관(關)한 연구(硏究)(제(第)1보(報)) - 한국식품(韓國食品)(김치류(類)) 및 인타액중(人唾液中) 아초산근(亞醋酸根), 초산근등(醋酸根等)의 함량(含量)에 대(對)하여 -)

  • Kwon, Hyuk-Hee
    • Journal of Nutrition and Health
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    • v.7 no.4
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    • pp.21-23
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    • 1974
  • Nitrite, one of the precursors of dimethylnitrosamine distributes widely in natural foods and also used as a color fixative in meat products. In this paper Nitrites and Nitrates contents in Korean-Kimchi and Human Saliva were as follows. (1) pH: $pH:\;3.8{\sim}5.8$(in Korean-Kimchi soup) (2) NaCl: $1.5{\sim}3.1%$(in Korean-Kimchi soup) (3) Acidity: $0.38{\sim}0.62%$(in Korean-Kimchi soup) (4) $NO_2-$ $0.25{\sim}0.68ppm$ (in Korean-Kimchi) $1.9{\sim}5.0ppm$ (in Human Saliva) (5) $NO_3-$ $35.0{\sim}92.0ppm$ (in Korean-Kimchi) $7.6{\sim}28.0ppm$ (in Human Saliva) These results showed low contents in Korean-Kimchi and Human Saliva.

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Synthesis and Characterization of Nanosized MnxFe2O4 Powders by Glycothermal Process

  • Bae, Dong-Sik;Kim, Eun-Jung;Lee, Hae-Won;Han, Kyong-Sop
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.903-906
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    • 2002
  • Nanosized $Mn_xFe_2O_4$ powders were prepared in ethylene glycol solution under mild temperature and pressure conditions by precipitation from metal nitrates with aqueous potassium hydroxide. The average size and distribution of the synthesized $Mn_xFe_2O_4$ powders was about 20 nm and broad, respectively. The phase of synthesized particles was crystalline reacted at 200${\circ}C$ for 6h. The magnetic properties of the synthesized $Mn_xFe_2O_4$ powders were about 35-60 (emu/g) with superparamagnetic character.

Quantification of Sampling Artifacts in PM2.5 Inorganic Ion Species using Teflon Filter (테플론 여과지를 이용한 미세입자 무기이온 성분 측정에서의 오차 정량)

  • Kim, Jung-Youn;Kim, Yong-Pyo
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.1
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    • pp.74-83
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    • 2007
  • Artifacts due to inter-particle and gas-particle interactions during PM2.5 sampling were quantified by comparing the measurement results between the annular denuder-filterpack system and the filterpack system without denuder. Measurements were carried in Seoul for 10 days in each season; Nov. 2004, Jan. 2005, Mar. 2005, and Jul. 2005, respectively. In each day, two 12-h samples were obtained. The concentrations of nitrate and chloride showed seasonal variations mainly due to the availability of ammonium to neutralize nitrate or chloride. Nitrates and chloride losses were prominent in summer. Since most of ammonia was used to neutralize sulfuric acid and formed ammonium sulfate in summer, nitrate and chloride could not exist in particles and ammonium loss was smaller than other seasons.