• Title/Summary/Keyword: Nickel (Ni)

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Emission Characteristics of Fine Particles, Vanadium and Nickel from Heavy Oil Combustion (중유 연소 시 발생하는 미세입자 및 니켈과 바나듐의 대기 중 배출특성)

  • Jang, Ha-Na;Kim, Sung-Heon;Lee, Ju-Hyung;Hwang, Kyu-Won;Yoo, Jong-Ik;Sok, Chong-Hui;Seo, Yong-Chil
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.3
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    • pp.353-360
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    • 2006
  • This study identified a particle size distribution (PSD) of fine particulate matter and emission characteristics of V and Ni by the comparison between anthropogenic sources of oil combustion (industrial boiler, oil power plant, etc.) and lab-scale combustion using a drop-tube furnace. In oil combustion source, the mass fraction of fine particles (less than 2.5 micrometers in diameter) was higher than that of coarse particles (larger than 2.5 micrometers in diameter) in $PM_{10}$ (less than 10 micrometers in diameter) as like in lab-scale oil combustion. In addition to this, it was identified that ultra-fine particles (less than 0.1 micrometers in diameter) had a large distribution in fine particles. Toxic metals like V and Ni had large mass fractions in fine particles, and most of all was distributed in ultra-fine particles. Most of ultra-fine particles containing toxic metals have been emitted into ambient by combustion source because it is hard to control by the existing air pollution control device. Hence, we must be careful on these pollutants because it is obvious that these are associated with adverse health and environmental effect.

A study on the brazed bonding of alumina ceramic to aluminum in the air atmosphere (알루미나($Al_2O_3$)세라믹과 알루미늄(A1050)과의 대기중 브레이징 접합에 관한 연구)

  • 최영국;박성현;김윤해;김영식
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.3
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    • pp.50-61
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    • 1995
  • In recent years, many ceramic researchers have discoved various methods of joining ceramic to metal. However, most of these joining methods are perfomed under vacuum and pressured circumstances. So, when we join ceramic to metal,the proceedings are very complicated and require a very high cost. The purpose of this study is to develop a new joining method of an alumina ceramic to an aluminum metal in air atmosphere. The joining condition, such as copper metallizing, nickel plating, brazing, etc. was investigated through the shear strength test of the trial joint. The results obtained from the above experimenta are summarized as follows : 1) In the case of the $Al_2O_3$/$Al_2O_3$joint, the shear strength of the joint was affected by the various foctor such as kaolin content, copper metallizing thickness, firing temperature, firing time. 2) The better shear strength of the $Al_2O_3$/Al joint was obtained when Ni plating was conducted under higher current density than existing plating condition. 3) The shear strength of the $Al_2O_3$/Al joint increases with the Ni plating thickness is confined to the range of this paper. 4) The shear strength of the thermal-shocked specimen($Al_2O_3$/Al joint) was far more deteriorated than that of the as-bonded specimen.

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Distribution of Some Metallic Elements in Surface Sediments of the Southeastern Yellow Sea. (황해 남동해역 표층퇴적물 중 수종 금속원소의 분포 특성에 관한 연구)

  • 이창복;정회수
    • 한국해양학회지
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    • v.27 no.1
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    • pp.55-65
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    • 1992
  • Ninety-seven surface sediment samples, collected from the southeastern part of the Yellow Sea, were analyzed for their contents of five metallic elements, including Fe, Mn, Ni, Cu and Pb as well as their grain-size and calcium carbonate content. The result showed a contrasting behaviour among the five metallic elements. with respect to their relationship with the sediment grain0size. contents of nickel and copper demonstrated a fairly linear relationship with the pediment grain-size whereas those of manganese and lead did not. This different behaviour in these metals was interpreted as being the result of the anthropogenic inputs (for Pb) and modification during the early diagenesis (for Mn). The R0mode factor analysis result also confirmed the different behaviour of manganese and lead from that of copper and nickel. Based on this different behaviour in metals the (Mn+Pb)/(Cu+Ni) ratio was suggested as a possible criterion for distinguishing the fine sediments in the study area, which originated from two different source area. China and Korea.

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A Study on the Variation of Physical Properties of Line-heated for Type-B LNG Fuel Tank with 9% Nickel Steel Plate (9% Nickel강이 적용된 Type-B LNG 연료탱크 선상가열의 물성 변화에 관한 연구)

  • Choi, Kyung-Shin;Lee, Ji-Han;Hong, Ji-Ung;Chung, Won-Jee
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.7
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    • pp.89-97
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    • 2020
  • Container vessels continue to grow in size, led by global shipowner. Large ships can be loaded more cargo at a time, reducing the cost of transportation per teu. this eventually leads to economies of sale, in which the production cost per unit decreases with increasing output. in accordance with the 70th Convention of the Marine Environment Protection Committee of the International Maritime Organization, as of January 1, 2020, MARPOL Annex VI Regulation 14.1.3 will be effective. All vessels must be meet these criteria to reduce Sox emissions and reduce NOx emissions by reducing the content of manned sulfur oxides from 3.5% to less than 0.5%, otherwise IACS Member States Entry to the port is denied. in order to do that need to LNG storage tank. in this study characteristic of the material after line heating (600℃,700℃,800℃,900℃) of 9% Ni steel used in the manufacture of LNG fuel tank of ship were verified using by mechanical test. In the heating method by line heating. The initial properties of steel are changed by variables such as temperature, time, speed. The experimental data of line heating presented in this paper confirmed that the initial change of 9% Ni steel could be minimized.

Improvement of Coating Properties of Metal/diamond Composite Through Ni Coated Diamond in the Kinetic Spraying Process (저온 분사 공정에서 니켈이 코팅된 다이아몬드 적용을 통한 금속/다이아몬드 복합재료의 코팅성 향상)

  • Na, Hyun-Taek;Bae, Gyu-Yeol;Kang, Ki-Cheol;Kim, Hyung-Jun;Lee, Chang-Hee
    • Journal of Surface Science and Engineering
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    • v.41 no.6
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    • pp.255-263
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    • 2008
  • Generally, deposition mechanism of diamond particle is mainly embedding effect in the kinetic spray process. Accordingly, in spite of high cost, helium gas was employed as process gas to get high diamond fraction in the composite coating. In this study, the deposition behavior of bronze/diamond by kinetic spray process was compared using different process gas (helium and nitrogen). Bare (mean size of $5{\mu}m$, $20{\mu}m$) and nickel coated diamond (mean size of $26{\mu}m$) were deposited on Al 6061-T6 substrate with fixed process temperature and pressure. For comparison with experimental results, plastic deformation behavior of nickel layer was simulated by finite element analysis (using ABAQUS/Explicit 6.7-2). The size, broken ratio, and fraction of diamond in the composite coating were analyzed through scanning electron microscopy and image analysis method. The uniform distribution and deposition efficiency of diamond particles in the coating layer could be achieved by tailoring the physical properties of the feedstock.

Influence of the Thin Anode Geometry on the Performance of Molten Carbonate Fuel Cells (얇은 연료극 구조가 용융탄산염 연료전지 성능에 미치는 영향)

  • Seo, Dong-Ho;Park, Dong-Nyeok;Yoon, Sung-Pil;Han, Jong-Hee;Oh, In-Hwan
    • Journal of Hydrogen and New Energy
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    • v.22 no.5
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    • pp.599-608
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    • 2011
  • The Ni-Al anodes of the molten carbonate fuel cell (MCFC) with three different structures were successfully fabricated in order to reduce the thickness of the anode down to 0.3 mm; one was the non-supported anode made by a conventional tape casting method, and others were the supported anodes made by lamination or direct casting on the nickel screen. It was seen from the physical analyses and cell operation that the supported thin anodes made by direct casting showed good mechanical strength and cell performance because of a good contact between the anode materials and the support. The single cell using the above anode showed the cell voltage of 0.858 V at the current density of 150$mA/cm^2$ with the nitrogen cross-over of only 0.6% at the operation time of 1,000 h, which was similar to the performance of the conventional thick (0.7 mm) anode. The ability to utilize a thin configuration of anode should cut down the amount of nickel alloy and consequently reduce its manufacturing cost.

A Study on Pretreatment and Acid Leaching for Wet Recycling of Waste Industrial Ni-Cd Secondary Battery (산업용 니켈-카드뮴 폐 이차전지 습식 재활용을 위한 전처리 및 산 침출에 대한 연구)

  • Jung, Soo-Hoon;Kim, Dae-Weon;Park, Il-Jeong;Choi, Joong-Yup;Yang, Dae-Hoon;Choi, Hee-Lack
    • Resources Recycling
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    • v.26 no.5
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    • pp.67-76
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    • 2017
  • In order to efficiently recycle waste industrial nickel-cadmium batteries, anodic and cathodic materials were crushed by a cut mill and classified by sieves. We used wet magnetic separation method for eliminating iron components from the crushed powders. In addition, the acid leaching test for the obtained anode and cathode powders was carried out under various conditions by means of the wet process. At the optimum leaching conditions with 2.0 M $H_2SO_4$ at $90^{\circ}C$, 15 wt $H_2O_2$ and L/S=20 for 3 hours, the leaching efficiency of nickel and cadmium was 99%, respectively.

Cyclic fatigue, bending resistance, and surface roughness of ProTaper Gold and EdgeEvolve files in canals with single- and double-curvature

  • Khalil, Wafaa A.;Natto, Zuhair S.
    • Restorative Dentistry and Endodontics
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    • v.44 no.2
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    • pp.19.1-19.9
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    • 2019
  • Objectives: The purpose of this study was to evaluate the cyclic fatigue, bending resistance, and surface roughness of EdgeEvolve (EdgeEndo) and ProTaper Gold (Dentsply Tulsa Dental Specialties) nickel-titanium (NiTi) rotary files. Materials and Methods: The instruments (n = 15/each) were tested for cyclic fatigue in single- ($60^{\circ}$ curvature, 5-mm radius) and double-curved (coronal curvature $60^{\circ}$, 5-mm radius, and apical curvature of $30^{\circ}$ and 2-mm radius) artificial canals. The number of cycles to fracture was calculated. The bending resistance of both files were tested using a universal testing machine where the files were bent until reach $45^{\circ}$. Scanning electron microscopy and x-ray energy-dispersive spectrometric analysis were used for imaging the fractured segments, while the atomic force microscope was used to quantify the surface roughness average (Ra). Results: EdgeEvolve files exhibited higher cyclic fatigue resistance than ProTaper Gold files in single- and double-curved canals (p < 0.05) and both files were more resistant to cyclic fatigue in single-curved canals than double-curved canals (p < 0.05). EdgeEvolve files exhibited significantly more flexibility than did ProTaper Gold files (p < 0.05). Both files had approximately similar Ni and Ti contents (p > 0.05). EdgeEvolve files showed significantly lower Ra values than ProTaper Gold files (p < 0.05). Conclusions: Within the limitation of this study, EdgeEvolve files exhibited significantly higher cyclic fatigue resistance than ProTaper Gold files in both single- and double-curved canals.

Characteristics of methane reforming with carbon dioxide using transition metal catalyts (전이금속 촉매를 이용한 이산화탄소와 메탄의 개질 특성)

  • Jang, Hyun Tae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.2
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    • pp.644-650
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    • 2021
  • This study characterized the reforming of methane with carbon dioxide, which is a major cause of global warming. The methane decomposition reaction with carbon dioxide was carried out using transition metal catalysts. The reactivity of tin was lower than that of a transition metal, such as nickel and iron. Most of the decomposition reaction occurred in the solid state. The melting point of tin is 505.03 K. Tin reacts in a liquid phase at the reaction temperature and has the advantage of separating carbon produced by the decomposition of methane from the liquid tin catalyst. Therefore, deactivation due to the deposition of carbon in the liquid tin can be prevented. Methane decomposition with carbon dioxide produced carbon monoxide and hydrogen. Ni was used to promote the catalyst performance and enhance the activity of the catalyst and lifetime. In this study, catalysts were synthesized using the excess wet impregnation method. The effect of the reaction temperature, space velocity was measured to calculate the activity of catalysts, such as the activation energy and regeneration of catalysts. The carbon-deposited tin catalyst regeneration temperature was 1023 K. The reactivity was improved using a nickel co-catalyst and a water supply.

Effect of Shearing Speed on High Speed Shear Properties of Sn1.0Ag0.5Cu Solder Bump on Various UBM's (다양한 UBM층상의 Sn0Ag0.5Cu 솔더 범프의 고속 전단특성에 미치는 전단속도의 영향)

  • Lee, Wang-Gu;Jung, Jae Pil
    • Korean Journal of Metals and Materials
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    • v.49 no.3
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    • pp.237-242
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    • 2011
  • The effect of shearing speed on the shear force and energy of Sn-0Ag-0.5Cu solder ball was investigated. Various UBM (under bump metallurgy)'s on Cu pads were used such as ENEPIG (Electroless Nickel, Electroless Palladium, Immersion Gold; Ni/Pd/Au), ENIG (Electroless Nickel, Immersion Gold; Ni/Au), OSP (Organic Solderability Preservative). To fabricate a shear test specimen, a solder ball, $300{\mu}m$ in diameter, was soldered on a pad of FR4 PCB (printed circuit board) by a reflow soldering machine at $245^{\circ}C$. The solder bump on the PCB was shear tested by changing the shearing speed from 0.01 m/s to 3.0 m/s. As experimental results, the shear force increased with a shearing speed of up to 0.6 m/s for the ENIG and the OSP pads, and up to 0 m/s for the ENEPIG pad. The shear energy increased with a shearing speed up to 0.3 m/s for the ENIG and the OSP pads, and up to 0.6 m/s for the ENEPIG pad. With a high shear speed of over 0 m/s, the ENEPIG showed a higher shear force and energy than those of the ENIG and OSP. The fracture surfaces of the shear tested specimens were analyzed, and the fracture modes were found to have closer relationship with the shear energy than the shear force.