• 한국세라믹학회지
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• 제39권8호
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• pp.769-774
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• 2002

금속 산화물 상태으 혼합분말을 수소 환원하여 $Al_2O_3$ 분말 표면에 20 nm 크기의 Fe-Ni 합금이 균일하게 분산된 복합분말을 합성하였다. 상압소결을 이용하여 제조한 $Al_2O_3$/Fe-Ni 나노복합재료는 전 소결 온도 범위에서 단지 $Al_2O_3$와 ${gamma}$-Fe-Ni 상만으로 구성되어 있었고, $1350^{\circ}C$ 이상의 소결 온도에서 98% 이상의 치밀화를 이루었다. 최대 파괴강도와 파괴인성은 각각 574 MPa과 3.9 MP$a{\cdot}m1/2$로서 동일한 소결 조건의 순수 $Al_2O_3$ 보다 약 20% 증가하였다. 나노복합재료는 강자성 거동을 보였으며 분산상의 평균 입자 크기가 감소함에 따라 증가된 보자력 값을 나타내었다.

• 한국표면공학회지
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• 제50권3호
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• pp.212-218
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• 2017

$Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrite powders were prepared by self-propagating high temperature synthesis followed by classifying with an ultrasonic wet-magnetic separation unit to get high pure nano-sized particles. The $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrites were well formed by using several powders like iron, nickel oxide, zinc oxide and magnesium oxide at 0.1 MPa of oxygen pressure. The ultrasonic wet-magnetic separation of pre-mechanical milled ferrite powders resulted in producing the powders with average size of 800 nm. The addition of a surfactant during the wet-magnetic separation process improved productivity more than twice. The coercive force, maximum magnetization and residual magnetization of the $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ nano-powders with 800 nm size were 3651 A/m, $53.92Am^2/kg$ and $4.0Am^2/kg$, respectively.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.201.2-201.2
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• 2016

$Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrite powders were prepared by self-propagating high temperature synthesis followed by classified by ultrasonic wet-magnetic separation method to get nano-sized particles with high purity. The $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrites were well formed by using several powders like iron, nickel oxide, zinc oxide and magnesium oxide at 0.1 MPa of oxygen pressure. The ultrasonic wet-magnetic separation of pre-mechanical milled ferrite powders produced the powders with average size of $3.7-0.8{\mu}m$. The addition of a surfactant during the separation process improved productivity more than twice. The coercive force, maximum magnetization and residual magnetization of the $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ nano-powders with 810 nm size were 45.89 Oe, 53.92 emu/gOe, 0.4 emu/Oe, respectively.

• 한국수소및신에너지학회논문집
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• 제9권2호
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• pp.65-75
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• 1998

실용적인 Fe-Ti계 수소저장합금전극을 제조하기위한 적절한 공정을 확립하기위하여 다섯가지의 서로다른 제조공정을 선택하여 조사하여 보았다. 전극제조를 위해 먼저 FeTi 합금을 플라즈마 아크 용해로에서 용해제조한 후 분쇄하여 분말을 만들고 이를 성형하였다. 성형전에 합금분말을 Ni무전해도금하여 본 결과 Fe-Ti 합금의 방전특성이 개선되었으며 열처리효과에 대하여도 검토하여 보았다. 성형전 합금분말을 열처리하는 경우 열처리 온도가 증가함에 따라 전극의 방전용량이 증가함을 확인하였으며 특히 성형후 $100^{\circ}C$의 온도에서 열처리하는 경우 가장 좋은 결과를 얻을 수 있었다. 이들 결과로 부터, Ni무전해도금과 열처리가 Fe-Ti 계 전극의 방전성능을 향상시키는데 결정적인 역할을 함을 알 수 있었다. 또한, 본 연구에서 제안된 공정에 따라서 Mn을 첨가하여 Fe-Ti-Mn 전극을 제조하고 그 성능을 조사하여 본 결과 대단히 바람직한 결과를 얻었다.

• Composites Research
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• 제21권5호
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• pp.9-14
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• 2008

유전성 손실재료로 CNFs가 사용되었고, 강자성의 submicron 크리 NiFe 분말을 자성 손실재료로 사용하였다. 획득한 손실재료의 함량과 혼합비에 따라 세 가지(dielectric, magnetic. mixed RAMs)의 타입으로 분류되고, 전체 12 종류의 복합재료를 제작하였다. 이들의 복소 유전율 및 투자율을 $2{\sim}18$ GHz 범위에서 측정하였다. 측정된 전자기적 물성과 다층형 매질에서의 투과 빛 반사와 관련된 이론을 사용하여 단층형 흡수체를 설계를 위한 매개변수 연구를 수행하였다. 혼합형 타입의 하나인 MD3 복합재료는 2.00 mm의 투께로 X-band ($8.2{\sim}12.4$ GHz)에서 약 4.0 GHz의 10 dB 흡수 대역폭을 나타내었고, 1.49mm의 두께로 Ku-band ($12.0{\sim}l8.0$ GHz)에서 약 6.0 GHz의 10 dB 흡수 대역폭을 나타내었다. 몇 종류의 복합재료에 대판 성능평가 실험이 수행되었고, 전반적인 흡수성능 경향과 10 dB 흡수 대역폭에서 예측 결과와 일치하였다.

• 한국수소및신에너지학회논문집
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• 제34권5호
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• pp.421-430
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• 2023

Fe-Ni-Pt nanocatalysts were loaded on carbon black powders which were synthesized by a spontaneous reduction reaction of iron (II) acetylacetonate, nickel (II) acetylacetonate and platinum (II) acetylacetonate. The morphology and the loading weight of Fe-Ni-Pt nanoparticles were characterized by transmission electron microscopy and thermogravimetric analyzer. The amount of Fe-Ni-Pt catalyst supported on the carbon black surface was about 6.42-9.28 wt%, and the higher the Fe content and the lower the Pt content, the higher the total amount of the metal catalyst supported. The Brunauer-Emmett-Teller Analysis (BET) specific surface area of carbon black itself without metal nanoparticles supported was 233.9 m²/g, and when metal nanoparticles were introduced, the specific surface area value was greatly reduced. This is because the metal nanocatalyst particles block the pore entrance of the carbon black, and thereby the catalytic activity of the metal catalysts generated inside the pores is reduced. From the I-V curves, as the content of the Pt nanocatalyst increased, the electrolytic properties of water increased, and the activity of the metal nanocatalyst was in the order of Pt > Ni > Fe.

• 한국수소및신에너지학회논문집
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• 제14권1호
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• pp.24-34
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• 2003

For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion may yield great advantages for the savings of energy to $CO_2$ separation and suppressing the effect on environment, In chemical-looping combustor, fuel is oxidized by metal oxide medium in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. In this study, five oxygen carrier particles such as NiO/bentonite, NiO/YSZ, $(NiO+Fe_2O_3)VYSZ$, $NiO/NiAl_2O_4$, and $Co_{\chi}O_y/CoAl_2O_4$ were examined &om the viewpoints of reaction kinetics, oxygen transfer capacity, and carbon deposition characteristics. Among five oxygen particles, NiO/YSZ particle is superior in reaction rate, oxygen carrier capacity, and carbon deposition to other particles. However, at high temperature ($>900^{\circ}C$), NiO/bentonite particle also shows enough reactivity and oxygen carrier capacity to be applied in a practical system.

• 한국세라믹학회지
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• 제44권11호
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• pp.639-644
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• 2007

Spinel pigments, developing black color in high temperature glazes at oxidation or reduction atmosphere, without CoO because of its high price were synthesized by solid solution method. Ten mixed compositions consisted of NiO, MnO, $Fe_2O_3 and $Mn_2O_3$ were fired at $1250^{\circ}C$ for 1h. The resulting pigments were characterized by using XRD, FT-IR, SEM and UV-vis spectrometer. Structure of the pigments are spinel and particles' shape are spherical or cubic. Glazed tiles containing 5 wt% pigments were fired at $1260^{\circ}C$ and $1240^{\circ}C$ in reduction atmosphere. Color in glazes were analyzed by UV-vis spectrometer. Colors of NiO 0.875 MnO $0.125{\cdot}Fe_2O_3$ $0.4875{\cdot}Cr_2O_3$ $0.50{\cdot}Mn_2O_3$ 0.0125 mole% and NiO 0.875 MnO $0.125{\cdot}Fe_2O_3$ $0.3875{\cdot}Cr_2O_3$ $0.50{\cdot}Mn_2O_3$ 0.1125 mole% in lime glaze showed black in oxidation, in reduction NiO 0.875 MnO $0.125{\cdot}Fe_2O_3$ $0.4875{\cdot}Cr_2O_3$ $0.50{\cdot}Mn_2O_3$ 0.0125 mole% and NiO 0.875 MnO $0.125{\cdot}Fe_2O_3$ $0.4375{\cdot}Cr_2O_3$ $0.55{\cdot}Mn_2O_3$ 0.0125 mole% showed black. In case of lime-barium glaze, NiO 0.875 MnO $0.125{\cdot}Fe_2O_3$ $0.3875{\cdot}Cr_2O_3$ $0.50{\cdot}Mn_2O_3$ 0.1125 mole%, NiO 0.975 MnO $0.075{\cdot}Fe_2O_3$ $0.4375{\cdot}Cr_2O_3$ $0.50{\cdot}Mn_2O_3$ 0.0625 mole% and NiO 0.925 MnO $0.075{\cdot}Fe_2O_3$ $0.4375{\cdot}Cr_2O_3$ $0.50{\cdot}Mn_2O_3$ 0.0625 mole% showed black color in oxidation and NiO 0.875 MnO $0.125{\cdot}Fe_2O_3$ $0.3875{\cdot}Cr_2O_3$ $0.50{\cdot}Mn_2O_3$ 0.1125 mole%, NiO 0.925 MnO $0.075{\cdot}Fe_2O_3$ $0.4375{\cdot}Cr_2O_3$ $0.50{\cdot}Mn_2O_3$ 0.0625 mole% and NiO 0.725 MnO $0.275{\cdot}Fe_2O_3$ $0.4375{\cdot}Cr_2O_3$ $0.50{\cdot}Mn_2O_3$ 0.0625 mole% showed black one in reduction.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 1991년도 춘계연구발표회 논문개요집
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• pp.73-74
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• 1991

The films with ferromagnetic fine particles dispersed in nonmagnetic matrix, such as $Fe-Al_2O_3$ and Fe-Cu have been studied for use of magnetic recording medium, optically device and sensor. Their magnetic properties depend strongly on structural parameter such as size and volume fraction of ferromagnetic particles. Fe-Cr-Ni alloy sputtered films also have microstructure with ferromagnetic -- b.c.c phase and nonmagnetic f.c.c phase grains. Magnetic properties of these films depend strongly on such a unique structure. These are depend on the ratio in volume of ferromagnetic particles to nonmagnetic ones $V_F/V_N$, the saturation magnetization Ms increased with increase of $V_F/V_N$. The coercivity Hc of the as-deposited films took maximum value of about 200 Oe at adequate $V_F/V_N$ and then Ms and Squareness S were 500 emu/cc and 0.5, respectively.(omitted)

• 한국환경과학회지
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• 제15권12호
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• pp.1171-1175
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• 2006

Deposited road particles (DRPs) were analysed for heavy metal concentrations at four different roads in a city, Korea. The samples were collected using a roadway surface vacuum cleaning vehicle which was commonly used in collecting roadway surface particles. Six particle size ranges were analyzed separately for twelve heavy metal elements (Cd, Cr, Pb, Ni, Al, As, Co, Cu, Fe, Mn, Zn and Hg). At all sampling sites, the high concentration of the heavy metals occurred in the <74um particle size range, which conventional roadway cleaning vehicles do not remove efficiently. The Pb concentration significantly increased with decreasing particle size of DRPs, and other toxic heavy metals (Cd, Cr and Ni) also showed similar results. The heavy metal concentrations in the smaller size fraction of DRPs is important because they are contaminants that are preferentially transported by road runoff during rainfall.