• 한국표면공학회지
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• 제29권1호
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• pp.26-35
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• 1996

The Ni-SiC composite plating was performed in a Watt nickel solution and the wear resistance of the composite layer was studied on a pin-on-flat type wear tester. The volume losses and friction coefficients were measured. It was found that the quantity of SiC powder in the composite layers was affected by SiC concentration, pH, temperature, and agitation speed in the Watt nickel solution. The hardness and wear resistance of the coatings increased with SiC content. The quantity of SiC powder in the coating from a nickel sulfamate solution is larger than that of the Watt nickel solution, because the amount of nickel ions absorbed on the SiC powder in the nickel sulfamate solution is greater than that in the Watt's solution.

• 한국표면공학회지
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• 제29권6호
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• pp.720-723
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• 1996

The behavior of electrodeposition of amorphous nickel-phosphorus has been studied from the point of deposition mechanism, kinetic parameters, morphology and formation of alloy films. The electorode reaction and electrode kinetics of deposition of nickel were significantly influenced by the content of phosphorus. The cathodic deposition of nickel-phosphorus alloy might be governed by the diffusion process of phosphorous acid. The direction of growth layer of the nickel-phosphorus alloy was different with substrate material. The formation of nickel-phosphorus alloy films was affected considerably by the solution compositions, electrolytic conditions and properties of the material as an underlayer.

• 한국분말재료학회지
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• 제30권6호
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• pp.502-508
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• 2023

With the increasing demand for electronic products, the amount of multilayer ceramic capacitor (MLCC) waste has also increased. Recycling technology has recently gained attention because it can simultaneously address raw material supply and waste disposal issues. However, research on recovering valuable metals from MLCCs and converting the recovered metals into high-value-added materials remains insufficient. Herein, we describe an electrospinning (E-spinning) process to recover nickel from MLCCs and modulate the morphology of the recovered nickel oxide particles. The nickel oxalate powder was recovered using organic acid leaching and precipitation. Nickel oxide nanoparticles were prepared via heat treatment and ultrasonic milling. A mixture of nickel oxide particles and polyvinylpyrrolidone (PVP) was used as the E-spinning solution. A PVP/NiO nanowire composite was fabricated via E-spinning, and a nickel oxide nanowire with a network structure was manufactured through calcination. The nanowire diameters and morphologies are discussed based on the nickel oxide content in the E-spinning solution.

• 한국산업보건학회지
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• 제18권2호
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• pp.99-107
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• 2008

We quantified the human carcinogenic metals (chromium, nickel) in fumes from flux cored arc welding using stainless steel (FCAW/SS) wires. Zinc and calcium were also quantified because of their possibility of zinc chromate and calcium chromate, respectively. Welding was performed in an American Welding Society standard fume collection chamber. Insoluble and soluble forms of metals were analyzed by ISO 15202 method. Total chromium (insoluble+soluble) content and total nickel content were lower in FCAW/SS fumes (4.65%, 1.05%, respectively)than in stainless steel content (ca. 18%, 8%,respectively). Insoluble fraction in total chromium was 79.8 (range 64.5~95.1)% and 94.4(range 90.1~98.1)% in total nickel. Atomic emission spectroscopy used in this study does not differentiate the chromium valence status while ACGIH defines its carcinogenicity according to the valence status. From this study and previous study, we estimated the hexavalent chromium content in FCAW/SS was 0.2~1.1% and about 85% of them was soluble. The content of zinc and calcium, which can be existed as chromate forms, was low (0.02 %, 0.04% respectively) in FCAW/SS. Exposure assessment for zinc chromate and calcium chromate is possible because chromium in both compounds is used as a surrogate even though it is not well known that what compounds of zinc and calcium are formed in welding fume.

• 대한기계학회논문집A
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• 제33권7호
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• pp.621-628
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• 2009

Nickel-phosphorus alloys are attractive materials for diamond turning applications such as fabrication of large optics and other high precision parts. It is also well-known that the higher phosphorus content of the alloys minimizes the diamond tool wear. Due to the weakness of electoless nickel plating that the phosphorus contents is limited to 13-14% (wgt), increased attention has been paid at electro-nickel plating which enables the alloys with 15-16% phosphorus. In this study, experiments were carried out to observe the wear characteristic of single crystal diamond tools in micro-grooving of electro-nickel plated drums. The experiments shows that long distance (50km) machining of micro-grooving on electro-nickel plated drum is possible with a single crystal diamond tool without any significant tool wear and defective machined surface.

• 폴리머
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• 제27권1호
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• pp.61-68
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• 2003

본 연구에서는 도금폐수 중 니켈이온의 분리 회수를 위한 혼성 이온교환체의 제조 및 흡착 특성을 확인하였다. 니켈 흡착량은 이온교환체의 혼합비에 큰 영향이 없었으며, 비드상 이온교환수지 양이 증가할수록 증가하였다. 또한 Langmuir와 Freundlich흡착 등온식이 직선성을 보였으며 이로부터 니켈의 이온교환 친화력이 큰 것을 확인하였다. 또한 충전방식에 따른 압력손실은 다단충전법에서 적층수가 많아질수록 작아졌고, 혼합충전법에서는 비드 이온교환수지의 양이 증가할수록 압력손실은 감소하였다. 한편, 연속식 흡착실험 결과 다단충전방식의 경우 적층수가 증가할수록 초기 파괴 시간은 짧아졌으며, 최종 파괴 시간은 거의 동일한 것으로 나타났다. 반면, 혼합충전방식의 경우 이온교환섬유의 양이 증가할수록 흡착파괴 시간이 짧았으며, 이때 최대 흡착량은 각각 2.51 meq/g과 2.69 meq/g이었다. 한편, 모든 이온 교환체의 흡착된 니켈이온의 탈착은 10분 이내에 98% 이상 탈착되었다.

• Nuclear Engineering and Technology
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• 제56권5호
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• pp.1830-1835
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• 2024

The current study aims to study the impacts of the substitution of magnesium with nickel concentrations on physical and γ-ray shielding capacity of magnesium alloys. The density of the magnesium alloys under study is varied from 3.677 g/cm³ to 5.652 g/cm³, with raising the nickel content from 26.7 wt% to 54.8 wt% and reducing the magnesium concentration from 72.6 wt% to 44.2 wt%, respectively. Additionally, the examination of the γ-ray shielding capacity using the Monte Carlo simulation code shows that the substitution of magnesium by nickel content in the magnesium alloys was associated with an enhancement in the γ-ray shielding capacity, where the linear attenuation coefficient for the studied alloys was enhanced by 53.22 %, 52.45 %, and 52.52 % at γ-ray energies of 0.662 MeV, 1.252 MeV, and 1.408 MeV, respectively, with raising the nickel concentration from 26.7 wt% to 54.8 wt%. Simultaneously, the half-value thickness for magnesium alloys was reduced from 2.47 cm to 1.62 cm (at gamma ray energy of 0.662 MeV), from 3.39 cm to 2.22 cm (at gamma ray energy of 1.252 MeV), and from 3.60 cm to 2.36 cm (at gamma ray energy of 1.408 MeV), raising the nickel concentration from 26.7 wt % to 54.8 wt%, respectively. The study shows that the substitution of magnesium for nickel greatly enhanced the radiation shielding capacity of the magnesium alloys.

• 한국산학기술학회논문지
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• 제21권3호
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• pp.576-584
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• 2020

압출기 스크류 소재는 주로 냉간 금형 공구강(SKD11)이 사용되고 있는데, 최근 합성 수지의 발달로 화학적 부식 및 마모 발생이 증가하고 있다. 이를 개선하기 위해 내마모성과 내식성이 우수한 고크롬 주철의 사용이 요구되지만, 난가공성으로 사용이 기피되고 있다. 본 연구에서는 고크롬 합금의 난가공성을 개선하기 위해 Fe-23Cr-2.5C-1.2Si-1.08Mn-0.48Mo-0.3V 조성의 고크롬 주철에 가공성이 우수한 니켈을 0, 0.5, 1.0, 1.5 % 첨가하여 주조하고 열처리를 진행한 후, 선삭 시험과 동전위 분극 시험을 통해 니켈이 피삭성 및 내식성에 미치는 영향을 분석하여 SKD11과 비교하였다. 고크롬 주철은 고주파 진공유도용해로를 사용하여 주조하고, 이후 750 ℃에서 5시간 동안 풀림 처리와 풀림 처리 후 1100 ℃에서 5시간동안 재열처리를 실시하였다. 750 ℃ 풀림 처리 후 선삭 시험을 실시한 결과 니켈의 함량이 1.0% 이상에서 피삭성은 현저히 향상되었다. 5% NaCl 용액에서 동전위 분극 시험 결과 주방상태와 750 ℃ 풀림 처리에서는 니켈의 함량이 증가할수록 내식성은 저하되었으나, 1100 ℃ 재열처리 후에는 1.5% 니켈에서 가장 우수한 내식성을 나타냈다.

• 분석과학
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• 제24권6호
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• pp.443-450
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• 2011

ICP-AES와 AAS를 이용하여 세라믹, 금속 및 플라스틱 소재에 함유된 니켈을 정량하기 위한 조건을 연구하였다. 니켈 정량을 위해 산분해하여 조제된 시험 용액을 직접 ICP-AES 또는 AAS로 분석할 때 철이나 크로뮴 등의 원소가 방해하므로, 니켈을 dimethylglyoxime으로 착화시키고 $CHCl_3$로 추출하여 방해원소로부터 분리한 후 $CHCl_3$을 제거하고 염산으로 용해하여 측정하였다. 니켈에 대한 측정 회수율이 우수하였고, 방해를 일으키는 매질원소를 효율적으로 제거할 수 있어 본 방법은 인증표준물질(BAM-376 및 PACS-2)에 대한 용매추출시험에서 matrix의 영향을 받지 않고 니겔을 정량할 수 있었다.

• 한국주조공학회지
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• 제3권3호
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• pp.174-180
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• 1983

The matrix changes and graphite formation in high manganese cast iron (Fe-12Mn-3.5C) are studied with increasing nickel and silicon content. Also, the decomposition of carbides and graphite precipitation are studied by adequate heat treatment.The results obtained in this work are as follows. 1. In high manganese cast iron, fine flakes graphite appeared by adding 5 wt% nickel and A-type flakes graphite can be obtained by adding 7 wt% nickel. 2. Nodular graphite are obtained by graphite spheroidizing treatment with same melt. 3. In high manganese cast iron containing 7 wt% nickel, full austenitic matrix with nodular graphite can be achieved by water quenching after 10 hours' solution heat treatment at $1050^{\circ}C$ in case of containing 2.0 wt% silicon, and 6 hours' at the same temperature in case of containing 2.5 wt% silicon.