• Title/Summary/Keyword: Nitrate Reduction

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Synthesis of Ultrafine TiC-15%Co Powder by Thermochemical Method (열화학적 방법에 의한 초미립 TiC-15%Co 분말의 합성)

  • 홍성현;탁영우;김병기
    • Journal of Powder Materials
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    • v.10 no.4
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    • pp.281-287
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    • 2003
  • Ultrafine TiC-15%Co powders were synthesized by a thermochemical process, including spray drying, calcination, and carbothermal reaction. Ti-Co oxide powders were prepared by spray drying of aqueous solution of titanium chloride and $Ti(OH)_2$ slurry, both containing cobalt nitrate, fellowed by calcination. The oxide powders were mixed with carbon powder to reduce and carburize at 1100~125$0^{\circ}C$ under argon or hydrogen atmosphere. Ultrafine TiC particles were formed by carbothermal reaction at 1200~125$0^{\circ}C$, which is significantly lower than the formation temperature (~1$700^{\circ}C$) of TiC particles prepared by conventional method. The oxygen content of TiC-15%Co powder synthesized under hydrogen atmosphere was lower than that synthesized under argon, suggesting that hydrogen accelerates the reduction rate of Ti-Co oxides. The size of TiC-15%Co powder was evaluated by FE-SEM and TEM and Identified to be smaller than 300 nm.

Synthesis of Nanostructured TiC/Co Composite Powder by the Spray Thermal Conversion Process

  • Lee, Gil-Geun;Ha, Gook-Hyun;Kim, Byoung-Kee
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.418-419
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    • 2006
  • In the present, the focus is on the synthesis of nanostructured TiC/Co composite powder by the spray thermal conversion process using titanium dioxide powder has an average particle size of 50 nm and cobalt nitrate as raw materials. The titanium-cobalt-oxygen based oxide powder prepared by the combination of the spray drying and desalting methods. The titanium-cobalt-oxygen based oxide powder carbothermally reduced by the solid carbon. The synthesized TiC-15wt.%Co composite powder at 1473K for 2 hours had an average particle size of 150 nm.

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Silver nano-ink formulation based on alcohol and its application to inkjet printing (알코올 용제의 은 나노 잉크 제조와 프린팅 기술의 응용)

  • Cho, Hye-Jin;Kim, Tae-Hoon;Joung, Jae-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.551-552
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    • 2006
  • This study was attended to demonstrate synthesis of silver nanoparticles stabilized with polymer and their applicability to printed electronics. Silver nanoparticles were synthesized by reduction of silver nitrate in aqueous solution in the presence of polyvinyl pyrrolidone (PVP) as a stabilizer. The ink used here is composed of 50 wt% Ag NP, 15 wt% humectant and then were printed on polyimide film. Particle deposit morphologies were controlled by varying the ink compositions. Printed silver patterns and dots were cured on a convection oven in air at $300^{\circ}C$ for 60 min. The printed patterns show good shape definition and the resistivity of the printed films is about $5{\mu}{\Omega}{\cdot}cm$.

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UV Light Induced Photocatalytic Degradation of Cyanides in Aqueous Solution over Modified $TiO_2$

  • Kim, Hyeong Ju;Kim, Jae Hyeon;Lee, Cheong Hak;Hyeon, Taek Hwan;Choe, Won Yong;Lee, Ho In
    • Bulletin of the Korean Chemical Society
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    • v.22 no.12
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    • pp.1371-1374
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    • 2001
  • Metal doping was adopted to modify TiO2 (P-25) and enhance the photocatalytic degradation of harmful cyanides in aqueous solution. Ni, Cu, Co, and Ag doped TiO2 were found to be active photocatalysts for UV light induced degradation of aqueous cyanides generating cyanate, nitrate and ammonia as main nitrogen-containing products. The photoactivity of Ni doped TiO2 was greatly affected by the state of Ni, that is, the crystal size and the degree of reduction of Ni. The modification effects of some mixed oxides, that is, Ni-Cu/TiO2 were also studied. The activity of Ni-Cu/TiO2 for any ratio of Cu/Ni was higher than that of Ni- or Cu-doped TiO2, and the catalyst at the Cu/Ni ratio of 0.3 showed the highest activity for cyanide conversion.

Treatment of surface water using cold plasma for domestic water supply

  • Nguyen, Dung Van;Ho, Phong Quoc;Pham, Toan Van;Nguyen, Tuyen Van;Kim, Lavane
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.412-417
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    • 2019
  • This paper presents the results of using cold plasma to treat surface water for domestic use purpose. Experimental results showed that cold plasma was an effective method for destroying bacteria in water. After treatment with cold plasma, concentration of coliform and Escherichia coli dramatically reduced. Besides, cold plasma significantly removed water odor, increased dissolved oxygen and decreased the concentration of chemical oxygen demand. However, cold plasma significantly raised the concentration of nitrite and nitrate. Other disadvantages of treating with cold plasma were conductivity increase and pH reduction. Pretreatment steps of coagulation, flocculation, sedimentation and sand filtration followed by disinfection with cold plasma exhibited a high efficiency in surface water treatment. All parameters of surface water after treatment by using the prototype satisfied with the allowance standard of domestic water quality.

The removal characteristics of dissolved solid in wastewater during a capacitive deionization process (축전식 탈염공정을 이용한 하수중의 용존염 제거특성 연구)

  • Shin, Kyong-Suk;Yi, Tae-Woo;Cha, Jae-Hwan;Lim, Yoon-Dae;Park, Seung-Kook;Kang, Kyoung-Suk;Song, Eui-Yeol
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.2
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    • pp.151-160
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    • 2014
  • Capacitive deionization(CDI) has many advantages over other desalination technologies due to its low energy consumption, less environmental pollution and relative low fouling potential. The objectives of this study are evaluate the performance of CDI which can be used for dissolved salts removal from sewage. To identify ion selectivity of nitrate and phosphate in multiionic solutions and adsorption/desorption performance related to applied potential, a series of laboratory scale experiments were conducted using a CDI unit cell with activated carbon electrodes. The CDI process was able to achieve more than 75 % TDS and $NO_3{^-}$, $NH_4{^+}$ removals, while phosphate removal was 60.8 % and is inversely related in initial TDS and $HCO_3{^-}$ concentration. In continuous operation, increasing the inner cell pressure and reduction of TDS removal ability were investigated which are caused by inorganic scaling and biofouling. However a relative mild cleaning solution(5 % of citric acid for calcium scaling and 500 mg/L of NaOCl for organic fouling) restored the electrochemical adsorption capacity of the CDI unit to its initial level.

Effects of Nutrient Composition on Yield and Quality of Mushroom in Lentinula edodes Cultivation Using Softwood Sawdust

  • Jung, Ji-Young;Hong, Seong-Cheol;Rinker, Danny Lee;Choi, Myung-Suk;Lee, Byung-Hyun;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.2
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    • pp.124-134
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    • 2010
  • This study was performed to evaluate the efficiency of using softwood as the sawdust medium for Lentinula edodes cultivation, effect of nutrient on the mycelial growth, spawning, the mushroom yield, and quality. The nitrogen nutrition significantly enhanced the mycelial growth of L. edodes. The glutamic acid in the L. leptolepis and P. koraiensis, and asparagine in the P. densiflora were appeared to slight increase in the mycelial growth. The vegetable oil showed very effective on the mycelial growth in the P. koraiensis sawdust medium. Carbon/nitrogen ratio of all the test was reduced after mycelial growth. The mycelial growth was exclusively dependent on reduction of carbon. The mushroom yield (32.7%) of the P. densiflora sawdust medium (carbon source: 3% active carbon, nitrogen source: 0.4% asparagines) was the best in mushroom production of L. edodes, followed by the Q. variabilis sawdust (35.4%) of the control medium. The diameter of mushroom cap was obtained from the P. densiflora sawdust (carbon source: 3% sucrose, nitrogen source: 0.4% potassium nitrate) and P. koraiensis sawdust (carbon source: 3% sucrose, nitrogen source: 0.4% potassium nitrate), and the P. koraiensis sawdust (carbon source: 3% xylose, nitrogen source: 0.4% glutamic acid, supplement: 0.05% amino acid), with values 71.5 mm, 71.5 mm and 72.1 mm, respectively. In the polypropylene bag cultivation, the weight losses of the block medium gradually increased for 80 days in the dark (13.8~16.8%) and then became stable in the range of 20.7~25.8%.

Membrane Diffuser Coupled Bioreactor for Methanotrophic Denitrification under Non-aerated Condition: Suggestion as a Post-denitrification Option

  • Lee, Kwanhyoung;Choi, Oh Kyung;Song, Ji Hyun;Lee, Jae Woo
    • Environmental Engineering Research
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    • v.19 no.1
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    • pp.75-81
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    • 2014
  • Methanotrophic denitrification under a non-aerated condition (without external supply of oxygen or air) was investigated in a bioreactor coupled with a membrane diffuser. Batch experiment demonstrated that both methane consumption and nitrogen production rates were not high in the absence of oxygen, but most of the nitrate was reduced into $N_2$ with 88% recovery efficiency. The methane utilized for nitrate reduction was determined at 1.63 mmol $CH_4$/mmol $NO_3{^-}$-N, which was 2.6 times higher than the theoretical value. In spite of no oxygen supply, methanotrophic denitrification was well performed in the bioreactor, due to enhanced mass transfer of the methane by the membrane diffuser and utilization of oxygen remaining in the influent. The denitrification efficiency and specific denitrification rate were 47% and 1.69 mg $NO_3{^-}-N/g\;VSS{\cdot}hr$, respectively, which were slightly lower than for methanotrophic denitrification under an aerobic condition. The average concentration of total organic carbon in the effluent was as low as 2.45 mg/L, which indicates that it can be applicable as a post-denitrification method for the reclamation of secondary wastewater effluent. The dominant fatty acid methyl ester of mixed culture in the bioreactor was $C_{16:1{\omega}7c}$ and $C_{18:1{\omega}7c}$, which was predominantly found in type I and II methanotrophs, respectively. This study presents the potential of methanotrophic denitrification without externally excess oxygen supply as a post-denitrification option for various water treatment or reclamation.

Production of Anthocyanins by Vitis Hybrid Cell Culture (Vitis Hybrid 세포배양에 의한 Anthocyanin의 생산)

  • 박형환;강신권;이재호;최장윤;이윤수;권익부;유주현
    • Microbiology and Biotechnology Letters
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    • v.17 no.3
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    • pp.257-262
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    • 1989
  • The induction of calli from tissues of a grape, Vitis hybrid, and their suspension cultures were performed and various factors were investigated on cell growth and anthocyanin production. It was shown that light intensity and inorganic nitrogen concentration played an important role on anthocyanin production.1:he contents of anthocyanin produced under 10,000 Iux light irradiation were about twice as much as under the dark. The reduction of inorganic nitrogen concentration of MS medium to one to twenty brought about the increase of approximately five to six-fold in total anthocyanin or sixteenfold in anthocyanin content per dry cell weight and addition of nitrate only as inorganic nitrogen source was shown to be the best for anthocyanin production. Miller medium and Gamborg medium were suitable for the anthocyanin production, as well as high concentrations of Co$^{2+}$ and Fe$^{2+}$. And high yield of 40mg anthocyanins per 200m1 flask was obtained by two stage culture using MS medium for the first stage and the modified MS medium for the second stage.

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Effect of plant growth regulators and antioxidants on in vitro plant regeneration and callus induction from leaf explants of purple passion fruit (Passiflora edulis Sims)

  • Huh, Yoon Sun;Lee, Joung Kwan;Nam, Sang Young
    • Journal of Plant Biotechnology
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    • v.44 no.3
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    • pp.335-342
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    • 2017
  • Purple passion fruit (Passiflora edulis Sims) is one of the introduced tropical plants, an increasing interest has arisen due to its distinctive taste and attractive flavor. It is expected that passion fruit production and planted area will increase gradually in the years ahead because of high profitability and consumer's demands of healthful ingredients. So we tried to investigate the effect of plant growth regulators and antioxidants on in vitro plant regeneration and callus induction from leaf explants of passion fruit for an establishment of optimal mass propagation system. Young leaf explants of purple passion fruit were cultured in Murashige and Skoog (MS) medium containing different growth regulators and antioxidant additives to induce the shoot organogenesis. After 8 weeks, the highest embryogenic callus formation rate was obtained in MS medium supplemented with $1mg{\cdot}L^{-1}$ 6-benzylaminopurine (BAP) and $2mg{\cdot}L^{-1}$ 2,4-dichlorophenoxyacetic acid (2,4-D), furthermore, the shoot development via organogenesis was also observed. Silver nitrate ($AgNO_3$), which was added into the medium to minimize the adverse effects of leached phenolics, was effective for reduction of medium browning and sudden explant death. In the medium supplemented with $1mg{\cdot}L^{-1}$ BAP and $1mg{\cdot}L^{-1}$ gibberellic acid ($GA_3$), shoots were most vigorously regenerated and elongated. Most shoots rooted successfully in half strength medium with $1mg{\cdot}L^{-1}$ indol-3 acetic acid (IAA), and more than 90% of plantlets survived after 4-month acclimatization period.