• Title/Summary/Keyword: Ni-solution

Search Result 1,041, Processing Time 0.026 seconds

Spin Spray-Deposited Spinel Thin Films for Microbolometer Applications (마이크로볼로미터 응용을 위한 스핀 스프레이로 증착된 스피넬 박막)

  • Jeon, Chang Jun;Lee, Kui Woong;Le, Duc Thang;Jeong, Young Hun;Yun, Ji Sun;Paik, Jong Hoo;Cho, Jeong Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.27 no.12
    • /
    • pp.809-814
    • /
    • 2014
  • Spinel thin films were prepared by the spin spray technique to develop new thermal imaging materials annealed at low temperature for uncooled microbolometer applications. The spinel thin films were deposited from $[(Ni_{0.30}Co_{0.33}Mn_{0.37})_{1-x}Cu_x]_3O_4$ ($0.1{\leq}x{\leq}0.2$) solutions and then annealed at $400^{\circ}C$ for 1 h in argon. Effects of Cu content (x) and deposition time on the electrical properties of the annealed films were investigated. With increasing deposition time, the resistivity of the annealed films increased. For the annealed films deposited for 1 min, the resistivity of x=0.15 films was lower than that of x=0.1 films due to the different grain sizes. The high temperature coefficient of resistance (TCR) of the annealed films could be obtained at temperature below $50^{\circ}C$. Typically, the resistivity of $127{\Omega}{\cdot}cm$ and TCR of -5.69%/K at $30^{\circ}C$ were obtained for x=0.1 films with deposition time of 1 min annealed at $400^{\circ}C$ for 1 h in argon.

Thermoelectric/electrical characterization of electrodeposited BixTey thin films (전기도금법에 의해 전착된 BixTey 박막의 전기 및 열전 특성)

  • Yu, In-Jun;Lee, Gyu-Hwan;Kim, Yang-Do;Im, Jae-Hong
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2012.05a
    • /
    • pp.308-308
    • /
    • 2012
  • Electrodeposition of thermoelectric materials, including binary and ternary compounds, have been attracting attentions, because its many advantages including cost-effectiveness, rapid deposition rate, and ease of control their microstructure and crystallinity by adjusting electrodeposition parameters. In this work, $Bi_xTe_y$ films were potentiostatically electrodeposited using Au/Ni(80/20 nm)/Si substrate as the working electrode in solutions consisting of 10mM $TeO_2$ and 1M $HNO_3$ where $Bi(NO_3)_3$ was varied from 2.5 to 10 mM. Prior to electrodeposition potentiostatically, linear sweep voltammograms (LSV) were acquired with a standard three-electrode cell. The $Bi_xTe_y$ films deposited using the electrolyte containing low Bi ions shows p-type conductivity, which might be attributed by the large incorporation of Te phases. Near stoichiometric $Bi_2Te_3$ thin films were obtained from electrolytes containing 5mM $Bi(NO_3)_3$. This film shows the maximum Seebeck coefficient of $-100.3{\pm}12.7{\mu}V/K$. As the increase of Bi ions in electrolytes decreases the Seebeck coefficient and resistivity. The maximum power factor of $336.2{\mu}W/m{\cdot}K^2$ was obtained from the film deposited using the solution of 7.5mM $Bi(NO_3)_3$.

  • PDF

Study on Separation of Heavy Metal Ions in A Neutral Macrocycle-Mediated Emulsion Liquid Membrane System

  • Moon-Hwan Cho;Hea-Suk Chun;Jin-Ho Kim;Chang-Hwan Rhee;Si-Joong Kim
    • Bulletin of the Korean Chemical Society
    • /
    • v.12 no.5
    • /
    • pp.474-477
    • /
    • 1991
  • The preferential transport phenomena of neutral cation-anion moieties in neutral macrocycle-facilitated emulsion liquid membrane were described in this study. Emulsion membrane systems consisting of (1) aqueous source phase containing 0.001 M M($NO_3$)$_2(M=Mn^{2+},\;Co^{2+},\;Ni^{2+},\;Cu^{2+},\;Zn^{2+},\;Sr^{2+},\;Cd^{2+},\;and\;Pb^{2+})$ (2) a toluene membrane containing 0.01 M ligand $(DBN_3O_2$, DA18C6, DT18C6, TT18C6, HT18C6) and the surfactant span 80 (sorbitan monooleate) (3% v/v) and (3) an aqueous receiving phase containing $Na_2S_2O_3$ or $NaNO_3$ were studied with respect to the disappearence of transition metal ions from the source phase as a function of time. Cation transports for various two component or three component equimolar mixture of transition metal and $Cu^{2+}$ in a emulsion membrane system incorporating macrocyclic ligand (HT18C6) as carrier were determinded. $Cu^{2+}$ was transported higher rates than the other $M^{2+}$ in the mixture solution. Equilibrium constants for cation-source phase co-anion, cation macrocycle and cation-receiving phase reagent interaction are examined as parameters for the prediction of cation transport selectivities.

Stochastic micro-vibration response characteristics of a sandwich plate with MR visco-elastomer core and mass

  • Ying, Z.G.;Ni, Y.Q.;Duan, Y.F.
    • Smart Structures and Systems
    • /
    • v.16 no.1
    • /
    • pp.141-162
    • /
    • 2015
  • The magneto-rheological visco-elastomer (MRVE) is used as a smart core to control the stochastic micro-vibration of a sandwich plate with supported mass. The micro-vibration response of the sandwich plate with MRVE core and supported mass under stochastic support motion excitations is studied and compared to evaluate the vibration suppression capability. The effects of the supported mass and localized magnetic field on the stochastic micro-vibration response of the MRVE sandwich plate are taken into account. The dynamic characteristics of the MRVE core in micro-vibration are described by a non-homogeneous complex modulus dependent on vibration frequency and controllable by applied magnetic fields. The partial differential equations for the coupled transverse and longitudinal motions of the MRVE sandwich plate with supported mass are derived from the dynamic equilibrium, constitutive and geometric relations. The simplified ordinary differential equations are obtained for the transverse vibration of the MRVE sandwich plate under localized magnetic fields. A frequency-domain solution method for the stochastic micro-vibration response of sandwich plates with supported mass is developed based on the Galerkin method and random vibration theory. The expressions of frequency-response functions, response power spectral densities and root-mean-square velocity responses of the plate in terms of the one-third octave frequency band are obtained for micro-vibration evaluation. Finally, numerical results are given to illustrate the large response reduction capacity of the MRVE sandwich plate with supported mass under stochastic support motion excitations, and the influences of MRVE parameters, supported mass and localized magnetic field placement on the micro-vibration response.

Sorption of Heavy Metals from the Wastewater by the Artificial Zeolite (인공 제올라이트에 의한 폐수중 중금속 흡착)

  • Lee, Deog-Bae;Lee, Kyeong-Bo;Lee, Sang-Bok;Han, Sang-Soo;Henmi, Teruo
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.31 no.1
    • /
    • pp.61-66
    • /
    • 1998
  • An artificial zeolite was synthesized from bituminous coal fly ash by thermo-alkali treatment, $100{\pm}3^{\circ}C$ and 3.5 N NaOH solution for 24 hours, to develope new useful material in waste water treatment system. The artificial zeolite had much higher cation exchange capacity, $299cmol^+\;kg^{-1}$ and lower concentration of extractable heavy metals than bituminous coal fly ash. The higher the temperature and the longer the shaking time, the more Zn, Cu, Cd and Pb were sorbed chemically by the artificial zeolite. Shaking artificial zeolite and wastewater at $35^{\circ}C$ for 9 hours, the amount of sorbed heavy metals were $123.5g\;kg^{-1}$ for Zn, $164.7g\;kg^{-1}$ for Cu, $184.4g\;kg^{-1}$ for Cd and $350.6g\;kg^{-1}$ for Pb, respectively.

  • PDF

Design formulas for vibration control of sagged cables using passive MR dampers

  • Duan, Yuanfeng;Ni, Yi-Qing;Zhang, Hongmei;Spencer, Billie F. Jr.;Ko, Jan-Ming;Dong, Shenghao
    • Smart Structures and Systems
    • /
    • v.23 no.6
    • /
    • pp.537-551
    • /
    • 2019
  • In this paper, a method for analyzing the damping performance of stay cables incorporating magnetorheological (MR) dampers in the passive control mode is developed taking into account the cable sag and inclination, the damper coefficient, stiffness and mass, and the stiffness of damper support. Both numerical and asymptotic solutions are obtained from complex modal analysis. With the asymptotic solution, analytical formulas that evaluate the equivalent damping ratio of the sagged cable-damper system in consideration of all the above parameters are derived. The main thrust of the present study is to develop an general design formula and a universal curve for the optimal design of MR dampers for adjustable passive control of sagged cables. Two sag-affecting coefficients are derived to reflect the effects of cable sag on the maximum attainable damping ratio and the optimal damper coefficient. For the cable configurations commonly used in cable-stayed bridges, the sag-affecting coefficients are directly expressed in terms of the sag-extensibility parameter to facilitate the control design. A case study on adjustable passive vibration control of the longest cable (536 m) on Stonecutters Bridge is carried out to demonstrate the influence of the sag for the damper design, and to figure out the necessity of adjustability of damper coefficients for achieving maximum damping ratio for different vibration modes.

Corrosion resistance at high temperature condition of Cr Films Formed on hot-dip Al-Si plated steel sheet (용융Al-Si도금 강재에 형성한 Cr 막의 고온 환경 중 내식특성)

  • Gang, Min-Ju;Lee, Seung-Hyo;Lee, Myeong-Hoon
    • Journal of the Korean institute of surface engineering
    • /
    • v.55 no.6
    • /
    • pp.448-459
    • /
    • 2022
  • Generally, steel is the most commonly used in the industry because of good strength, processability and cost-effectiveness. Steel can be surface-treated such as coating or used as an alloy by adding elements such as Cr, Ni, Zr, and Al to increase corrosion resistance. However, even if steel is used in same environment corrosion resistance is sharply lowered when it is exposed to a high temperature for a fixed or extended period of time due to an overload or other factors. In particular, the use of hot-dip aluminized plated steel, which is used in high-temperature atmospheres, is increasing due to the surface Al2O3 oxide film. This steel necessitates an urgent solution as issues of corrosion resistance limitations often appear. It is an important issue that not only cause analysis but also the research for the surface treatment method that can be solved. Thus, in this study, Cr in which it is expected to be effective in corrosion resistance and heat resistance attempted to deposit on hot dip aluminized plated steel with PVD sputtering. And it was possible to present the surface treatment application of various types of industrial equipment exposed to high temperature and basic design guidelines for use by confirming the corrosion resistance of hot dip Al-Si plated steel with Cr film deposited at high temperature.

Efficiency of Median Modified Wiener Filter Algorithm for Noise Reduction in PET/MR Images: A Phantom Study (PET/MR 영상에서의 팬텀을 활용한 노이즈 감소를 위한 변형된 중간값 위너필터의 적용 효율성 연구)

  • Cho, Young Hyun;Lee, Se Jeong;Lee, Youngjin;Park, Chan Rok
    • Journal of radiological science and technology
    • /
    • v.44 no.3
    • /
    • pp.225-229
    • /
    • 2021
  • The digital image such as medical X-ray and nuclear medicine field mainly contains noise distribution. The noise degree in image degrades image quality. That is why, the noise reduction algorithm is efficient for medical image field. In this study, we confirmed effectiveness of application for median modified Wiener filter (MMWF) algorithm for noise reduction in PET/MR image compared with median filter image, which is used as conventional noise redcution algorithm. The Jaszczak PET phantom was used by using 18F solution and filled with NaCl+NiSO4 fluids. In addition, the radioactivity ratio between background and six spheres in the phantom is maintained to 1:8. In order to mimic noise distribution in the image, we applied Gaussian noise using MATLAB software. To evlauate image quality, the contrast to noise ratio (CNR) and coefficient of variation (COV) were used. According to the results, compared with noise image and images with MMWF algorithm, the image with MMWF algorithm is increased approximately 33.2% for CNR result, decreased approximately 79.3% for COV result. In conclusion, we proved usefulness of MMWF algorithm in the PET/MR images.

A Study on the Characteristics of Shaft Electric Motive Force of Controllable Pitch Propeller - Focusing on the M/V Segero - (가변피치 프로펠러의 축기전력 특성에 관한 연구 - 세계로호를 중심으로 -)

  • Park, Kyung-Min;Im, Myeong-Hwan;Choe, Sang-Bom;Ahn, Byong-Won
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.28 no.1
    • /
    • pp.135-140
    • /
    • 2022
  • Most machines are made of several types of . In particular, the shaft system of the ship consists of the brass of the propeller blade and the stainless steel of the shaft. When dissimilar the electrolyte solution of seawater, a voltaic cell and a shaft electromotive force is generated. This electromotive force causes electrical corrosion of the bearing and shaft supporting the shaft system. prevent this corrosion, a shaft grounding system is installed in ships. As for the experimental method, various information acquired by designing a program to periodically measure the electromotive force of the controllable pitchpropeller) system using an A/D converter of NI. This study analyzed the generation and characteristics of accumulator electromotive force for CPP and considered the installation location of the grounding system to remove the accumulator electromotive force.

Development of Optimal Stage Calculation Program for the Design of Waste Etchant Recovering Process (폐식각액 재생공정 설계를 위한 최적단수계산 프로그램 개발)

  • So, Won-Shoup;Park, Jin-Soo;Jung, Jae-Hak;Sur, Gil-Soo
    • Clean Technology
    • /
    • v.15 no.3
    • /
    • pp.165-171
    • /
    • 2009
  • In this study, we found out the relation between $FeCl_3$ recovering-concentration and stage number of extraction process for invar (Fe+Ni) etching process. In order to get the desired $FeCl_3$ recovering-concentration economically, we developed the simulation program for designing the optimal $FeCl_3$ extraction process. We got the key parameter for this simulation program through pilot scale experiments. The process simulation by the developed program could reduce the emission of waste etching solution as well as the treatment costs. In addition, the developed program could calculate the number of stage of the etchant recovering system and the process time to get the desired concentration of $FeCl_3$. This program was used to compute the optimal capacity of the etchant recovering system and applied to the optimization of the stage of the etchant recovering system in real IT industry.